| Common Name: | POLISHING BLOCK LARGE RED, WALBUCK RAILROAD CHALK RED, WALBUCK TURKEY CALL CHALK |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 10/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 21U690 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LA-CO INDUSTRIES, INC.
POLISHING BLOCK LARGE RED, WALBUCK(R*) RAILROAD CHALK RED, WALBUCK(R*)
TURKEY CALL CHALK
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26,
2012 / RULES AND REGULATIONS
ACCORDING TO CANADIAN HAZARDOUS PRODUCTS REGULATIONS (HPR)
DATE OF ISSUE: 10/07/2015
VERSION: 1.0
SAFETY DATA SHEET
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME:
POLISHING BLOCK LARGE RED, WALBUCK(R*) RAILROAD CHALK RED, WALBUCK(R*)
TURKEY CALL CHALK
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: MARKING.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD
ELK GROVE VILLAGE, IL.
60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC- U.S. : 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH THE GLOBALLY HARMONIZED STANDARD:
CARC. 1A: H350
AQUATIC CHRONIC 3: H412
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
2.2 LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H350: MAY CAUSE CANCER
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P273: AVOID RELEASE TO THE ENVIRONMENT
P280: WEAR PROTECTIVE GLOVES
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS/CONTAINER TO AN AUTHORISED WASTE COLLECTION POINT
2.3. OTHER HAZARDS:
2.4 UNKNOWN ACUTE TOXICITY (GHS US):
1.53 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (ORAL)
1.53 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (DERMAL)
1.53 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (INHALATION (DUST/MIST))
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % (W/W) GHS-US
CLASSIFICATION
IRON OXIDE RED (CAS NO) 1309-37-1 4.25 RAILROAD AQUATIC CHRONIC 2,
CHALK RED H411
5.78 TURKEY
CALL CHALK
5.5 POLISHING
BLOCK LARGE RED
SILICON DIOXIDE (CAS NO) 14808-60-7 0.48 - 1.44 CARC. 1A, H350
(CRISTOBALITE) RAILROAD CHALK
RED
0.47 - 1.41
TURKEY CALL
CHALK
0.47 - 1.24
POLISHING BLOCK
LARGE RED
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
GENTLY WASH WITH PLENTY OF SOAP AND WATER.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER.
FIRST-AID MEASURES AFTER INGESTION:
DRINK PLENTY OF WATER. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU
FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE CANCER BY INHALATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: BURNING PRODUCES IRRITATING, TOXIC AND NOXIOUS FUMES.
EXPLOSION HAZARD: PRODUCT IS NOT EXPLOSIVE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
WEAR A SELF CONTAINED BREATHING APPARATUS. WEAR FIRE/FLAME
RESISTANT/RETARDANT CLOTHING.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: AVOID CREATING OR SPREADING DUST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: STOP LEAK IF SAFE TO DO SO.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT DISCHARGE INTO DRAINS OR THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN AND COLLECT AS ANY SOLID. AVOID GENERATING DUST.
METHODS FOR CLEANING UP:
WIPE UP WITH ABSORBENT MATERIAL (FOR EXAMPLE CLOTH). SWEEP SPILLED
SUBSTANCE INTO CONTAINERS; IF APPROPRIATE, MOISTEN FIRST TO PREVENT
DUSTING.
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 8: PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES, ON SKIN,
OR ON CLOTHING.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
INCOMPATIBLE MATERIALS: HEAT SOURCES.
STORAGE AREA: STORE IN DRY, COOL, WELL-VENTILATED AREA.
7.3. SPECIFIC END USE(S): MARKING
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
POLISHING BLOCK LARGE RED, WALBUCK(R*) RAILROAD CHALK RED, WALBUCK(R*)
TURKEY CALL CHALK:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
ACGIH:
ACGIH TWA (MG/M3): 0.025 MG/M3
ACGIH:
REMARK (ACGIH): (RESPIRABLE DUST)
OSHA:
OSHA PEL (TWA) (PPM): 250 MPPCF
OSHA:
REMARK (OSHA): (3) SEE TABLE Z-3.
