| Common Name: | MAG 1 FICC 12/12OZ 147 |
| Manufacturer: | WARREN DISTRIBUTION |
| SDS Revision Date: | 4/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20RW73 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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WD
WARREN DISTRIBUTION
SINCE 1922
SAFETY DATA SHEET
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT NAME: MAG 1 FICC 12/12OZ #147
PRODUCT CODE: MG810147
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RECOMMENDED USE: FUEL ADDITIVE
RECOMMENDED RESTRICTIONS: NOT APPLICABLE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
WARREN DISTRIBUTION, INC.
727 S. 13TH STREET
OMAHA, NE 68102
INFORMATION PHONE:
+01 (800) 825-1235
+01 (402) 341-9397
E-MAIL: SDS@WD-WPP.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBER:
CHEMTREC: +1 (800) 424-9300
INTERNATIONAL: +01 (703) 527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN SENSITISATION: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 1B
CARCINOGENICITY: CATEGORY 1A
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (STOT) - REPEATED EXPOSURE:
CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE: CATEGORY 1
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC: CATEGORY 1
SKIN CORROSION/IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
FLAMMABLE LIQUID: CATEGORY 3
ACUTE TOXICITY - INHALATION DUST / MIST: CATEGORY 3
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (STOT) - SINGLE EXPOSURE:
CATEGORY 3
2.2. LABEL ELEMENTS:
GHS HAZARD SYMBOLS:
FLAME
HEALTH HAZARD
SKULLS AND CROSSBONES
EXCLAMATION MARK
ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H226: FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
H331: TOXIC IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H340: MAY CAUSE GENETIC DEFECTS.
H350: MAY CAUSE CANCER.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/.../ EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P264: WASH EXPOSED AREAS THOROUGHLY AFTER HANDLING.
P270: DO NO EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
RESPONSE:
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR/....
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER/SHOWER.
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (SEE SECTION 4).
P331: DO NOT INDUCE VOMITING.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378:
IN CASE OF FIRE: USE ... TO EXTINGUISH.
P391: COLLECT SPILLAGE.
STORAGE:
P233: KEEP CONTAINER TIGHTLY CLOSED.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. OTHER HAZARDS:
HAZARDS NOT OTHERWISE CLASSIFIED: NO DATA AVAILABLE.
UNKNOWN ACUTE TOXICITY (GHS-US):
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME % CAS # GHS CLASSIFICATION
DISTILLATES, PETROLEUM, 90 - 99 64741-44-2 AQUATIC CHRONIC 2; H411
STRAIGHT-RUN MIDDLE ASP. TOX. 1; H304
