| Common Name: | 1,3-BUTADIENE |
| Manufacturer: | AIRGAS |
| SDS Revision Date: | 2/1/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 20MK25 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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AIRGAS(R*)
AN AIR LIQUIDE COMPANY
SAFETY DATA SHEET
1,3-BUTADIENE
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: 1,3-BUTADIENE
CHEMICAL NAME: 1,3-BUTADIENE
OTHER MEANS OF IDENTIFICATION:
(ALPHA), (GAMMA)-BUTADIENE; TRANS-BUTADIENE; BIETHYLENE; BIVINYL;
BUTA-1,3-DIENE; BUTADIENE; DIVINYL; ERYTHRENE; PYRROLYLENE; VINYLETHYLENE;
(E)-CH2=CHCH=CH2; BUTADIEEN; BUTA1,3- DIEEN; BUTADIEN; BUTA-1,3-DIEN;
NCI-C50602
PRODUCT TYPE: LIQUEFIED GAS
PRODUCT USE: SYNTHETIC/ANALYTICAL CHEMISTRY.
SYNONYM:
(ALPHA), (GAMMA)-BUTADIENE; TRANS-BUTADIENE; BIETHYLENE; BIVINYL;
BUTA-1,3-DIENE; BUTADIENE; DIVINYL; ERYTHRENE; PYRROLYLENE; VINYLETHYLENE;
(E)-CH2=CHCH=CH2; BUTADIEEN; BUTA1,3- DIEEN; BUTADIEN; BUTA-1,3-DIEN;
NCI-C50602
SDS #: 001008
SUPPLIER'S DETAILS:
AIRGAS USA, LLC AND ITS AFFILIATES
259 NORTH RADNOR-CHESTER ROAD
SUITE 100
RADNOR, PA 19087-5283
1-610-687-5253
24-HOUR TELEPHONE: 1-866-734-3438
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE GASES - CATEGORY 1
GASES UNDER PRESSURE - LIQUEFIED GAS
ACUTE TOXICITY (INHALATION) - CATEGORY 4
GERM CELL MUTAGENICITY - CATEGORY 1B
CARCINOGENICITY - CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE GAS.
MAY FORM EXPLOSIVE MIXTURES WITH AIR.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
MAY CAUSE FROSTBITE.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
HARMFUL IF INHALED.
MAY CAUSE GENETIC DEFECTS.
MAY CAUSE CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ AND FOLLOW ALL SAFETY DATA SHEETS (SDS'S) BEFORE USE. READ LABEL
BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS NEEDED,
HAVE PRODUCT CONTAINER OR LABEL AT HAND. CLOSE VALVE AFTER EACH USE AND
WHEN EMPTY. USE EQUIPMENT RATED FOR CYLINDER PRESSURE. DO NOT OPEN VALVE
UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE. USE A BACK FLOW
PREVENTATIVE DEVICE IN THE PIPING. USE ONLY EQUIPMENT OF COMPATIBLE
MATERIALS OF CONSTRUCTION. ALWAYS KEEP CONTAINER IN UPRIGHT POSITION.
APPROACH SUSPECTED LEAK AREA WITH CAUTION.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR EYE
OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. AVOID BREATHING GAS.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
LEAKING GAS FIRE:
DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY. ELIMINATE ALL
IGNITION SOURCES IF SAFE TO DO SO.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
LIQUID CAN CAUSE BURNS SIMILAR TO FROSTBITE.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: SUBSTANCE
CHEMICAL NAME: 1,3-BUTADIENE
OTHER MEANS OF IDENTIFICATION:
(ALPHA), (GAMMA)-BUTADIENE; TRANS-BUTADIENE; BIETHYLENE; BIVINYL;
BUTA-1,3-DIENE; BUTADIENE; DIVINYL; ERYTHRENE; PYRROLYLENE; VINYLETHYLENE;
(E)-CH2=CHCH=CH2; BUTADIEEN; BUTA1,3- DIEEN; BUTADIEN; BUTA-1,3-DIEN;
NCI-C50602
PRODUCT CODE: 001008
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: 106-99-0
INGREDIENT NAME % CAS NUMBER
1,3-BUTADIENE 100 106-99-0
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. TO AVOID THE RISK OF STATIC DISCHARGES AND GAS IGNITION, SOAK
CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION. IN CASE OF CONTACT
WITH LIQUID, WARM FROZEN TISSUES SLOWLY WITH LUKEWARM WATER AND GET MEDICAL
ATTENTION. DO NOT RUB AFFECTED AREA. WASH CLOTHING BEFORE REUSE. CLEAN
SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. GET MEDICAL ATTENTION. INGESTION OF LIQUID CAN CAUSE BURNS
SIMILAR TO FROSTBITE. IF FROSTBITE OCCURS, GET MEDICAL ATTENTION. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. AS
THIS PRODUCT RAPIDLY BECOMES A GAS WHEN RELEASED, REFER TO THE INHALATION
SECTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: LIQUID CAN CAUSE BURNS SIMILAR TO FROSTBITE.
