| Common Name: | SULFIDE NO.2 |
| Manufacturer: | TINTOMETER |
| SDS Revision Date: | 1/15/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 24AP22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LOVIBOND(R*) WATER TESTING
TINTOMETER(R*) GROUP
LOVIBOND(R*)
SAFETY DATA SHEET
ACC. TO OSHA HCS (HAZCOM 2012)
PRINTING DATE: 01/15/2020
REVIEWED ON: 01/15/2020
| 1 IDENTIFICATION |  |
|
PRODUCT IDENTIFIER:
TRADE NAME: SULFIDE NO.2
CATALOGUE NUMBER: 00512941, 00502940, 502940
APPLICATION OF THE SUBSTANCE / THE MIXTURE: REAGENT FOR WATER ANALYSIS
MANUFACTURER/SUPPLIER:
TINTOMETER INC.
6456 PARKLAND DRIVE
SARASOTA, FL 34243
USA
PHONE: (941) 756-6410
FAX: (941) 727-9654
WWW.LOVIBOND.US
MADE IN GERMANY
EMERGENCY TELEPHONE NUMBER: + 1 866 928 0789 (ENGLISH, FRENCH, SPANISH)
| 2 HAZARD(S) IDENTIFICATION | |
|
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS08: HEALTH HAZARD
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MUTA. 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARC. 1B:
H350: MAY CAUSE CANCER.
REPR. 1B:
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
GHS05: CORROSION
EYE DAM. 1:
H318: CAUSES SERIOUS EYE DAMAGE.
GHS07: EXCLAMATION MARK
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
AQUATIC CHRONIC 3:
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE HAZARD COMMUNICATION
STANDARD (HCS).
HAZARD PICTOGRAMS:
GHS05: CORROSION
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING:
SODIUM BISULFATE
BORIC ACID
POTASSIUM DICHROMATE
POTASSIUM CHROMATE
HAZARD STATEMENTS:
H318: CAUSES SERIOUS EYE DAMAGE.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H340: MAY CAUSE GENETIC DEFECTS.
H350: MAY CAUSE CANCER.
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P302+P352 IF ON SKIN: WASH WITH PLENTY OF WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P310:
IF EXPOSED OR CONCERNED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P405: STORE LOCKED UP.
OTHER HAZARDS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
|
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION:
MIXTURE: CONSISTING OF THE FOLLOWING HAZARDOUS COMPONENTS.
COMPOSITION AND INFORMATION ON INGREDIENTS:
THE PERCENT CONTENT OF THE CHROMIUM COMPOUND MENTIONED BELOW REFERS TO THE
AMOUNT OF THE CHROMATE IONS DISSOLVED IN WATER. PERCENT RANGES ARE USED DUE
TO THE CONFIDENTIAL PRODUCT INFORMATION.
CAS: 7681-38-1 SODIUM BISULFATE 60-70%
EINECS: 231-665-7 EYE DAM. 1, H318
INDEX NUMBER: 016-046-00-X
RTECS: VZ1860000
CAS: 10043-35-3 BORIC ACID 10-20%
EINECS: 233-139-2 REPR. 1B, H360
INDEX NUMBER: 005-007-00-2
RTECS: ED 4550000
CAS: 124-04-9 ADIPIC ACID 10-20%
EINECS: 204-673-3 EYE IRRIT. 2A, H319
INDEX NUMBER: 607-144-00-9
RTECS: AU 8400000
CAS: 7778-50-9 POTASSIUM DICHROMATE 0.1-<0.25%
EINECS: 231-906-6 OX. SOL. 2, H272
INDEX NUMBER: 024-002-00-6 ACUTE TOX. 3, H301
RTECS: HX 7680000 ACUTE TOX. 2, H330
RESP. SENS. 1, H334
MUTA. 1B, H340
CARC. 1B, H350
REPR. 1B, H360
STOT RE 1, H372
SKIN CORR. 1B, H314
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
ACUTE TOX. 4, H312
SKIN SENS. 1, H317
CAS: 7789-00-6 POTASSIUM CHROMATE 0.1-<0.25%
EINECS: 232-140-5 MUTA. 1B, H340
INDEX NUMBER: 024-006-00-8 CARC. 1B, H350
RTECS: GB 2940000 AQUATIC ACUTE 1,
H400 (M=10)
AQUATIC CHRONIC 1,
H410 (M=10)
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
SKIN SENS. 1, H317
STOT SE 3, H335
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD PHRASES REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION: IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
AFTER INHALATION:
SUPPLY FRESH AIR.
