| Common Name: | XTREME, PART A, XTREME, PART B |
| Manufacturer: | PROTECTIVE COATINGS |
| SDS Revision Date: | 3/13/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 25F527, 25F528 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
PC
SAFETY DATA SHEET
ISSUE DATE: 21-MAY-2013
REVISION DATE: 13-MAR-2014
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: PC XTREME, PART A
OTHER MEANS OF IDENTIFICATION:
SDS #: 130612-41A
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVES.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
PROTECTIVE COATINGS CO.
221 S THIRD ST.
ALLENTOWN, PA 18102
USA
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER: 610-432-3543 / 800-220-2103
EMERGENCY TELEPHONE (24 HR):
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
APPEARANCE: LIGHT BROWN LIQUID
PHYSICAL STATE: LIQUID
ODOR: STALE
CLASSIFICATION:
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
RESPIRATORY SENSITIZATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HARMFUL IF INHALED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
MAY CAUSE AN ALLERGIC SKIN REACTION
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WEAR RESPIRATORY PROTECTION
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
WEAR PROTECTIVE GLOVES
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-%
4,4' DIPHENYLMETHANE DIISOCYANATE 101-68-8 70-90
NON-HAZARDOUS PROPRIETARY INGREDIENTS PROPRIETARY 10-30
**IF CHEMICAL NAME/CAS NO IS "PROPRIETARY" AND/OR WEIGHT-% IS LISTED AS A
RANGE, THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS
BEEN WITHHELD AS A TRADE SECRET.**
| 4. FIRST-AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
PROVIDE THIS SDS TO MEDICAL PERSONNEL FOR TREATMENT. AFTER FIRST AID, GET
APPROPRIATE IN-PLANT, PARAMEDIC, OR COMMUNITY MEDICAL SUPPORT.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE
REUSE. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF BREATHING
HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION
IMMEDIATELY.
INGESTION:
CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY OF WATER. DO NOT INDUCE
VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. REMOVE
STOMACH CONTENTS BY MEDICAL PERSONNEL ONLY. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS:
SYMPTOMS:
EYES:
IRRITATION, REDNESS, TEARING AND BLURRED VISION. CORNEAL INJURY IS NOT
EXPECTED.
SKIN:
IRRITATION. CAN CAUSE ALLERGIC SKIN REACTIONS IN SUSCEPTIBLE INDIVIDUALS,
E.G. ITCHING, REDNESS, SWELLING, ETC.
INHALATION: NO ILL EFFECTS EXPECTED. HEATED VAPORS CAN CAUSE IRRITATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
SKIN AND EYE CONDITIONS MAY BE AGGRAVATED BY LONG TERM EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY LONG-TERM EXPOSURE:
SKIN DISORDERS AND ALLERGIES AND EYE CONDITIONS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2), DRY CHEMICAL, WATER SPRAY (FOG).
UNSUITABLE EXTINGUISHING MEDIA: PRODUCT REACTS WITH WATER.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
MAY GENERATE TOXIC OR IRRITATING COMBUSTION PRODUCTS.
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE (CO2)
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
KEEP CONTAINERS COOL WITH WATER SPRAY. AS IN ANY FIRE, WEAR SELF-CONTAINED
BREATHING APPARATUS PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT)
AND FULL PROTECTIVE GEAR. DO NOT RELEASE RUNOFF FROM FIRE CONTROL METHODS
TO SEWERS OR WATERWAYS. HEATING MAY CAUSE PRESSURE BUILDUP AND POSSIBLE
RUPTURE OF THE CONTAINER. COOL EXPOSED CONTAINERS WITH WATER TO PREVENT
RUPTURING.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION. REMOVE
ANY CONTAMINATED CLOTHING AND WASH THOROUGHLY BEFORE REUSE. IN ENCLOSED
AREAS, CLEANUP PERSONNEL SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.
FOR EMERGENCY RESPONDERS:
FOLLOW APPLICABLE OSHA REGULATIONS (29 CFR 1910.120).
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. COVER SPILLS WITH
SAWDUST, VERMICULITE, OR OTHER ABSORBENT MATERIAL TO MINIMIZE SPREADING
OF THE MATERIAL BEFORE COLLECTING.
