| Common Name: | PYROIL STARTING FLUID |
| Manufacturer: | ASHLAND |
| SDS Revision Date: | 8/16/2012 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 21A071 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ASHLAND(R*)
SAFETY DATA SHEET
PYROIL(TM) STARTING FLUID PYSFR7.5
REVISION DATE: 08/16/2012
PRINT DATE: 1/3/2015
MSDS NUMBER: R0340954
VERSION: 6.0
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
REGULATORY INFORMATION NUMBER: 1-800-325-3751
TELEPHONE: 614-790-3333
EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263)
PRODUCT NAME: PYROIL(TM) STARTING FLUID
PRODUCT CODE: PYSFR7.5
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE: AEROSOL
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. CONTENTS
UNDER PRESSURE. MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS,
HEADACHE OR NAUSEA. CAUSES EYE IRRITATION. PROLONGED OR REPEATED CONTACT
MAY DRY THE SKIN AND CAUSE IRRITATION AND BURNS.
POTENTIAL HEALTH EFFECTS:
EXPOSURE ROUTES:
INHALATION, SKIN ABSORPTION, SKIN CONTACT, EYE CONTACT, INGESTION
EYE CONTACT:
CAN CAUSE SEVERE EYE IRRITATION. SYMPTOMS INCLUDE STINGING, TEARING,
REDNESS, AND SWELLING OF EYES. CAN INJURE EYE TISSUE.
SKIN CONTACT:
MAY CAUSE SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY
THE SKIN. SYMPTOMS MAY INCLUDE REDNESS, BURNING, AND DRYING AND CRACKING
OF SKIN, SKIN BURNS, AND OTHER SKIN DAMAGE.
INGESTION:
SWALLOWING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT
LIKELY TO CAUSE HARMFUL EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL.
THIS MATERIAL CAN GET INTO THE LUNGS DURING SWALLOWING OR VOMITING. THIS
RESULTS IN LUNG INFLAMMATION AND OTHER LUNG INJURY.
INHALATION:
BREATHING AEROSOL AND/OR MIST IS POSSIBLE WHEN MATERIAL IS SPRAYED. AEROSOL
AND MIST MAY PRESENT A GREATER RISK OF INJURY BECAUSE MORE MATERIAL MAY BE
PRESENT IN THE AIR THAN FROM VAPOR ALONE. BREATHING SMALL AMOUNTS OF THIS
MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS.
BREATHING LARGE AMOUNTS MAY BE HARMFUL. SYMPTOMS ARE NOT EXPECTED AT AIR
CONCENTRATIONS BELOW THE RECOMMENDED EXPOSURE LIMITS, IF APPLICABLE
(SEE SECTION 8.).
AGGRAVATED MEDICAL CONDITION:
PREEXISTING DISORDERS OF THE FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE
AGGRAVATED BY EXPOSURE TO THIS MATERIAL:
SKIN, LUNG (FOR EXAMPLE, ASTHMA-LIKE CONDITIONS), LIVER, CENTRAL NERVOUS
SYSTEM, MALE REPRODUCTIVE SYSTEM, INDIVIDUALS WITH PREEXISTING HEART
DISORDERS MAYBE MORE SUSCEPTIBLE TO ARRHYTHMIAS (IRREGULAR HEARTBEATS)
IF EXPOSED TO HIGH CONCENTRATIONS OF THIS MATERIAL.
SYMPTOMS:
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION
(NOSE, THROAT, AIRWAYS), COUGH, CENTRAL NERVOUS SYSTEM DEPRESSION
(DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE,
UNCONSCIOUSNESS), LOSS OF APPETITE, RESPIRATORY DEPRESSION (SLOWING OF
THE BREATHING RATE), LACK OF COORDINATION, CONFUSION, IRREGULAR HEARTBEAT,
RESPIRATORY FAILURE, COMA
TARGET ORGANS:
THIS PRODUCT CONTAINS ETHANOL. ALCOHOLIC BEVERAGE CONSUMPTION HAS BEEN
ASSOCIATED WITH BRAIN DAMAGE, HEART DAMAGE, AND PANCREATITIS IN HUMANS.
