SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. NITROGEN DIOXIDE 0.001-0.022%, CARBON MONOXIDE 0.0005-1.0%, METHANE 0.0-2.5%, OXYGEN 0.0-23.5% MSA THE SAFETY COMPANY SAFETY DATA SHEET 50116MSA
AND OF THE COMPANY/UNDERTAKING 1.1 PRODUCT IDENTIFIER: PRODUCT NAME: NITROGEN DIOXIDE 0.001-0.022%, CARBON MONOXIDE 0.0005-1.0%, METHANE 0.0-2.5%, OXYGEN 0.0-23.5% MSA P/N: 10058036, 10058034, 10058171, 10058172, 10150597, 10150598, 10153803, 10153804, 10153805 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: RELEVANT IDENTIFIED USE(S): CALIBRATION OF MONITORING AND RESEARCH EQUIPMENT 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: MANUFACTURER: AIR LIQUIDE 2700 POST OAK BLVD. HOUSTON, TX 77056 UNITED STATES WWW.US.AIRLIQUIDE.COM SDS@AIRLIQUIDE.COM U.S. SUPPLIER: MINE SAFETY APPLIANCES COMPANY CRANBERRY TOWNSHIP PENNSYLVANIA 16066 U.S.A. 1-800-MSA-2222 WWW.MSANET.COM/PRISM TELEPHONE (TECHNICAL): 713-896-2896 TELEPHONE (TECHNICAL): 800-819-1704 1.4 EMERGENCY TELEPHONE NUMBER: MANUFACTURER: 800-424-9300 - CHEMTREC MANUFACTURER: +1 703-527-3887 - OUTSIDE UNITED STATES
EU/EEC: ACCORDING TO REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006 [AMENDED BY 453/2010] ACCORDING TO EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD) 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: CLP: COMPRESSED GAS - H280 REPRODUCTIVE TOXICITY 1A - H360D SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 2 - H373 DSD/DPD: HARMFUL (XN) SUBSTANCES TOXIC TO REPRODUCTION - CATEGORY 1 R20, R48/20, R61 2.2 LABEL ELEMENTS: CLP: DANGER GAS CYLINDER HEALTH HAZARD HAZARD STATEMENTS: H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED H360D: MAY DAMAGE THE UNBORN CHILD. H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. PRECAUTIONARY STATEMENTS: PREVENTION: P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. P202: DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. P260: DO NOT BREATHE GAS. P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. RESPONSE: P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL. P308+P313: IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. STORAGE/DISPOSAL: P403: STORE IN A WELL-VENTILATED PLACE. P405: STORE LOCKED UP. P501: DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, AND/OR INTERNATIONAL REGULATIONS. DSD/DPD: HARMFUL OR IRRITANT TOXIC OR VERY TOXIC RISK PHRASES: R20: HARMFUL BY INHALATION. R48/20: HARMFUL: DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH INHALATION. R61: MAY CAUSE HARM TO THE UNBORN CHILD. SAFETY PHRASES: S53: AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. 2.3 OTHER HAZARDS: CLP: THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS CONSIDERED HAZARDOUS. DSD/DPD: THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS MATERIAL IS CONSIDERED DANGEROUS. UNITED STATES (US): ACCORDING TO OSHA 29 CFR 1910.1200 HCS: 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: OSHA HCS 2012: COMPRESSED GAS - H280 REPRODUCTIVE TOXICITY 1A - H360 SIMPLE ASPHYXIANT 2.2 LABEL ELEMENTS: OSHA HCS 2012: DANGER GAS CYLINDER HEALTH HAZARD HAZARD STATEMENTS: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED - H280 MAY DAMAGE FERTILITY OR THE UNBORN CHILD. - H360 MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. PRECAUTIONARY STATEMENTS: PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. - P201 DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. - P202 WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. - P280 RESPONSE: IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. - P308+P313 STORAGE/DISPOSAL: STORE IN A WELL-VENTILATED PLACE. - P403 STORE LOCKED UP. - P405 DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, AND/OR INTERNATIONAL REGULATIONS. - P501 2.3 OTHER HAZARDS: OSHA HCS 2012: UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS. CANADA: ACCORDING TO WHMIS: 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: WHMIS: COMPRESSED GAS A VERY TOXIC - D1A OTHER TOXIC EFFECTS - D2A 2.2 LABEL ELEMENTS: WHMIS: COMPRESSED GAS A VERY TOXIC - D1A OTHER TOXIC EFFECTS - D2A 2.3 OTHER HAZARDS: WHMIS: THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
