| Common Name: | PRO-LINE XT PAINT MARKER BLACK |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 10/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 23YT76 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
LA-CO INDUSTRIES, INC.
PRO-LINE(R*) XT PAINT MARKER BLACK
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ACCORDING TO CANADIAN HAZARDOUS PRODUCTS REGULATIONS (HPR)
DATE OF ISSUE: 07/28/2015
REVISION DATE: 10/29/2015
VERSION: 1.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: PRO-LINE(R*) XT PAINT MARKER BLACK
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: PAINT.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD
ELK GROVE VILLAGE, IL. 60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC - U.S.: 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH THE GLOBALLY HARMONIZED STANDARD:
FLAM. LIQ. 3 H226
REPR. 2 H361
STOT RE 1 H372
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
2.2 LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOUR
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, VAPOURS
P264: WASH HANDS THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P280: WEAR PROTECTIVE GLOVES
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL
P370+P378:
IN CASE OF FIRE: USE SUITABLE EXTINGUISHING MEDIA TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS/CONTAINER TO AN AUTHORISED WASTE COLLECTION POINT
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % (W/W) GHS-US
CLASSIFICATION
TERT-BUTYL (CAS NO): 540-88-5 1.88 - 25.67 FLAM. LIQ. 2, H225
ACETATE
CYCLOHEXANONE (CAS NO): 108-94-1 1.89 - 19.19 FLAM. LIQ. 3, H226
ACUTE TOX. 4
(INHALATION), H332
NAPHTHA (CAS NO): 64742-48-9 0 - 8.7 FLAM. LIQ. 4, H227
(PETROLEUM), ASP. TOX. 1, H304
HYDROTREATED
HEAVY (BENZENE
<0.1%)
CARBON BLACK (CAS NO): 1333-86-4 5.39 CARC. 2, H351
BUTYL ACETATE (CAS NO): 123-86-4 2.34 - 4.37 FLAM. LIQ. 3, H226
STOT SE 3, H336
2-METHOXY- (CAS NO): 108-65-6 1.62 - 3.24 FLAM. LIQ. 3, H226
1-METHYLETHYL
ACETATE
STODDARD SOLVENT (CAS NO): 8052-41-3 0 - 2.01 FLAM. LIQ. 3, H226
(BENZENE <0.1%) STOT RE 1, H372
ASP. TOX. 1, H304
ETHYL ACETATE (CAS NO): 141-78-6 0 - 1.15 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
2-ETHYLHEXANOIC (CAS NO): 22464-99-9 0 - 0.46 REPR. 2, H361
ACID, ZIRCONIUM
SALT
2-ETHYLHEXANOIC (CAS NO): 15956-58-8 0 - 0.12 ACUTE TOX. 4
ACID, MANGANESE (ORAL), H302
SALT EYE IRRIT. 2A, H319
REPR. 2, H361
STOT RE 2, H373
AQUATIC CHRONIC 2,
H411
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER.
FIRST-AID MEASURES AFTER INGESTION: RINSE MOUTH. DO NOT INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOUR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. EXERCISE CAUTION WHEN
FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. USE SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO OPEN FLAMES. NO SMOKING. AVOID ALL EYE AND SKIN CONTACT AND DO NOT
BREATHE VAPOUR AND MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: WEAR SUITABLE GLOVES.
EMERGENCY PROCEDURES: STOP LEAK IF SAFE TO DO SO. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
WIPE UP WITH ABSORBENT MATERIAL (FOR EXAMPLE CLOTH).
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 13: DISPOSAL INFORMATION.
SECTION 7: SAFE HANDLING.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
NO OPEN FLAMES. NO SMOKING. TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE. USE ONLY NON-SPARKING TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE
USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT BREATHE MIST, VAPOURS.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH HANDS AND OTHER
EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING
AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT.
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: OXIDIZING AGENT. ACIDS. ALKALI. MOISTURE.
INCOMPATIBLE MATERIALS: HEAT SOURCES.
HEAT AND IGNITION SOURCES: KEEP AWAY FROM HEAT, SPARKS AND FLAME.
PROHIBITIONS ON MIXED STORAGE: INCOMPATIBLE MATERIALS.
