| Common Name: | PRO-LINE XT PAINT MARKER RED |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 7/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 23YT75 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
LA-CO INDUSTRIES, INC.
PRO-LINE(R*) XT PAINT MARKER RED
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ACCORDING TO CANADIAN HAZARDOUS PRODUCTS REGULATIONS (HPR)
DATE OF ISSUE: 07/28/2015
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: PRO-LINE(R*) XT PAINT MARKER RED
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: PAINT.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD
ELK GROVE VILLAGE, IL. 60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC - U.S.: 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH THE GLOBALLY HARMONIZED STANDARD:
FLAM. LIQ. 3: H226
SKIN SENS. 1: H317
REPR. 2: H361
FULL TEXT OF CLASSIFICATION CATEGORIES AND H STATEMENTS: SEE SECTION 16
2.2 LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAM (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOUR
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, OPEN FLAMES, SPARKS. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P261: AVOID BREATHING MIST, VAPOURS
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE
P280: WEAR PROTECTIVE CLOTHING, PROTECTIVE GLOVES
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P321: SPECIFIC TREATMENT (SEE FIRST AID MEASURES ON THIS LABEL)
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P370+P378:
IN CASE OF FIRE: USE SUITABLE EXTINGUISHING MEDIA TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO AN AUTHORISED WASTE COLLECTION POINT
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % (W/W) GHS-US
CLASSIFICATION
TERT-BUTYL ACETATE (CAS NO): 540-88-5 39.93 - 40.13 FLAM. LIQ. 2, H225
4-[[4- (CAS NO): 2786-76-7 12 SKIN SENS. 1, H317
(AMINOCARBONYL)
PHENYL]AZO]-
N-(2-ETHOXYPHENYL)
-3-HYDROXYNAPHT-
HALENE-2-
CARBOXAMIDE,
C.I. PIGMENT RED
170 (NAPHTHOL
<1%)
CYCLOHEXANONE (CAS NO): 108-94-1 10.24 FLAM. LIQ. 3, H226
ACUTE TOX. 4
(INHALATION), H332
2-METHOXY- (CAS NO): 108-65-6 2.09 - 4.18 FLAM. LIQ. 3, H226
1-METHYLETHYL
ACETATE
BUTYL ACETATE (CAS NO): 123-86-4 2.72 - 3.54 FLAM. LIQ. 3, H226
STOT SE 3, H336
NAPHTHA (CAS NO): 64742-48-9 2.48 - 2.49 FLAM. LIQ. 4, H227
(PETROLEUM), ASP. TOX. 1, H304
HYDROTREATED HEAVY
(BENZENE <0.1%)
2-ETHYLHEXANOIC (CAS NO): 22464-99-9 0.13 REPR. 2, H361
ACID, ZIRCONIUM
SALT
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER.
FIRST-AID MEASURES AFTER INGESTION: RINSE MOUTH. DO NOT INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOUR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. EXERCISE CAUTION WHEN
FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. USE SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO OPEN FLAMES. NO SMOKING. AVOID ALL EYE AND SKIN CONTACT AND DO NOT
BREATHE VAPOUR AND MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: STOP LEAK IF SAFE TO DO SO. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
WIPE UP WITH ABSORBENT MATERIAL (FOR EXAMPLE CLOTH).
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 13: DISPOSAL INFORMATION.
SECTION 7: SAFE HANDLING.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
NO OPEN FLAMES. NO SMOKING. TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE. USE ONLY NON-SPARKING TOOLS. AVOID ALL EYE AND SKIN CONTACT AND
DO NOT BREATHE VAPOUR AND MIST. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
HYGIENE MEASURES:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH
CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AND OTHER EXPOSED AREAS WITH
MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING AND WHEN LEAVING
WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT.
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: OXIDIZING AGENT. ACIDS. ALKALI. MOISTURE.
INCOMPATIBLE MATERIALS: HEAT SOURCES.
HEAT AND IGNITION SOURCES: KEEP AWAY FROM HEAT, SPARKS AND FLAME.
PROHIBITIONS ON MIXED STORAGE: INCOMPATIBLE MATERIALS.
STORAGE AREA: STORE IN DRY, COOL, WELL-VENTILATED AREA.