3.1 SUBSTANCES: MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. 3.2 MIXTURES: COMPOSITION: CHEMICAL NAME IDENTIFIERS % OXYGEN CAS: 7782-44-7 0% TO 23.5% EC NUMBER: 231-956-9 EU INDEX: 008-001-00-8 METHANE CAS: 74-82-8 0% TO 2.5% EC NUMBER: 200-812-7 EU INDEX: 601-001-00-4 CARBON MONOXIDE CAS: 630-08-0 0.0005% TO 1% EC NUMBER: 211-128-3 EU INDEX: 606-001-00-2 NITROGEN DIOXIDE CAS: 10102-44-0 0.001% TO 0.022% EC NUMBER: 233-272-6 EU INDEX: 007-002-00-0 NITROGEN CAS: 7727-37-9 BALANCE EINECS: 231-783-9 CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING TO REGULATION/DIRECTIVE OXYGEN NDA EU DSD/DPD: ANNEX VI, TABLE 3.2: O R8 EU CLP: ANNEX VI, TABLE 3.1: OX. GAS 1, H270 PRESS. GAS - COMP., H280 OSHA HCS 2012: OX. GAS 1 PRESS GAS. - COMP. METHANE NDA EU DSD/DPD: ANNEX VI, TABLE 3.2: F+ R12 EU CLP: ANNEX VI, TABLE 3.1: FLAM. GAS 1, H220 PRESS. GAS - COMP., H280 OSHA HCS 2012: FLAM. GAS 1 PRESS. GAS - COMP SIMP. ASPHYX. CARBON MONOXIDE INHALATION-RAT LC50: EU DSD/DPD: 1807 PPM 4 HOUR(S) ANNEX VI, TABLE 3.2: F+ R12 T R23-48/23 REPR.CAT.1 R61 EU CLP: ANNEX VI, TABLE 3.1: FLAM GAS 1, H220 PRESS, GAS - COMP., H280 REPR. 1A, H360D ACUTE TOX. 3*, H331 STOT RE 1, H372 OSHA HCS 2012: FLAM. GAS 1 PRESS GAS - COMP. REPR 1A ACUTE TOX. 3 (INHL) NITROGEN INHALATION-RAT LC50: EU DSD/DPD: DIOXIDE 88 PPM 4 HOUR(S) ANNEX VI, TABLE 3.2: T+ R26 C R34 O R8 EU CLP: ANNEX VI, TABLE 3.1: PRESS GAS - LIQ., H280 OX. GAS 1, H270 ACUTE TOX. 1, H330 SKIN CORR. 1B, H314 OSHA HCS 2012: PRESS. GAS - LIQ. OX. GAS 1 SKIN CORR. 1 EYE DAM. 1 STOT SE 1 (LUNGS, BLOOD (METHEMEGLOBIN FORMER)) STOT RE 1 (LUNGS, INHL) ACUTE TOX. 1 (INHL) MUTA. 2 NITROGEN NDA EU DSD/DPD: NOT CLASSIFIED EU CLP: SELF CLASSIFIED: PRESS. GAS - COMP., H280 OSHA HCS 2012: PRESS. GAS - COMP.; SIMP. ASPHYX. SEE SECTION 16 FOR FULL TEXT OF H-STATEMENTS AND R-PHRASES.
4.1 DESCRIPTION OF FIRST AID MEASURES: INHALATION: IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS CONTINUE, GET MEDICAL ATTENTION. SKIN: ALTHOUGH EXPOSURE IS UNLIKELY, IN CASE OF CONTACT IMMEDIATELY FLUSH SKIN WITH RUNNING WATER. IF SKIN IRRITATION DEVELOPS GET MEDICAL ADVICE/ATTENTION. EYE: FIRST AID IS NOT EXPECTED TO BE NECESSARY IF MATERIAL IS USED UNDER ORDINARY CONDITIONS AND AS RECOMMENDED. IF IRRITATION DEVELOPS AND PERSISTS, GET MEDICAL ATTENTION. INGESTION: INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: NOTES TO PHYSICIAN: ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED. A POTENTIAL HEALTH HAZARD ASSOCIATED WITH THIS GAS IS ANOXIA. 4.4 OTHER INFORMATION: ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO GASES WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS MUST BE WORN. VICTIM(S) WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVEREXPOSURE TO THIS GAS MIXTURE MUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN FOR MEDICAL ATTENTION IF NECESSARY. TAKE A COPY OF THE LABEL AND THE MSDS TO PHYSICIAN OR OTHER HEALTH PROFESSIONAL WITH VICTIM(S).
5.1 EXTINGUISHING MEDIA: SUITABLE EXTINGUISHING MEDIA: USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTAINERS MAY EXPLODE WHEN HEATED. RUPTURED CYLINDERS MAY ROCKET. HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE 5.3 ADVICE FOR FIREFIGHTERS: STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING PROVIDES LIMITED PROTECTION IN FIRE SITUATIONS ONLY; IT IS NOT EFFECTIVE IN SPILL SITUATIONS WHERE DIRECT CONTACT WITH THE SUBSTANCE IS POSSIBLE. ALWAYS WEAR THERMAL PROTECTIVE CLOTHING WHEN HANDLING REFRIGERATED/ CRYOGENIC LIQUIDS. WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA). MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. FIRE: IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS. FIRE INVOLVING TANKS: FIGHT FIRE FROM MAXIMUM DISTANCE OR USE UNMANNED HOSE HOLDERS OR MONITOR NOZZLES. FIRE INVOLVING TANKS: COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. FIRE INVOLVING TANKS: DO NOT DIRECT WATER AT SOURCE OF LEAK OR SAFETY DEVICES; ICING MAY OCCUR. FIRE INVOLVING TANKS: WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICES OR DISCOLORATION OF TANK. FIRE INVOLVING TANKS: ALWAYS STAY AWAY FROM TANKS ENGULFED IN FIRE.