ACUTE TOX. 4; H332
ACUTE TOX. 2; H330
CARC. 2; H351
FLAM. LIQ. 3; H226
STOT RE 2; H373
STOT SE 3; H335, H336
KEROSENE 90 - 99 8008-20-6 AQUATIC CHRONIC 2; H411
ASP. TOX. 1; H304
FLAM. LIQ. 3; H226
SKIN IRRIT. 2; H315
STOT SE 3; H335, H336
DISTILLATES, PETROLEUM, 90 - 99 64742-80-9 AQUATIC CHRONIC 2; H411
HYDRODESULFURIZED ASP. TOX. 1; H304
MIDDLE ACUTE TOX. 4; H332
CARC. 1A; H350
SKIN IRRIT. 2; H315
STOT RE 2; H373
DISTILLATES, PETROLEUM, 90 - 99 68333-25-5 AQUATIC ACUTE 1; H400
HYDRODESULFURIZED AQUATIC CHRONIC 1; H410
LIGHT CATALYTIC ASP. TOX. 1; H304
CRACKED ACUTE TOX. 4; H332
CARC. 1A; H350
SKIN IRRIT. 2; H315
STOT RE 2; H373
KEROSINE, PETROLEUM, 10 - 30 64742-81-0 AQUATIC CHRONIC 2; H411
HYDRODESULFURIZED ASP. TOX. 1; H304
FLAM. LIQ. 3; H226
SKIN IRRIT. 2; H315
STOT SE 3; H335, H336
LIGHT HYDROCRACKED 7 - 13 64741-77-1 AQUATIC CHRONIC 2; H411
DISTILLATE ASP. TOX. 1; H304
ACUTE TOX. 4; H332
CARC. 2; H351
SKIN IRRIT. 2; H315
STOT RE 2; H373
NAPHTHALENE 0.5 - 1.5 91-20-3 AQUATIC ACUTE 1; H400
AQUATIC CHRONIC 1; H410
ACUTE TOX. 4; H302
CARC. 2; H351
FLAM. SOL. 1; H228
NAPHTHA (PETROLEUM), 0.5 - 1.5 64742-94-5 AQUATIC ACUTE 1; H400
HEAVY AROMATIC ACUTE TOX. 1; H310
ACUTE TOX. 3; H331
ACUTE TOX. 3; H331
ACUTE TOX. 2; H330
FLAM. LIQ. 3; H226
ETHANOL 2,2'- 0.1 - 1 61791-44-4 AQUATIC ACUTE 1; H400
IMINOBIS-, N-TALLOW ACUTE TOX. 4; H302
ALKYL DERIVS EYE DAM. 1; H318
MET. CORR. 1; H290
SKIN CORR. 1C; H314
SKIN SENS. 1; H317
TOLUENE 0.1 - 1 108-88-3 ASP. TOX. 1; H304
ACUTE TOX. 4; H302
ACUTE TOX. 4; H332
FLAM. LIQ. 1; H224
REPR. 2; H361
SKIN IRRIT. 2; H315
STOT RE 2; H373
STOT SE 3; H335, H336
ETHYLBENZENE 0.1 - 1 100-41-4 AQUATIC CHRONIC 3; H412
ASP. TOX. 1; H304
ACUTE TOX. 4; H332
ACUTE TOX. 4; H332
CARC. 1A; H350
FLAM. LIQ. 2; H225
MUTA. 1B; H340
STOT RE 2; H373
BENZENE 0.1 - 1 71-43-2 ASP. TOX. 1; H304
ACUTE TOX. 4; H332
ACUTE TOX. 4; H302
CARC. 1A; H350
EYE IRRIT. 2; H319
FLAM. LIQ. 2; H225
MUTA. 1B; H340
SKIN IRRIT. 2; H315
STOT RE 1; H372
COMPONENTS NOT LISTED ARE NOT PHYSICAL OR HEALTH HAZARDS AS DEFINED IN 29
CFR 1910.1200 (HAZARD COMMUNICATION STANDARD).
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, HAVE A TRAINED INDIVIDUAL
ADMINISTER OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION AND HAVE A
TRAINED INDIVIDUAL ADMINISTER OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY.
EYES:
FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 20 MINUTES RETRACTING EYELIDS
OFTEN. TILT THE HEAD TO PREVENT CHEMICAL FROM TRANSFERRING TO THE
UNCONTAMINATED EYE. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH AREA OF CONTACT THOROUGHLY
WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. HIGH
PRESSURE SKIN INJECTIONS ARE SERIOUS MEDICAL EMERGENCIES. GET IMMEDIATE
MEDICAL ATTENTION. THERMAL BURNS REQUIRE IMMEDIATE MEDICAL ATTENTION.