STORAGE AREA: STORE IN DRY, COOL, WELL-VENTILATED AREA.
7.3. SPECIFIC END USE(S): MARKING.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PRO-LINE(R*) XT PAINT MARKER BLACK:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
TERT-BUTYL ACETATE (540-88-5):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
CYCLOHEXANONE (108-94-1):
ACGIH:
ACGIH TWA (MG/M3): 50 MG/M3
ACGIH:
ACGIH TWA (PPM): 20 PPM
ACGIH:
ACGIH STEL (PPM): 50 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 200 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 100 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 25 PPM
CANADA (QUEBEC):
NOTATIONS AND REMARKS: (PEAU)
CARBON BLACK (1333-86-4):
ACGIH:
ACGIH TWA (MG/M3): 3.5 MG/M3
ACGIH:
REMARK (ACGIH): BRONCHITIS
OSHA:
OSHA PEL (TWA) (MG/M3): 3.5 MG/M3
CANADA (QUEBEC):
VEMP (MG/M3):
10 MG/M3 (FIBRES DE CARBONE ET DE GRAPHITE; POUSSIERE TOTALE)
5 MG/M3 (FIBRES DE CARBONE ET DE GRAPHITE; POUSSIERE RESPIRABLE)
3.5 MG/M3
BUTYL ACETATE (123-86-4):
ACGIH:
ACGIH TWA (MG/M3): 713 MG/M3
ACGIH:
ACGIH TWA (PPM): 150 PPM
ACGIH:
ACGIH STEL (MG/M3): 950 MG/M3
ACGIH:
ACGIH STEL (PPM): 200 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 710 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 150 PPM
CANADA (QUEBEC):
VECD (MG/M3): 950 MG/M3
CANADA (QUEBEC):
VECD (PPM): 200 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 713 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 150 PPM
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ETHYL ACETATE (141-78-6):
ACGIH:
ACGIH TWA (MG/M3): 1440 MG/M3
ACGIH:
ACGIH TWA (PPM): 400 PPM
ACGIH:
REMARK (ACGIH): URT & EYE IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 1400 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 1440 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 400 PPM
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3
ACGIH:
ACGIH STEL (MG/M3): 10 MG/M3
OSHA: NOT APPLICABLE
2-ETHYLHEXANOIC ACID, MANGANESE SALT (15956-58-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
ACGIH:
ACGIH TWA (PPM): 100 PPM
ACGIH:
REMARK (ACGIH): EYE, SKIN, & KIDNEY DAM
OSHA:
OSHA PEL (TWA) (MG/M3): 2900 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 500 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 525 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 100 PPM
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3 AS Zr
ACGIH:
ACGIH STEL (MG/M3): 10 MG/M3 AS Zr
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
ENSURE GOOD VENTILATION OF THE WORK STATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: USE RUBBER GLOVES. E
EYE PROTECTION: NONE UNDER NORMAL USE.
RESPIRATORY PROTECTION: NONE UNDER NORMAL USE.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: SOLID MARKER CONTAINING LIQUID COLORED PAINT.
COLOUR: BLACK.
ODOUR: SOLVENT.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 23 - 37.8 DEG. C
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 67%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOUR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
OPEN FLAME. OVERHEATING. DIRECT SUNLIGHT. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: OXIDIZER. ACIDS. ALKALI. MOISTURE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: MAY RELEASE FLAMMABLE GASES.