THE RELEVANCE OF THESE FINDINGS TO ETHANOL EXPOSURE IN INDUSTRIAL
ENVIRONMENTS IS UNCERTAIN., EXPOSURE TO THIS MATERIAL (OR A COMPONENT) HAS
BEEN FOUND TO CAUSE KIDNEY DAMAGE IN MALE RATS. THE MECHANISM BY WHICH THIS
TOXICITY OCCURS IS SPECIFIC TO THE MALE RAT AND THE KIDNEY EFFECTS ARE NOT
EXPECTED TO OCCUR IN HUMANS.
OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A
CAUSE OF THE FOLLOWING EFFECTS IN LABORATORY ANIMALS:
PANCREATIC DAMAGE, LIVER DAMAGE, BRAIN DAMAGE, TESTIS DAMAGE
OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A
CAUSE OF THE FOLLOWING EFFECTS IN HUMANS:
LIVER DAMAGE, REPEATED EXPOSURE TO HYDROQUINONE VAPOR OR DUST FOR MORE
THAN 5 YEARS HAS CAUSED BROWNISH STAINING AND DAMAGE TO THE SURFACE OF THE
CORNEA WITH REDUCTION IN VISION.
CARCINOGENICITY:
ETHYL CHLORIDE HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS. THE
RELEVANCE OF THIS FINDING TO HUMANS IS UNCERTAIN. THIS PRODUCT CONTAINS
ETHANOL. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS
DETERMINED THAT EXPOSURE TO ETHANOL THROUGH CHRONIC HUMAN CONSUMPTION OF
ALCOHOLIC BEVERAGES CAN CAUSE CANCER. THE RELEVANCE OF THIS FINDING TO
ETHANOL EXPOSURE IN INDUSTRIAL ENVIRONMENTS IS UNCERTAIN.
REPRODUCTIVE HAZARD:
THIS PRODUCT CONTAINS ETHANOL. ALCOHOLIC BEVERAGE CONSUMPTION HAS BEEN
ASSOCIATED WITH BIRTH DEFECTS IN HUMANS. THE RELEVANCE OF THIS FINDING
TO ETHANOL EXPOSURE IN INDUSTRIAL ENVIRONMENTS IS UNCERTAIN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS CAS-NO. / TRADE SECRET NO. CONCENTRATION
SOLVENT NAPHTHA (PETROLEUM), 64742-89-8 >=70-<80%
LIGHT ALIPHATIC
ETHYL ETHER 60-29-7 >=15-<20%
CARBON DIOXIDE 124-38-9 >=1.5-<5%
ETHANOL 64-17-5 >=1-<1.5%
DISTILLATES (PETROLEUM), 64742-53-6 >=0.5-<1%
HYDROTREATED LIGHT
NAPHTHENIC
ETHYL CHLORIDE 75-00-3 >=0.1-<0.5%
| 4. FIRST AID MEASURES | |
EYES:
IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY FROM EXPOSURE AND
INTO FRESH AIR. FLUSH EYES GENTLY WITH WATER FOR AT LEAST 15 MINUTES WHILE
HOLDING EYELIDS APART; SEEK IMMEDIATE MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. IF
SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE REUSE.
INGESTION:
SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DO NOT GIVE
ANYTHING BY MOUTH; PLACE INDIVIDUAL ON THE LEFT SIDE WITH THE HEAD DOWN.
CONTACT A PHYSICIAN, MEDICAL FACILITY, OR POISON CONTROL CENTER FOR ADVICE
ABOUT WHETHER TO INDUCE VOMITING. IF POSSIBLE, DO NOT LEAVE INDIVIDUAL
UNATTENDED.
INHALATION:
IF SYMPTOMS DEVELOP, MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR.
IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. KEEP PERSON WARM AND QUIET; SEEK IMMEDIATE MEDICAL
ATTENTION.
NOTES TO PHYSICIAN:
HAZARDS:
INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL, AS COULD OCCUR IN
ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE ASSOCIATED WITH CARDIAC
ARRHYTHMIAS. SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN
PERSONS EXPOSED TO THIS MATERIAL. THIS MATERIAL IS AN ASPIRATION HAZARD.
POTENTIAL DANGER FROM ASPIRATION MUST BE WEIGHED AGAINST POSSIBLE ORAL
TOXICITY (SEE SECTION 2 - SWALLOWING) WHEN DECIDING WHETHER TO INDUCE
VOMITING. ACUTE ASPIRATION OF LARGE AMOUNTS OF OIL-LADEN MATERIAL MAY
PRODUCE A SERIOUS ASPIRATION PNEUMONIA. PATIENTS WHO ASPIRATE THESE OILS
SHOULD BE FOLLOWED FOR THE DEVELOPMENT OF LONG-TERM SEQUELAE. REPEATED
ASPIRATION OF SMALL QUANTITIES OF MINERAL OIL CAN PRODUCE CHRONIC
INFLAMMATION OF THE LUNGS (I.E. LIPOID PNEUMONIA) THAT MAY PROGRESS TO
PULMONARY FIBROSIS. SYMPTOMS ARE OFTEN SUBTLE AND RADIOLOGICAL CHANGES
APPEAR WORSE THAN CLINICAL ABNORMALITIES. OCCASIONALLY, PERSISTENT COUGH,
IRRITATION OF THE UPPER RESPIRATORY TRACT, SHORTNESS OF BREATH WITH
EXERTION, FEVER, AND BLOODY SPUTUM OCCUR. INHALATION EXPOSURE TO OIL MISTS
BELOW CURRENT WORKPLACE EXPOSURE LIMITS IS UNLIKELY TO CAUSE PULMONARY
ABNORMALITIES.
TREATMENT:
SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS EXPOSED
TO THIS MATERIAL.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY, CARBON DIOXIDE (CO2), FOAM, DRY CHEMICAL
HAZARDOUS COMBUSTION PRODUCTS:
ALDEHYDES, CARBON DIOXIDE AND CARBON MONOXIDE, FORMALDEHYDE-LIKE,
HYDROCARBONS, ORGANIC COMPOUNDS
PRECAUTIONS FOR FIRE-FIGHTING:
WEAR FULL FIREFIGHTING TURN-OUT GEAR (FULL BUNKER GEAR), AND RESPIRATORY
PROTECTION (SCBA). USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND
STRUCTURES UNTIL FIRE IS OUT IF IT CAN BE DONE WITH MINIMAL RISK. AVOID
SPREADING BURNING MATERIAL WITH WATER USED FOR COOLING PURPOSES.