INGESTION:
SEEK MEDICAL ATTENTION IMMEDIATELY OR CALL THE POISON CONTROL CENTER. DO
NOT INDUCE VOMITING. IF PATIENT IS FULLY CONSCIOUS, GIVE UP TO TWO GLASSES
OF WATER. PROVIDE MEDICAL CARE PROVIDER WITH THIS SDS. INDUCE VOMITING AS A
LAST MEASURE. INDUCED VOMITING MAY LEAD TO ASPIRATION OF THE MATERIAL INTO
THE LUNGS POTENTIALLY CAUSING CHEMICAL PNEUMONITIS THAT MAY BE FATAL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: DIZZINESS, DROWSINESS, SEVERE PULMONARY IRRITATION
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTE TO DOCTOR:
IN CASE OF INGESTION, GASTRIC LAVAGE WITH ACTIVATED CHARCOAL CAN BE USED
PROMPTLY TO PREVENT ABSORPTION. CONSIDERATION SHOULD BE GIVEN TO THE USE OF
AN ENDOTRACHEAL TUBE, TO PREVENT ASPIRATION. INDIVIDUALS INTOXICATED BY
MIDDLE DISTILLATES SHOULD BE HOSPITALIZED IMMEDIATELY, WITH ACUTE AND
CONTINUING ATTENTION TO NEUROLOGIC AND CARDIOPULMONARY FUNCTION. POSITIVE
PRESSURE VENTILATION MAY BE NECESSARY. AFTER THE INITIAL EPISODE,
INDIVIDUALS SHOULD BE FOLLOWED FOR CHANGES IN BLOOD VARIABLES AND THE
DELAYED APPEARANCE OF PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. SUCH
PATIENTS SHOULD BE FOLLOWED FOR SEVERAL DAYS OR WEEKS FOR DELAYED EFFECTS,
INCLUDING BONE MARROW TOXICITY, HEPATIC, AND RENAL IMPAIRMENT. INDIVIDUALS
WITH CHRONIC PULMONARY DISEASE WILL BE MORE SERIOUSLY IMPAIRED, AND
RECOVERY FROM INHALATION EXPOSURE MAY BE COMPLICATED. AVOID EMESIS UNLESS A
LARGE AMOUNT HAS BEEN INGESTED OR IT CONTAINS A TOXIC ADDITIVE. GASTRIC
LAVAGE AFTER ENDOTRACHEAL INTUBATION SHOULD BE RESERVED FOR A PATIENT WHO
REQUIRES GI DECONTAMINATION AND IS LETHARGIC OR OBTUNDED. SAFE USE OF
ACTIVATED CHARCOAL AND CATHARTIC SHOULD BE CONSIDERED IF INGESTED. MINERAL
OIL CATHARTICS SHOULD NOT BE GIVEN TO PATIENTS. SALINE CATHARTICS OR
SORBATOL IS PREFERRABLE. IN CASE OF SKIN INJECTION, PROMPT DEBRIDEMENT OF
THE WOUND IS NECESSARY TO MINIMIZE NECROSIS AND TISSUE LOSS. ASPIRATION
DURING SWALLOWING OR VOMITING MAY SEVERELY DAMAGE THE LUNGS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE AND UNSUITABLE EXTINGUISHING MEDIA:
USE ALCOHOL RESISTANT FOAM, CARBON DIOXIDE, DRY CHEMICAL, OR WATER SPRAY
WHEN FIGHTING FIRES. WATER OR FOAM MAY CAUSE FROTHING IF LIQUID IS BURNING
BUT IT STILL MAY BE A USEFUL EXTINGUISHING AGENT IF CAREFULLY APPLIED TO
THE FIRE. DO NOT DIRECT A WATER STREAM DIRECTLY INTO THE HOT BURNING
LIQUID.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE AND/OR EXPLOSION HAZARDS:
VAPORS MAY BE IGNITED BY SPARKS, FLAMES OR OTHER SOURCES OF IGNITION IF
MATERIAL IS ABOVE THE FLASH POINT GIVING RISE TO A FIRE (CLASS B). VAPORS
ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK.
5.3. ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING METHODS AND PROTECTION:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION INCLUDING SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. FIGHT FIRE FROM A SAFE
DISTANCE AND A PROTECTED LOCATION DUE TO THE POTENTIAL FOR HAZARDOUS VAPORS
AND DECOMPOSITION PRODUCTS. FLAMMABLE COMPONENT(S) OF THIS MATERIAL MAY BE
LIGHTER THAN WATER AND BURN WHILE FLOATING ON THE SURFACE.
