| Common Name: | FIRST ZINC, FZ-200 |
| Manufacturer: | WELD-AID PRODUCTS |
| SDS Revision Date: | 10/6/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 24A434 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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WELD-AID SPATTER PRODUCTS
SAFETY DATA SHEET
FIRST ZINC
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: FIRST ZINC
PRODUCT NUMBER: FZ-200
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PRODUCT USE: WELDING PROCESS AID
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
WELD-AID PRODUCTS
14650 DEQUINDRE
DETROIT, MICHIGAN
INFORMATION PHONE NUMBER:
+1 (313) 883-6977
+1 (313) 883-4930
E-MAIL: INFO@WELDAID.COM
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY SPILL INFORMATION: +1 (800) 255-3924
SDS DATE OF PREPARATION: OCTOBER 6, 2014
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP/GHS CLASSIFICATION (1272/2008):
PHYSICAL:
FLAMMABLE LIQUID: CATEGORY 2
HEALTH:
ASPIRATION TOXICITY: CATEGORY 1
SKIN IRRITATION: CATEGORY 2
CARCINOGEN: CATEGORY 2
ENVIRONMENTAL
AQUATIC ACUTE: CATEGORY 1
AQUATIC CHRONIC: CATEGORY 1
EU CLASSIFICATION (67/548/EEC):
HIGHLY FLAMMABLE (F), HARMFUL (XN), IRRITANT (XI), DANGEROUS FOR THE
ENVIRONMENT (N) R11, R20/21, R38, R50/53
2.2 LABEL ELEMENTS:
DANGER!
CONTAINS ETHYLBENZENE AND XYLENE
FLAME
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
HAZARD PHRASES:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H411: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY PHRASES:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P264: WASH THOROUGHLY AFTER HANDLING.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P301 + P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR.
P331: DO NOT INDUCE VOMITING.
P302 + P352:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
P370 + P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL FOR EXTINCTION.
P391: COLLECT SPILLAGE.
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL AND NATIONAL
REGULATIONS.
2.3 OTHER HAZARDS: NONE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
CHEMICAL NAME CAS# / EINECS# EU CLASSIFICATION (67/548/EEC)
ZINC 7440-66-6 231-175-3 N R50/53
XYLENE 1330-20-7 215-535-7 XN, XI R10, R20/21, R38
ETHYLBENZENE 100-41-4 202-849-4 F, XN, R11, R20
ALIPHATIC PETROLEUM 64742-89-8 265-192-2 F, XN R11, R65
DISTILLATES
STODDARD SOLVENT 8052-41-3 232-489-3 XN R10, R65
VM&P NAPHTHA 64742-95-6 265-199-0 XN R10, R65
CHEMICAL NAME GHS CLASSIFICATION REGULATION %
(EC) NO 1272/2008
ZINC AQUATIC ACUTE CATEGORY 1 (H400) 30-40
AQUATIC CHRONIC CATEGORY 1 (H410)
XYLENE FLAMMABLE LIQUID CATEGORY 3 (H226) 30-40
SKIN IRRITATION CATEGORY 2 (H315)
ACUTE TOXICITY CATEGORY 4 (H332)
ACUTE TOXICITY CATEGORY 4 (H312)
ETHYLBENZENE FLAMMABLE LIQUID CATEGORY 2 (H225) <5
ACUTE TOXICITY CATEGORY 4 (H332)
CARCINOGEN CATEGORY 2 (H351)
ALIPHATIC PETROLEUM FLAMMABLE LIQUID 3 (H226) <5
DISTILLATES ASPIRATION TOXICITY CATEGORY 1 (H304)
STODDARD SOLVENT FLAMMABLE LIQUID 3 (H226) <5
ASPIRATION TOXICITY CATEGORY 1 (H304)
VM&P NAPHTHA FLAMMABLE LIQUID 3 (H226) <5
ASPIRATION TOXICITY CATEGORY 1 (H304)
SEE SECTION 16 FOR FURTHER INFORMATION ON EU AND GHS CLASSIFICATION.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
EYES:
FLUSH EYES IMMEDIATELY WITH WATER FOR SEVERAL MINUTES, HOLDING THE EYELIDS
APART. IF IRRITATION DEVELOPS, MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH EXPOSED AREA THOROUGHLY WITH
SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. GET MEDICAL
ATTENTION IF IRRITATION PERSISTS.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT HAVE QUALIFIED PERSONNEL
ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, ADMINISTER ARTIFICIAL
RESPIRATION. GET MEDICAL ATTENTION.