SEEK MEDICAL TREATMENT.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
SEEK MEDICAL TREATMENT.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 15 MIN) UNDER RUNNING WATER.
CALL A DOCTOR IMMEDIATELY.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER.
CALL A DOCTOR IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITATIONS
ALLERGIC REACTIONS
AFTER INHALATION:
MUCOSAL IRRITATIONS, COUGH, BREATHING DIFFICULTY
AFTER SWALLOWING:
RESORPTION
SICKNESS
VOMITING
AFTER ABSORPTION OF LARGE AMOUNTS:
BREATHING DIFFICULTY
DROP IN TEMPERATURE
CNS DISORDERS
FATIGUE
ATAXIA (IMPAIRED LOCOMOTOR COORDINATION)
CARDIOVASCULAR DISORDERS
DANGER:
DANGER OF CIRCULATORY COLLAPSE.
DANGER OF PULMONARY EDEMA.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT COMBUSTIBLE.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
IN CASE OF FIRE, THE FOLLOWING CAN BE RELEASED:
NITROGEN OXIDES (NOx)
SULFUR OXIDES (SOx)
CHROMIUM OXIDES
SODIUM OXIDE
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER THE
SEWAGE SYSTEM.
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPORS.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
AVOID SUBSTANCE CONTACT.
ENSURE ADEQUATE VENTILATION
ADVICE FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: SEE SECTION 8
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
PICK UP MECHANICALLY.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING: PROVIDE SUCTION EXTRACTORS IF DUST IS FORMED.
HYGIENE MEASURES:
DO NOT INHALE DUST / SMOKE / MIST.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
STORE PROTECTIVE CLOTHING SEPARATELY.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FLAMMABLE SUBSTANCES.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE UNDER LOCK AND KEY AND WITH ACCESS RESTRICTED TO TECHNICAL EXPERTS OR
THEIR ASSISTANTS ONLY.
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
PROTECT FROM EXPOSURE TO THE LIGHT.
PROTECT FROM HUMIDITY AND WATER.
THIS PRODUCT IS HYGROSCOPIC.
RECOMMENDED STORAGE TEMPERATURE: 20 DEG. C +/- 5 DEG. C (APPROX. 68 DEG. F)
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
|
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT.
CAS: 10043-35-3 BORIC ACID
TLV (USA):
SHORT-TERM VALUE: 6* MG/M3
LONG-TERM VALUE: 2* MG/M3
*AS INHALABLE FRACTION
EL (CANADA):
SHORT-TERM VALUE: 6 MG/M3
LONG-TERM VALUE: 2 MG/M3
EV (CANADA):
SHORT-TERM VALUE: 6 MG/M3
LONG-TERM VALUE: 2 MG/M3
INORGANIC, INHALABLE:
CAS: 124-04-9 ADIPIC ACID
TLV (USA):
LONG-TERM VALUE: 5 MG/M3
EL (CANADA):
LONG-TERM VALUE: 5 MG/M3
EV (CANADA):
LONG-TERM VALUE: 5 MG/M3
CAS: 7778-50-9 POTASSIUM DICHROMATE
PEL (USA):
LONG-TERM VALUE: 0.005* MG/M3
CEILING LIMIT VALUE: 0.1** MG/M3
*AS Cr(VI) **AS CrO3; SEE 29 CFR 1910.1026
REL (USA):
LONG-TERM VALUE: 0.0002 MG/M3
AS Cr; SEE POCKET GUIDE APPS. A AND C
TLV (USA):
SHORT-TERM VALUE: 0.0005 MG/M3
LONG-TERM VALUE: 0.0002 MG/M3
AS Cr(VI); INHALABLE, SKIN; BEI, DSEN, RSEN
EL (CANADA):
LONG-TERM VALUE: 0.025 MG/M3
CEILING LIMIT VALUE: 0.1 MG/M3
AS Cr; ACGIH A1, IARC 1; SKIN; S(D), S(R)
CAS: 7789-00-6 POTASSIUM CHROMATE
PEL (USA):
LONG-TERM VALUE: 0.005* MG/M3
CEILING LIMIT VALUE: 0.1** MG/M3
*AS Cr(VI) **AS CrO3; SEE 29 CFR 1910.1026
REL (USA):
LONG-TERM VALUE: 0.0002 MG/M3
AS Cr; SEE POCKET GUIDE APPS. A AND C
TLV (USA):
SHORT-TERM VALUE: 0.0005 MG/M3
LONG-TERM VALUE: 0.0002 MG/M3
AS Cr(VI); INHALABLE, SKIN; BEI, DSEN, RSEN
EL (CANADA):
LONG-TERM VALUE: 0.025 MG/M3
CEILING LIMIT VALUE: 0.1 MG/M3
AS Cr; ACGIH A1, IARC 1; SKIN; S(D), S(R)
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
CAS: 7778-50-9 POTASSIUM DICHROMATE
BEI (USA):
25 (MICRO)G/L
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER: TOTAL CHROMIUM (FUME)
10 (MICRO)G/L
MEDIUM: URINE
TIME: INCREASE DURING SHIFT
PARAMETER: TOTAL CHROMIUM (FUME)
CAS: 7789-00-6 POTASSIUM CHROMATE
BEI (USA):
25 (MICRO)G/L
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER: TOTAL CHROMIUM (FUME)
10 (MICRO)G/L
MEDIUM: URINE
TIME: INCREASE DURING SHIFT
PARAMETER: TOTAL CHROMIUM (FUME)
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT.