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: PERSONAL PRECAUTIONS: DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. VENTILATE THE AREA BEFORE ENTRY. EMERGENCY PROCEDURES: STOP LEAK IF YOU CAN DO IT WITHOUT RISK. KEEP UNAUTHORIZED PERSONNEL AWAY. KEEP OUT OF LOW AREAS. STAY UPWIND. DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK. LARGE SPILL: CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST 500 METERS (1/3 MILE) 6.2 ENVIRONMENTAL PRECAUTIONS: PREVENT SPREADING OF VAPORS THROUGH SEWERS, VENTILATION SYSTEMS AND CONFINED AREAS. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: CONTAINMENT/CLEAN-UP MEASURES: STOP LEAK IF YOU CAN DO IT WITHOUT RISK. DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK. USE WATER SPRAY TO REDUCE VAPORS; DO NOT PUT WATER DIRECTLY ON LEAK, SPILL AREA OR INSIDE CONTAINER. IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN LIQUID. ISOLATE AREA UNTIL GAS HAS DISPERSED. VENTILATE THE AREA. 6.4 REFERENCE TO OTHER SECTIONS: REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND SECTION 13 - DISPOSAL CONSIDERATIONS.
7.1 PRECAUTIONS FOR SAFE HANDLING: HANDLING: USE ONLY WITH ADEQUATE VENTILATION. VENTILATE CLOSED SPACES BEFORE ENTERING. BE AWARE OF ANY SIGNS OF DIZZINESS OR FATIGUE, ESPECIALLY IF WORK IS DONE IN A POORLY VENTILATED AREA; EXPOSURES TO FATAL CONCENTRATIONS OF THIS GAS MIXTURE COULD OCCUR WITHOUT ANY SIGNIFICANT WARNING SYMPTOMS, DUE TO OLFACTORY FATIGUE OR OXYGEN DEFICIENCY. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED-OVER. DO NOT ATTEMPT TO REPAIR, ADJUST, OR IN ANY OTHER WAY MODIFY CYLINDERS. IF THERE IS A MALFUNCTION OR ANOTHER TYPE OF OPERATIONAL PROBLEM, CONTACT NEAREST DISTRIBUTOR IMMEDIATELY. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT CUT, WELD, PUNCTURE OR INCINERATE CONTAINER. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: STORAGE: STORE IN A COOL, DRY, WELL-VENTILATED PLACE. PROTECT CYLINDERS AGAINST PHYSICAL DAMAGE. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED-OVER. 7.3 SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
8.1 CONTROL PARAMETERS: EXPOSURE LIMITS/GUIDELINES: RESULT ACGIH CANADA ONTARIO CANADA QUEBEC METHANE TWAS 1000 PPM TWA 1000 PPM TWA NOT ESTABLISHED (74-82-8) (LISTED UNDER ALIPHATIC HYDROCARBON GASES: ALKANE C1-4) CARBON CEILINGS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED MONOXIDE (630-08-0) STELS NOT ESTABLISHED NOT ESTABLISHED 200 PPM STEV 230 MG/M3 STEV TWAS 25 PPM TWA 25 PPM TWA 35 PPM TWAEV 40 MG/M3 TWAEV NITROGEN STELS NOT ESTABLISHED 5 PPM STEL NOT ESTABLISHED DIOXIDE (10102-44-0) TWAS 0.2 PPM TWA 3 PPM TWA 3 PPM TWAEV 5.6 MG/M3 TWAEV RESULT CHINA CHINA HIGHLY TOXIC GOODS METHANE TWAS NOT ESTABLISHED NOT ESTABLISHED CARBON CEILINGS 20 MG/M3 CEILING NOT ESTABLISHED MONOXIDE [MAC] (HIGH ALTITUDE AREA, 2000-3000M) 15 MG/M3 CEILING [MAC] (HIGH ALTITUDE AREA, >3000M) STELS 30 MG/M3 STEL (NOT 30 MG/M3 STEL (NOT IN HIGH ALTITUDE AREA) IN HIGH ALTITUDE AREA) TWAS 20 MG/M3 TWA (NOT 20 MG/M3 TWA (NOT IN HIGH ALTITUDE AREA) IN HIGH ALTITUDE AREA) NITROGEN STELS 10 MG/M3 STEL 10 MG/M3 STEL DIOXIDE TWAS 5 MG/M3 TWA 5 MG/M3 TWA RESULT FRANCE GERMANY DFG GERMANY TRGS METHANE TWAS NOT NOT NOT (74-82-8) ESTABLISHED ESTABLISHED ESTABLISHED CARBON TWAS 50 PPM TWA NOT 30 PPM TWA AGW MONOXIDE [VME] ESTABLISHED (THE RISK OF DAMAGE (630-08-0) 55 MG/M3 TWA TO THE EMBRYO OR [VME] FETUS CANNOT BE EXCLUDED EVEN WHEN AGW AND BGW VALUES ARE OBSERVED, EXPOSURE FACTOR 2) 35 MG/M3 TWA AGW (THE RISK OF DAMAGE TO THE EMBRYO OR FETUS CANNOT BE EXCLUDED EVEN WHEN AGW AND BGW VALUES ARE OBSERVED, EXPOSURE FACTOR 2) STELS NOT NOT NOT ESTABLISHED ESTABLISHED ESTABLISHED CEILINGS NOT 60 PPM PEAK NOT ESTABLISHED 70 MG/M3 PEAK ESTABLISHED MAKS NOT 33 PPM TWA NOT ESTABLISHED MAK ESTABLISHED 