INGESTION:
RINSE MOUTH WITH A SMALL AMOUNT OF WATER. ASPIRATION HAZARD - DO NOT INDUCE
VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR DROWSY PERSON.
GET IMMEDIATE MEDICAL ATTENTION.
NOTES TO PHYSICIANS: TREAT SYMPTOMATICALLY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY CAUSES EYE AND SKIN IRRITATION. INHALATION OF VAPORS OR MIST MAY CAUSE
RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS HEADACHE,
DIZZINESS, DROWSINESS, NAUSEA AND UNCONSCIOUSNESS. HARMFUL OR FATAL IF
SWALLOWED. ASPIRATION DURING SWALLOWING OR VOMITING MAY CAUSE LUNG DAMAGE.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: IMMEDIATE MEDICAL TREATMENT IS REQUIRED INGESTION
| SECTION 5: FIRE FIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
USE CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL. DO NOT USE WATER TO
EXTINGUISH FIRE. WATER SPRAY CAN BE USED TO COOL EXPOSED CONTAINERS AND
STRUCTURES.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLAMMABLE LIQUID AND VAPOR. VAPORS ARE HEAVIER THAN AIR AND MAY AND
ACCUMULATE IN LOW LYING AREA.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND ZINC OXIDE.
5.3 ADVICE FOR FIRE-FIGHTERS:
FIREFIGHTERS SHOULD ALWAYS WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING FOR FIRES INVOLVING CHEMICALS OR IN CONFINED SPACES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE SPILL AREA AND KEEP UNPROTECTED PERSONNEL AWAY. ELIMINATE ALL
IGNITION SOURCES. VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE CLOTHING AS
DESCRIBED IN SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS:
AVOID CONTAMINATION OF SOIL, SURFACE WATER AND GROUND WATER. DO NOT FLUSH
TO SEWER! REPORT RELEASES AS REQUIRED BY LOCAL, STATE AND FEDERAL
AUTHORITIES.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN AND COLLECT USING AN ABSORBENT MATERIAL AND PLACE IN AN APPROPRIATE
CONTAINER FOR DISPOSAL.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 FOR PROTECTIVE EQUIPMENT AND SECTION 15 FOR DISPOSAL
CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH THE EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS. DO
NOT SWALLOW. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE
VENTILATION. DO NOT USE IN POORLY VENTILATED OR CONFINED SPACES. VAPORS ARE
HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. WASH THOROUGHLY WITH SOAP
AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING OR USING RESTROOM. DO
NOT EAT, DRINK OR SMOKE IN WORK AREAS.
DO NOT CUT, DRILL, GRIND OR WELD ON OR NEAR CONTAINERS, EVEN EMPTY
CONTAINERS. FOLLOW ALL SDS PRECAUTIONS WHEN HANDLING EMPTY CONTAINERS.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY OXIDIZING AGENTS AND OTHER
INCOMPATIBLE MATERIALS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
KEEP AWAY FROM HEAT, SPARKS AND FLAMES.
