| Common Name: | PYROIL NON-CHLORINATED BRAKE PARTS CLEANER |
| Manufacturer: | NITEO PRODUCTS |
| SDS Revision Date: | 6/7/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 21A052 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NITEO(TM) PRODUCTS
SAFETY DATA SHEET
PYROIL(TM) NON-CHLORINATED BRAKE PARTS CLEANER
VERSION: 1.2
REVISION DATE: 06/07/2017
SDS NUMBER: 600000000466
DATE OF LAST ISSUE: 09/26/2016
DATE OF FIRST ISSUE: 05/23/2016
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: PYROIL(TM) NON-CHLORINATED BRAKE PARTS CLEANER
PRODUCT CODE: PY4003
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: NITEO PRODUCTS, LLC
ADDRESS: DALLAS TX 19162
TELEPHONE: 1-844-696-4836
EMERGENCY TELEPHONE NUMBER: 1-800-424-9300
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: BRAKE PARTS CLEANER
RESTRICTIONS ON USE: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE AEROSOLS: CATEGORY 1
ACUTE TOXICITY (ORAL): CATEGORY 4
ACUTE TOXICITY (INHALATION): CATEGORY 4
ACUTE TOXICITY (DERMAL): CATEGORY 4
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM, EYES)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (CENTRAL NERVOUS SYSTEM)
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (INHALATION):
CATEGORY 2 (NEUROLOGIC: OTHER (NEUROPSYCHOLOGICAL EFFECTS, AUDI-TORY
DYSFUNCTION AND EFFECTS ON COLOR VISION))
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H302 + H312 + H332:
HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
H370: CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
H373:
MAY CAUSE DAMAGE TO ORGANS (NEUROLOGIC: OTHER (NEUROPSYCHOLOGICAL EFFECTS,
AUDITORY DYSFUNCTION AND EFFECTS ON COLOR VISION)) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301 + P312 + P330:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
P302 + P352 + P312:
IF ON SKIN:
WASH WITH PLENTY OF WATER. CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P307 + P311:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
P403 + P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P410 + P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG.
C/122 DEG. F.
DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION
(% W/W)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8 >=30 - <50
METHANOL 67-56-1 >=20 - <30
ACETONE 67-64-1 >=20 - <30
TOLUENE 108-88-3 >=5 - <10
CARBON DIOXIDE 124-38-9 >=5 - <10
N-HEPTANE 142-82-5 >=1 - <5
THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CONSULT A PHYSICIAN.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
IF ON CLOTHES, REMOVE CLOTHES.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
CALL A PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
KEEP EYE WIDE OPEN WHILE RINSING.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
GET MEDICAL ATTENTION IMMEDIATELY.
RINSE MOUTH WITH WATER.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
INHALED.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
CARBON DIOXIDE (CO2)
DRY CHEMICAL
ALCOHOL-RESISTANT FOAM
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIRE-FIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
BURNING PRODUCES NOXIOUS AND TOXIC FUMES.
CARBON MONOXIDE, CARBON DIOXIDE AND UNBURNED HYDROCARBONS (SMOKE).
NO HAZARDOUS COMBUSTION PRODUCTS ARE KNOWN
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS.
USE A WATER SPRAY TO COOL FULLY CLOSED CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
REMOVE ALL SOURCES OF IGNITION.
ENSURE ADEQUATE VENTILATION.
AVOID BREATHING DUST.
BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE CONCENTRATIONS. VAPOURS
CAN ACCUMULATE IN LOW AREAS.
EVACUATE PERSONNEL TO SAFE AREAS.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
COMPLY WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT PRODUCT FROM ENTERING DRAINS.
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
VENTILATE THE AREA.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
TAKE NECESSARY ACTION TO AVOID STATIC ELECTRICITY DISCHARGE (WHICH MIGHT
CAUSE IGNITION OF ORGANIC VAPOURS). KEEP AWAY FROM OPEN FLAMES, HOT
SURFACES AND SOURCES OF IGNITION. USE ONLY EXPLOSION-PROOF EQUIPMENT. DO
NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
ADVICE ON SAFE HANDLING:
OPEN DRUM CAREFULLY AS CONTENT MAY BE UNDER PRESSURE.