HAZARDOUS COMBUSTION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
EXPOSURE TO THE SPILLED MATERIAL MAY BE IRRITATING OR HARMFUL. FOLLOW
PERSONAL PROTECTIVE EQUIPMENT RECOMMENDATIONS FOUND IN SECTION 8 OF THIS
SDS. ADDITIONAL PRECAUTIONS MAY BE NECESSARY BASED ON SPECIAL CIRCUMSTANCES
CREATED BY THE SPILL INCLUDING; THE MATERIAL SPILLED, THE QUANTITY OF THE
SPILL, THE AREA IN WHICH THE SPILL OCCURRED. ALSO CONSIDER THE EXPERTISE OF
EMPLOYEES IN THE AREA RESPONDING TO THE SPILL. EVAPORATION OF VOLATILE
SUBSTANCES CAN LEAD TO THE DISPLACEMENT OF AIR CREATING AN ENVIRONMENT THAT
CAN CAUSE ASPHYXIATION.
6.2. ENVIRONMENTAL PRECAUTIONS: NO DATA AVAILABLE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
PREVENT THE SPREAD OF ANY SPILL TO MINIMIZE HARM TO HUMAN HEALTH AND THE
ENVIRONMENT IF SAFE TO DO SO. WEAR COMPLETE AND PROPER PERSONAL PROTECTIVE
EQUIPMENT FOLLOWING THE RECOMMENDATION OF SECTION 8 AT A MINIMUM. DIKE WITH
SUITABLE ABSORBENT MATERIAL LIKE GRANULATED CLAY. DISPOSE OF ACCORDING TO
FEDERAL, STATE, LOCAL, OR PROVINCIAL REGULATIONS. USED FLUID SHOULD BE
DISPOSED OF AT A RECYCLING CENTER. P391 - COLLECT SPILLAGE.
6.4. REFERENCE TO OTHER SECTIONS:
FOLLOW ALL PROTECTIVE EQUIPMENT RECOMMENDATIONS PROVIDED IN SECTION 8.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
HARMFUL OR IRRITATING MATERIAL. AVOID CONTACTING AND AVOID BREATHING THE
MATERIAL. USE ONLY IN A WELL VENTILATED AREA. EMPTY CONTAINERS MAY RETAIN
PRODUCT RESIDUES/ VAPORS. USE PROPER BONDING AND GROUNDING DURING BULK
PRODUCT TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL DRY PLACE. ISOLATE FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: SEE SECTION 10.
7.3. SPECIFIC END USE(S): FUEL ADDITIVE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
CHEMICAL NAME OCCUPATIONAL VALUE
EXPOSURE LIMITS
OIL MIST, MINERAL OSHA PEL 5 MG/M3
NAPHTHALENE OSHA PEL 10 PPM TWA; 50 MG/M3 TWA
TOLUENE OSHA PEL 200 PPM TWA
BENZENE OSHA PEL 10 PPM TWA (APPLIES TO
INDUSTRY SEGMENTS EXEMPT
FROM THE BENZENE STANDARD
AT 29 CFR 1910.1028);
1 PPM TWA
ETHYLBENZENE OSHA PEL 100 PPM TWA; 435 MG/M3 TWA
NAPHTHALENE OSHA STEL 15 PPM STEL; 75 MG/M3 STEL
TOLUENE OSHA STEL 150 PPM STEL; 560 MG/M3 STEL
BENZENE OSHA STEL 1 PPM STEL
ETHYLBENZENE OSHA STEL 125 PPM STEL; 545 MG/M3 STEL
KEROSENE ACGIH TLV-TWA 200 MG/M3 TWA (APPLICATION