7.3 SPECIFIC END USE(S): WELDING PRODUCT
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME EXPOSURE LIMITS
ZINC (AS METAL) 0.1 MG/M3 TWA DFG MAK; 0.4 MG/M3 STEL (RESPIRABLE)
2 MG/M3 TWA DFG MAK
XYLENE 100 PPM TWA ACGIH TLV; 150 PPM STEL
100 PPM OSHA PEL
50 PPM TWA EU IOEL; 100 PPM STEL
100 PPM TWA DFG MAK; 200 PPM STEL
50 PPM TWA UK OEL; 100 PPM STEL
ETHYLBENZENE 20 PPM TWA ACGIH TLV
100 PPM OSHA PEL
100 PPM TWA EU IOEL; 200 PPM STEL
20 PPM TWA DFG MAK; 40 PPM STEL
100 PPM TWA UK OEL; 125 PPM STEL
ALIPHATIC PETROLEUM 5 MG/M3 TWA ACGIH TLV (INHALABLE) (AS MINERAL OIL)
DISTILLATES 5 MG/M3 TWA OSHA PEL (AS OIL MIST)
10 MG/M3 STEL UK OEL
STODDARD SOLVENT 100 PPM TWA ACGIH TLV
500 PPM TWA OSHA PEL
VM&P NAPHTHA 5 MG/M3 TWA ACGIH TLV (INHALABLE) (AS MINERAL OIL)
5 MG/M3 TWA OSHA PEL (AS OIL MIST)
10 MG/M3 STEL UK OEL
8.2 EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE WITH ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURES BELOW THE
OCCUPATIONAL EXPOSURE LIMITS. USE EXPLOSION PROOF EQUIPMENT WHERE REQUIRED.
RESPIRATORY PROTECTION:
IF THE EXPOSURE LIMITS ARE EXCEEDED AN APPROVED ORGANIC VAPOR RESPIRATOR
APPROPRIATE FOR THE FORM AND CONCENTRATION OF THE CONTAMINANTS SHOULD BE
USED. SELECTION AND USE OF RESPIRATORY EQUIPMENT MUST BE IN ACCORDANCE WITH
APPLICABLE REGULATIONS AND GOOD INDUSTRIAL HYGIENE PRACTICE.
SKIN PROTECTION: WEAR IMPERVIOUS GLOVES SUCH AS VITON OR TEFLON.
EYE PROTECTION:
CHEMICAL SAFETY GOGGLES SHOULD BE WORN TO WHERE SPLASHING IS POSSIBLE.
OTHER:
IMPERVIOUS CLOTHING AS NEEDED TO PREVENT CONTACT. WASHING FACILITIES SHOULD
BE AVAILABLE IN THE WORK AREA.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: SILVER LIQUID
ODOR: SWEET
ODOR THRESHOLD: 0.85 PPM (XYLENE)
PH: NOT AVAILABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE
BOILING POINT: 210 DEG. F (98.9 DEG. C)
FLASH POINT: 45 DEG. F (7.2 DEG. C)
EVAPORATION RATE: >1 (BUTYL ACETATE = 1)
FLAMMABLE LIMITS:
LEL: 0.9% (ETHYLBENZENE)
UEL: 8.0% VM&P NAPHTHA
VAPOR PRESSURE: NOT AVAILABLE
VAPOR DENSITY: >1 (AIR = 1)
SPECIFIC GRAVITY: 1.42
WATER SOLUBILITY: NOT AVAILABLE
OCTANOL/WATER PARTITION COEFFICIENT: NOT AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
EXPLOSION PROPERTIES: VAPORS MAY BE EXPLOSIVE IN CONFINE AREAS.
OXIDIZING PROPERTIES: NOT AN OXIDIZER.
9.2 OTHER INFORMATION: NONE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS OF USE.
10.2 CHEMICAL STABILITY:
STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN
10.4 CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES.
10.5 INCOMPATIBLE MATERIALS: AVOID ALKALIS, ACIDS AND OXIDIZING AGENTS.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE, CARBON DIOXIDE AND ZINC OXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
EYE: MAY CAUSE IRRITATION WITH REDNESS, TEARING AND SWELLING.
