| Common Name: | PREMIUM POLYURETHANE CONSTRUCTION ADHESIVE SEALANT - WHITE |
| Manufacturer: | DAP |
| SDS Revision Date: | 6/19/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20VK37 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SDS NUMBER: 00077348004
REVISION DATE: 6/19/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS:
MEDICAL/POISON CONTROL:
IN U.S.:
CALL: 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSE CENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE EVENT
OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT. THIS
PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND THIS
DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER DESCRIBED IN
SECTION 16.
| 1. IDENTIFICATION |  |
THIS SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON REQUEST.
PRODUCT NAME: PREMIUM POLYURETHANE CONSTRUCTION ADHESIVE SEALANT - WHITE
PRODUCT UPC NUMBER: 18810
PRODUCT USE/CLASS: CAULKING COMPOUND
REVISION DATE: 6/19/2015
SUPERCEDES DATE: NEW SDS
SDS NO: 00077348004
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET
SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
MAY CAUSE NAUSEA, HEADACHES, AND DIZZINESS. MAY CAUSE EYE, SKIN, NOSE,
THROAT AND RESPIRATORY TRACT IRRITATION. USE ONLY WITH ADEQUATE
VENTILATION. PREVENT BUILD-UP OF VAPORS BY OPENING ALL WINDOWS AND DOORS TO
ACHIEVE CROSS-VENTILATION. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN
CONTACT. THE PRIMARY ADVERSE HEALTH EFFECTS OF THIS PRODUCT ARE RELATED TO
THE POLYMERIC ISOCYANATE (MDI) COMPONENT. THEREFORE, ADEQUATE VENTILATION
SHOULD BE PROVIDED TO AVOID EXCEEDING THE EXPOSURE LIMITS OF THESE
COMPONENTS (SEE SECTION 8). THE LIKELIHOOD OF EXCEEDING THESE LIMITS ARE
LOW DUE TO THE LOW CONCENTRATION OF VAPOR PRODUCED DURING NORMAL USE.
HOWEVER, IF USED INDOORS, MECHANICAL VENTILATION OR EXHAUST SHOULD BE
PROVIDED DURING USE AND UNTIL PRODUCT IS CURED. THIS PRODUCT HAS STRONG
ADHESIVE-LIKE CHARACTERISTICS AND WILL ADHERE AGGRESSIVELY TO SKIN AND
OTHER SURFACES. IF ACCIDENTAL CONTACT OCCURS, FOLLOW THE APPROPRIATE
FIRST-AID PROCEDURE DESCRIBED IN SECTION 4 OF THIS MSDS.
GHS CLASSIFICATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
SYMBOL(S) OF PRODUCT: NONE
SIGNAL WORD: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. % GHS SYMBOLS GHS STATEMENTS
XYLENES 1330-20-7 1.0-2.5 GHS02-GHS03- H226-270-312-
GHS07 315-332
TITANIUM DIOXIDE 13463-67-7 1.0-2.5 NO INFORMATION NO INFORMATION
CARBON BLACK 1333-86-4 1.0-2.5 NO INFORMATION NO INFORMATION
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: 465 <UNDEFINED>
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. IN CASE OF
SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN ACCORDANCE WITH
APPLICABLE REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. AVOID BREATHING VAPOR AND CONTACT WITH EYES, SKIN
AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. ENSURE FRESH AIR ENTRY
DURING APPLICATION AND DRYING. WASH THOROUGHLY AFTER HANDLING. CONTAINS
ISOCYANATES. SEE INFORMATION SUPPLIED BY THE MANUFACTURER. PERSONS ALLERGIC
TO ISOCYANATES, AND PARTICULARLY THOSE SUFFERING FROM ASTHMA OR OTHER
RESPIRATORY CONDITIONS, SHOULD NOT WORK WITH ISOCYANATES.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH ACGIH-TLV OSHA OSHA
TLV-TWA STEL PEL-TWA PEL-CEILING
XYLENES 100 PPM TWA 150 PPM STEL 100 PPM TWA, N.E.
435 MG/M3 TWA
CARBON BLACK 3 MG/M3 TWA N.E. 3.5 MG/M3 TWA N.E.
INHALABLE
FRACTION
TITANIUM DIOXIDE 10 MG/M3 TWA N.E. 15 MG/M3 TWA N.E.
TOTAL DUST
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. IF
CONCENTRATIONS EXCEED THE EXPOSURE LIMITS SPECIFIED, USE OF A
NIOSH-APPROVED SUPPLIED AIR RESPIRATOR IS RECOMMENDED. WHERE THE PROTECTION
FACTOR IS EXCEEDED, USE OF A SELF CONTAINED BREATHING APPARATUS (SCBA) MAY
BE NECESSARY. A RESPIRATORY PROTECTION PROGRAM THAT MEETS THE OSHA 1910.134
AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE.
SKIN PROTECTION: WEAR SOLVENT IMPERVIOUS GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT:
PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF BODY CONTACT MAY OCCUR.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: WHITE TO OFF-WHITE
PHYSICAL STATE: PASTE
ODOR: SLIGHT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 1.40 - 1.40
PH: NOT ESTABLISHED
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: N.I. - N.I.
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 93.3
VAPOR PRESSURE, MMHg: NO INFORMATION
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
FLAMMABILITY: NO INFORMATION
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: INCOMPATIBLE WITH STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
VAPORS MAY BE IRRITATING TO EYES, NOSE, THROAT, AND LUNGS. INHALATION OF
HIGH CONCENTRATIONS MAY CAUSE HEADACHE, NAUSEA, AND DIZZINESS.
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
MAY CAUSE SENSITIZATION BY SKIN CONTACT. MAY CAUSE LOCALIZED IRRITATION,
REDDENING OR SWELLING. PROLONGED OR REPEATED EXPOSURE MAY LEAD TO
SENSITIZATION AND/OR CONTACT DERMATITIS. THIS PRODUCT HAS STRONG
ADHESIVE-LIKE CHARACTERISTICS AND WILL ADHERE AGGRESSIVELY TO SKIN AND
OTHER SURFACES. IF ACCIDENTAL CONTACT OCCURS, FOLLOW THE APPROPRIATE
FIRST-AID PROCEDURE DESCRIBED IN SECTION 4 OF THIS MSDS.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
DIRECT EYE CONTACT MAY CAUSE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: NO INFORMATION
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
1330-20-7 XYLENES 4300 MG/KG 1700 MG/KG 47635 MG/L
RAT RABBIT RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
1333-86-4 CARBON BLACK >8000 MG/KG >3000 MG/KG 6.750 MG/M3
RAT RABBIT RAT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NO INFORMATION
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING TO
U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261. DISPOSE
AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND PROVINCIAL
REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE COMPLEX AND MAY
DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER WASTE DISPOSAL
IS WITH THE OWNER OF THE WASTE. LIQUIDS CANNOT BE DISPOSED OF IN A
LANDFILL.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED.
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9
XYLENES 1330-20-7
ETHYL BENEZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPORODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65: NO INFORMATION
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: CONSUMER COMMODITY
| 16. OTHER INFORMATION | |
REVISION DATE: 6/19/2015
SUPERSEDES DATE: NEW MSDS
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 1
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 35.7
VOC MATERIAL, G/L: 36
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 2.6
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H226: FLAMMABLE LIQUID AND VAPOUR.
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H332: HARMFUL IF INHALED.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS03: FLAME OVER CIRCLE
GHS07: EXCLAMATION MARK
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THIS DOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.