| Common Name: | PYROIL PARTS CLEANER PL 5 GA |
| Manufacturer: | NITEO PRODUCTS |
| SDS Revision Date: | 9/6/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 21A053 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NITEO(TM) PRODUCTS
SAFETY DATA SHEET
PYROIL(TM) NON-CHLORINATED PARTS CLEANER
VERSION: 3.0
REVISION DATE: 09/06/2018
SDS NUMBER: 600000000113
DATE OF LAST ISSUE: 05/18/2018
DATE OF FIRST ISSUE: 05/23/2016
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: PYROIL PARTS CLEANER PL 5 GA
PRODUCT CODE: 857432
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: NITEO PRODUCTS, LLC
ADDRESS: DALLAS TX 75225
EMAIL ADDRESS: EHS@NITEOPRODUCTS.COM
TELEPHONE: 1-844-696-4836
EMERGENCY TELEPHONE NUMBER: 1-800-424-9300 / 1-703-741-5970
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: BRAKE PARTS CLEANER
RESTRICTIONS ON USE: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200:
FLAMMABLE LIQUIDS: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM, EYES)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (CENTRAL NERVOUS SYSTEM)
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CATEGORY 2 (AUDITORY SYSTEM)
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOUR.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
MAY CAUSE DAMAGE TO ORGANS (AUDITORY SYSTEM) THROUGH PRO-LONGED OR
REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/ VENTILATING/ LIGHTING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/ EYE PROTECTION/ FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/ PHYSICIAN.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: STATIC-ACCUMULATING FLAMMABLE LIQUID.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (% W/W)
ACETONE 67-64-1 >=90 - <100
XYLENE 1330-20-7 >=5 - <10
METHANOL 67-56-1 >=1 - <5
ETHYLBENZENE 100-41-4 >=1 - <5
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
SYMPTOMS OF POISONING MAY APPEAR SEVERAL HOURS LATER.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
MOVE TO FRESH AIR.
CONSULT A PHYSICIAN AFTER SIGNIFICANT EXPOSURE.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
IF ON CLOTHES, REMOVE CLOTHES.
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
KEEP EYE WIDE OPEN WHILE RINSING.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT INDUCE VOMITING.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL, AS COULD OCCUR IN
ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE ASSOCIATED WITH CARDIAC
ARRHYTHMIAS. SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN
PERSONS EXPOSED TO THIS MATERIAL.
THIS PRODUCT CONTAINS METHANOL WHICH CAN CAUSE INTOXICATION AND CENTRAL
NERVOUS SYSTEM DEPRESSION. METHANOL IS METABOLIZED TO FORMIC ACID AND
FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC ACIDOSIS, VISUAL
DISTURBANCES AND BLINDNESS. SINCE METABOLISM IS REQUIRED FOR THESE
TOXIC SYMPTOMS, THEIR ONSET MAY BE DELAYED FROM 6 TO 30 HOURS FOLLOWING
INGESTION. ETHANOL COMPETES FOR THE SAME METABOLIC PATHWAY AND HAS BEEN
USED TO PREVENT METHANOL METABOLISM. ETHANOL ADMINISTRATION IS INDICATED
IN SYMPTOMATIC PATIENTS OR AT BLOOD METH-ANOL CONCENTRATIONS ABOVE
20 UG/DL. METHANOL IS EFFECTIVELY REMOVED BY HEMODIALYSIS.
THIS MATERIAL (OR A COMPONENT) HAS PRODUCED HYPERGLYCEMIA AND KETOSIS
FOLLOWING SUBSTANTIAL INGESTION.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
CARBON DIOXIDE (CO2)
DRY CHEMICAL
ALCOHOL-RESISTANT FOAM
UNSUITABLE EXTINGUISHING MEDIA:
HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIRE-FIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED
OF IN ACCORDANCE WITH LOCAL REGULATIONS.
USE A WATER SPRAY TO COOL FULLY CLOSED CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
REMOVE ALL SOURCES OF IGNITION.
ENSURE ADEQUATE VENTILATION.
AVOID BREATHING DUST.
BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE CONCENTRATIONS. VAPOURS
CAN ACCUMULATE IN LOW AREAS.
EVACUATE PERSONNEL TO SAFE AREAS.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT PRODUCT FROM ENTERING DRAINS.
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM
RESPECTIVE AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT
MATERIAL, (E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND
PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS
(SEE SECTION 13).
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
TAKE NECESSARY ACTION TO AVOID STATIC ELECTRICITY DISCHARGE (WHICH MIGHT
CAUSE IGNITION OF ORGANIC VAPOURS).