35 MG/M3 TWA MAK NITROGEN STELS 3 PPM STEL NOT NOT ESTABLISHED DIOXIDE [VLCT] ESTABLISHED (10102-44-0) 6 MG/M3 STEL [VLCT] TWAS NOT NOT NOT ESTABLISHED ESTABLISHED ESTABLISHED CEILINGS NOT 0.5 PPM PEAK NOT ESTABLISHED 0.95 MG/M3 ESTABLISHED PEAK MAKS NOT 0.5 PPM TWA NOT ESTABLISHED MAK ESTABLISHED 0.95 MG/M3 TWA MAK RESULT IRELAND ISRAEL METHANE TWAS 1000 PPM TWA 1000 PPM TWA (GAS, LISTED UNDER ALIPHATIC HYDROCARBON GASES: ALKANE C1-4) CARBON TWAS 20 PPM TWA 25 PPM TWA MONOXIDE 23 MG/M3 TWA STELS 100 PPM STEL NOT ESTABLISHED 115 MG/M3 STEL CEILINGS NOT ESTABLISHED NOT ESTABLISHED MAKS NOT ESTABLISHED NOT ESTABLISHED NITROGEN STELS 5 PPM STEL NOT ESTABLISHED DIOXIDE 9 MG/M3 STEL TWAS 3 PPM TWA 0.2 PPM TWA 5 MG/M3 TWA CEILINGS NOT ESTABLISHED NOT ESTABLISHED MAKS NOT ESTABLISHED NOT ESTABLISHED RESULT NIOSH OSHA PORTUGAL METHANE TWAS NOT ESTABLISHED NOT ESTABLISHED 1000 PPM TWA (74-82-8) [VLE-MP] CARBON TWAS 35 PPM TWA 50 PPM TWA 25 PPM TWA MONOXIDE 40 MG/M3 TWA 55 MG/M3 TWA [VLE-MP] (630-08-0) BIOLOGICAL NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED LIMIT VALUES (BLV) STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED CEILINGS 200 PPM CEILING NOT ESTABLISHED NOT ESTABLISHED 229 MG/M3 CEILING NITROGEN STELS 1 PPM STEL NOT ESTABLISHED 5 PPM STEL DIOXIDE 1.8 MG/M3 STEL [VLE-CD] (10102-44-0) TWAS NOT ESTABLISHED NOT ESTABLISHED 3 PPM TWA [VLE-MP] CEILINGS NOT ESTABLISHED 5 PPM CEILING NOT ESTABLISHED 9 MG/M3 CEILING RESULT SPAIN SWEDEN METHANE TWAS 1000 PPM TWA [VLA-ED] NOT ESTABLISHED CARBON TWAS 25 PPM TWA [VLA-ED] 20 PPM LLV (REGULATED MONOXIDE 29 MG/M3 TWA [VLA-ED] UNDER EXHAUST FUMES, LISTED UNDER EXHAUST FUMES) 25 MG/M3 LLV (REGULATED UNDER EXHAUST FUMES, LISTED UNDER EXHAUST FUMES) 35 PPM LLV 40 MG/M3 LLV BIOLOGICAL 3.5% OF NOT ESTABLISHED LIMIT CARBOXYHEMOGLOBIN IN VALUES TOTAL HEMOGLOBIN BLOOD (BLV) END OF SHIFT CARBOXYHEMOGLOBIN (2,F,I); 20 PPM ALVEOLAR AIR END OF SHIFT CO END-CUT OF EXHALED AIR (2,F,I) STELS NOT ESTABLISHED 100 PPM STV 120 MG/M3 STV CEILINGS NOT ESTABLISHED NOT ESTABLISHED NITROGEN STELS 5 PPM STEL [VLA-EC] NOT ESTABLISHED DIOXIDE 9.6 MG/M3 STEL [VLA-EC] TWAS 3 PPM TWA [VLA-ED] 1 PPM LLV (LISTED UNDER 5.7 MG/M3 TWA [VLA-ED] EXHAUSTED GASSES) 2 MG/M3 LLV (LISTED UNDER EXHAUSTED GASSES) 2 PPM LLV (AS NITROGEN OXIDE) 4 MG/M3 LLV (AS NITROGEN OXIDE) CEILINGS NOT ESTABLISHED 5 PPM CLV 10 MG/M3 CLV EXPOSURE CONTROL NOTATIONS: PORTUGAL: NITROGEN DIOXIDE (10102-44-0): CARCINOGENS: (A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN) NITROGEN (7727-37-9): SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT) FRANCE: CARBON MONOXIDE (630-08-0): REPRODUCTIVE TOXINS: (REPRODUCTIVE TOXIN CATEGORY 1) IRELAND: CARBON MONOXIDE (630-08-0): SUBSTANCES WITH POTENTIAL CHRONIC HEALTH EFFECTS: (REPR1A) METHANE (74-82-8): SIMPLE ASPHYXIANTS: (ASPHYXIANT) NITROGEN (7727-37-9): SIMPLE ASPHYXIANTS: (ASPHYXIANT) SPAIN: CARBON MONOXIDE (630-08-0): REPRODUCTIVE TOXINS: (KNOWN REPRODUCTIVE TOXINS WITH CLASSIFICATION FROM HUMAN DATA) NITROGEN (7727-37-9): SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT) SWEDEN: CARBON MONOXIDE (630-08-0): REPRODUCTIVE TOXINS: (CAUSES REPRODUCTIVE DISTURBANCES) GERMANY DFG: NITROGEN DIOXIDE (10102-44-0): CARCINOGENS: (CATEGORY 3B (COULD BE CARCINOGENIC FOR MAN)) PREGNANCY: (CLASSIFICATION NOT YET POSSIBLE) CARBON MONOXIDE (630-08-0): PREGNANCY: (RISK TO EMBRYO/FETUS PROBABLE) 8.2 EXPOSURE CONTROLS: ENGINEERING MEASURES/CONTROLS: GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY: FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE EXPERIENCED. EYE/FACE: WEAR SAFETY GLASSES. SKIN/BODY: WEAR LEATHER GLOVES WHEN HANDLING CYLINDERS. ENVIRONMENTAL EXPOSURE CONTROLS: FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS. KEY TO ABBREVIATIONS: ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE LLV: LIMIT LEVEL VALUE IS THE EXPOSURE LIMIT FOR 8-HOUR WORK DAY MAK: MAXIMALE ARBEITSPLATZ KONZENTRATION IS THE MAXIMUM PERMISSIBLE CONCENTRATION NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION STEL: SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES TWA: TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES TWAEV: TIME-WEIGHTED AVERAGE EXPOSURE VALUE