METHODS FOR CLEAN-UP:
DO NOT HEAT OR CUT EMPTY CONTAINERS WITH ELECTRIC OR GAS TORCH. "ISO"
COMPONENT MUST BE NEUTRALIZED WITH AN EQUAL VOLUME OF A 6% AMMONIA
SOLUTION IN WATER AND ALLOWED TO REACT FOR 10 MINUTES. COLLECT INTO OPEN
CONTAINERS AND ADD MORE SOLUTION. COVER LOOSELY TO VENT CARBON DIOXIDE GAS
GENERATED.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTION
RECOMMENDED IN SECTION 8. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR RESPIRATORY
PROTECTION. WASH FACE, HANDS, AND ANY EXPOSED SKIN THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. DO NOT ALLOW CONTAMINATED CLOTHING OUT OF THE WORKPLACE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE IN A COOL DRY PLACE AWAY FROM DIRECT SUNLIGHT. KEEP FROM FREEZING.
RECOMMENDED STORAGE TEMPERATURE RANGE IN BETWEEN 40 DEG. AND 95 DEG. F.
INCOMPATIBLE MATERIALS:
"A COMPONENT (ISO)" REACTS WITH WATER, ALCOHOL, CARBOXYLIC ACIDS, AMINES
AND AMMONIA.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
4,4' DIPHENYLMETHANE TWA: (VACATED) CEILING: IDLH: 75 MG/M3
DIISOCYANATE 0.005 PPM 0.02 PPM REGULATED CEILING:
101-68-8 UNDER METHYLENE 0.020 PPM 10 MIN
BISPHENYL CEILING:
ISOCYANATE 0.2 MG/M3 10 MIN
(VACATED) CEILING: TWA: 0.005 PPM
0.2 MG/M3 REGULATED TWA: 0.05 MG/M3
UNDER METHYLENE
BISPHENYL
ISOCYANATE
CEILING: 0.02 PPM
CEILING: 0.2 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
PROVIDE GENERAL OR LOCAL EXHAUST VENTILATION SYSTEMS IF POSSIBLE. MAKE
EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH SHOWERS, AND WASHING
FACILITIES AVAILABLE IN WORK AREA.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: CHEMICAL SAFETY GOGGLES/FACESHIELD.
SKIN AND BODY PROTECTION:
WEAR CHEMICALLY PROTECTIVE GLOVES TO PREVENT SKIN CONTACT.
CONTAMINATED EQUIPMENT:
SEPARATE CONTAMINATED WORK CLOTHES FROM STREET CLOTHES. LAUNDER BEFORE
REUSE. REMOVE THIS MATERIAL FROM YOUR SHOES AND CLEAN PERSONAL PROTECTIVE
EQUIPMENT.
RESPIRATORY PROTECTION:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. FOLLOW OSHA
RESPIRATOR REGULATIONS (29 CFR 1910.134) AND, IF NECESSARY, WEAR A
MSHA/NIOSH-APPROVED RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
NEVER EAT, DRINK, OR SMOKE IN WORK AREAS. PRACTICE GOOD PERSONAL HYGIENE
AFTER USING THIS MATERIAL, ESPECIALLY BEFORE EATING, DRINKING, SMOKING,
USING THE TOILET, OR APPLYING COSMETICS. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIGHT BROWN LIQUID
ODOR: STALE
COLOR: LIGHT BROWN
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS - METHOD
PH NOT DETERMINED
MELTING POINT/FREEZING POINT NOT DETERMINED
BOILING POINT/BOILING RANGE >207 DEG. C /
>405 DEG. F
FLASH POINT >93.33 DEG. C /
>200 DEG. F
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY (SOLID, GAS) NOT DETERMINED
UPPER FLAMMABILITY LIMITS NOT AVAILABLE
LOWER FLAMMABILITY LIMIT NOT AVAILABLE
VAPOR PRESSURE 4 MMHg @ 121 DEG. C /
250 DEG. F
VAPOR DENSITY NOT DETERMINED
SPECIFIC GRAVITY 1.1
WATER SOLUBILITY IMMISCIBLE IN WATER
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTO-IGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
VOC CONTENT (%) 0%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: PRODUCT WILL REACT WITH WATER.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION:
POLYMERIZATION MAY OCCUR AT ELEVATED TEMPERATURES IN THE PRESENCE OF
ALKALIS, TERTIARY AMINES AND METAL COMPOUNDS.