SEE ITEM 7.
PERSONAL PROTECTIVE EQUIPMENT:
PROTECTIVE CLOTHING SHOULD BE SELECTED SPECIFICALLY FOR THE WORKPLACE,
DEPENDING ON CONCENTRATION AND QUANTITY OF THE HAZARDOUS SUBSTANCES
HANDLED.
BREATHING EQUIPMENT:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUME/DUST/AEROSOL.
IN CASE OF BRIEF EXPOSURE OR LOW POLLUTION USE RESPIRATORY FILTER DEVICE.
IN CASE OF INTENSIVE OR LONGER EXPOSURE USE RESPIRATORY PROTECTIVE DEVICE
THAT IS INDEPENDENT OF CIRCULATING AIR.
RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: FILTER P3
PROTECTION OF HANDS:
PROTECTIVE GLOVES
PREVENTIVE SKIN PROTECTION BY USE OF SKIN-PROTECTING AGENTS IS RECOMMENDED.
AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
RECOMMENDED THICKNESS OF THE MATERIAL: >/= 0.11 MM
PENETRATION TIME OF GLOVE MATERIAL:
VALUE FOR THE PERMEATION: LEVEL </= 1 (10 MIN)
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM / PHYSICAL STATE: TABLETS
COLOR: WHITE
ODOR: ODORLESS
ODOR THRESHOLD: NOT APPLICABLE.
PH-VALUE (11.1 G/L) AT 20 DEG. C (68 DEG. F): 1.7
MELTING POINT/FREEZING POINT: NOT DETERMINED.
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED.
FLASH POINT: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): THE PRODUCT IS NOT COMBUSTIBLE.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: NOT APPLICABLE.
UPPER: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE
VAPOR PRESSURE: NOT APPLICABLE.
DENSITY AT 20 DEG. C (68 DEG. F): 1.9 G/CM3 (15.86 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY(IES):
WATER: SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE.
VISCOSITY: NOT APPLICABLE.
SOLVENT CONTENT:
SOLIDS CONTENT: 100%
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: SEE SECTION "POSSIBILITY OF HAZARDOUS REACTIONS"
CHEMICAL STABILITY: STABLE AT AMBIENT TEMPERATURE (ROOM TEMPERATURE).
POSSIBILITY OF HAZARDOUS REACTIONS:
AQUEOUS SOLUTION REACTS WITH METALS.
FORMS HYDROGEN IN AQUEOUS SOLUTION WITH METALS (DANGER OF EXPLOSION!).
LIBERATES ACID IN CONTACT WITH WATER OR ALCOHOL.
REACTS WITH STRONG ALKALIS AND OXIDIZING AGENTS.
CONDITIONS TO AVOID: TO AVOID THERMAL DECOMPOSITION DO NOT OVERHEAT.
INCOMPATIBLE MATERIALS:
METALS
STEEL
IRON
ORGANIC SUBSTANCES
HAZARDOUS DECOMPOSITION PRODUCTS: SEE SECTION 5
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ACUTE TOXICITY ESTIMATE (ATE(MIX)) - CALCULATION METHOD:
ORAL:
GHS ATE(MIX): 2817 MG/KG (.)