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES: MATERIAL DESCRIPTION: PHYSICAL FORM: GAS APPEARANCE/DESCRIPTION: COLORLESS GAS WITH A FAINT PUNGENT ODOR. COLOR: COLORLESS ODOR: PUNGENT ODOR THRESHOLD: 0.11 TO 0.14 PPM (NITROGEN DIOXIDE) GENERAL PROPERTIES: BOILING POINT: -195.8 C (-320.44 F) (NITROGEN) MELTING POINT: -210 C (-346 F) (NITROGEN) DECOMPOSITION TEMPERATURE: DATA LACKING PH: NOT RELEVANT SPECIFIC GRAVITY/RELATIVE DENSITY: 0.906 WATER=1 (NITROGEN) DENSITY: 0.072 LB(S)/FT3 @ 0 C (32 F) (NITROGEN) WATER SOLUBILITY: DATA LACKING VISCOSITY: DATA LACKING EXPLOSIVE PROPERTIES: DATA LACKING OXIDIZING PROPERTIES: DATA LACKING VOLATILITY: VAPOR PRESSURE: DATA LACKING VAPOR DENSITY: DATA LACKING EVAPORATION RATE: DATA LACKING FLAMMABILITY: FLASH POINT: NOT RELEVANT UEL: NOT RELEVANT LEL: NOT RELEVANT AUTOIGNITION: DATA LACKING FLAMMABILITY (SOLID, GAS): NONFLAMMABLE GAS. ENVIRONMENTAL: OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING 9.2 OTHER INFORMATION: NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
10.1 REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE. 10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION WILL NOT OCCUR. 10.4 CONDITIONS TO AVOID: EXCESS HEAT. 10.5 INCOMPATIBLE MATERIALS: NITROGEN REACTS WITH Li, ND, AND Ti AT HIGH TEMPERATURES. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS: UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION PRODUCTS SHOULD NOT BE PRODUCED.
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS: COMPONENTS: NITROGEN DIOXIDE (0.001% TO 0.022%) 10102-44-0: ACUTE TOXICITY: INHALATION-RAT LC50: 88 PPM 4 HOUR(S) MUTAGEN: UNSCHEDULED DNA SYNTHESIS: INHALATION-RAT: 30 PPM 1 HOUR(S) CYTOGENETIC ANALYSIS: INHALATION-RAT: 27 PPM 3 HOUR(S)-CONTINUOUS MUTATION IN MAMMALIAN SOMATIC CELLS: INHALATION-RAT: 15 PPM 3 HOUR(S)-CONTINUOUS DNA ADDUCT: INHALATION-RAT: 108 MG/KG 300 DAY(S)-INTERMITTENT CARBON MONOXIDE (0.0005% TO 1%) 630-08-0: ACUTE TOXICITY: INHALATION-RAT LC50: 1807 PPM 4 HOUR(S) REPRODUCTIVE: INHALATION-RAT TCLO: 150 PPM (0-20D PREG) REPRODUCTIVE EFFECTS: MATERNAL EFFECTS: OTHER EFFECTS REPRODUCTIVE EFFECTS: EFFECTS ON NEWBORN: BIOCHEMICAL AND METABOLIC REPRODUCTIVE EFFECTS: EFFECTS ON NEWBORN: PHYSICAL OXYGEN (0% TO 23.5%) 7782-44-7: REPRODUCTIVE: INHALATION-RAT TCLO: 10 PPH 9 HOUR(S)(22D PREG) REPRODUCTIVE EFFECTS: SPECIFIC DEVELOPMENTAL ABNORMALITIES: RESPIRATORY SYSTEM REPRODUCTIVE EFFECTS: EFFECTS ON NEWBORN: PHYSICAL GHS PROPERTIES CLASSIFICATION ACUTE TOXICITY EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING ASPIRATION HAZARD EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING CARCINOGENICITY EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING GERM CELL MUTAGENICITY EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING SKIN CORROSION/IRRITATION EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING SKIN SENSITIZATION EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING STOT-RE EU/CLP: SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 2 OSHA HCS 2012: DATA LACKING STOT-SE EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING TOXICITY FOR REPRODUCTION EU/CLP: TOXIC TO REPRODUCTION 1A OSHA HCS 2012: TOXIC TO REPRODUCTION 1A RESPIRATORY SENSITIZATION EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING SERIOUS EYE DAMAGE/IRRITATION EU/CLP: DATA LACKING OSHA HCS 2012: DATA LACKING ROUTE(S) OF ENTRY/EXPOSURE: INHALATION, SKIN, EYE POTENTIAL HEALTH EFFECTS: INHALATION: ACUTE (IMMEDIATE): THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. IF THIS MATERIAL IS RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN ENCLOSED OR CONFINED SPACE), AN OXYGEN-DEFICIENT ENVIRONMENT MAY OCCUR. INDIVIDUALS BREATHING SUCH AN ATMOSPHERE MAY EXPERIENCE SYMPTOMS WHICH INCLUDE HEADACHES, RINGING IN EARS, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS, NAUSEA, VOMITING, AND DEPRESSION OF ALL THE SENSES. UNDER SOME CIRCUMSTANCES OF OVER-EXPOSURE, DEATH MAY OCCUR. THE FOLLOWING EFFECTS ASSOCIATED WITH DECREASED LEVELS OF OXYGEN: INCREASE IN BREATHING AND PULSE RATE, EMOTIONAL UPSET, ABNORMAL FATIGUE, NAUSEA, VOMITING, COLLAPSE, LOSS OF CONSCIOUSNESS, CONVULSIVE MOVEMENTS, RESPIRATORY COLLAPSE AND DEATH. CHRONIC (DELAYED): NO DATA AVAILABLE SKIN: ACUTE (IMMEDIATE): UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED. CHRONIC (DELAYED): NO DATA AVAILABLE EYE: ACUTE (IMMEDIATE): UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED. CHRONIC (DELAYED): NO DATA AVAILABLE INGESTION: ACUTE (IMMEDIATE): INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS PRODUCT. CHRONIC (DELAYED): INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS PRODUCT. OTHER: CHRONIC (DELAYED): MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. THE TRANSPORT OF OXYGEN IN BLOOD ENSURED BY HAEMOGLOBIN WILL BE SLOWED DOWN BECAUSE CARBOXYHAEMOGLOBIN INSTEAD OF OXYHAEMOGLOBIN WILL BE FORMED IN LUNGS. THE AFFINITY OF HEAMOGLOBIN FOR CARBON MONOXIDE IS 200 TO 300 HIGHER THEN FOR OXYGEN. ALL RELATED HEALTH HAZARDS WILL BE CAUSED BY SLOW RESPIRATION OF CELLS WHICH WILL DAMAGE THE CENTRAL NERVOUS SYSTEM, COLLAPSE THE CARDIOVASCULAR SYSTEM, CAUSE KIDNEY INSUFFICIENCY, COMA, ETC. REPRODUCTIVE EFFECTS: THE CARBON MONOXIDE COMPONENT OF THIS GAS MIXTURE CAN CAUSE TERATOGENIC EFFECTS IN HUMANS. SEVERE EXPOSURE TO CARBON MONOXIDE DURING PREGNANCY HAS CAUSED ADVERSE EFFECTS AND THE DEATH OF THE FETUS. IN GENERAL, MATERNAL SYMPTOMS ARE AN INDICATOR OF THE POTENTIAL RISK TO THE FETUS SINCE CARBON MONOXIDE IS TOXIC TO THE MOTHER BEFORE IT IS TOXIC TO THE FETUS. KEY TO ABBREVIATIONS: LC = LETHAL CONCENTRATION TC = TOXIC CONCENTRATION
12.1 TOXICITY: MATERIAL DATA LACKING. 12.2 PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING. 12.3 BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING. 12.4 MOBILITY IN SOIL: MATERIAL DATA LACKING. 12.5 RESULTS OF PBT AND VPVB ASSESSMENT: PBT AND VPVB ASSESSMENT HAS NOT BEEN CONDUCTED FOR THIS MATERIAL. 12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
13.1 WASTE TREATMENT METHODS: PRODUCT WASTE: DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, AND/OR INTERNATIONAL REGULATIONS. PACKAGING WASTE: DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
14.1 UN 14.2 UN 14.3 14.4 14.5 NUMBER PROPER SHIPPING TRANSPORT PACKING ENVIRONMENTAL NAME HAZARD GROUP HAZARDS CLASS(ES) DOT UN1956 COMPRESSED GASES, 2.2 NDA NDA N.O.S. (NITROGEN, OXYGEN, CARBON MONOXIDE) TDG UN1956 COMPRESSED GASES, 2.2 NDA NDA N.O.S. (NITROGEN, OXYGEN, CARBON MONOXIDE) IMO/IMDG UN1956 COMPRESSED GASES, 2.2 NDA NDA N.O.S. (NITROGEN, OXYGEN, CARBON MONOXIDE) IATA/ICAO UN1956 COMPRESSED GASES, 2.2 NDA NDA N.O.S. (NITROGEN, OXYGEN, CARBON MONOXIDE) 14.6 SPECIAL PRECAUTIONS FOR USER: CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES OR IN CLOSED-BODY VEHICLES CAN PRESENT SERIOUS SAFETY HAZARDS. IF TRANSPORTING THESE CYLINDERS IN VEHICLES, ENSURE THESE CYLINDERS ARE NOT EXPOSED TO EXTREMELY HIGH TEMPERATURES (AS MAY OCCUR IN AN ENCLOSED VEHICLE ON A HOT DAY). ADDITIONALLY, THE VEHICLE SHOULD BE WELL-VENTILATED DURING TRANSPORTATION. 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE: DATA LACKING.