ELECTRICALLY BOND AND GROUND ALL CONTAINERS, PERSONNEL AND EQUIPMENT
BEFORE TRANSFER OR USE OF MATERIAL. SPECIAL PRECAUTIONS MAY BE NECESSARY
TO DISSIPATE STATIC ELECTRICITY FOR NON-CONDUCTIVE CONTAINERS. USE PROPER
BONDING AND GROUNDING DURING PRODUCT TRANSFER AS DESCRIBED IN NATIONAL
FIRE PROTECTION ASSOCIATION DOCUMENT NFPA 77.
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION.
USE ONLY EXPLOSION-PROOF EQUIPMENT.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
ADVICE ON SAFE HANDLING:
OPEN DRUM CAREFULLY AS CONTENT MAY BE UNDER PRESSURE.
AVOID FORMATION OF AEROSOL.
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS.
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
AVOID CONTACT WITH SKIN AND EYES.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONTAINER HAZARDOUS WHEN EMPTY.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
OBSERVE LABEL PRECAUTIONS.
NO SMOKING.
FURTHER INFORMATION ON STORAGE STABILITY:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
ACETONE 67-64-1 TWA 250 PPM ACGIH
STEL 500 PPM ACGIH
TWA 250 PPM NIOSH REL
590 MG/M3
TWA 1,000 PPM OSHA Z-1
2,400 MG/M3
TWA 750 PPM OSHA P0
1,800 MG/M3
STEL 1,000 PPM OSHA P0
2,400 MG/M3
METHANOL 67-56-1 TWA 200 PPM ACGIH
STEL 250 PPM ACGIH
TWA 200 PPM NIOSH REL
260 MG/M3
ST 250 PPM NIOSH REL
325 MG/M3
TWA 200 PPM OSHA Z-1
260 MG/M3
STEL 250 PPM OSHA P0
325 MG/M3
TWA 200 PPM OSHA P0
260 MG/M3
ETHYLBENZENE 100-41-4 TWA 20 PPM ACGIH
TWA 100 PPM NIOSH REL
435 MG/M3
ST 125 PPM NIOSH REL
545 MG/M3
TWA 100 PPM OSHA Z-1
435 MG/M3
TWA 100 PPM OSHA P0
435 MG/M3
STEL 125 PPM OSHA P0
545 MG/M3
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO.
XYLENE 1330-20-7
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING PERMISSIBLE BASIS
PARAMETERS SPECIMEN TIME CONCENTR-
ATION
ACETONE 67-64-1 ACETONE URINE END OF 25 MG/L ACGIH
SHIFT BEI
(AS SOON
AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
METHANOL 67-56-1 METHANOL URINE END OF 15 MG/L ACGIH
SHIFT BEI
(AS SOON
AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
ETHYLBE- 100-41-4 SUM OF URINE END OF 0.15 G/G ACGIH
NZENE MANDELIC SHIFT CREATININE BEI
ACID AND (AS SOON
PHENYL AS
GLYOXYLIC POSSIBLE
ACID AFTER
EXPOSURE
CEASES)
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW
LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN THE CASE OF VAPOUR FORMATION USE A RESPIRATOR WITH AN APPROVED FILTER.
HAND PROTECTION:
REMARKS:
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLI-ER). THE
SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DIS-CUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
FLAME-RESISTANT CLOTHING
SAFETY SHOES
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WHEN USING DO NOT SMOKE.
WHEN USING DO NOT EAT OR DRINK.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOUR: COLOURLESS
ODOUR: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE: 56 DEG. C (1,013 HPA) THE VALUE IS CALCULATED
FLASH POINT: -20 DEG. C THE VALUE IS CALCULATED
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLAMMABILITY (LIQUIDS): STATIC-ACCUMULATING FLAMMABLE LIQUID.