CONDITIONS TO AVOID:
EXPOSURE TO EXCESSIVE HEAT AND STORAGE ABOVE 35 DEG. C (95 DEG. F) WILL
SHORTEN SHELF LIFE.
INCOMPATIBLE MATERIALS:
"A COMPONENT (ISO)" REACTS WITH WATER, ALCOHOL, CARBOXYLIC ACIDS, AMINES
AND AMMONIA.
HAZARDOUS DECOMPOSITION PRODUCTS:
INCOMPLETE BURNING MAY PRODUCE NITROGEN OXIDES, HYDROGEN CYANIDES, CARBON
MONOXIDE, AND/OR CARBON DIOXIDE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INHALATION:
HARMFUL IF INHALED. MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE ALLERGY OR
ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
INGESTION: MAY CAUSE NAUSEA, VOMITING, STOMACH ACHE, AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
4,4' DIPHENYLMETHANE =9200 MG/KG
DIISOCYANATE (RAT)
101-68-8
INFORMATION ON PHYSICAL, CHEMICAL AND TOXICOLOGICAL EFFECTS:
SYMPTOMS: PLEASE SEE SECTION 4 OF THIS SDS FOR SYMPTOMS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT
AS A CARCINOGEN. HOWEVER, THE PRODUCT AS A WHOLE HAS NOT BEEN TESTED.
CHEMICAL NAME ACGIH IARC NTP OSHA
4,4' DIPHENYLMETHANE GROUP 3
DIISOCYANATE
101-68-8
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 3 IARC COMPONENTS ARE "NOT CLASSIFIABLE AS HUMAN CARCINOGENS"
STOT - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
NUMERICAL MEASURES OF TOXICITY: NOT DETERMINED
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL.
PERSISTENCE/DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: NOT DETERMINED.
MOBILITY: NOT DETERMINED
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES CONTACT YOUR SUPPLIER OR A LICENSED CONTRACTOR FOR
DETAILED RECOMMENDATIONS. DISPOSAL SHOULD BE IN ACCORDANCE WITH
APPLICABLE REGIONAL, NATIONAL AND LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING
INFORMATION, INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES.
DOT: NOT REGULATED
IATA: NOT REGULATED
IMDG: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: LISTED
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
CERCLA:
CHEMICAL NAME HAZARDOUS CERCLA/SARA REPORTABLE
SUBSTANCES RQS RQ QUANTITY (RQ)
4,4' DIPHENYLMETHANE 5000 LB RQ 5000 LB FINAL RQ
DIISOCYANATE RQ 2270 KG FINAL RQ
101-68-8
SARA 311/312 HAZARD CATEGORIES:
CHRONIC HEALTH HAZARD: YES
SARA 313:
CHEMICAL NAME CAS NO WEIGHT-% SARA 313 - THRESHOLD VALUES %
4,4' DIPHENYLMETHANE 101-68-8 70-90 1.0
DIISOCYANATE
101-68-8
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
4,4' DIPHENYLMETHANE X X
DIISOCYANATE
101-68-8
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS 2*
FLAMMABILITY 1
PHYSICAL HAZARDS 1
PERSONAL PROTECTION G
CHRONIC HAZARD STAR LEGEND:
* = CHRONIC HEALTH HAZARD
ISSUE DATE: 21-MAY-2013
REVISION DATE: 13-MAR-2014
REVISION NOTE: NEW FORMAT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
PC
SAFETY DATA SHEET
ISSUE DATE: 21-MAY-2013
REVISION DATE: 13-MAR-2014
VERSION: 1
| 1. IDENTIFICATION | |
PRODUCT IDENTIFIER:
PRODUCT NAME: PC XTREME, PART B
OTHER MEANS OF IDENTIFICATION:
SDS #: 130612-41B
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVES.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
PROTECTIVE COATINGS CO.