THERMAL DECOMPOSITION GENERATES: METALLIC OXIDES. CARBON OXIDES (CO, CO2).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
TERT-BUTYL ACETATE (540-88-5):
LD50 ORAL RAT: 4100 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (PPM): 4211 PPM 6 H
ATE CLP (ORAL): 4100.000 MG/KG BODYWEIGHT
CYCLOHEXANONE (108-94-1):
ATE CLP (DUST, MIST): 1.500 MG/L/4H
CARBON BLACK (1333-86-4):
LD50 ORAL RAT: >8000 MG/KG
LC50 INHALATION RAT (MG/L): >4.6 MG/M3 4 H
BUTYL ACETATE (123-86-4):
LD50 ORAL RAT: 10760 MG/KG
LD50 DERMAL RABBIT: >14112 MG/KG
LC50 INHALATION RAT (MG/L): >21 MG/L/4H
ATE CLP (ORAL): 10760.000 MG/KG BODYWEIGHT
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LD50 ORAL RAT: 8532 MG/KG
LD50 DERMAL RAT: >2000 MG/KG
LC50 INHALATION RAT (PPM): 4345 PPM 6 H
ATE CLP (ORAL): 8532.000 MG/KG BODYWEIGHT
ETHYL ACETATE (141-78-6):
LD50 ORAL RAT: 5620 MG/KG
LD50 DERMAL RABBIT: >20000 MG/KG
LC50 INHALATION RAT (MG/L): >18 MG/L/4H
ATE CLP (ORAL): 5620.000 MG/KG BODYWEIGHT
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (MG/L): >5610 MG/M3
2-ETHYLHEXANOIC ACID, MANGANESE SALT (15956-58-8):
LD50 ORAL RAT: 1470 MG/KG BODYWEIGHT READ-ACROSS MnCl2
ATE CLP (ORAL): 1470.000 MG/KG BODYWEIGHT
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (MG/L): >10 MG/L/4H
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RAT: >2000 MG/KG
LC50 INHALATION RAT (MG/L): >4.3 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED.
CYCLOHEXANONE (108-94-1):
IARC GROUP: 3 - NOT CLASSIFIABLE
CARBON BLACK (1333-86-4):
IARC GROUP: 2B - POSSIBLY CARCINOGENIC TO HUMANS, INHALATION OF DUST
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS:
NOT LISTED IN CARCINOGENICITY CLASS
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
NOAEL (ORAL, RAT, 90 DAYS):
300 MG/KG BODYWEIGHT/DAY READ ACROSS 2-ETHYLHEXANOIC ACID; P-GENERATION
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TERT-BUTYL ACETATE (540-88-5):
LC50 FISH 1: 240 MG/L 96 H
EC50 DAPHNIA 1: 410 MG/L 24 H
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LC50 FISH 1: 100 - 180 MG/L
EC50 DAPHNIA 1: >500 MG/L 48 H
ERC50 (ALGAE): >1000 MG/L
ETHYL ACETATE (141-78-6):
LC50 FISH 1: 220 MG/L
EC50 DAPHNIA 1: 1200 MG/L
NOEC CHRONIC FISH: <9.35 MG/L
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LC50 FISH 1: 8.2 MG/L
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LC50 FISH 1: >100 MG/L 96 H
EC50 DAPHNIA 1: >0.17 MG/L 48 H
12.2. PERSISTENCE AND DEGRADABILITY:
TERT-BUTYL ACETATE (540-88-5):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 50% 28 D
CARBON BLACK (1333-86-4):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 89% 10 D
ETHYL ACETATE (141-78-6):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
12.3. BIOACCUMULATIVE POTENTIAL:
TERT-BUTYL ACETATE (540-88-5):
BCF FISH 1: 5.61
LOG POW: 1.64
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LOG POW: 0.43
ETHYL ACETATE (141-78-6):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
LOG POW: 3.16 - 7.15
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT AND TDG:
TRANSPORT DOCUMENT DESCRIPTION:
UN1263 PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE), 3, III
UN-NO.(DOT): UN1263
PROPER SHIPPING NAME (DOT):
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TRANSPORT HAZARD CLASS(ES) (DOT): 3 - FLAMMABLE LIQUID
PACKING GROUP (DOT): III - MINOR DANGER
ADR:
TRANSPORT DOCUMENT DESCRIPTION: UN 1263 PAINT, 3, III, (D/E)
PROPER SHIPPING NAME (ADR): PAINT
PACKING GROUP (ADR): III
TRANSPORT HAZARD CLASS(ES) (ADR): 3
TRANSPORT BY SEA:
UN-NO. (IMDG): UN 1263
PROPER SHIPPING NAME (IMDG): PAINT
TRANSPORT HAZARD CLASS(ES) (IMDG): 3
PACKING GROUP (IMDG): III
AIR TRANSPORT:
UN-NO. (IATA): UN 1263
PROPER SHIPPING NAME (IATA): PAINT
TRANSPORT HAZARD CLASS(ES) (IATA): 3
PACKING GROUP (IATA): III
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CYCLOHEXANONE (108-94-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CARBON BLACK (1333-86-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
BUTYL ACETATE (123-86-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ETHYL ACETATE (141-78-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
2-ETHYLHEXANOIC ACID, MANGANESE SALT (15956-58-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
CYCLOHEXANONE (108-94-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
CARBON BLACK (1333-86-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
BUTYL ACETATE (123-86-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
ETHYL ACETATE (141-78-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
2-ETHYLHEXANOIC ACID, MANGANESE SALT (15956-58-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CYCLOHEXANONE (108-94-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CARBON BLACK (1333-86-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
BUTYL ACETATE (123-86-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
2-METHOXY-1-METHYLETHYL ACETATE (108-65-6):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
ETHYL ACETATE (141-78-6):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (BENZENE <0.1%) (64742-48-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
2-ETHYLHEXANOIC ACID, MANGANESE SALT (15956-58-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT (22464-99-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NATIONAL REGULATIONS:
PRO-LINE(R*) XT PAINT MARKER BLACK:
ALL COMPONENTS ARE LISTED ON THE EEC INVENTORY EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS).