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS.
DO NOT SMOKE.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
AVOID CONTACT WITH SKIN AND EYES.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONTAINER HAZARDOUS WHEN EMPTY.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DO NOT BREATHE VAPOURS OR SPRAY MIST.
CONDITIONS FOR SAFE STORAGE:
BEWARE:
AEROSOL IS PRESSURIZED. KEEP AWAY FROM DIRECT SUN EXPOSURE AND TEMPERATURES
OVER 50 DEG. C. DO NOT OPEN BY FORCE OR THROW INTO FIRE EVEN AFTER USE. DO
NOT SPRAY ON FLAMES OR RED-HOT OBJECTS.
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
OBSERVE LABEL PRECAUTIONS.
NO SMOKING.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
METHANOL 67-56-1 TWA 200 PPM ACGIH
STEL 250 PPM ACGIH
TWA 200 PPM NIOSH REL
260 MG/M3
ST 250 PPM NIOSH REL
325 MG/M3
TWA 200 PPM OSHA Z-1
260 MG/M3
STEL 250 PPM OSHA P0
325 MG/M3
TWA 200 PPM OSHA P0
260 MG/M3
ACETONE 67-64-1 TWA 250 PPM ACGIH
STEL 500 PPM ACGIH
TWA 250 PPM NIOSH REL
590 MG/M3
TWA 1,000 PPM OSHA Z-1
2,400 MG/M3
TWA 750 PPM OSHA P0
1,800 MG/M3
STEL 1,000 PPM OSHA P0
2,400 MG/M3
TOLUENE 108-88-3 TWA 20 PPM ACGIH
TWA 100 PPM NIOSH REL
375 MG/M3
ST 150 PPM NIOSH REL
560 MG/M3
TWA 200 PPM OSHA Z-2
CEIL 300 PPM OSHA Z-2
PEAK 500 PPM OSHA Z-2
(10 MINUTES)
TWA 100 PPM OSHA P0
375 MG/M3
STEL 150 PPM OSHA P0
560 MG/M3
CARBON 124-38-9 TWA 5,000 PPM ACGIH
DIOXIDE
STEL 30,000 PPM ACGIH
TWA 5,000 PPM NIOSH REL
9,000 MG/M3
ST 30,000 PPM NIOSH REL
54,000 MG/M3
TWA 5,000 PPM OSHA Z-1
9,000 MG/M3
TWA 10,000 PPM OSHA P0
18,000 MG/M3
STEL 30,000 PPM OSHA P0
54,000 MG/M3
N-HEPTANE 142-82-5 TWA 85 PPM NIOSH REL
350 MG/M3
C 440 PPM NIOSH REL
1,800 MG/M3
TWA 500 PPM OSHA Z-1
2,000 MG/M3
TWA 400 PPM OSHA P0
1,600 MG/M3
STEL 500 PPM OSHA P0
2,000 MG/M3
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO.
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. CONTROL PARAMETERS BIOLOGICAL SPECIMEN
METHANOL 67-56-1 METHANOL URINE
ACETONE 67-64-1 ACETONE URINE
TOLUENE 108-88-3 TOLUENE IN BLOOD
TOLUENE URINE
O-CRESOL URINE
COMPONENTS SAMPLING TIME PERMISSIBLE BASIS
CONCENTRATION
METHANOL END OF SHIFT (AS SOON AS POSSIBLE 15 MG/L ACGIH BEI
AFTER EXPOSURE CEASES)
ACETONE END OF SHIFT (AS SOON AS POSSIBLE 25 MG/L ACGIH BEI
AFTER EXPOSURE CEASES)
TOLUENE PRIOR TO LAST SHIFT OF WORK-WEEK 0.02 MG/L ACGIH BEI
END OF SHIFT (AS SOON AS POSSIBLE 0.03 MG/L ACGIH BEI
AFTER EXPOSURE CEASES)
END OF SHIFT (AS SOON AS POSSIBLE 0.3 MG/G ACGIH BEI
AFTER EXPOSURE CEASES) CREATININE
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS
THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
USE NIOSH APPROVED RESPIRATORY PROTECTION.