221 S THIRD ST.
ALLENTOWN, PA 18102
USA
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER: 610-432-3543 / 800-220-2103
EMERGENCY TELEPHONE (24 HR):
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
APPEARANCE: GRAY LIQUID
PHYSICAL STATE: LIQUID
ODOR: SLIGHT AMINE
CLASSIFICATION:
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 4
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): MAY BE HARMFUL IF SWALLOWED
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
HARMFUL IF INHALED
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
EXCLAMATION MARK
HEALTH HAZARD
PRECAUTIONARY STATEMENTS - PREVENTION:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR EYE/FACE PROTECTION
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
PRECAUTIONARY STATEMENTS - RESPONSE:
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING GET MEDICAL ATTENTION IF SYMPTOMS PERSIST
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
OTHER HAZARDS: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-%
NON-HAZARDOUS PROPRIETARY INGREDIENTS PROPRIETARY 70-90
DIETHYLTOLUENEDIAMINE 68479-98-1 10-30
**IF CHEMICAL NAME/CAS NO IS "PROPRIETARY" AND/OR WEIGHT-% IS LISTED AS A
RANGE, THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS
BEEN WITHHELD AS A TRADE SECRET.**
| 4. FIRST-AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
PROVIDE THIS SDS TO MEDICAL PERSONNEL FOR TREATMENT. AFTER FIRST AID, GET
APPROPRIATE IN-PLANT, PARAMEDIC, OR COMMUNITY MEDICAL SUPPORT.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE
REUSE. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS
PERSIST, CALL A PHYSICIAN.
INGESTION:
CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY OF WATER. DO NOT INDUCE
VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. REMOVE
STOMACH CONTENTS BY MEDICAL PERSONNEL ONLY. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS:
SYMPTOMS:
EYES:
IRRITATION, REDNESS, TEARING AND BLURRED VISION. CORNEAL INJURY IS NOT
EXPECTED.
SKIN:
IRRITATION. CAN CAUSE ALLERGIC SKIN REACTIONS IN SUSCEPTIBLE INDIVIDUALS,
E.G. ITCHING, REDNESS, SWELLING, ETC.
INHALATION: NO ILL EFFECTS EXPECTED. HEATED VAPORS CAN CAUSE IRRITATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
SKIN AND EYE CONDITIONS MAY BE AGGRAVATED BY LONG TERM EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY LONG-TERM EXPOSURE:
SKIN DISORDERS AND ALLERGIES AND EYE CONDITIONS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2), DRY CHEMICAL, WATER SPRAY (FOG).
UNSUITABLE EXTINGUISHING MEDIA: WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
MAY GENERATE TOXIC OR IRRITATING COMBUSTION PRODUCTS.
HAZARDOUS COMBUSTION PRODUCTS:
THERMAL DECOMPOSITION PRODUCTS ARE TOXIC AND MAY INCLUDE OXIDES OF CARBON
AND NITROGEN, AMINES, HYDROGEN CYANIDE AND OTHER IRRITATING OR TOXIC GASES.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
KEEP CONTAINERS COOL WITH WATER SPRAY. AS IN ANY FIRE, WEAR SELF-CONTAINED
BREATHING APPARATUS PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT)
AND FULL PROTECTIVE GEAR. DO NOT RELEASE RUNOFF FROM FIRE CONTROL METHODS
TO SEWERS OR WATERWAYS. HEATING MAY CAUSE PRESSURE BUILDUP AND POSSIBLE
RUPTURE OF THE CONTAINER. COOL EXPOSED CONTAINERS WITH WATER TO PREVENT
RUPTURING.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING AND EYE/FACE PROTECTION. REMOVE
ANY CONTAMINATED CLOTHING AND WASH THOROUGHLY BEFORE REUSE. IN ENCLOSED
AREAS, CLEANUP PERSONNEL SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.
FOR EMERGENCY RESPONDERS:
FOLLOW APPLICABLE OSHA REGULATIONS (29 CFR 1910.120).
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. COVER SPILLS WITH
SAWDUST, VERMICULITE, OR OTHER ABSORBENT MATERIAL TO MINIMIZE SPREADING OF
THE MATERIAL BEFORE COLLECTING.
METHODS FOR CLEAN-UP:
SWEEP UP ABSORBED MATERIAL AND SHOVEL INTO SUITABLE CONTAINERS FOR
DISPOSAL. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN
FULL COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. FOR WASTE
DISPOSAL, SEE SECTION 13 OF THE SDS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH FACE, HANDS, AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING.
USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN, EYES OR
CLOTHING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL DRY PLACE AWAY FROM DIRECT SUNLIGHT. KEEP FROM FREEZING.
RECOMMENDED STORAGE TEMPERATURE RANGE IN BETWEEN 4 DEG. C AND 35 DEG. C
(40 DEG. F AND 95 DEG. F).