SKIN:
CAUSES IRRITATION. REPEATED EXPOSURE MAY CAUSE DERMATITIS. MAY BE HARMFUL
IF ABSORBED THROUGH THE SKIN WITH SYMPTOMS SIMILAR TO INHALATION.
INGESTION:
SWALLOWING MAY CAUSE GASTROINTESTINAL EFFECTS, AND CENTRAL NERVOUS SYSTEM
EFFECTS INCLUDING NAUSEA, VOMITING, DIARRHEA, DIZZINESS, DROWSINESS, AND
UNCONSCIOUSNESS. ASPIRATION DURING SWALLOWING OR VOMITING MAY CAUSE
CHEMICAL PNEUMONIA OR LUNG DAMAGE.
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION AND CENTRAL NERVOUS SYSTEM EFFECTS
SUCH AS DIZZINESS, DROWSINESS, NAUSEA, HEADACHE LIGHTHEADEDNESS, STUPOR,
AND UNCONSCIOUSNESS.
ACUTE TOXICITY VALUES:
ACUTE TOXICITY ESTIMATE FOR THE PRODUCT:
ORAL: 3736 MG/KG
INHALATION: 16.2 MG/L/4 HR
DERMAL: 19611.7 MG/KG
ZINC:
ORAL RAT LD50: >2000 MG/KG
INHALATION RAT LC50: >5.41 MG/M3/4 HR
XYLENE:
LD50 ORAL RAT: 5637 MG/KG
LD50 DERMAL RABBIT: 12126 MG/KG
LC50 INHALATION RAT: 29 MG/L/4 HR
ETHYLBENZENE:
ORAL RAT LD50: 3500 MG/KG
INHALATION RAT LC50: 17.4 MG/L/4 HR
DERMAL RABBIT LD50: 15.4 G/KG
ALIPHATIC PETROLEUM DISTILLATES:
ORAL RAT LD50: >5000 MG/KG
SKIN RABBIT LD50: >2000 MG/KG
VM&P NAPHTHA:
ORAL RAT LD50: >8000 MG/KG
INHALATION RAT LC50: 3400 PPM/4 HR
SKIN RAT LC50: >4,000 MG/KG
STODDARD SOLVENT:
ORAL RAT LD50: >3000 MG/KG
SKIN RABBIT LD50: 3160 MG/KG
IRRITATION:
THIS PRODUCT IS EXPECTED TO CAUSE SKIN IRRITATION. PROLONGED SKIN CONTACT
WITH PETROLEUM SOLVENT MAY CAUSE DEFATTING OF THE SKIN AND DERMATITIS.
CORROSIVITY: THIS IS NOT A CORROSIVE PRODUCT.
SENSITIZATION: THIS PRODUCT IS NOT EXPECTED TO CAUSE SENSITIZATION.
REPEAT DOSE TOXICITY:
IN REPEATED DOSE STUDIES, THE PRINCIPLE EFFECTS OF XYLENES WERE ADAPTIVE
CHANGES IN THE LIVER, BODY WEIGHT CHANGES, ORGAN WEIGHT CHANGES AND ALTERED
MOTOR COORDINATION. AVAILABLE CASE REPORTS, OCCUPATIONAL STUDIES, AND
STUDIES ON HUMAN VOLUNTEERS SUGGEST THAT BOTH SHORT-AND LONG-TERM
EXPOSURES RESULT IN A VARIETY OF ADVERSE NERVOUS SYSTEM EFFECTS THAT
INCLUDE HEADACHE, MENTAL CONFUSION, NARCOSIS, EQUILIBRIUM, IMPAIRED
SHORT-TERM MEMORY, DIZZINESS AND TREMORS. REPORTS HAVE ASSOCIATED REPEATED
AND PROLONGED OVEREXPOSURE TO PETROLEUM DISTILLATES WITH ADVERSE LIVER,
KIDNEY AND BONE MARROW EFFECTS AND WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE
PRODUCT MAY BE HARMFUL OR FATAL. STODDARD SOLVENT AND VM&P NAPHTHA HAVE
BEEN SHOWN TO CAUSE KIDNEY AND LIVER DAMAGE IN REPEAT DOSE ANIMAL STUDIES.