7.3. SPECIFIC END USE(S): MARKING.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PRO-LINE(R*) XT PAINT MARKER RED:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
TERT-BUTYL ACETATE (540-88-5):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
CYCLOHEXANONE (108-94-1):
ACGIH:
ACGIH TWA (MG/M3): 50 MG/M3
ACGIH:
ACGIH TWA (PPM): 20 PPM
ACGIH:
ACGIH STEL (PPM): 50 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 200 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 100 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 25 PPM
CANADA (QUEBEC):
NOTATIONS AND REMARKS: (PEAU)
BUTYL ACETATE (123-86-4):
ACGIH:
ACGIH TWA (MG/M3): 713 MG/M3
ACGIH:
ACGIH TWA (PPM): 150 PPM
ACGIH:
ACGIH STEL (MG/M3): 950 MG/M3
ACGIH:
ACGIH STEL (PPM): 200 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 710 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 150 PPM
CANADA:
(QUEBEC) VECD (MG/M3): 950 MG/M3
CANADA (QUEBEC):
VECD (PPM): 200 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 713 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 150 PPM
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3
ACGIH:
ACGIH STEL (MG/M3): 10 MG/M3
OSHA: NOT APPLICABLE
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3 AS Zr
ACGIH:
ACGIH STEL (MG/M3): 10 MG/M3 AS Zr
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
ENSURE GOOD VENTILATION OF THE WORK STATION.
HAND PROTECTION: USE RUBBER GLOVES. EN374.
EYE PROTECTION: NONE UNDER NORMAL USE.
SKIN AND BODY PROTECTION: LONG SLEEVED PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION: NONE UNDER NORMAL USE.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: SOLID MARKER CONTAINING LIQUID COLORED PAINT.
COLOUR: RED.
ODOUR: SOLVENT.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 23 - 37.8 DEG. C
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 67%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOUR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
OPEN FLAME. OVERHEATING. DIRECT SUNLIGHT. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: OXIDIZER. ACIDS. ALKALI. MOISTURE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
MAY RELEASE FLAMMABLE GASES. THERMAL DECOMPOSITION GENERATES: METALLIC
OXIDES. CARBON OXIDES (CO, CO2).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
TERT-BUTYL ACETATE (540-88-5):
LD50 ORAL RAT: 4100 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (PPM): 4211 PPM 6 H
ATE CLP (ORAL): 4100.000 MG/KG BODYWEIGHT
CYCLOHEXANONE (108-94-1):
ATE CLP (DUST, MIST): 1.500 MG/L/4H
BUTYL ACETATE (123-86-4):
LD50 ORAL RAT: 10760 MG/KG
LD50 DERMAL RABBIT: >14112 MG/KG
LC50 INHALATION RAT (MG/L): >21 MG/L/4H
ATE CLP (ORAL): 10760.000 MG/KG BODYWEIGHT
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LD50 ORAL RAT: 8532 MG/KG
LD50 DERMAL RAT: >2000 MG/KG
LC50 INHALATION RAT (PPM): 4345 PPM 6 H
ATE CLP (ORAL): 8532.000 MG/KG BODYWEIGHT
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LD50 ORAL RAT: >15000 MG/KG
LC50 INHALATION RAT (MG/L): >1580 MG/M3 4 H
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (MG/L): >5610 MG/M3
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RAT: >2000 MG/KG
LC50 INHALATION RAT (MG/L): >4.3 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
CYCLOHEXANONE (108-94-1):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
NOAEL (ORAL, RAT, 90 DAYS):
300 MG/KG BODYWEIGHT/DAY READ ACROSS 2-ETHYLHEXANOIC ACID; P-GENERATION
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TERT-BUTYL ACETATE (540-88-5):
LC50 FISH 1: 240 MG/L 96 H
EC50 DAPHNIA 1: 410 MG/L 24 H
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LC50 FISH 1: 100 - 180 MG/L
EC50 DAPHNIA 1: >500 MG/L 48 H
ERC50 (ALGAE): >1000 MG/L
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LC50 FISH 1: >500 MG/L 96 H
EC50 DAPHNIA 1: >110 MG/L 48 H
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LC50 FISH 1: 8.2 MG/L
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LC50 FISH 1: >100 MG/L 96 H
EC50 DAPHNIA 1: >0.17 MG/L 48 H
12.2. PERSISTENCE AND DEGRADABILITY:
TERT-BUTYL ACETATE (540-88-5):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 50% 28 D