RESTRICTED TO CONDITIONS IN
WHICH THERE ARE NEGLIGIBLE
AEROSOL EXPOSURES, TOTAL
HYDROCARBON VAPOR)
OIL MIST, MINERAL ACGIH TLV-TWA 5 MG/M3
KEROSENE, ACGIH TLV-TWA 200 MG/M3 TWA (APPLICATION
HYDRODESULFURIZED RESTRICTED TO CONDITIONS IN
WHICH THERE ARE NEGLIGIBLE
AEROSOL EXPOSURES, TOTAL
HYDROCARBON VAPOR)
NAPHTHALENE ACGIH TLV-TWA 10 PPM TWA
TOLUENE ACGIH TLV-TWA 20 PPM TWA
BENZENE ACGIH TLV-TWA 0.5 PPM TWA
ETHYLBENZENE ACGIH TLV-TWA 20 PPM TWA
OIL MIST, MINERAL ACGIH STEL 10 MG/M3
NAPHTHALENE ACGIH STEL 15 PPM STEL
BENZENE ACGIH STEL 2.5 PPM STEL
NAPHTHALENE IDLH 250 PPM IDLH
TOLUENE IDLH 500 PPM IDLH
BENZENE IDLH 500 PPM IDLH
ETHYLBENZENE IDLH 800 PPM IDLH (10% LEL)
NONE. OSHA PEL-SKIN
NOTATION
KEROSENE ACGIH TLV-SKIN SKIN - POTENTIAL SIGNIFICANT
DESIGNATION CONTRIBUTION TO OVERALL
EXPOSURE BY THE CUTANEOUS
ROUTE
KEROSENE, ACGIH TLV-SKIN SKIN - POTENTIAL SIGNIFICANT
HYDRODESULFURIZED DESIGNATION CONTRIBUTION TO OVERALL
EXPOSURE BY THE CUTANEOUS
ROUTE
NAPHTHALENE ACGIH TLV-SKIN SKIN - POTENTIAL SIGNIFICANT
DESIGNATION CONTRIBUTION TO OVERALL
EXPOSURE BY THE CUTANEOUS
ROUTE
BENZENE ACGIH TLV-SKIN SKIN - POTENTIAL SIGNIFICANT
DESIGNATION CONTRIBUTION TO OVERALL
EXPOSURE BY THE CUTANEOUS
ROUTE
8.2. EXPOSURE CONTROLS:
ENGINEERING MEASURES:
LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS ARE NORMALLY
REQUIRED WHEN HANDLING OR USING THIS PRODUCT TO AVOID OVEREXPOSURE.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION MAY BE REQUIRED TO AVOID OVEREXPOSURE WHEN HANDLING
THIS PRODUCT. GENERAL OR LOCAL EXHAUST VENTILATION IS THE PREFERRED MEANS
OF PROTECTION. USE A RESPIRATOR IF GENERAL ROOM VENTILATION IS NOT
AVAILABLE OR SUFFICIENT TO ELIMINATE SYMPTOMS.
RESPIRATOR TYPE(S):
IF AIRBORNE CONCENTRATIONS ARE ABOVE THE APPLICABLE EXPOSURE LIMITS, USE
NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
EYE PROTECTION:
WEAR CHEMICALLY RESISTANT SAFETY GLASSES WITH SIDE SHIELDS WHEN HANDLING
THIS PRODUCT. DO NOT WEAR CONTACT LENSES.
SKIN PROTECTION:
AVOID SKIN CONTACT BY WEARING CHEMICALLY RESISTANT GLOVES, AN APRON AND
OTHER PROTECTIVE EQUIPMENT DEPENDING UPON CONDITIONS OF USE. INSPECT GLOVES
FOR CHEMICAL BREAK-THROUGH AND REPLACE AT REGULAR INTERVALS. CLEAN
PROTECTIVE EQUIPMENT REGULARLY. WASH HANDS AND OTHER EXPOSED AREAS WITH
MILD SOAP AND WATER BEFORE EATING, DRINKING, AND WHEN LEAVING WORK.