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: SARA HAZARD CLASSIFICATIONS: ACUTE, CHRONIC, PRESSURE (SUDDEN RELEASE OF) STATE RIGHT TO KNOW: COMPONENT CAS MA NJ PA CARBON MONOXIDE 630-08-0 YES YES YES METHANE 74-82-8 YES YES YES NITROGEN 7727-37-9 YES YES YES NITROGEN DIOXIDE 10102-44-0 YES YES YES OXYGEN 7782-44-7 YES YES YES INVENTORY: COMPONENT CAS CANADA CANADA CHINA EU EINECS EU ELNICS DSL NDSL CARBON MONOXIDE 630-08-0 YES NO YES YES NO METHANE 74-82-8 YES NO YES YES NO NITROGEN 7727-37-9 YES NO YES YES NO NITROGEN DIOXIDE 10102-44-0 YES NO YES YES NO OXYGEN 7782-44-7 YES NO YES YES NO COMPONENT CAS TSCA CARBON MONOXIDE 630-08-0 YES METHANE 74-82-8 YES NITROGEN 7727-37-9 YES NITROGEN DIOXIDE 10102-44-0 YES OXYGEN 7782-44-7 YES CANADA: LABOR: CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES: CARBON MONOXIDE 630-08-0 A, B1, D1A, D2A OXYGEN 7782-44-7 A, C NITROGEN DIOXIDE 10102-44-0 A, C, D1A, D2B, E NITROGEN 7727-37-9 A METHANE 74-82-8 A, B1 CANADA - WHMIS - INGREDIENT DISCLOSURE LIST: CARBON MONOXIDE 630-08-0 0.1% OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 1% NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED ENVIRONMENT: CANADA - 2004 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY): CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CANADA - 2005 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY): CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CANADA - CEPA - GREENHOUSE GASES SUBJECT TO MANDATORY REPORTING: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 21 GWP CANADA - CEPA - PRIORITY SUBSTANCES LIST: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CANADA - DWQ (DRINKING WATER QUALITY) - IMACS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED OTHER: CANADA - ACCELERATED REDUCTION/ELIMINATION OF TOXICS (ARET): CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CANADA NEW BRUNSWICK: ENVIRONMENT: CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE A: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE B: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CHINA: ENVIRONMENT: CHINA - OZONE DEPLETING SUBSTANCES - FIRST SCHEDULE: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CHINA - OZONE DEPLETING SUBSTANCES - SECOND SCHEDULE: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CHINA - OZONE DEPLETING SUBSTANCES - THIRD SCHEDULE: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED OTHER: CHINA - ANNEX I & II - CONTROLLED CHEMICALS LISTS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED CHINA - DANGEROUS GOODS LIST: CARBON MONOXIDE 630-08-0 OXYGEN 7782-44-7 (COMPRESSED OR REFRIGERATED LIQUID) NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 (COMPRESSED OR REFRIGERATED LIQUID) METHANE 74-82-8 (COMPRESSED OR REFRIGERATED LIQUID) CHINA - EXPORT CONTROL LIST - PART I CHEMICALS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED EUROPE: OTHER: EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CLASSIFICATION: CARBON MONOXIDE 630-08-0 F+; R12 T; R23-48/23 REPR. CAT. 1; R61 OXYGEN 7782-44-7 O; R8 NITROGEN DIOXIDE 10102-44-0 T+; R26 C; R34 O; R8 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 F+; R12 EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CONCENTRATION LIMITS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 10%<=C: T+ R: 26 1% <=C<10%: T R: 23 0.1% <=C<1%: XN R: 20 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - LABELLING: CARBON MONOXIDE 630-08-0 F+ T R: 61-12-23-48/23 S: 53-45 OXYGEN 7782-44-7 O R: 8 S: (2)-17 NITROGEN DIOXIDE 10102-44-0 O T+ R: 8-26-34 S: (1/2)-9-26-28-36/37/39-45 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 F+ R: 12 S: (2)-9-16-33 EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - NOTES - SUBSTANCES AND PREPARATIONS: CARBON MONOXIDE 630-08-0 E OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 5 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - SAFETY PHRASES: CARBON MONOXIDE 630-08-0 S: 53-45 OXYGEN 7782-44-7 S: (2)-17 NITROGEN DIOXIDE 10102-44-0 S: (1/2)-9-26-28-36/37/39-45 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 S: (2)-9-16-33 GERMANY: ENVIRONMENT: GERMANY - TA LUFT - TYPES AND CLASSES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 INORGANIC GAS SUBSTANCE: 5.2.4, CLASS IV NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 1: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 ID NUMBER 743, NOT CONSIDERED HAZARDOUS TO WATER NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 ID NUMBER 1351, NOT CONSIDERED HAZARDOUS TO WATER METHANE 74-82-8 ID NUMBER 1343, NOT CONSIDERED HAZARDOUS TO WATER GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 