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 89% 10 D
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 0% 28 D
12.3. BIOACCUMULATIVE POTENTIAL:
TERT-BUTYL ACETATE (540-88-5):
BCF FISH 1: 5.61
LOG POW: 1.64
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LOG POW: 0.43
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
BCF FISH 1: 53 L/KG
LOG POW: 1.28
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT AND TDG:
TRANSPORT DOCUMENT DESCRIPTION:
UN1263 PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE), 3, III
UN-NO.(DOT): UN1263
PROPER SHIPPING NAME (DOT):
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TRANSPORT HAZARD CLASS(ES) (DOT): 3 - FLAMMABLE LIQUID
PACKING GROUP (DOT): III - MINOR DANGER
ADR:
TRANSPORT DOCUMENT DESCRIPTION: UN 1263 PAINT, 3, III, (D/E)
PROPER SHIPPING NAME (ADR): PAINT
PACKING GROUP (ADR): III
CLASS (ADR): 3 - FLAMMABLE LIQUID
TRANSPORT BY SEA:
UN-NO. (IMDG): UN 1263
PROPER SHIPPING NAME (IMDG): PAINT
CLASS (IMDG): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IMDG): III
AIR TRANSPORT:
UN-NO. (IATA): UN 1263
PROPER SHIPPING NAME (IATA): PAINT
CLASS (IATA): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IATA): III
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CYCLOHEXANONE (108-94-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
BUTYL ACETATE (123-86-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
CYCLOHEXANONE (108-94-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
BUTYL ACETATE (123-86-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CYCLOHEXANONE (108-94-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
BUTYL ACETATE (123-86-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)- DIRECTIVE 79/831/EEC, SIXTH AMENDMENT OF
DIRECTIVE 67/548/EEC (DANGEROUS SUBSTANCES)
NATIONAL REGULATIONS:
PRO-LINE(R*) XT PAINT MARKER RED:
ALL COMPONENTS ARE LISTED ON THE EEC INVENTORY EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS).
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
15.3. US STATE REGULATIONS:
TERT-BUTYL ACETATE (540-88-5):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
CYCLOHEXANONE (108-94-1):
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
BUTYL ACETATE (123-86-4):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES: ORIGINAL DOCUMENT.
DATA SOURCES:
ACGIH (AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS).
EUROPEAN CHEMICALS AGENCY (ECHA) C&L INVENTORY DATABASE. ACCESSED AT
HTTP://ECHA.EUROPA.EU/WEB/GUEST/INFORMATION-ON-CHEMICALS/
CL-INVENTORY-DATABASE.
KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK SELECTION GUIDE TO CHEMICAL
PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION. FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
ABBREVIATIONS AND ACRONYMS:
ATE: ACUTE TOXICITY ESTIMATE. CAS (CHEMICAL ABSTRACTS SERVICE) NUMBER.
CLP: CLASSIFICATION, LABELLING, PACKAGING.
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION.
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION.
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC.
TWA: TIME WEIGHT AVERAGE.
TSCA: TOXIC SUBSTANCES CONTROL ACT.
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 1 - NORMALLY STABLE, BUT CAN BECOME UNSTABLE AT ELEVATED
TEMPERATURES AND PRESSURES OR MAY REACT WITH WATER
WITH SOME RELEASE OF ENERGY, BUT NOT VIOLENTLY.
FULL TEXT OF H-STATEMENTS:
ACUTE TOX. 4 (INHALATION): ACUTE TOXICITY (INHAL.), CATEGORY 4
ASP. TOX. 1: ASPIRATION HAZARD, CATEGORY 1
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS, CATEGORY 3
FLAM. LIQ. 4: FLAMMABLE LIQUIDS, CATEGORY 4
REPR. 2: REPRODUCTIVE TOXICITY, CATEGORY 2
SKIN SENS. 1: SENSITISATION - SKIN, CATEGORY 1
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, NARCOSIS
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H226: FLAMMABLE LIQUID AND VAPOUR
H227: COMBUSTIBLE LIQUID
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H332: HARMFUL IF INHALED
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
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LACO NA GHS SDS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT
EN (ENGLISH)
SDS REF.: LACO1507040