GLOVES: NITRILE, NEOPRENE
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: AMBER
ODOR: MILD
ODOR THRESHOLD: NOT DETERMINED
PH: NOT DETERMINED
FREEZING POINT: -40
BOILING POINT: NOT DETERMINED
FLASH POINT: 41
FLASH POINT METHOD: COC
EVAPORATION RATE: NOT DETERMINED
UPPER FLAMMABLE/EXPLOSIVE LIMIT, % IN AIR: 5
LOWER FLAMMABLE/EXPLOSIVE LIMIT, % IN AIR: 0.7
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
VAPOR PRESSURE: 1-10
VAPOR DENSITY: 4.42 3.66
RELATIVE DENSITY: 0.82
SOLUBILITY IN WATER: NEGLIGIBLE; 0-1%
OCTANOL/WATER PARTITION COEFFICIENT: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VISCOSITY (DEG. C): 1.4
9.2. OTHER INFORMATION:
VOLATILES, % BY WEIGHT: 0.000000
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DATA AVAILABLE.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
TEMPERATURES ABOVE FLASH POINT IN COMBINATION WITH SPARKS, OPEN FLAMES, OR
OTHER SOURCES OF IGNITION.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
INGESTION TOXICITY:
ALTHOUGH THIS PRODUCT HAS A LOW ORDER OF ACUTE ORAL TOXICITY, ASPIRATION OF
MINUTE AMOUNTS INTO THE LUNGS DURING INGESTION OR VOMITING MAY CAUSE MILD
TO SEVERE PULMONARY INJURY AND POSSIBLY DEATH. ESTIMATED TO BE
2.0 - 5.0 G/KG.
SKIN CONTACT:
THIS MATERIAL IS ESTIMATED TO BE SEVERELY IRRITATING (PRIMARY IRRITATION
INDEX IS 6.0 - 6.5 [RABBITS]). CONTACT MAY RESULT IN DEFATTING, REDNESS,
ITCHING, INFLAMMATION, CRACKING, AND POSSIBLE SECONDARY INFECTION. HIGH
PRESSURE SKIN INJECTIONS ARE SERIOUS MEDICAL EMERGENCIES. INJURY MAY NOT
APPEAR SERIOUS AT FIRST; WITHIN A FEW HOURS, TISSUE WILL BECOME SWOLLEN,
DISCOLORED AND EXTREMELY PAINFUL (SEE NOTES TO DOCTOR). CONTACT WITH
HEATED MATERIAL MAY CAUSE THERMAL BURNS.
ABSORPTION: LIKELY TO BE PRACTICALLY NON-TOXIC BASED ON ANIMAL DATA.
INHALATION TOXICITY:
TOXIC!
CAN CAUSE SYSTEMIC DAMAGE (SEE "TARGET ORGANS"). RESPIRATORY FAILURE IS
POSSIBLE AT HIGH DOSES. LIKELY TO BE MODERATELY TOXIC BASED ON ANIMAL DATA.
EYE CONTACT:
THE MATERIAL IS LIKELY TO BE MODERATELY IRRITATING TO EYES BASED ON ANIMAL
DATA. CAN CAUSE MODERATE IRRITATION, TEARING AND REDDENING, BUT NOT LIKELY
TO PERMANENTLY INJURE EYE TISSUE.
SENSITIZATION:
NON-HAZARDOUS UNDER RESPIRATORY SENSITIZATION CATEGORY. CONTAINS A
SUBSTANCE THAT MAY CAUSE SKIN SENSITIZATION.
MUTAGENICITY: MUTAGENIC AFFECTS IN HUMANS MAY OCCUR.
CARCINOGENICITY: CONTAINS A KNOWN HUMAN CARCINOGEN.
REPRODUCTIVE AND DEVELOPMENTAL TOXICITY:
CONTAINS A SUBSTANCE THAT IS A POSSIBLE REPRODUCTIVE SYSTEM HAZARD BASED ON
ANIMAL STUDIES AT DOSES THAT COULD BE ENCOUNTERED IN THE WORKPLACE.
SPECIFIC TARGET ORGAN TOXICITY-SINGLE EXPOSURE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H335: MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY-REPEATED EXPOSURE:
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
LONG-TERM (CHRONIC) HEALTH EFFECTS:
DIZZINESS, DROWSINESS, SEVERE PULMONARY IRRITATION
ASPIRATION TOXICITY:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OTHER INFORMATION: NO DATA AVAILABLE.
AGENTS CLASSIFIED BY IARC MONOGRAPHS:
BENZENE: IARC GROUP 1
NOT APPLICABLE: IARC GROUP 2A
NAPHTHALENE: IARC GROUP 2B
ETHYLBENZENE: IARC GROUP 2B
NATIONAL TOXICITY PROGRAM (NTP) STATUS:
BENZENE: KNOWN HUMAN CARCINOGEN
NAPHTHALENE: REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ACUTE AQUATIC ECOTOXICITY:
H400: VERY TOXIC TO AQUATIC LIFE.