CARCINOGEN STATUS:
ETHYLBENZENE IS LISTED BY IARC AS "POSSIBLY CARCINOGENIC TO HUMANS (GROUP
2B) AND AS A "CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
(A3) BY ACGIH. NTP CONDUCTED A TWO YEAR CARCINOGENICITY STUDY WITH STODDARD
SOLVENT IN RATS AND MICE. THE STUDIES INDICATED THERE WAS SOME EVIDENCE OF
CARCINOGENIC ACTIVITY IN MALE RATS BUT NONE IN FEMALE RATS. IN MICE THERE
IS EQUIVOCAL EVIDENCE IN FEMALE MICE FOR CARCINOGENIC ACTIVITY BUT NO
EVIDENCE IN MALE MICE. IARC HAS CLASSIFIED PETROLEUM SOLVENTS "NOT
CLASSIFIABLE AS TO THEIR CARCINOGENICITY TO HUMANS. NONE OF THE OTHER
COMPONENTS ARE LISTED AS CARCINOGENS BY IARC, NTP, ACGIH, OSHA OR THE CLP
REGULATION (EC) NO 1272/2008.
GERM CELL MUTAGENICITY:
ETHYLBENZENE WAS NEGATIVE IN THE AMES TEST, CHROMOSOME ABERRATION ASSAY,
SISTER CHROMATID EXCHANGE AND IN VIVO MICRONUCLEUS ASSAY. IT WAS POSITIVE
IN A MOUSE LYMPHOMA ASSAY. AVAILABLE DATA FROM BOTH IN VITRO AND IN VIVO
STUDIES SUGGEST THAT XYLENES ARE NOT GENOTOXIC. STODDARD SOLVENT WAS
NEGATIVE IN THE AMES TEST, IN A MOUSE LYMPHOMA ASSAY AND IN AN IN VIVO BONE
MARROW ASSAY.
TOXICITY FOR REPRODUCTION:
ETHYLBENZENE:
IN A DEVELOPMENTAL STUDY, RATS WERE EXPOSED TO 100 TO 1000 PPM FOR 1-19
DAYS AFTER GESTATION. AT 1000 PPM MATERNAL TOXICITY AND LIMITED
DEVELOPMENTAL TOXICITY WAS OBSERVED. NOEAL (MATERNAL AND DEVELOPMENTAL)
WAS CONSIDERED TO BE 100 PPM.
XYLENE:
INHALATION EXPOSURE OF RATS FROM GESTATION DAY 6-20 FOR 6HR/DAY PRODUCED
MATERNAL TOXICITY AT 100 PPM AND FETAL TOXICITY EFFECTS AT 500 PPM. NOEAL
FOR MATERNAL TOXICITY WAS CONSIDERED TO BE 500 PPM AND DEVELOPMENTAL
TOXICITY WAS 100 PPM.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
ZINC:
96 HE LC50 COTTUS BAIRDII: 439 (MICRO)G/L
48 HR EC50 DAPHNIA MAGNA: 1833 (MICRO)G/L
72 HR IC50 PSEUDOKIRCHNERELLA SUBCAPITATA: 150 (MICRO)G/L
XYLENE:
96 HR EC50 ONCORHYNCHUS MYKISS: 12.4 MG/L
24 HR IC50 DAPHNIA MAGNA: 1 MG/L
72 HE EC50 PSEUDOKIRCHNERELLA SUBCAPITATA: 4.36 MG/L
ETHYLBENZENE:
96 HR LC50 ONCORHYNCHUS MYKISS.: 4.2 MG/L
48 HR EC50 DAPHNIA MAGNA: 1.8 MG/L
72 HR EC50 PSEUDOKIRCHNERELLA SUBCAPITATA: 5.4 MG/L
ALIPHATIC PETROLEUM DISTILLATES:
96 HR LL50 PIMEPHALES PROMELAS: 8.2 MG/L
48 HE EL50 DAPHNIA MAGNA: 4.5 MG/L
72 HE EL50 PSEUDOKIRCHNERELLA SUBCAPITATA: 3.1 MG/L
VM&P NAPHTHA:
96 HR LL50 ONCORHYNCHUS MYKISS: 8.2 MG/L
48 HR LL50 DAPHNIA MAGNA: 4.5 MG/L
72 HR EL50 PSEUDOKIRCHNERELLA SUBCAPITATA: 3.1 MG/L
STODDARD SOLVENT: NO DATA AVAILABLE
12.2 PERSISTENCE AND DEGRADABILITY:
XYLENE, ETHYLBENZENE, STODDARD SOLVENT, VM&P NAPHTHA AND VM&P NAPHTHA ARE
READILY BIODEGRADABLE.
