| Common Name: | C-4S REFRIGERATION OIL |
| Manufacturer: | CALUMET REFINING |
| SDS Revision Date: | 11/20/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 22NV48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
SAFETY DATA SHEET
C-4S REFRIGERATION OIL
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: C-4S REFRIGERATION OIL
PRODUCT CODE: 4304-01; 4304-05; 4304-07
CHEMICAL NAME: DISTILLATES (PETROLEUM), CLAY-TREATED HEAVY NAPHTHENIC
OTHER MEANS OF IDENTIFICATION:
BASEOIL - UNSPECIFIED; DISTILLATES, PETROLEUM, CLAY TREATED HEAVY
NAPHTHENIC; PETROLEUM DISTILLATES, CLAY-TREATED HEAVY NAPHTHENIC;
DISTILLATES (PETROLEUM), CLAY TREATED HEAVY NAPHTHENIC; DISTILLATES,
PETROLEUM, CLAY-TREATED HEAVY NAPHTHENIC; DISTILLATES, CLAY-TREATED HEAVY
NAPHTHENIC; DISTILLATES (PETROLEUM), CLAY-TREATED HEAVY NAPHTHENIC, BASEOIL
- UNSPECIFIED
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES:
PETROCHEMICAL INDUSTRY: PETROLEUM REFINING. NAPHTHENIC LUBRICANT.
USES ADVISED AGAINST REASON
NONE KNOWN.
SUPPLIER'S DETAILS:
CALUMET REFINING, LLC
2780 WATERFRONT PKWY E. DRIVE SUITE 200
INDIANAPOLIS, IN 46214
USA
TECHNICAL SERVICES: 317-328-5660
DISTRIBUTOR:
NU-CALGON
2611 SCHUETZ ROAD
ST. LOUIS MO 63043
USA
24 HR. CHEMTREC 1-800-424-9300 / INTERNATIONAL 1-703-527-3887:
24 HR. CHEMTREC: 1-800-424-9300 / INTERNATIONAL 1-703-527-3887
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
WHILE THIS MATERIAL IS NOT CONSIDERED HAZARDOUS BY THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200), THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT.
THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR EMPLOYEES AND OTHER USERS
OF THIS PRODUCT.
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: NOT CLASSIFIED.
GHS LABEL ELEMENTS:
SIGNAL WORD: NO SIGNAL WORD.
HAZARD STATEMENTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
PRECAUTIONARY STATEMENTS:
PREVENTION: NOT APPLICABLE.
RESPONSE: NOT APPLICABLE.
STORAGE: NOT APPLICABLE.
DISPOSAL: NOT APPLICABLE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: SUBSTANCE
CHEMICAL NAME: DISTILLATES (PETROLEUM), CLAY-TREATED HEAVY NAPHTHENIC
OTHER MEANS OF IDENTIFICATION:
BASEOIL - UNSPECIFIED; DISTILLATES, PETROLEUM, CLAY TREATED HEAVY
NAPHTHENIC; PETROLEUM DISTILLATES, CLAY-TREATED HEAVY NAPHTHENIC;
DISTILLATES (PETROLEUM), CLAY TREATED HEAVY NAPHTHENIC; DISTILLATES,
PETROLEUM, CLAY-TREATED HEAVY NAPHTHENIC; DISTILLATES, CLAY-TREATED
HEAVY NAPHTHENIC; DISTILLATES (PETROLEUM), CLAY-TREATED HEAVY NAPHTHENIC,
BASEOIL - UNSPECIFIED
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: 64742-44-5
INGREDIENT NAME % CAS NUMBER
DISTILLATES (PETROLEUM), CLAY-TREATED HEAVY NAPHTHENIC 100 64742-44-5
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET MEDICAL
ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND THE
EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK. DO
NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. PREVENT ENTRY
INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH SPILLAGES
INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN AND COLLECT
SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND, EARTH,
VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR DISPOSAL
ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A LICENSED
WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
DISTILLATES (PETROLEUM), CLAY-TREATED ACGIH TLV (UNITED STATES, 3/2017).
HEAVY NAPHTHENIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2016).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: 185 DEG. C (365 DEG. F) [CLEVELAND.]
EVAPORATION RATE: <0.04 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.916
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): 0.6143 CM2/S (61.43 CST)
FLOW TIME (ISO 2431): NOT AVAILABLE.
POUR POINT: -36 DEG. C (-32.8 DEG. F)
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
DISTILLATES (PETROLEUM), LC50 INHALATION RAT >5.53 MG/L 4 HOURS
CLAY-TREATED HEAVY DUSTS AND MISTS
NAPHTHENIC
LD50 DERMAL RABBIT >2000 MG/KG
LD50 ORAL RAT >5000 MG/KG
IRRITATION/CORROSION: NOT AVAILABLE.
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY:
THE CLASSIFICATION AS A CARCINOGEN NEED NOT APPLY AS IT CAN BE SHOWN THAT
THE SUBSTANCE CONTAINS LESS THAN 3% DMSO EXTRACT AS MEASURED BY IP 346.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: ORAL, DERMAL, INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES EXPOSURE
DISTILLATES (PETROLEUM), ACUTE EC50: >100 MG/L ALGAE 72 HOURS
CLAY-TREATED HEAVY ACUTE EC50: >100 MG/L DAPHNIA 48 HOURS
NAPHTHENIC ACUTE LC50: >100 MG/L FISH 96 HOURS
CHRONIC NOEL: >1 MG/L DAPHNIA 21 DAYS
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
DISTILLATES (PETROLEUM), INHERENT
CLAY-TREATED HEAVY
NAPHTHENIC
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
DISTILLATES (PETROLEUM), CLAY- 2 TO 6 HIGH
TREATED HEAVY NAPHTHENIC
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND
CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION TDG CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT NOT
REGULATED. REGULATED.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION:
ALL COMPONENTS ARE LISTED OR EXEMPTED.
| CLEAN WATER ACT (CWA) 307: BENZO[K]FLUORANTHENE
| CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING BENZO[K]FLUORANTHENE 207-08-9 0.00064
REQUIREMENTS
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: OIL MIST, MINERAL
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY: NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO BENZO[K]FLUORANTHENE, WHICH IS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
INGREDIENT NAME CONCENTRATION NO SIGNIFICANT MAXIMUM ACCEPTABLE
RISK (%) LEVEL DOSAGE LEVEL
BENZO[K]FLUORANTHENE 0.00064
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN:
JAPAN INVENTORY (ENCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
MALAYSIA: NOT DETERMINED.
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
THAILAND: NOT DETERMINED.
TURKEY: NOT DETERMINED.
UNITED STATES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
NOT CLASSIFIED.
HISTORY:
DATE OF ISSUE/DATE OF REVISION: 11/20/2018
VERSION: 1.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
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TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.