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: NOT APPLICABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
FOR PERSONAL PROTECTION SEE SECTION 8. ELIMINATE ALL IGNITION SOURCES
(FLARES, FLAMES INCLUDING PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT
WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL
CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
METHODS FOR CLEANING UP:
SUPPRESS (KNOCK DOWN) GASES/VAPOURS/MISTS WITH A WATER SPRAY JET. CONTAIN
SPILLAGE, SOAK UP WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G. SAND,
EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND TRANSFER TO A CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL
HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
STORAGE:
DO NOT STORE NEAR EXTREME HEAT, OPEN FLAME, OR SOURCES OF IGNITION. STORE
IN A COOL, DRY, VENTILATED AREA. MAXIMUM RECOMMENDED STORAGE TEMPERATURE
50 DEGREES C (122 DEGREES F).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8:
OSHA Z1:
TIME WEIGHTED AVERAGE: 500 PPM
ACGIH:
TIME WEIGHTED AVERAGE: 300 PPM
OSHA Z1:
TIME WEIGHTED AVERAGE: 2,000 MG/M3
ACGIH:
TIME WEIGHTED AVERAGE: 1,370 MG/M3
ETHYL ETHER 60-29-7:
ACGIH:
TIME WEIGHTED AVERAGE: 400 PPM
ACGIH:
SHORT TERM EXPOSURE LIMIT: 500 PPM
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 400 PPM
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 1,200 MG/M3
CARBON DIOXIDE 124-38-9:
ACGIH:
TIME WEIGHTED AVERAGE: 5,000 PPM
ACGIH:
SHORT TERM EXPOSURE LIMIT: 30,000 PPM
NIOSH:
RECOMMENDED EXPOSURE LIMIT (REL): 5,000 PPM
NIOSH:
RECOMMENDED EXPOSURE LIMIT (REL): 9,000 MG/M3
NIOSH:
SHORT TERM EXPOSURE LIMIT: 30,000 PPM
NIOSH:
SHORT TERM EXPOSURE LIMIT: 54,000 MG/M3
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 5,000 PPM
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 9,000 MG/M3
ETHANOL 64-17-5:
NIOSH:
RECOMMENDED EXPOSURE LIMIT (REL): 1,000 PPM
NIOSH:
RECOMMENDED EXPOSURE LIMIT (REL): 1,900 MG/M3
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 1,000 PPM
OSHA Z1:
PERMISSIBLE EXPOSURE LIMIT: 1,900 MG/M3
ACGIH:
SHORT TERM EXPOSURE LIMIT: 1,000 PPM
GENERAL ADVICE:
THESE RECOMMENDATIONS PROVIDE GENERAL GUIDANCE FOR HANDLING THIS PRODUCT.
PERSONAL PROTECTIVE EQUIPMENT SHOULD BE SELECTED FOR INDIVIDUAL
APPLICATIONS AND SHOULD CONSIDER FACTORS WHICH AFFECT EXPOSURE POTENTIAL,
SUCH AS HANDLING PRACTICES, CHEMICAL CONCENTRATIONS AND VENTILATION. IT IS
ULTIMATELY THE RESPONSIBILITY OF THE EMPLOYER TO FOLLOW REGULATORY
GUIDELINES ESTABLISHED BY LOCAL AUTHORITIES.
EXPOSURE CONTROLS:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW
LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST. MAINTAIN EYE WASH STATION NEAR WORK
AREA.
SKIN AND BODY PROTECTION:
WEAR NORMAL WORK CLOTHING INCLUDING LONG PANTS, LONG-SLEEVED SHIRTS AND
FOOT COVERING TO PREVENT DIRECT CONTACT OF THE PRODUCT WITH THE SKIN.
LAUNDER CLOTHING BEFORE REUSE. IF SKIN IRRITATION DEVELOPS, CONTACT YOUR
FACILITY HEALTH AND SAFETY PROFESSIONAL OR YOUR LOCAL SAFETY EQUIPMENT
SUPPLIER TO DETERMINE THE PROPER PERSONAL PROTECTIVE EQUIPMENT FOR YOUR
USE.