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
15.3. US STATE REGULATIONS:
PRO-LINE(R*) XT PAINT MARKER BLACK:
STATE OR LOCAL REGULATIONS:
THE CARBON BLACK IN THIS PRODUCT IS BOUND AND IS NOT RESPIRABLE.
CALIFORNIA PROP. 65 WARNINGS ARE NOT REQUIRED.
CARBON BLACK (1333-86-4):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
TERT-BUTYL ACETATE (540-88-5):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
CYCLOHEXANONE (108-94-1):
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
CARBON BLACK (1333-86-4):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
BUTYL ACETATE (123-86-4):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
ETHYL ACETATE (141-78-6):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
STODDARD SOLVENT (BENZENE <0.1%) (8052-41-3):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES: SECTION 15.
DATA SOURCES:
ACGIH (AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS).
EUROPEAN CHEMICALS AGENCY (ECHA) C&L INVENTORY DATABASE. ACCESSED AT
HTTP://ECHA.EUROPA.EU/WEB/GUEST/INFORMATION-ON-CHEMICALS/CL-INVENTORY-
DATABASE.
KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK SELECTION GUIDE TO CHEMICAL
PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION. FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
ABBREVIATIONS AND ACRONYMS:
ATE: ACUTE TOXICITY ESTIMATE.
CAS (CHEMICAL ABSTRACTS SERVICE) NUMBER.
CLP: CLASSIFICATION, LABELLING, PACKAGING.
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION.
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION.
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC.
TWA: TIME WEIGHT AVERAGE.
TSCA: TOXIC SUBSTANCES CONTROL ACT.
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 1 - NORMALLY STABLE, BUT CAN BECOME UNSTABLE AT ELEVATED
TEMPERATURES AND PRESSURES OR MAY REACT WITH WATER
WITH SOME RELEASE OF ENERGY, BUT NOT VIOLENTLY.
FULL TEXT OF H-STATEMENTS:
ACUTE TOX. 4 (INHALATION): ACUTE TOXICITY (INHAL.), CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL), CATEGORY 4
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD, CATEGORY 1
CARC. 2: CARCINOGENICITY, CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS, CATEGORY 3
FLAM. LIQ. 4: FLAMMABLE LIQUIDS, CATEGORY 4
REPR. 2: REPRODUCTIVE TOXICITY, CATEGORY 2
STOT RE 1: SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 1
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, NARCOSIS
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H226: FLAMMABLE LIQUID AND VAPOUR
H227: COMBUSTIBLE LIQUID
H302: HARMFUL IF SWALLOWED
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H319: CAUSES SERIOUS EYE IRRITATION
H332: HARMFUL IF INHALED
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H351: SUSPECTED OF CAUSING CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
SDS PREPARED BY:
THE REDSTONE GROUP, LLC
6077 FRANTZ RD.
SUITE 206
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T: 614-923-7472
WWW.REDSTONEGRP.COM
LACO NA GHS SDS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT
EN (ENGLISH)
SDS REF.: LACO1507041