| Common Name: | TOUGH GUY ORANGE PUMICE HAND CLEANER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 2/10/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20PV72 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
TOUGH GUY ORANGE PUMICE HAND CLEANER
VERSION: 1.1
REVISION DATE: 02/10/2015
MSDS NUMBER: 28583-00002
DATE OF LAST ISSUE: 11/05/2014
DATE OF FIRST ISSUE: 11/05/2014
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY ORANGE PUMICE HAND CLEANER
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: W.W. GRAINGER, INC.
ADDRESS:
100 N GRAINGER PARKWAY
LAKE FOREST, ILLINOIS 60045
TELEPHONE: 847-535-1000
EMERGENCY TELEPHONE: 800-983-4582
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: SKIN-CARE
RESTRICTIONS ON USE:
THIS IS A PERSONAL CARE OR COSMETIC PRODUCT THAT IS SAFE FOR CONSUMERS AND
OTHER USERS UNDER NORMAL AND REASONABLY FORESEEABLE USE. COSMETICS AND
CONSUMER PRODUCTS, SPECIFICALLY DEFINED BY REGULATIONS AROUND THE WORLD,
ARE EXEMPT FROM THE REQUIREMENT OF AN SDS FOR THE CONSUMER. WHILE THIS
MATERIAL IS NOT CONSIDERED HAZARDOUS, THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT FOR
INDUSTRIAL WORKPLACE CONDITIONS AS WELL AS UNUSUAL AND UNINTENDED EXPOSURES
SUCH AS LARGE SPILLS. THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR
EMPLOYEES AND OTHER USERS OF THIS PRODUCT. FOR SPECIFIC INTENDED-USE
GUIDANCE, PLEASE REFER TO THE INFORMATION PROVIDED ON THE PACKAGE OR
INSTRUCTION SHEET.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
GHS LABEL ELEMENT: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (%)
DISTILLATES (PETROLEUM), 64742-47-8 >=5 - <10
HYDROTREATED LIGHT
1-METHYL 4-(1-METHYLETHENYL) 5989-27-5 >=0.1 - <1
CYCLOHEXENE
| SECTION 4. FIRST AID MEASURES | |
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF SKIN CONTACT:
WASH WITH WATER AND SOAP AS A PRECAUTION.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AS A PRECAUTION.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
RINSE MOUTH THOROUGHLY WITH WATER.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: NONE KNOWN.
PROTECTION OF FIRST-AIDERS:
NO SPECIAL PRECAUTIONS ARE NECESSARY FOR FIRST AID RESPONDERS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
DRY CHEMICAL
CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT SPREADING OVER A WIDE AREA (E.G. BY CONTAINMENT OR OIL BARRIERS).
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER.
CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
SEE ENGINEERING MEASURES UNDER EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION.
LOCAL/TOTAL VENTILATION: USE ONLY WITH ADEQUATE VENTILATION.
ADVICE ON SAFE HANDLING:
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES: STRONG OXIDIZING AGENTS
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
DISTILLATES 64742-47-8 TWA (MIST) 5 MG/M3 OSHA Z-1
(PETROLEUM),
HYDROTREATED TWA (MIST) 5 MG/M3 NIOSH REL
LIGHT
ST (MIST) 10 MG/M3 NIOSH REL
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE 5989-27-5
ENGINEERING MEASURES:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
DUST FORMATION MAY BE RELEVANT IN THE PROCESSING OF THIS PRODUCT. IN
ADDITION TO SUBSTANCE-SPECIFIC OELS, GENERAL LIMITATIONS OF CONCENTRATIONS
OF PARTICULATES IN THE AIR AT WORKPLACES HAVE TO BE CONSIDERED IN WORKPLACE
RISK ASSESSMENT.
RELEVANT LIMITS INCLUDE:
OSHA PEL FOR PARTICULATES NOT OTHERWISE REGULATED OF 15 MG/M3 - TOTAL DUST,
5 MG/M3 - RESPIRABLE FRACTION; AND ACGIH TWA FOR PARTICLES (INSOLUBLE OR
POORLY SOLUBLE) NOT OTHERWISE SPECIFIED OF 3 MG/M3 - RESPIRABLE PARTICLES,
10 MG/M3 -INHALABLE PARTICLES.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND
USE NIOSH/MSHA APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCE WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
HAND PROTECTION:
REMARKS:
FOR PROLONGED OR REPEATED CONTACT USE PROTECTIVE GLOVES.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT: SAFETY GLASSES
SKIN AND BODY PROTECTION: SKIN SHOULD BE WASHED AFTER CONTACT.