INHALATION: HARMFUL IF INHALED.
SKIN CONTACT:
DERMAL CONTACT WITH RAPIDLY EVAPORATING LIQUID COULD RESULT IN FREEZING OF
THE TISSUES OR FROSTBITE.
FROSTBITE: TRY TO WARM UP THE FROZEN TISSUES AND SEEK MEDICAL ATTENTION.
INGESTION: INGESTION OF LIQUID CAN CAUSE BURNS SIMILAR TO FROSTBITE.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTAINS GAS UNDER PRESSURE. EXTREMELY FLAMMABLE GAS. IN A FIRE OR IF
HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH
THE RISK OF A SUBSEQUENT EXPLOSION. THE VAPOR/GAS IS HEAVIER THAN AIR AND
WILL SPREAD ALONG THE GROUND. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS
OR TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK,
CAUSING FIRE OR EXPLOSION.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. CONTACT SUPPLIER IMMEDIATELY
FOR SPECIALIST ADVICE. MOVE CONTAINERS FROM FIRE AREA IF THIS CAN BE DONE
WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. IF
INVOLVED IN FIRE, SHUT OFF FLOW IMMEDIATELY IF IT CAN BE DONE WITHOUT RISK.
IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA AND ALLOW FIRE TO BURN. FIGHT
FIRE FROM PROTECTED LOCATION OR MAXIMUM POSSIBLE DISTANCE. ELIMINATE ALL
IGNITION SOURCES IF SAFE TO DO SO.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE. FOR INCIDENTS INVOLVING LARGE QUANTITIES,
THERMALLY INSULATED UNDERGARMENTS AND THICK TEXTILE OR LEATHER GLOVES
SHOULD BE WORN.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
ACCIDENTAL RELEASES POSE A SERIOUS FIRE OR EXPLOSION HAZARD. NO ACTION
SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL
FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL
IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID
BREATHING GAS. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
ENSURE EMERGENCY PROCEDURES TO DEAL WITH ACCIDENTAL GAS RELEASES ARE IN
PLACE TO AVOID CONTAMINATION OF THE ENVIRONMENT. AVOID DISPERSAL OF SPILLED
MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
INFORM THE RELEVANT AUTHORITIES IF THE PRODUCT HAS CAUSED ENVIRONMENTAL
POLLUTION (SEWERS, WATERWAYS, SOIL OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
IMMEDIATELY CONTACT EMERGENCY PERSONNEL. STOP LEAK IF WITHOUT RISK. USE
SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
LARGE SPILL:
IMMEDIATELY CONTACT EMERGENCY PERSONNEL. STOP LEAK IF WITHOUT RISK. USE
SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). CONTAINS
GAS UNDER PRESSURE. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. AVOID
BREATHING GAS. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. DO NOT ENTER STORAGE AREAS AND
CONFINED SPACES UNLESS ADEQUATELY VENTILATED. DO NOT PUNCTURE OR INCINERATE
CONTAINER. USE EQUIPMENT RATED FOR CYLINDER PRESSURE. CLOSE VALVE AFTER
EACH USE AND WHEN EMPTY. PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT
DRAG, ROLL, SLIDE, OR DROP. USE A SUITABLE HAND TRUCK FOR CYLINDER
MOVEMENT. USE ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE AND CAN BE HAZARDOUS. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN
FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL
(VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. AVOID EXPOSURE -
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE AWAY FROM DIRECT SUNLIGHT IN A DRY, COOL AND
WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10).
ELIMINATE ALL IGNITION SOURCES. CYLINDERS SHOULD BE STORED UPRIGHT, WITH
VALVE PROTECTION CAP IN PLACE, AND FIRMLY SECURED TO PREVENT FALLING OR
BEING KNOCKED OVER. CYLINDER TEMPERATURES SHOULD NOT EXCEED 52 DEG. C (125
DEG. F). STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL
READY FOR USE. SEE SECTION 10 FOR INCOMPATIBLE MATERIALS BEFORE HANDLING
OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
1,3-BUTADIENE ACGIH TLV (UNITED STATES, 3/2017).
TWA: 4.4 MG/M3 8 HOURS.
TWA: 2 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
STEL: 5 PPM 15 MINUTES.
TWA: 1 PPM 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
STEL: 5 PPM 15 MINUTES.
TWA: 1 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE- SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. IF CONTACT WITH THE LIQUID IS
POSSIBLE, INSULATED GLOVES SUITABLE FOR LOW TEMPERATURES SHOULD BE WORN.