HAND PROTECTION:
REMARKS:
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER). THE
SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE PRODUCERS
OF THE PROTECTIVE GLOVES. DISCARD GLOVES THAT SHOW TEARS, PINHOLES, OR
SIGNS OF WEAR.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
FLAME-RESISTANT CLOTHING
SAFETY SHOES
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE.
PROTECTIVE MEASURES:
WHEN USING DO NOT EAT, DRINK OR SMOKE.
AVOID CONTACT WITH SKIN.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOL
ODOUR: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
FLASH POINT: -6.7 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
DENSITY: 0.8057 G/CM3 (15.56 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
ACIDS
BASES
ALUMINIUM
AMINES
AMMONIA
HALOGENS
LEAD
PEROXIDES
REDUCING AGENTS
STRONG BASES
STRONG OXIDIZING AGENTS
ZINC
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
EYE CONTACT
SKIN CONTACT
ACUTE TOXICITY: HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 362.47 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 10.87 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
METHOD: CALCULATION METHOD
ACUTE DERMAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 1,088 MG/KG
METHOD: CALCULATION METHOD
COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
ACUTE ORAL TOXICITY:
LD50 (RAT): >8,000 MG/KG
METHANOL:
ACUTE ORAL TOXICITY:
LDLO (HUMANS): 300 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE INGESTION.
ACUTE INHALATION TOXICITY:
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SHORT TERM INHALATION.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 12,800 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE CONTACT WITH SKIN.
ACETONE:
ACUTE ORAL TOXICITY:
LD50 (RAT, FEMALE): 5,800 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT, FEMALE): 76 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >7,426 MG/KG
TOLUENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 8000 PPM
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 12,124 MG/KG
N-HEPTANE:
ACUTE ORAL TOXICITY:
LD50 (RAT): EXPECTED >5,000 MG/KG
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
ACUTE INHALATION TOXICITY:
LC50 (RAT, MALE AND FEMALE): >29.29 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
METHOD: OECD TEST GUIDELINE 403
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): EXPECTED >2,000 MG/KG
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE DERMAL TOXICITY TESTS.
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PRODUCT:
RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
REMARKS: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
RESULT: POSSIBLY IRRITATING TO SKIN
METHANOL:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
ACETONE:
RESULT: POSSIBLY IRRITATING TO SKIN
RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
TOLUENE:
RESULT: IRRITATING TO SKIN.
CARBON DIOXIDE:
ASSESSMENT: NO SKIN IRRITATION
RESULT: NO SKIN IRRITATION
N-HEPTANE:
RESULT: IRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.
CAUSES SERIOUS EYE IRRITATION.
COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
RESULT: POSSIBLY IRRITATING TO EYES
METHANOL:
SPECIES: RABBIT
RESULT: POSSIBLY IRRITATING TO EYES
ACETONE:
RESULT: IRRITATING TO EYES.
ASSESSMENT: IRRITATING TO EYES.
TOLUENE:
RESULT: IRRITATING TO EYES.
CARBON DIOXIDE:
RESULT: NO EYE IRRITATION
N-HEPTANE:
RESULT: POSSIBLY IRRITATING TO EYES
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
METHANOL:
TEST TYPE: MAXIMIZATION TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
METHOD: OECD TEST GUIDELINE 406
N-HEPTANE:
TEST TYPE: MAXIMIZATION TEST
SPECIES: GUINEA PIG
RESULT: DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS.
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
N-HEPTANE:
GENOTOXICITY IN VITRO:
REMARKS: IN VITRO TESTS DID NOT SHOW MUTAGENIC EFFECTS
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
COMPONENTS:
TOLUENE:
REPRODUCTIVE TOXICITY - ASSESSMENT:
SOME EVIDENCE OF ADVERSE EFFECTS ON DEVELOPMENT, BASED ON ANIMAL
EXPERIMENTS.
STOT - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
COMPONENTS:
METHANOL:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM, EYES
ASSESSMENT:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS SPECIFIC TARGET ORGAN TOXICANT,
SINGLE EXPOSURE, CATEGORY 1.