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS AND STRONG ALKALIS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
DIETHYLTOLUENEDIAMINE TWA:
68479-98-1 0.02 PPM
0.2 MG/M3 (CEILING)
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
PROVIDE GENERAL OR LOCAL EXHAUST VENTILATION SYSTEMS IF POSSIBLE. MAKE
EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH SHOWERS, AND WASHING
FACILITIES AVAILABLE IN WORK AREA.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: CHEMICAL SAFETY GOGGLES/FACESHIELD.
SKIN AND BODY PROTECTION:
WEAR CHEMICALLY PROTECTIVE GLOVES TO PREVENT SKIN CONTACT.
CONTAMINATED EQUIPMENT:
SEPARATE CONTAMINATED WORK CLOTHES FROM STREET CLOTHES. LAUNDER BEFORE
REUSE. REMOVE THIS MATERIAL FROM YOUR SHOES AND CLEAN PERSONAL PROTECTIVE
EQUIPMENT.
RESPIRATORY PROTECTION:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. FOLLOW OSHA
RESPIRATOR REGULATIONS (29 CFR 1910.134) AND, IF NECESSARY, WEAR A
MSHA/NIOSH-APPROVED RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
NEVER EAT, DRINK, OR SMOKE IN WORK AREAS. PRACTICE GOOD PERSONAL HYGIENE
AFTER USING THIS MATERIAL, ESPECIALLY BEFORE EATING, DRINKING, SMOKING,
USING THE TOILET, OR APPLYING COSMETICS. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: GRAY LIQUID
ODOR: SLIGHT AMINE
COLOR: GRAY
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS - METHOD
PH NOT DETERMINED
MELTING POINT/FREEZING POINT NOT DETERMINED
BOILING POINT/BOILING RANGE >260 DEG. C /
>500 DEG. F
FLASH POINT >160 DEG. C /
>320 DEG. F
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY (SOLID, GAS) NOT DETERMINED
UPPER FLAMMABILITY LIMITS NOT AVAILABLE
LOWER FLAMMABILITY LIMIT NOT AVAILABLE
VAPOR PRESSURE 4 MMHg @
121 DEG. C /
250 DEG. F
VAPOR DENSITY NOT DETERMINED
SPECIFIC GRAVITY 1.04
WATER SOLUBILITY NOT SOLUBLE
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTO-IGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
VOC CONTENT (%) 0%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID:
EXPOSURE TO EXCESSIVE HEAT AND STORAGE ABOVE 35 DEG. C (95 DEG. F) WILL
SHORTEN SHELF LIFE.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS AND STRONG ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
INCOMPLETE BURNING MAY PRODUCE NITROGEN OXIDES, HYDROGEN CYANIDES, CARBON
MONOXIDE, AND/OR CARBON DIOXIDE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SKIN CONTACT: SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION.
INHALATION: HARMFUL IF INHALED.
INGESTION: MAY CAUSE NAUSEA, VOMITING, STOMACH ACHE, AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
DIETHYLTOLUENEDIAMINE =472 MG/KG
68479-98-1 (RAT)
INFORMATION ON PHYSICAL, CHEMICAL AND TOXICOLOGICAL EFFECTS:
SYMPTOMS: PLEASE SEE SECTION 4 OF THIS SDS FOR SYMPTOMS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY CARCINOGENS OR POTENTIAL CARCINOGENS AS
LISTED BY OSHA, IARC OR NTP.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
NUMERICAL MEASURES OF TOXICITY: NOT DETERMINED
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PERSISTENCE/DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: NOT DETERMINED.
MOBILITY: NOT DETERMINED
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
CONTACT YOUR SUPPLIER OR A LICENSED CONTRACTOR FOR DETAILED
RECOMMENDATIONS. DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE
REGIONAL, NATIONAL AND LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING INFORMATION,
INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES.
DOT: NOT REGULATED
IATA: NOT REGULATED
IMDG: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: LISTED
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
SARA 313: NOT DETERMINED
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS: NOT DETERMINED
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 1
PHYSICAL HAZARDS 1
PERSONAL PROTECTION B
ISSUE DATE: 21-MAY-2013
REVISION DATE: 13-MAR-2014
REVISION NOTE: NEW FORMAT
DISCLAIMER
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.