INHALATIVE:
GHS ATE(MIX): 62 MG/L/4H (DUST)
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
CAS: 7681-38-1 SODIUM BISULFATE
ORAL:
LD50: 2490 MG/KG (RAT) (IUCLID)
DERMAL:
LD50.: >2000 MG/KG (RABBIT)
CAS: 10043-35-3 BORIC ACID
ORAL:
LD50: 2660 MG/KG (RAT) (OECD 401) (GESTIS, ECHA REGISTRANT)
DERMAL:
LD50.: >2000 MG/KG (RAT) (ECHA, REGISTRANT: NO DEATHS OCCURRED.)
LD0: 1500 MG/KG (CHILD) (MERCK)
INHALATIVE:
LC50.:
>2.03 MG/L/4H (RAT) (OECD 403, AEROSOL) (ECHA, REGISTRANT: NO DEATHS
OCCURRED)
NOAEL: 9.6 MG/KG (RAT) (NTP)
CAS: 124-04-9 ADIPIC ACID
ORAL:
LD50: 5700 MG/KG (RAT) (MERCK)
DERMAL:
LD50: >7940 MG/KG (RABBIT) (REGISTRANT, ECHA: NO DEATHS OCCURRED)
INHALATIVE:
LC50.:
>7.7 MG/L/4H (RAT) (DUST, AEROSOL) (REGISTRANT, ECHA: NO DEATHS OCCURRED)
CAS: 7778-50-9 POTASSIUM DICHROMATE
ORAL:
LD50:
90.5 MG/KG (RAT) (OECD 401) (ECHA, REGISTRANT: LD50 = 90.5 MG/KG FEMALE TO
168.0 MG/KG MALE)
LDLO:
26 MG/KG (CHILD)
143 MG/KG (MAN)
DERMAL:
LD50: 1170 MG/KG (RAT) (IUCLID)
INHALATIVE:
LC50: 0.094 MG/L/4H (RAT) (OECD 403, AEROSOL)
LD50 IPR: 28 MG/KG (RAT)
CAS: 7789-00-6 POTASSIUM CHROMATE
ORAL:
LD50.: 180 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ON THE EYE:
CAUSES SERIOUS EYE DAMAGE.
RISK OF CORNEAL CLOUDING.
INFORMATION ON COMPONENTS:
CAS: 7681-38-1 SODIUM BISULFATE
IRRITATION OF SKIN:
OECD 404: (RABBIT: NO IRRITATION)
IRRITATION OF EYES:
OECD 405: (RABBIT: SEVERE IRRITATIONS)
CAS: 10043-35-3 BORIC ACID
IRRITATION OF SKIN:
OECD 404: (RABBIT: NO IRRITATION) (REGISTRANT, ECHA)
IRRITATION OF EYES:
OECD 405: (RABBIT: SLIGHT IRRITATION) (IUCLID)
CAS: 124-04-9 ADIPIC ACID
IRRITATION OF SKIN:
OECD 404: (RABBIT: NO IRRITATION)
IRRITATION OF EYES:
OECD 405: (RABBIT: SEVERE IRRITATIONS)
CAS: 7778-50-9 POTASSIUM DICHROMATE
IRRITATION OF SKIN:
OECD 404: (RABBIT: IRRITATION)
SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
INFORMATION ON COMPONENTS:
CAS: 10043-35-3 BORIC ACID
SENSITIZATION:
OECD 406: (GUINEA PIG: NEGATIVE)
CAS: 124-04-9 ADIPIC ACID
SENSITIZATION:
OECD 406: (GUINEA PIG: NEGATIVE) (IUCLID)
CAS: 7778-50-9 POTASSIUM DICHROMATE
SENSITIZATION:
PATCH TEST (HUMAN): (POSITIVE) (IUCLID)
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
CAS: 7778-50-9 POTASSIUM DICHROMATE 1
CAS: 7789-00-6 POTASSIUM CHROMATE 1
NTP (NATIONAL TOXICOLOGY PROGRAM):
CAS: 7778-50-9 POTASSIUM DICHROMATE K
CAS: 7789-00-6 POTASSIUM CHROMATE K
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
OTHER INFORMATION: SEE SECTION 8 / 15
SYNERGISTIC PRODUCTS: NONE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
THE FOLLOWING STATEMENTS REFER TO THE MIXTURE:
MUTA. 1B, CARC. 1B, REPR. 1B
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
INFORMATION ON COMPONENTS:
CAS 10043-35-3:
EVALUATION FOR CARCINOGENICITY: NEGATIVE IN ANIMALS (NTP)
OECD 414: TERATOGENICITY TESTING
OECD 473: MUTAGENICITY TESTING
OECD 471, 474, 476, 487: GERM CELL MUTAGENICITY TESTING
CAS: 10043-35-3 BORIC ACID
OECD 471: (NEGATIVE) (BACTERIAL REVERSE MUTATION TEST - AMES TEST)
OECD 476:
(NEGATIVE) (IN VITRO MAMMALIAN CELL GENE MUTATION TEST) (MOUSE LYMPHOMEA
TEST)
OECD 414:
(NEGATIVE) (ORAL, RAT) (ECHA, REGISTRANT: NO EVIDENCE OF DEVELOPMENTAL
TOXICITY UP TO 55 MG/KG BW. AT 76 MG/KG BW THERE WAS REDUCED FETAL
BODYWEIGHT, SHORT AND WAVY RIBS, AND THESE EFFECTS DISAPPEARED DURING THE
POSTNATAL PERIOD.)