CANADA (QUEBEC):
VEMP (MG/M3): 0.1 MG/M3
CANADA (QUEBEC):
NOTATIONS AND REMARKS: (LA POUSSIERE RESPIRABLE), (C2)
IRON OXIDE RED (1309-37-1):
ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3
ACGIH:
REMARK (ACGIH): PNEUMOCONIOSIS
OSHA:
OSHA PEL (TWA) (MG/M3): 10 MG/M3
CANADA (QUEBEC):
VEMP (MG/M3):
5 MG/M3 (FER, TRIOXYDE DE, FUMEES ET POUSSIERES (EXPRIMEE EN FE))
10 MG/M3 (ROUGE)
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
ENSURE GOOD VENTILATION OF THE WORK STATION.
HAND PROTECTION: USE RUBBER GLOVES.
EYE PROTECTION: NONE UNDER NORMAL USE.
RESPIRATORY PROTECTION: NONE UNDER NORMAL USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: A SOLID CRAYON-LIKE MARKER.
COLOUR: RED.
ODOUR: ODOURLESS.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0 %
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
BURNING PRODUCES IRRITATING, TOXIC AND NOXIOUS FUMES. CARBON OXIDES
(CO, CO2).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
IRON OXIDE RED (1309-37-1):
LD50 ORAL RAT: >10000 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: MAY CAUSE CANCER.
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS, INHALATION OF DUST
IRON OXIDE RED (1309-37-1):
IARC GROUP: 3 - NOT CLASSIFIABLE
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS:
NOT LISTED IN CARCINOGENICITY CLASS
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE CANCER BY INHALATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
LIKELY ROUTES OF EXPOSURE: INHALATION;SKIN AND EYE CONTACT
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
ECOLOGY - WATER:
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
IRON OXIDE RED (1309-37-1):
EC50 DAPHNIA 1: >100 MG/L
12.2. PERSISTENCE AND DEGRADABILITY:
POLISHING BLOCK LARGE RED, WALBUCK(R*) RAILROAD CHALK RED, WALBUCK(R*)
TURKEY CALL CHALK
PERSISTENCE AND DEGRADABILITY:
MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
12.3. BIOACCUMULATIVE POTENTIAL: NO ADDITIONAL INFORMATION AVAILABLE
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT AND TDG:
NOT CONSIDERED A DANGEROUS GOOD FOR TRANSPORT REGULATIONS
PROPER SHIPPING NAME (ADR): NOT APPLICABLE
TRANSPORT HAZARD CLASS(ES) (ADR):
TRANSPORT BY SEA:
TRANSPORT HAZARD CLASS(ES) (IMDG):
AIR TRANSPORT:
TRANSPORT HAZARD CLASS(ES) (IATA):
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
IRON OXIDE RED (1309-37-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
IRON OXIDE RED (1309-37-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
IRON OXIDE RED (1309-37-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NATIONAL REGULATIONS:
POLISHING BLOCK LARGE RED, WALBUCK(R*) RAILROAD CHALK RED, WALBUCK(R*)
TURKEY CALL CHALK:
ALL COMPONENTS ARE LISTED ON THE EEC INVENTORY EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
15.3. US STATE REGULATIONS:
SILICON DIOXIDE (CRISTOBALITE) (14808-60-7):
U.S.: NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
IRON OXIDE RED (1309-37-1):
U.S.: MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S.: NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES: ORIGINAL DOCUMENT.
DATA SOURCES:
ACGIH (AMERICAN CONFERENCE OF GOVERNEMENT INDUSTRIAL HYGIENISTS).
EUROPEAN CHEMICALS AGENCY (ECHA) C&L INVENTORY DATABASE. ACCESSED AT
HTTP://ECHA.EUROPA.EU/WEB/GUEST/INFORMATION-ON-CHEMICALS/
CL-INVENTORY-DATABASE.
KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK SELECTION GUIDE TO CHEMICAL
PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION. FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
ABBREVIATIONS AND ACRONYMS:
ATE: ACUTE TOXICITY ESTIMATE. CAS (CHEMICAL ABSTRACTS SERVICE) NUMBER.
CLP: CLASSIFICATION, LABELLING, PACKAGING.
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION.
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION.
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC.
TWA: TIME WEIGHT AVERAGE.
TSCA: TOXIC SUBSTANCES CONTROL ACT.
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND NOT REACTIVE WITH WATER.
FULL TEXT OF H-STATEMENTS:
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 3
CARC. 1A: CARCINOGENICITY, CATEGORY 1A
H350: MAY CAUSE CANCER
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
SDS PREPARED BY:
THE REDSTONE GROUP, LLC
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SUITE 206
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LACO NA GHS SDS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT
07/10/2015
EN (ENGLISH)
SDS REF.: LACO1510012