SELF-IGNITION: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT / UPPER FLAMMABILITY LIMIT:
36 %(V) THE VALUE IS CALCULATED
LOWER EXPLOSION LIMIT / LOWER FLAMMABILITY LIMIT:
1 %(V) THE VALUE IS CALCULATED
VAPOUR PRESSURE:
307.97 HPA (25 DEG. C) THE VALUE IS CALCULATED
DENSITY: 0.795 G/CM3 (20 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
ACIDS
BASES
ALUMINIUM
AMINES
AMMONIA
HALOGENS
LEAD
PEROXIDES
REDUCING AGENTS
STRONG BASES
STRONG OXIDIZING AGENTS
ZINC
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
EYE CONTACT
SKIN CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 3,093 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 61.23 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
METHOD: CALCULATION METHOD
ACUTE DERMAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
COMPONENTS:
ACETONE:
ACUTE ORAL TOXICITY:
LD50 (RAT, FEMALE): 5,800 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT, FEMALE): 76 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >7,426 MG/KG
XYLENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): 3,523 - 8,600 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 6700 PPM
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ASSESSMENT:
THE COMPONENT/MIXTURE IS MODERATELY TOXIC AFTER SHORT TERM INHALATION.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 1,700 MG/KG
METHANOL:
ACUTE ORAL TOXICITY:
LDLO (HUMANS): 300 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE INGESTION.
ACUTE INHALATION TOXICITY:
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SHORT TERM INHALATION.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 12,800 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE CONTACT WITH SKIN.
ETHYLBENZENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): CA. 3,500 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 4000 PPM
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 17,800 MG/KG
SKIN CORROSION/IRRITATION:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
REMARKS: MAY IRRITATE SKIN.
COMPONENTS:
ACETONE:
RESULT: POSSIBLY IRRITATING TO SKIN
RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
XYLENE:
ASSESSMENT: IRRITATING TO SKIN.
RESULT: IRRITATING TO SKIN.
METHANOL:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
ETHYLBENZENE:
RESULT: IRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.
COMPONENTS:
ACETONE:
RESULT: IRRITATING TO EYES.
ASSESSMENT: IRRITATING TO EYES.
XYLENE:
RESULT: IRRITATING TO EYES.
METHANOL:
SPECIES: RABBIT
RESULT: POSSIBLY IRRITATING TO EYES
ETHYLBENZENE:
RESULT: IRRITATING TO EYES.
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
METHANOL:
TEST TYPE: MAXIMISATION TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
METHOD: OECD TEST GUIDELINE 406
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLBENZENE:
CARCINOGENICITY - ASSESSMENT: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC:
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
ETHYLBENZENE 100-41-4
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR
EQUAL TO 0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
COMPONENTS:
ACETONE:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS: NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
XYLENE:
ASSESSMENT:
MAY CAUSE DROWSINESS OR DIZZINESS., MAY CAUSE RESPIRATORY IRRITATION.
METHANOL:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM, EYES
ASSESSMENT:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS SPECIFIC TARGET ORGAN TOXICANT,
SINGLE EX-POSURE, CATEGORY 1.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (AUDITORY SYSTEM) THROUGH PROLONGED OR REPEATED
EXPOSURE.
COMPONENTS:
ETHYLBENZENE:
TARGET ORGANS: AUDITORY SYSTEM
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ACETONE: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
XYLENE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
ETHYLBENZENE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA
AND VOMITING.
| SECTION 12. ECOLOGICAL INFORMATION | |
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
DO NOT RE-USE EMPTY CONTAINERS.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
| SECTION 14. TRANSPORT INFORMATION | |
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED BELOW) MAY NOT REFLECT
QUANTITY, END-USE, OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED.
CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE
SHIPMENT.
INTERNATIONAL REGULATIONS:
IATA-DGR:
UN/ID NO.: UN 1993
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (ACETONE, METHANOL)
CLASS: 3
PACKING GROUP: II
LABELS: 3
PACKING INSTRUCTION (CARGO AIRCRAFT): 364
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 353
IMDG-CODE:
UN NUMBER: UN 1993
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (ACETONE, METHANOL)
CLASS: 3
PACKING GROUP: II
LABELS: 3
EMS CODE: F-E, S-E
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
NATIONAL REGULATIONS:
49 CFR:
UN/ID/NA NUMBER: UN 1993
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (ACETONE, METHANOL)
CLASS: 3
PACKING GROUP: II
LABELS: 3
ERG CODE: 128
MARINE POLLUTANT: NO
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS)
XYLENE 1330-20-7 100 1836
XYLENE 1330-20-7 100 100 (F003)
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HAZARD NOT OTHERWISE CLASSIFIED (PHYSICAL HAZARDS)
SERIOUS EYE DAMAGE OR EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
METHANOL 67-56-1 >=1 - <5 %
ETHYLBENZENE 100-41-4 >=1 - <5 %
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING ETHYLBENZENE,
BENZENE, WHICH IS/ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, AND METHANOL, TOLUENE, BENZENE, WHICH IS/ARE KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARD.
REVISION DATE: 09/06/2018
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID
FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
US / EN