OECD 474: (NEGATIVE) (IN VIVO, MICE)
CAS: 124-04-9 ADIPIC ACID
OECD 471: (NEGATIVE) (BACTERIAL REVERSE MUTATION TEST - AMES TEST) (IUCLID)
OECD 474: (NEGATIVE) (MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST)
ADDITIONAL TOXICOLOGICAL INFORMATION:
INHALABLE CHROMIUM (VI) COMPOUNDS HAVE CLEARLY SHOWN THEMSELVES TO BE
CARCINOGENIC IN ANIMAL EXPERIMENTS.
POOR TENDENCY FOR ULCERS TO HEAL FOLLOWING PENETRATION OF SUBSTANCE INTO
THE WOUND.
LETHAL DOSE (MAN): 0.5 G
ANTIDOTES: CHELATING AGENTS SUCH AS EDTA, DMPS
CAS 10043-35-5:
ABSORPTION THROUGH GASTRO-INTESTINAL TRACT, MUCOUS MEMBRANES
BORIC ACID / BORATE MAY CAUSE DEVELOPMENTAL CHANGES BASED ON PUBLISHED
DATA, AT DOSES MANY TIMES IN EXCESS OF THOSE THAT
COULD OCCUR THROUGH INHALATION OF DUST IN OCCUPATIONAL SETTINGS.
EXPERIENCE WITH HUMANS:
CAS 7778-50-9, 7789-00-6: CAN CAUSE LIVER DAMAGE.
CAS 7778-50-9: CAN CAUSE KIDNEY DAMAGES.
CAS 7778-50-9: MAY CAUSE LUNG DAMAGES.
CAS 778-50-9: CAN CAUSE CARDIAC DAMAGES.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
CAS: 7681-38-1 SODIUM BISULFATE
EC50: 190 MG/L/48H (DAPHNIA MAGNA) (IUCLID)
CAS: 10043-35-3 BORIC ACID
EC50: 133 MG/L/48H (DAPHNIA MAGNA) (ECOTOX)
LC50: 50-100 MG/L/96H (RAINBOW TROUT) (ECOTOX)
CAS: 124-04-9 ADIPIC ACID
LC50: 511 MG/L/48H (GOLD ORFE)
EC50: 86 MG/L/48H (DAPHNIA MAGNA) (OECD 202)
IC50: 31 MG/L/72H (DESMODESMUS SUBSPICATUS) (IUCLID)
LC50: 97 MG/L/96H (FATHHEAD MINNOW) (ECOTOX)
CAS: 7778-50-9 POTASSIUM DICHROMATE
EC50: 0.62 MG/L/48H (DAPHNIA MAGNA) (OECD 202) (MERCK)
NOEC:
0.016-0.064 MG/L (DAPHNIA MAGNA) (7D)
6 MG/L (FATHHEAD MINNOW) (7D)
IC50: 0.16-0.59 MG/L/96 H (CHLORELLA VULGARIS) (IUCLID)
EC50: 0.31 MG/L/72 H (DESMODESMUS SUBSPICATUS)
LC50:
58.5 MG/L/96H (BYR)
0.131 MG/L/96H (BLUEGILL)
160 MG/L/96H (GUPPY)
26.13 MG/L/96H (FATHHEAD MINNOW)
(MERCK/IUCLID)
CAS: 7789-00-6 POTASSIUM CHROMATE
EC50:
0.02 MG/L/48H (DAPHNIA MAGNA) (ECOTOX)
0.18 MG/L/48H (DAPHNIA PULEX)
LC50: 39.8 MG/L/96H (FATHHEAD MINNOW) (ECOTOX)
BACTERIAL TOXICITY:
CAS: 7681-38-1 SODIUM BISULFATE
EC10: >1000 MG/L (PSEUDOMONAS PUTIDA) (16 H)
CAS: 124-04-9 ADIPIC ACID
EC50: 92 MG/L (PSEUDOMONAS PUTIDA) (DIN 38412) (IUCLID)
CAS: 7778-50-9 POTASSIUM DICHROMATE