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOR: GRAY, OPAQUE
ODOR: FRUITY
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 6 - 8
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
SOLIDIFICATION/SETTING POINT: 11.40 DEG. C
INITIAL BOILING POINT AND BOILING RANGE: 98.00 DEG. C
FLASH POINT: >100 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.0000 G/CM3
SOLUBILITY(IES):
WATER SOLUBILITY: SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED SELF-REACTIVE.
VISCOSITY:
VISCOSITY, KINEMATIC: 10,000 - 45,000 MM2/S (20 DEG. C)
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: CAN REACT WITH STRONG OXIDIZING AGENTS.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >5.3 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >3,160 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
RESULT: NO SKIN IRRITATION
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
ASSESSMENT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
SPECIES: RABBIT
RESULT: SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
TEST TYPE: MAXIMIZATION TEST (GPMT)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
TEST TYPE: LOCAL LYMPH NODE ASSAY (LLNA)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: MOUSE
RESULT: POSITIVE
ASSESSMENT: PROBABILITY OR EVIDENCE OF SKIN SENSITIZATION IN HUMANS
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE: CHROMOSOMAL ABERRATION
SPECIES: RAT
APPLICATION ROUTE: INTRAPERITONEAL INJECTION
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
GENOTOXICITY IN VITRO:
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE: TRANSGENIC RODENT SOMATIC CELL GENE MUTATION ASSAY
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 103 WEEKS
RESULT: NEGATIVE
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
EFFECTS ON FERTILITY:
TEST TYPE: ONE-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
STOT-SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT-REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPEATED DOSE TOXICITY:
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
SPECIES: RAT
NOAEL: >10.4 MG/L
APPLICATION ROUTE: INHALATION (VAPOR)
EXPOSURE TIME: 90 D
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
SPECIES: RAT
NOAEL: 600 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 13 W
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
TOXICITY TO FISH:
LL50 (DANIO RERIO (ZEBRA FISH)): >250 MG/L
EXPOSURE TIME: 96 H
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
METHOD: OECD TEST GUIDELINE 203
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EL50 (ACARTIA TONSA): >3,193 MG/L
EXPOSURE TIME: 48 H
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
TOXICITY TO ALGAE:
EL50 (SKELETONEMA COSTATUM (MARINE DIATOM)): >3,200 MG/L
EXPOSURE TIME: 72 H
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
NOELR (SKELETONEMA COSTATUM (MARINE DIATOM)): 993 MG/L
EXPOSURE TIME: 72 H
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOELR (CERIODAPHNIA DUBIA (WATER FLEA)): >70 MG/L
EXPOSURE TIME: 8 D
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
TOXICITY TO BACTERIA:
EC50: >100 MG/L
EXPOSURE TIME: 3 H
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 0.72 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 0.36 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
ERC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 150 MG/L
EXPOSURE TIME: 72 H
TEST SUBSTANCE: WATER ACCOMMODATED FRACTION
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
M-FACTOR (ACUTE AQUATIC TOXICITY): 1
PERSISTENCE AND DEGRADABILITY:
INGREDIENTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 82%
EXPOSURE TIME: 24 D
METHOD: OECD TEST GUIDELINE 301F
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 80%
EXPOSURE TIME: 28 D
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
BIOACCUMULATIVE POTENTIAL:
INGREDIENTS:
1-METHYL 4-(1-METHYLETHENYL) CYCLOHEXENE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 4.38
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATION:
UNRTDG: NOT REGULATED AS A DANGEROUS GOOD
IATA-DGR: NOT REGULATED AS A DANGEROUS GOOD
IMDG-CODE: NOT REGULATED AS A DANGEROUS GOOD
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR: NOT REGULATED AS A DANGEROUS GOOD
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A CERCLA RQ.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS: NO SARA HAZARDS
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
WATER 7732-18-5 70 - 90%
PUMICE 1332-09-8 5 - 10%
DISTILLATES (PETROLEUM), 64742-47-8 5 - 10%
HYDROTREATED LIGHT
NEW JERSEY RIGHT TO KNOW:
WATER 7732-18-5 70 - 90%
PUMICE 1332-09-8 5 - 10%
DISTILLATES (PETROLEUM), 64742-47-8 5 - 10%
HYDROTREATED LIGHT
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 0
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 0
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
FULL TEXT OF OTHER ABBREVIATIONS:
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
NIOSH REL / TWA:
TIME-WEIGHTED AVERAGE CONCENTRATION FOR UP TO A 10-HOUR WORKDAY DURING A
40-HOUR WORKWEEK
NIOSH REL / ST:
STEL - 15-MINUTE TWA EXPOSURE THAT SHOULD NOT BE EXCEEDED AT ANY TIME
DURING A WORKDAY
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 02/10/2015
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
US / Z8