2 - WATER HAZARD CLASSES: CARBON MONOXIDE 630-08-0 ID NUMBER 257, HAZARD CLASS 1 - LOW HAZARD TO WATERS OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 ID NUMBER 285, HAZARD CLASS 1 - LOW HAZARD TO WATERS NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 3: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED OTHER: GERMANY - SPECIFICALLY REGULATED CHEMICALS IN TRGS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED PORTUGAL: OTHER: PORTUGAL - PROHIBITED SUBSTANCES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED UNITED KINGDOM: ENVIRONMENT: UNITED KINGDOM - POLLUTION INVENTORY - SCHEDULE 1 - THRESHOLDS FOR RELEASES TO AIR: CARBON MONOXIDE 630-08-0 100000 KG OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 10000 KG UNITED KINGDOM - SUBSTANCES CONTAINED IN DANGEROUS SUBSTANCES OR PREPARATIONS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED OTHER: UNITED KINGDOM - WORKPLACE EXPOSURE LIMITS (WELS) - SUBSTANCES IN REVIEW: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED UNITED KINGDOM - LIST OF DANGEROUS SUBSTANCES IN WATER: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED UNITED STATES: LABOR: U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 250 LB TQ NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED ENVIRONMENT: U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 10 LB FINAL RQ (RELEASES TO THE AIR IN AMOUNTS <1000 POUNDS PER 24 HOURS WHICH ARE THE RESULT OF COMBUSTION AND COMBUSTION-RELATED ACTIVITIES ARE EXEMPT FROM THE NOTIFICATION REQUIREMENTS PER 40 CFR 302.6) 4.54 KG FINAL RQ (RELEASES TO THE AIR IN AMOUNTS <1000 POUNDS PER 24 HOURS WHICH ARE THE RESULT OF COMBUSTION AND COMBUSTION RELATED ACTIVITIES ARE EXEMPT FROM THE NOTIFICATION REQUIREMENTS PER 40 CFR 302.6) NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 10 LB EPCRA RQ (RELEASES TO THE AIR IN AMOUNTS <1000 POUNDS PER 24 HOURS WHICH ARE THE RESULT OF COMBUSTION AND COMBUSTION-RELATED ACTIVITIES ARE EXEMPT FROM THE NOTIFICATION REQUIREMENTS PER 40 CFR 355.31) NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 100 LB TPQ NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - HAZARDOUS CONSTITUENTS - APPENDIX VIII TO 40 CFR 261: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 WASTE NUMBER P078 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - P SERIES WASTES - ACUTELY TOXIC WASTES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 WASTE NUMBER P078 NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED UNITED STATES - CALIFORNIA: ENVIRONMENT: U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: CARBON MONOXIDE 630-08-0 DEVELOPMENTAL TOXICITY, INITIAL DATE 7/1/89 OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL): CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL): CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED UNITED STATES - PENNSYLVANIA: LABOR: U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST: CARBON MONOXIDE 630-08-0 OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 (LISTED UNDER NITROGEN OXIDE) NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - SPECIAL HAZARDOUS SUBSTANCES: CARBON MONOXIDE 630-08-0 NOT LISTED OXYGEN 7782-44-7 NOT LISTED NITROGEN DIOXIDE 10102-44-0 NOT LISTED NITROGEN 7727-37-9 NOT LISTED METHANE 74-82-8 NOT LISTED 15.2 CHEMICAL SAFETY ASSESSMENT: NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT. 15.3 OTHER INFORMATION: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
RELEVANT PHRASES (CODE & FULL TEXT): H220: EXTREMELY FLAMMABLE GAS H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. H330: FATAL IF INHALED H331: TOXIC IF INHALED H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. R12: EXTREMELY FLAMMABLE. R23: TOXIC BY INHALATION. R26: VERY TOXIC BY INHALATION. R34: CAUSES BURNS. R48/23: TOXIC: DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH INHALATION. LAST REVISION DATE: 05/SEPTEMBER/2014 PREPARATION DATE: 05/SEPTEMBER/2014 DISCLAIMER/STATEMENT OF LIABILITY: TO THE BEST OF AIR LIQUIDE'S KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS RELIABLE AND ACCURATE AS OF THIS DATE; HOWEVER, ACCURACY, SUITABILITY OR COMPLETENESS ARE NOT GUARANTEED AND NO WARRANTIES OF ANY TYPE, EITHER EXPRESS OR IMPLIED, ARE PROVIDED. THE INFORMATION CONTAINED HEREIN RELATES ONLY TO THIS SPECIFIC PRODUCT. IF THIS GAS MIXTURE IS COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED FROM TIME TO TIME. BE SURE TO CONSULT THE LATEST EDITION. KEY TO ABBREVIATIONS: NDA = NO DATA AVAILABLE REVISION DATE: 05/SEPTEMBER/2014 FORMAT: EU CLP/REACH LANGUAGE: ENGLISH (US) WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 |