EC50: 58 MG/L (PHOTOBACTERIUM PHOSPHOREUM) (30 MIN; MICROTOX-TEST)
OTHER INFORMATION:
TOXIC FOR FISH: SULFATES >7 G/L
PERSISTENCE AND DEGRADABILITY:
CAS: 124-04-9 ADIPIC ACID
OECD 301 B: 100% / 28 D (READILY BIODEGRADABLE) (CO2 EVOLUTION TEST)
BIOACCUMULATIVE POTENTIAL:
BCF: BIOCONCENTRATION FACTOR
POW: N-OCTANOL/WASSER PARTITION COEFFICIENT
LOG POW <1: DOES NOT ACCUMULATE IN ORGANISMS.
CAS: 10043-35-3 BORIC ACID
LOG POW: -1.09 (.) (OECD 107, 22 DEG. C) (MERCK)
CAS: 124-04-9 ADIPIC ACID
LOG POW: 0.081 (.) (25 DEG. C, OECD 107)
CAS: 7778-50-9 POTASSIUM DICHROMATE
BCF: 17.4 (RAINBOW TROUT)
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: AVOID TRANSFER INTO THE ENVIRONMENT.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO HAZARDOUS WASTE DISPOSERS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENT: WATER, IF NECESSARY WITH CLEANSING AGENTS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, IMDG, IATA: NONE
UN PROPER SHIPPING NAME:
DOT, IMDG, IATA: NONE
TRANSPORT HAZARD CLASS(ES):
DOT, IMDG, IATA:
CLASS: NONE
PACKING GROUP:
DOT, IMDG, IATA: NONE
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
NOT DANGEROUS ACCORDING TO THE ABOVE SPECIFICATIONS.
| 15 REGULATORY INFORMATION | |
|
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
THIS MIXTURE CONTAINS CHROMIC ACID, DIPOTASSIUM SALT [LISTED AS
UNDEFINED - Cr(VI)] WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 SARA TITLE III AND 40 CFR PART 372.
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL COMPONENTS HAVE THE VALUE ACTIVE.
HAZARDOUS AIR POLLUTANTS:
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER:
CHROMIUM (HEXAVALENT) COMPOUNDS ARE LISTED IN CALIFORNIA PROPOSITION 65 AS
CARCINOGENS.
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
CHROMIUM (HEXAVALENT) COMPOUNDS ARE LISTED IN CALIFORNIA PROPOSITION 65 AS
TOXIC TO REPRODUCTION FOR FEMALES.
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
CHROMIUM (HEXAVALENT) COMPOUNDS ARE LISTED IN CALIFORNIA PROPOSITION 65 AS
TOXIC TO REPRODUCTION FOR MALES.
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
CHROMIUM (HEXAVALENT) COMPOUNDS ARE LISTED IN CALIFORNIA PROPOSITION 65 AS
TOXIC TO DEVELOPMENT.