CHRONIC AQUATIC ECOTOXICITY:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
12.2. PERSISTENCE AND DEGRADABILITY: BIODEGRADES AT A MODERATE RATE.
12.3. BIOACCUMULATIVE POTENTIAL: BIOCONCENTRATION IS EXPECTED TO OCCUR.
12.4. MOBILITY IN SOIL:
THIS MATERIAL IS EXPECTED TO HAVE ESSENTIALLY NO MOBILITY IN SOIL. IT
ABSORBS STRONGLY TO MOST SOIL TYPES.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE.
12.6. OTHER ADVERSE EFFECTS: NOT DETERMINED
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DISPOSAL METHODS:
DISPOSE OF BY INCINERATION FOLLOWING FEDERAL, STATE, LOCAL, OR PROVINCIAL
REGULATIONS.
WASTE DISPOSAL CODE(S): D001
WASTE DESCRIPTION FOR SPENT PRODUCT:
SPENT OR DISCARDED MATERIAL IS A HAZARDOUS WASTE.
CONTAMINATED PACKAGING:
| SECTION 14: TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS: ORM-D
IMDG:
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S
TECHNICAL NAME: KEROSENE
UN NUMBER: UN1993
HAZARD CLASS: 3
PACKING GROUP: III
EXCEPTION: LTD QTY
EMS# F-E, S-E
IATA:
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S
TECHNICAL NAME: KEROSENE
UN NUMBER: UN1993
HAZARD CLASS: 3
PACKING GROUP: III
EXCEPTION: LTD QTY
| SECTION 15: REGULATORY INFORMATION | |
CHEMICAL INVENTORIES:
TSCA STATUS:
ALL COMPONENTS OF THIS MATERIAL ARE ON THE US TSCA INVENTORY OR ARE EXEMPT.
U.S. STATE RESTRICTIONS: NOT APPLICABLE
WHMIS: B3, D2B
CHEMICAL NAME REGULATION CAS # %
NAPHTHALENE CERCLA 91-20-3 0.5 - 1.5
BENZENE, METHYL- CERCLA 108-88-3 0.1 - 1
BENZENE CERCLA 71-43-2 0.1 - 1
ETHYLBENZENE CERCLA 100-41-4 0.1 - 1
NAPHTHALENE SARA 313 91-20-3 0.5 - 1.5
XYLENE (MIXED ISOMERS) SARA 313 1330-20-7 0.1 - 1
TOLUENE SARA 313 108-88-3 0.1 - 1
BENZENE SARA 313 71-43-2 0.1 - 1
ETHYLBENZENE SARA 313 100-41-4 0.1 - 1
BIPHENYL SARA 313 92-52-4 0.1 - 1
1,2,4-TRIMETHYLBENZENE SARA 313 95-63-6 0.01 - 0.1
NONE. SARA EHS
NONE. TSCA 12B
U.S. STATE REGULATIONS:
CHEMICAL NAME REGULATION CAS # %
NAPHTHALENE CALIFORNIA PROP 65- 91-20-3 0.5 - 1.5
CANCER
BENZENE CALIFORNIA PROP 65- 71-43-2 0.1 - 1
CANCER
ETHYLBENZENE CALIFORNIA PROP 65- 100-41-4 0.1 - 1
CANCER
TOLUENE CALIFORNIA PROP 65- 108-88-3 0.1 - 1
DEV. TOXICITY
BENZENE CALIFORNIA PROP 65- 71-43-2 0.1 - 1
DEV. TOXICITY
NONE. CALIFORNIA PROP 65-
REPROD -FEM
BENZENE CALIFORNIA PROP 65- 71-43-2 0.1 - 1
REPROD-MALE
KEROSINE MASSACHUSETTS RTK LIST 8008-20-6 90 - 99
NAPHTHALENE MASSACHUSETTS RTK LIST 91-20-3 0.5 - 1.5
TOLUENE MASSACHUSETTS RTK LIST 108-88-3 0.1 - 1