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL
BOILING POINT/BOILING RANGE:
94.3 DEG. F / 34.6 DEG. C @ 1,013.23 HPA CALCULATED
PHASE TRANSITION LIQUID/GAS
FLASH POINT:
-49 DEG. F / -45 DEG. C
CALCULATED FLASH POINT
LOWER EXPLOSION LIMIT/UPPER EXPLOSION LIMIT: 1.05 %(V) / 36.5 %(V)
VAPOUR PRESSURE:
717.261 HPA @ 77 DEG. F / 25 DEG. C CALCULATED VAPOR PRESSURE
DENSITY: 0.7114 G/CM3 @ 60.01 DEG. F / 15.56 DEG. C
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE PRODUCTS:
ACIDS, ALKALI METALS, AMMONIA, BASES, HALOGENS, OXIDIZING AGENTS, SODIUM,
SULPHUR COMPOUNDS
HAZARDOUS DECOMPOSITION PRODUCTS:
ALDEHYDES, CARBON DIOXIDE AND CARBON MONOXIDE, FORMALDEHYDE-LIKE,
HYDROCARBONS, ORGANIC COMPOUNDS
HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL TOXICITY:
ACUTE ORAL TOXICITY - PRODUCT: NO DATA AVAILABLE
ACUTE ORAL TOXICITY - COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
LD50: >8,000 MG/KG
SPECIES: RAT
ETHYL ETHER:
LD50: 3,230 - 3,920 MG/KG
SPECIES: RAT
ETHANOL:
LD50: 7,060 MG/KG
SPECIES: RAT
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT NAPHTHENIC:
LD50: >5 G/KG
SPECIES: RAT
ACUTE INHALATION TOXICITY:
ACUTE INHALATION TOXICITY - PRODUCT: NO DATA AVAILABLE
ACUTE INHALATION TOXICITY - COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
LC50: 3400 PPM
EXPOSURE TIME: 4 H
SPECIES: RAT
ETHYL ETHER:
LC50: 32,000 MG/L
EXPOSURE TIME: 4 H
SPECIES: RAT
ETHANOL:
LC50: 117 - 125 MG/L
EXPOSURE TIME: 4 H
SPECIES: RAT
ETHYL CHLORIDE:
LC50: >19000 PPM
EXPOSURE TIME: 4 H
SPECIES: RAT
METHOD: OECD TEST GUIDELINE 403
ACUTE DERMAL TOXICITY:
ACUTE DERMAL TOXICITY - PRODUCT: NO DATA AVAILABLE
ACUTE DERMAL TOXICITY - COMPONENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
LD50: >4,000 MG/KG
SPECIES: RAT
ETHANOL:
LDLO: 20 G/KG
SPECIES: RABBIT
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT NAPHTHENIC:
LD50: >2,000 MG/KG
SPECIES: RABBIT
ACUTE TOXICITY (OTHER ROUTES OF ADMINISTRATION):
ACUTE TOXICITY (OTHER ROUTES OF ADMINISTRATION): NO DATA AVAILABLE
| 12. ECOLOGICAL INFORMATION | |
BIODEGRADABILITY:
BIODEGRADABILITY - PRODUCT: NO DATA AVAILABLE
BIODEGRADABILITY - COMPONENTS:
ETHYL CHLORIDE: 0%
METHOD: CLOSED BOTTLE TEST
REMARKS: NOT READILY BIODEGRADABLE.
BIOACCUMULATION:
BIOACCUMULATION - PRODUCT: NO DATA AVAILABLE
ECOTOXICITY EFFECTS:
TOXICITY TO FISH:
TOXICITY TO FISH - PRODUCT: NO DATA AVAILABLE
TOXICITY TO FISH - COMPONENTS:
ETHANOL:
LC50: 12,000 - 16,000 MG/L
EXPOSURE TIME: 96 H
SPECIES: RAINBOW TROUT,DONALDSON TROUT (ONCORHYNCHUS MYKISS)
TEST TYPE: STATIC TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES - PRODUCT:
NO DATA AVAILABLE
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES - COMPONENTS:
ETHANOL:
EC50: >10,000 MG/L
EXPOSURE TIME: 48 H
SPECIES: WATER FLEA (DAPHNIA MAGNA)
TEST TYPE: STATIC TEST
ETHYL CHLORIDE:
LC50: 58 MG/L
EXPOSURE TIME: 48 H
SPECIES: WATER FLEA (DAPHNIA HYALINA)
TEST TYPE: STATIC TEST
TOXICITY TO ALGAE:
TOXICITY TO ALGAE - PRODUCT: NO DATA AVAILABLE
TOXICITY TO ALGAE - COMPONENTS:
ETHYL CHLORIDE: 118 MG/L
EXPOSURE TIME: 72 H
SPECIES: DESMODESMUS SUBSPICATUS (GREEN ALGAE)
TEST TYPE: STATIC TEST
TOXICITY TO BACTERIA:
TOXICITY TO BACTERIA - PRODUCT: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| 14. TRANSPORT INFORMATION | |
REGULATION:
ID NUMBER PROPER SHIPPING *HAZARD SUBSIDIARY PACKING MARINE
NAME CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.