CONSIDERING THE PARAMETERS SPECIFIED BY THE GLOVE MANUFACTURER, CHECK
DURING USE THAT THE GLOVES ARE STILL RETAINING THEIR PROTECTIVE PROPERTIES.
IT SHOULD BE NOTED THAT THE TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY
BE DIFFERENT FOR DIFFERENT GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES,
CONSISTING OF SEVERAL SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT
BE ACCURATELY ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
THERMAL HAZARDS:
IF THERE IS A RISK OF CONTACT WITH THE LIQUID, ALL PROTECTIVE EQUIPMENT
WORN SHOULD BE SUITABLE FOR USE WITH EXTREMELY LOW TEMPERATURE MATERIALS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS. [COMPRESSED GAS.]
COLOR: COLORLESS.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: -108.9 DEG. C (-164 DEG. F)
BOILING POINT: -4.41 DEG. C (24.1 DEG. F)
CRITICAL TEMPERATURE: 151.85 DEG. C (305.3 DEG. F)
FLASH POINT:
CLOSED CUP: -85 DEG. C (-121 DEG. F)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS):
EXTREMELY FLAMMABLE IN THE PRESENCE OF THE FOLLOWING MATERIALS OR
CONDITIONS: OPEN FLAMES, SPARKS AND STATIC DISCHARGE AND OXIDIZING
MATERIALS.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 2%
UPPER: 12%
VAPOR PRESSURE: 21.35 (PSIG)
VAPOR DENSITY: 1.9 (AIR = 1)
SPECIFIC VOLUME (FT 3/LB): 7.1942
GAS DENSITY (LB/FT 3): 0.139 (20 DEG. C / 68 TO DEG. F)
RELATIVE DENSITY: NOT APPLICABLE.
SOLUBILITY: NOT AVAILABLE.
SOLUBILITY IN WATER: 0.74 G/L
PARTITION COEFFICIENT N-OCTANOL/WATER: 1.99
AUTO-IGNITION TEMPERATURE: 420 DEG. C (788 DEG. F)
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT APPLICABLE.
FLOW TIME (ISO 2431): NOT AVAILABLE.
MOLECULAR WEIGHT: 54.09 G/MOLE
AEROSOL PRODUCT:
HEAT OF COMBUSTION: -44212608 J/KG
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY:
THE PRODUCT MAY NOT BE STABLE UNDER CERTAIN CONDITIONS OF STORAGE OR USE.
SEE "POSSIBILITY OF HAZARDOUS REACTIONS" FOR FURTHER INFORMATION.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS REACTIONS OR INSTABILITY MAY OCCUR UNDER CERTAIN CONDITIONS OF
STORAGE OR USE.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW GAS TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS: OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
CONDITIONS OF INSTABILITY:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS POLYMERIZATION WILL
NOT OCCUR. UNSTABLE. (AT HIGH TEMPERATURE)
HAZARDOUS POLYMERIZATION:
HAZARDOUS POLYMERIZATION MAY OCCUR UNDER CERTAIN CONDITIONS OF STORAGE OR
USE.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
1,3-BUTADIENE LC50 INHALATION GAS. RAT 128000 PPM 4 HOURS
IRRITATION/CORROSION: NOT AVAILABLE.
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
1,3-BUTADIENE 1 KNOWN TO BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: LIQUID CAN CAUSE BURNS SIMILAR TO FROSTBITE.
INHALATION: HARMFUL IF INHALED.
SKIN CONTACT:
DERMAL CONTACT WITH RAPIDLY EVAPORATING LIQUID COULD RESULT IN FREEZING OF
THE TISSUES OR FROSTBITE.
INGESTION: INGESTION OF LIQUID CAN CAUSE BURNS SIMILAR TO FROSTBITE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: FROSTBITE
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY:
MAY CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE.
MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
1,3-BUTADIENE 1.99 10 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
EMPTY AIRGAS-OWNED PRESSURE VESSELS SHOULD BE RETURNED TO AIRGAS. WASTE
PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO IMDG IATA
UN NUMBER UN1010 UN1010 UN1010 UN1010 UN1010
UN PROPER BUTADIENES, BUTADIENES, BUTADIENES, BUTADIENES, BUTADIENES,
SHIPPING STABILIZED STABILIZED STABILIZED STABILIZED STABILIZED
NAME 1,3- OR
BUTADIENE) BUTADIENES
AND
HYDROCARBON
MIXTURE,
STABILIZED
WITH MORE
THAN 40%
BUTADIENES
TRANSPORT 2.1 2.1 2.1 2.1 2.1
HAZARD FLAMMABLE CLASS 2.1, CLASS 2.1, CLASS 2.1 - CLASS 2.1,
CLASS(ES) GAS, FLAMMABLE FLAMMABLE FLAMMABLE FLAMMABLE
SOLID, GASES GASES GASES GASES
CLASS/
DIVISION
2.1
PACKING
GROUP
ENVIRON- NO. NO. NO. NO. NO.