12.3 BIOACCUMULATIVE POTENTIAL:
ETHYLBENZENE HAS A BCF OF 15 AND XYLENE HAS A BCF OF 6 TO 24.6 WHICH
SUGGESTS THE POTENTIAL FOR BIOACCUMULATION IN AQUATIC ANIMALS IS LOW FOR
THESE CHEMICALS. STODDARD SOLVENT, ALIPHATIC PETROLEUM DISTILLATES AND VM&P
NAPHTHA HAVE A CALCULATED BFC OF >3 WHICH INDICATES THERE IS A POTENTIAL
FOR BIOACCUMULATION.
12.4 MOBILITY IN SOIL:
XYLENE IS EXPECTED TO HAVE A HIGH TO MODERATE MOBILITY IN SOIL.
ETHYLBENZENE IS EXPECTED TO HAVE A LOW MOBILITY IN SOIL.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NOT REQUIRED.
12.6 OTHER ADVERSE EFFECTS:
THIS PRODUCT IS CLASSIFIED AS VERY TOXIC TO AQUATIC ORGANISMS BASED ON ZINC
CONTENT.
| SECTION 13: DISPOSAL INFORMATION | |
13.1 WASTE TREATMENT METHODS:
DISPOSE IN ACCORDANCE WITH LOCAL AND NATIONAL ENVIRONMENTAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
41.1 UN 41.2 UN PROPER 14.3 14.4 14.5
NUMBER SHIPPING NAME TRANSPORT PACKING ENVIRONMENTAL
HAZARD GROUP HAZARDS
CLASS(S)
US DOT UN1263 PAINT RELATED 3 PGII NO
MATERIAL
EU ADR/RID UN1263 PAINT RELATED 3 PGII YES
MATERIAL
IMDG UN1263 PAINT RELATED 3 PGII YES
MATERIAL
14.6 SPECIAL PRECAUTIONS FOR USER: NONE
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
INTERNATIONAL INVENTORIES:
US EPA TSCA INVENTORY:
ALL OF THE COMPONENTS ARE LISTED ON THE TSCA INVENTORY.
CANADIAN ENVIRONMENTAL PROTECTION ACT:
ALL OF THE INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
EUROPEAN UNION:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EUROPEAN INVENTORY
OF NEW AND EXISTING CHEMICAL SUBSTANCES (EINECS) INVENTORY.
AUSTRALIA:
ALL OF THE INGREDIENTS OF THIS PRODUCT ARE LISTED ON THE AUSTRALIAN
INVENTORY OF CHEMICAL SUBSTANCES (AICS).
CHINA:
ALL OF THE INGREDIENTS OF THIS PRODUCT ARE LISTED ON THE INVENTORY OF
EXISTING CHEMICAL SUBSTANCE IN CHINA (IECSC).