U.S. DOT - ROAD:
ORM-D, CONSUMER COMMODITY ORM
U.S. DOT - RAIL:
ORM-D, CONSUMER COMMODITY ORM
U.S. DOT - INLAND WATERWAYS:
ORM-D, CONSUMER COMMODITY ORM
TRANSPORT CANADA - ROAD:
UN 1950 AEROSOLS 2.1
TRANSPORT CANADA - RAIL
UN 1950 AEROSOLS 2.1
TRANSPORT CANADA - INLAND WATERWAYS:
UN 1950 AEROSOLS 2.1
INTERNATIONAL MARITIME DANGEROUS GOODS:
UN 1950 AEROSOLS 2.1 MARINE
POLLUTANT:
(ALIPHATIC
PETROLEUM
NAPHTHA)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO:
UN 1950 AEROSOLS, 2.1
FLAMMABLE
(ENGINE
STARTING
FLUID)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER:
UN 1950 AEROSOLS, 2.1
FLAMMABLE
(ENGINE
STARTING
FLUID)
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES:
UN 1950 AEROSOLES 2
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| 15. REGULATORY INFORMATION | |
CALIFORNIA PROP. 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
SARA HAZARD CLASSIFICATION:
SARA 311/312 CLASSIFICATION:
ACUTE HEALTH HAZARD
FIRE HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
CHRONIC HEALTH HAZARD
SARA 313 COMPONENT(S):
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
NEW JERSEY RTK LABEL INFORMATION:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8
ETHYL ETHER 60-29-7
CARBON DIOXIDE 124-38-9
ETHANOL 64-17-5
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT NAPHTHENIC 64742-53-6
TOLUENE 108-88-3
PENNSYLVANIA RTK LABEL INFORMATION:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8
ETHYL ETHER 60-29-7
CARBON DIOXIDE 124-38-9
ETHANOL 64-17-5
NOTIFICATION STATUS:
US. TOXIC SUBSTANCES CONTROL ACT: Y (POSITIVE LISTING)
CANADA. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA). DOMESTIC SUBSTANCES
LIST (DSL). (CAN. GAZ. PART II, VOL. 133): Y (POSITIVE LISTING)
AUSTRALIA. INDUSTRIAL CHEMICAL (NOTIFICATION AND ASSESSMENT) ACT:
Y (POSITIVE LISTING)
NEW ZEALAND. INVENTORY OF CHEMICALS (NZIOC), AS PUBLISHED BY ERMA NEW
ZEALAND: Y (POSITIVE LISTING)
JAPAN. KASHIN-HOU LAW LIST: N (NEGATIVE LISTING)
KOREA. TOXIC CHEMICAL CONTROL LAW (TCCL) LIST: Y (POSITIVE LISTING)
PHILIPPINES. THE TOXIC SUBSTANCES AND HAZARDOUS AND NUCLEAR WASTE CONTROL
ACT: Y (POSITIVE LISTING)
CHINA. INVENTORY OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
REPORTABLE QUANTITY - PRODUCT:
US. EPA CERCLA HAZARDOUS SUBSTANCES (40 CFR 302): 511 LBS
REPORTABLE QUANTITY-COMPONENTS:
ETHYL ETHER 60-29-7: 100 LBS
HMIS NFPA
HEALTH 2 1
FLAMMABILITY 4 4
PHYSICAL HAZARDS 0
INSTABILITY 0
SPECIFIC HAZARD
| 16. OTHER INFORMATION | |
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS MSDS HAS BEEN
PREPARED BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT
(1-800-325-3751).