ACETONE:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS: NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
TOLUENE:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
N-HEPTANE:
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (NEUROLOGIC: OTHER (NEUROPSYCHOLOGICAL EFFECTS,
AUDITORY DYSFUNCTION AND EFFECTS ON COLOR VISION)) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
COMPONENTS:
TOLUENE:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS:
NEUROLOGIC:
OTHER (NEUROPSYCHOLOGICAL EFFECTS, AUDITORY DYSFUNCTION AND EFFECTS ON
COLOR VISION)
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
ACETONE: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
TOLUENE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
N-HEPTANE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
| SECTION 12. ECOLOGICAL INFORMATION | |
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
DO NOT RE-USE EMPTY CONTAINERS.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATIONS:
IATA-DGR:
UN/ID NO.: UN 1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
CLASS: 2.1
PACKING GROUP: NOT ASSIGNED BY REGULATION
LABELS: 2.1
PACKING INSTRUCTION (CARGO AIRCRAFT): 203
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 203
IMDG-CODE:
UN NUMBER: UN 1950
PROPER SHIPPING NAME: AEROSOLS
CLASS: 2.1
PACKING GROUP: NOT ASSIGNED BY REGULATION
LABELS: 2.1
EMS CODE: F-D, S-U
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
NATIONAL REGULATIONS:
49 CFR:
UN/ID/NA NUMBER: UN 1950
PROPER SHIPPING NAME: AEROSOLS
CLASS: 2.1
PACKING GROUP: NOT ASSIGNED BY REGULATION
LABELS: 2.1
ERG CODE: 126
MARINE POLLUTANT: NO
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ (LBS) COMPONENT RQ (LBS)
METHANOL 67-56-1 5000 5000
ACETONE 67-64-1 5000 5000
TOLUENE 108-88-3 1000 1000
BENZENE 71-43-2 10 10
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS:
FIRE HAZARD
CHRONIC HEALTH HAZARD
ACUTE HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
SARA 302:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
METHANOL 67-56-1
TOLUENE 108-88-3
US STATE REGULATIONS:
MASSACHUSETTS RIGHT TO KNOW:
METHANOL 67-56-1 30 - 50%
TOLUENE 108-88-3 5 - 10%
ACETONE 67-64-1 5 - 10%
CARBON DIOXIDE 124-38-9 5 - 10%
N-HEPTANE 142-82-5 1 - 5%
BENZENE 71-43-2 0 - 0.1%
MASSACHUSETTS RIGHT TO KNOW:
METHANOL 67-56-1
ACETONE 67-64-1
TOLUENE 108-88-3
CARBON DIOXIDE 124-38-9
N-HEPTANE 142-82-5
BENZENE 71-43-2
PENNSYLVANIA RIGHT TO KNOW:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8 30 - 50%
METHANOL 67-56-1 30 - 50%
TOLUENE 108-88-3 5 - 10%
ACETONE 67-64-1 5 - 10%
CARBON DIOXIDE 124-38-9 5 - 10%
N-HEPTANE 142-82-5 1 - 5%
PENNSYLVANIA RIGHT TO KNOW:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8
METHANOL 67-56-1
ACETONE 67-64-1
TOLUENE 108-88-3
CARBON DIOXIDE 124-38-9
N-HEPTANE 142-82-5
NEW JERSEY RIGHT TO KNOW:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8 30 - 50%
METHANOL 67-56-1 30 - 50%
TOLUENE 108-88-3 5 - 10%
ACETONE 67-64-1 5 - 10%
CARBON DIOXIDE 124-38-9 5 - 10%
N-HEPTANE 142-82-5 1 - 5%
CALIFORNIA PROP. 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA LIST:
NO SUBSTANCES ARE SUBJECT TO A SIGNIFICANT NEW USE RULE.
NO SUBSTANCES ARE SUBJECT TO TSCA 12(B) EXPORT NOTIFICATION REQUIREMENTS.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 3*
FLAMMABILITY 4
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
REVISION DATE: 06/07/2017
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
US / EN