BENZENE MASSACHUSETTS RTK LIST 71-43-2 0.1 - 1
ETHYLBENZENE MASSACHUSETTS RTK LIST 100-41-4 0.1 - 1
KEROSENE NEW JERSEY RTK LIST 8008-20-6 90 - 99
NAPHTHALENE NEW JERSEY RTK LIST 91-20-3 0.5 - 1.5
TOLUENE NEW JERSEY RTK LIST 108-88-3 0.1 - 1
BENZENE NEW JERSEY RTK LIST 71-43-2 0.1 - 1
ETHYLBENZENE NEW JERSEY RTK LIST 100-41-4 0.1 - 1
KEROSINE PENNSYLVANIA RTK LIST 8008-20-6 90 - 99
NAPHTHALENE PENNSYLVANIA RTK LIST 91-20-3 0.5 - 1.5
BENZENE, METHYL- PENNSYLVANIA RTK LIST 108-88-3 0.1 - 1
BENZENE PENNSYLVANIA RTK LIST 71-43-2 0.1 - 1
BENZENE, ETHYL- PENNSYLVANIA RTK LIST 100-41-4 0.1 - 1
NONE. RHODE ISLAND RTK LIST
NAPHTHALENE MINNESOTA HAZARDOUS 91-20-3 0.5 - 1.5
SUBSTANCE LIST
TOLUENE MINNESOTA HAZARDOUS 108-88-3 0.1 - 1
SUBSTANCE LIST
BENZENE MINNESOTA HAZARDOUS 71-43-2 0.1 - 1
SUBSTANCE LIST
ETHYLBENZENE MINNESOTA HAZARDOUS 100-41-4 0.1 - 1
SUBSTANCE LIST
HMIS RATINGS:
HEALTH 2
FIRE 2
REACTIVITY 0
PPE B
NFPA RATINGS:
HEALTH 2
FIRE 2
REACTIVITY 0
KEY:
0 - LEAST
1 - SLIGHT
2 - MODERATE
3 - HIGH
4 - EXTREME
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 4/2/2015 3:33:05 AM
SUPERSEDES: 1/8/2015 2:02:10 PM
REFERENCES:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CFR: CODE OF FEDERAL REGULATIONS
DOT: UNITED STATES DEPARTMENT OF TRANSPORTATION
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORTATION ASSOCIATION
IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PEL: PERMISSIBLE EXPOSURE LIMIT
RTK: RIGHT-TO-KNOW
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
STEL: SHORT-TERM EXPOSURE LIMIT
TLV: THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCES CONTROL ACT
TWA: TIME WEIGHTED AVERAGE
UN: UNITED NATIONS
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
DISCLAIMER:
THIS SAFETY DATA SHEET AND THE INFORMATION IT CONTAINS IS OFFERED TO YOU IN
GOOD FAITH AS ACCURATE. WE HAVE REVIEWED ANY INFORMATION CONTAINED IN THE
DATA SHEET WHICH WE HAVE RECEIVED FROM OUTSIDE SOURCES AND WE BELIEVE THE
INFORMATION TO BE CORRECT, BUT CANNOT GUARANTEE ITS ACCURACY OR
COMPLETENESS. HEALTH AND SAFETY PRECAUTIONS IN THIS DATA SHEET MAY NOT BE
ADEQUATE FOR ALL INDIVIDUALS AND/OR SITUATIONS. IT IS THE USER'S OBLIGATION
TO EVALUATE AND USE THIS PRODUCT IN A SAFE MANNER AND TO COMPLY WITH ALL
APPLICABLE LAWS AND REGULATIONS. NO STATEMENT MADE IN THIS DATA SHEET SHALL
BE CONSTRUED AS PERMISSION OR RECOMMENDATION FOR THE USE OF ANY PRODUCT IN
A MANNER THAT MIGHT INFRINGE EXISTING PATENTS. NO WARRANTY IS MADE, EITHER
EXPRESSED OR IMPLIED.