MENTAL
HAZARDS
"REFER TO CFR 49 (OR AUTHORITY HAVING JURISDICTION) TO DETERMINE THE
INFORMATION REQUIRED FOR SHIPMENT OF THE PRODUCT."
ADDITIONAL INFORMATION:
DOT CLASSIFICATION:
REPORTABLE QUANTITY:
10 LBS / 4.54 KG. PACKAGE SIZES SHIPPED IN QUANTITIES LESS THAN THE PRODUCT
REPORTABLE QUANTITY ARE NOT SUBJECT TO THE RQ (REPORTABLE QUANTITY)
TRANSPORTATION REQUIREMENTS.
TDG CLASSIFICATION:
PRODUCT CLASSIFIED AS PER THE FOLLOWING SECTIONS OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS: 2.13-2.17 (CLASS 2).
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.125
ERAP INDEX: 3000
PASSENGER CARRYING ROAD OR RAIL INDEX: FORBIDDEN
IATA:
QUANTITY LIMITATION:
PASSENGER AND CARGO AIRCRAFT: FORBIDDEN.
CARGO AIRCRAFT ONLY: 150 KG.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
CLEAN AIR ACT (CAA) 112 REGULATED FLAMMABLE SUBSTANCES: 1,3-BUTADIENE
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
REFER TO SECTION 2: HAZARDS IDENTIFICATION OF THIS SDS FOR CLASSIFICATION
OF SUBSTANCE.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
1,3-BUTADIENE 106-99-0 100
SUPPLIER NOTIFICATION:
1,3-BUTADIENE 106-99-0 100
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS: THIS MATERIAL IS LISTED.
NEW YORK: THIS MATERIAL IS NOT LISTED.
NEW JERSEY: THIS MATERIAL IS LISTED.
PENNSYLVANIA: THIS MATERIAL IS LISTED.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO 1,3-BUTADIENE, WHICH IS KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
INGREDIENT NAME NO SIGNIFICANT MAXIMUM ACCEPTABLE
RISK LEVEL DOSAGE LEVEL
1,3-BUTADIENE YES.
INTERNATIONAL REGULATIONS:
CHEMICAL WEAPON CONVENTION LIST SCHEDULES I, II & III CHEMICALS:
NOT LISTED.
MONTREAL PROTOCOL (ANNEXES A, B, C, E): NOT LISTED.
STOCKHOLM CONVENTION ON PERSISTENT ORGANIC POLLUTANTS: NOT LISTED.
ROTTERDAM CONVENTION ON PRIOR INFORMED CONSENT (PIC): NOT LISTED.
UNECE AARHUS PROTOCOL ON POPS AND HEAVY METALS: NOT LISTED.
INVENTORY LIST:
AUSTRALIA: THIS MATERIAL IS LISTED OR EXEMPTED.
CANADA: THIS MATERIAL IS LISTED OR EXEMPTED.
CHINA: THIS MATERIAL IS LISTED OR EXEMPTED.
EUROPE: THIS MATERIAL IS LISTED OR EXEMPTED.
JAPAN:
JAPAN INVENTORY (ENCS): THIS MATERIAL IS LISTED OR EXEMPTED.
JAPAN INVENTORY (ISHL): THIS MATERIAL IS LISTED OR EXEMPTED.
MALAYSIA: THIS MATERIAL IS LISTED OR EXEMPTED.
NEW ZEALAND: THIS MATERIAL IS LISTED OR EXEMPTED.
PHILIPPINES: THIS MATERIAL IS LISTED OR EXEMPTED.
REPUBLIC OF KOREA: THIS MATERIAL IS LISTED OR EXEMPTED.
TAIWAN: THIS MATERIAL IS LISTED OR EXEMPTED.
THAILAND: NOT DETERMINED.
TURKEY: THIS MATERIAL IS LISTED OR EXEMPTED.
UNITED STATES: THIS MATERIAL IS LISTED OR EXEMPTED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARDS 3
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON SDSS
OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER MAY
CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 4
INSTABILITY/REACTIVITY 2
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE GASES - CATEGORY 1 EXPERT JUDGMENT
GASES UNDER PRESSURE - LIQUEFIED GAS EXPERT JUDGMENT
ACUTE TOXICITY (INHALATION) - CATEGORY 4 EXPERT JUDGMENT
GERM CELL MUTAGENICITY - CATEGORY 1B EXPERT JUDGMENT
CARCINOGENICITY - CATEGORY 1 EXPERT JUDGMENT
HISTORY:
DATE OF PRINTING: 2/1/2018
DATE OF ISSUE/DATE OF REVISION: 2/1/2018
DATE OF PREVIOUS ISSUE: 1/31/2018
VERSION: 1.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.