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
NEW JERSEY RIGHT-TO-KNOW LIST:
CAS: 124-04-9 ADIPIC ACID
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
NEW JERSEY SPECIAL HAZARDOUS SUBSTANCE LIST:
CAS: 7778-50-9 POTASSIUM DICHROMATE CA, MU
CAS: 7789-00-6 POTASSIUM CHROMATE CA, MU
PENNSYLVANIA RIGHT-TO-KNOW LIST:
CAS: 124-04-9 ADIPIC ACID
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE LIST:
CAS: 124-04-9 ADIPIC ACID E
CAS: 7778-50-9 POTASSIUM DICHROMATE E
CAS: 7789-00-6 POTASSIUM CHROMATE E
EPA (ENVIRONMENTAL PROTECTION AGENCY):
CAS: 10043-35-3 BORIC ACID I (ORAL)
CAS: 7778-50-9 POTASSIUM DICHROMATE A(INH), D(ORAL), K/L(INH), CBD(ORAL)
CAS: 7789-00-6 POTASSIUM CHROMATE A(INH), D(ORAL), K/L(INH), CBD(ORAL)
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
CHROMIUM, HEXAVALENT [Cr(VI)]
CAS: 7778-50-9 POTASSIUM DICHROMATE
CAS: 7789-00-6 POTASSIUM CHROMATE
INFORMATION ABOUT LIMITATION OF USE:
EMPLOYMENT RESTRICTIONS CONCERNING PREGNANT AND LACTATING WOMEN MUST BE
OBSERVED.
EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED.
CHEMICAL SAFETY ASSESSMENT: A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN
CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H272: MAY INTENSIFY FIRE; OXIDIZER.
H301: TOXIC IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H330: FATAL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H340: MAY CAUSE GENETIC DEFECTS.
H350: MAY CAUSE CANCER.
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
RECOMMENDED RESTRICTION OF USE: PROFESSIONAL/INDUSTRIAL USE ONLY
DATE OF PREPARATION / LAST REVISION: 01/15/2020 / 32
ABBREVIATIONS AND ACRONYMS:
IATA-DGR:
DANGEROUS GOODS REGULATIONS BY THE "INTERNATIONAL AIR TRANSPORT
ASSOCIATION" (IATA)
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI:
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
(ICAO)
EC50: EFFECTIVE CONCENTRATION, 50 PERCENT (IN VIVO)
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
STOT: SPECIFIC TARGET ORGAN TOXICITY
SE: SINGLE EXPOSURE
RE: REPEATED EXPOSURE
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
NOEL OR NOEC: NO OBSERVED EFFECT LEVEL OR CONCENTRATION
ACGIH(R*) - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
A1 - CONFIRMED HUMAN CARCINOGEN
A2 - SUSPECTED HUMAN CARCINOGEN
A3 - CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
A5 - NOT SUSPECTED AS A HUMAN CARCINOGEN
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
GROUP 1 - CARCINOGENIC TO HUMANS
GROUP 2A - PROBABLY CARCINOGENIC TO HUMANS
GROUP 2B - POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3 - NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS
GROUP 4 - PROBABLY NOT CARCINOGENIC TO HUMANS
NTP - NATIONAL TOXICOLOGY PROGRAM, U.S. DEPARTMENT OF HEALTH AND HUMAN
SERVICES
GROUP K - KNOWN TO BE HUMAN CARCINOGENS
GROUP R - REASONABLY ANTICIPATED TO BE HUMAN CARCINOGENS
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
BEI: BIOLOGICAL EXPOSURE LIMIT
OX. SOL. 2: OXIDIZING SOLIDS - CATEGORY 2
ACUTE TOX. 3: ACUTE TOXICITY - CATEGORY 3
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
ACUTE TOX. 2: ACUTE TOXICITY - CATEGORY 2
SKIN CORR. 1B: SKIN CORROSION/IRRITATION - CATEGORY 1B
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
RESP. SENS. 1: RESPIRATORY SENSITIZATION - CATEGORY 1
SKIN SENS. 1: SKIN SENSITIZATION - CATEGORY 1
MUTA. 1B: GERM CELL MUTAGENICITY - CATEGORY 1B
CARC. 1B: CARCINOGENICITY - CATEGORY 1B
REPR. 1B: REPRODUCTIVE TOXICITY - CATEGORY 1B
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
STOT RE 1: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 1
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE AQUATIC HAZARD - CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM AQUATIC HAZARD - CATEGORY
1
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM AQUATIC HAZARD - CATEGORY
3
SOURCES:
DATA ARISE FROM SAFETY DATA SHEETS, REFERENCE WORKS AND LITERATURE.
ECHA: EUROPEAN CHEMICALS AGENCY HTTP://ECHA.EUROPA.EU
ECOTOX DATABASE
IUCLID (INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE)
GESTIS- STOFFDATENBANK (SUBSTANCE DATABASE, GERMANY)
NTP (NATIONAL TOXICOLOGY PROGRAM)
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
US