KOREA:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE KOREAN EXISTING
CHEMICAL LIST (KECL).
NEW ZEALAND:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE NEW ZEALAND
INVENTORY OF CHEMICALS (NZIOC).
PHILIPPINES:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE PHILIPPINE
INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS).
U.S. REGULATIONS:
CERCLA:
THIS PRODUCT HAS A REPORTABLE QUANTITY (RQ) OF 307 LBS. BASED ON THE RQ FOR
XYLENE OF 100 LBS. RELEASES ABOVE THE RQ MUST BE REPORTED TO THE NATIONAL
RESPONSE CENTER. MANY STATES HAVE MORE STRINGENT RELEASE REPORTING
REQUIREMENTS. REPORT SPILLS REQUIRED UNDER FEDERAL, STATE AND LOCAL
REGULATIONS.
EPA SARA 302:
THIS PRODUCT DOES NOT CONTAIN CHEMICALS REGULATED UNDER SARA SECTION 302.
EPA SARA 311 HAZARD CLASSIFICATION:
ACUTE HEALTH, CHRONIC HEALTH, FIRE HAZARD
EPA SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS THAT ARE REGULATED UNDER SARA
TITLE III, SECTION 313:
XYLENE 1330-20-7 32.6%
ETHYLBENZENE 100-41-1 4.3%
ZINC 7440-66-6 39.5
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS WHICH ARE KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE CANCER, REPRODUCTIVE TOXICITY OR BIRTH DEFECTS:
ETHYLBENZENE 100-41-4 1-5% (CANCER)
INTERNATIONAL REGULATIONS:
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 (FLAMMABLE LIQUID), CLASS D DIVISION 2 SUBDIVISION A
(VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS)
15.2 CHEMICAL SAFETY ASSESSMENT: NOT REQUIRED
| SECTION 16: OTHER INFORMATION | |
SDS REVISION HISTORY:
12/06/11: CONVERTED US SDS TO EU REACH SDS
10/6/14:
SECTION 2 LABELING ELEMENTS, HAZARD PHRASES, PRECAUTIONARY PHRASES, SECTION
3 GHS CLASSIFICATION, SECTION 4 FIRST AID - EYES, SKIN, INHALATION, MOST
IMPORTANT SYMPTOMS AND EFFECTS, SECTION 7 PRECAUTIONS FOR SAFE HANDLING,
SECTION 8 OTHER, SECTION 9 OXIDIZING PROPERTIES, SECTION 11 ACUTE TOXICITY
VALUES, IRRITATION, SECTION 12 TOXICITY,
GHS PHRASES FOR REFERENCE (SEE SECTION 2 AND 3):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H312: HARMFUL IN CONTACT WITH SKIN.
H332: HARMFUL IF INHALED.
H351: SUSPECTED OF CAUSING CANCER.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
EU CLASSES AND RISK PHRASES FOR REFERENCE (SEE SECTIONS 2 AND 3):
F: HIGHLY FLAMMABLE
N: DANGEROUS FOR THE ENVIRONMENT
XI: IRRITANT
XN: HARMFUL
R10: FLAMMABLE
R11: HIGHLY FLAMMABLE
R20: HARMFUL BY INHALATION.
R20/21: HARMFUL BY INHALATION AND IN CONTACT WITH SKIN.
R38: IRRITATING TO SKIN.
R50/53:
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
R65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
THIS SHEET WAS COMPILED FROM THE LATEST AVAILABLE INFORMATION AND RELIABLE
SOURCES. PROCEDURES ARE BASED ON ACCEPTED USAGE. THEY ARE NOT NECESSARILY
ALL-INCLUSIVE AND MAY VARY IN EVERY CIRCUMSTANCE. WELD-AID PROVIDES NO
WARRANTIES EITHER EXPRESSED OR IMPLIED AND ASSUMES NO RESPONSIBILITY FOR
THE ACCURACY OR COMPLETENESS OF THE DATA HEREIN.