| Common Name: | 251991Y - COD REAGENT VARIO MR |
| Manufacturer: | TINTOMETER |
| SDS Revision Date: | 10/15/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 25KA16 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
YSI
A XYLEM BRAND
251991Y - COD REAGENT VARIO MR
TINTOMETER INC.
VERSION NO: 2.2
SAFETY DATA SHEET ACCORDING TO OSHA HAZCOM STANDARD (2012) REQUIREMENTS
CHEMWATCH HAZARD ALERT CODE: 4
ISSUE DATE: 10/15/2018
PRINT DATE: 10/15/2018
S.GHS.USA.EN
| SECTION 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: 251991Y - COD REAGENT VARIO MR
SYNONYMS: 251991Y, 420721, 2420721, 420726, 2420726
PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, TOXIC, N.O.S. SULPHURIC ACID, MERCURY SULPHATE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RELEVANT IDENTIFIED USES: REAGENT FOR WATER ANALYSIS
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE CHEMICAL MANUFACTURER,
IMPORTER, OR OTHER RESPONSIBLE PARTY:
REGISTERED COMPANY NAME TINTOMETER INC. YSI INC.
ADDRESS 6456 PARKLAND DRIVE 1700/1725 BRANNUM LN YELLOW
SARASOTA FL 34243 SPRINGS OH 45387
UNITED STATES UNITED STATES
TELEPHONE (941) 756-6410 (937) 767-7241
FAX (941) 727-9654 NOT AVAILABLE
WEBSITE WWW.LOVIBOND.US WWW.YSI.COM
EMAIL NOT AVAILABLE MSDSINFO@YSI.COM
EMERGENCY PHONE NUMBER:
ASSOCIATION / CHEMTREC CHEMTREC
ORGANISATION
EMERGENCY TELEPHONE (800) 424-9300 (800) 424-9300
NUMBERS
OTHER EMERGENCY 011 703-527-3887 011 703-527-3887
TELEPHONE NUMBERS
| SECTION 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
| CHEMWATCH HAZARD RATINGS:
MIN MAX
FLAMMABILITY 0
TOXICITY 3
BODY CONTACT 4
REACTIVITY 0
CHRONIC 1
0 = MINIMUM
1 = LOW
2 = MODERATE
3 = HIGH
4 = EXTREME
NFPA:
3
0
2
NOTE:
THE HAZARD CATEGORY NUMBERS FOUND IN GHS CLASSIFICATION IN SECTION 2 OF
THIS SDSS ARE NOT TO BE USED TO FILL IN THE NFPA 704 DIAMOND.
BLUE = HEALTH
RED = FIRE
YELLOW = REACTIVITY
WHITE = SPECIAL (OXIDIZER OR WATER REACTIVE SUBSTANCES)
| CANADIAN WHMIS SYMBOLS:
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
E - CORROSIVE MATERIAL
| CANADIAN WHMIS CLASSIFICATION:
INGREDIENT CAS NUMBER CLASSIFICATION CLASSIFICATION
DESCRIPTION CODE
SULFURIC ACID 7664-93-9 VERY TOXIC MATERIAL CAUSING D1A, E
WITH >51% ACID IMMEDIATE AND SERIOUS TOXIC
EFFECTS, CORROSIVE MATERIAL
CLASSIFICATION:
METAL CORROSION CATEGORY 1, ACUTE TOXICITY (ORAL) CATEGORY 4, ACUTE
TOXICITY (DERMAL) CATEGORY 4, SKIN CORROSION/IRRITATION CATEGORY 1A,
SERIOUS EYE DAMAGE CATEGORY 1, SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE CATEGORY 2, ACUTE AQUATIC HAZARD CATEGORY 3, CHRONIC AQUATIC
HAZARD CATEGORY 3
LABEL ELEMENTS:
HAZARD PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT(S):
H290: MAY BE CORROSIVE TO METALS.
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
HAZARD(S) NOT OTHERWISE SPECIFIED: NOT APPLICABLE
SUPPLEMENTARY STATEMENT(S): NOT APPLICABLE
CLP CLASSIFICATION (ADDITIONAL): NOT APPLICABLE
PRECAUTIONARY STATEMENT(S) PREVENTION:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P273: AVOID RELEASE TO THE ENVIRONMENT.
PRECAUTIONARY STATEMENT(S) RESPONSE:
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P390: ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
PRECAUTIONARY STATEMENT(S) STORAGE:
P405: STORE LOCKED UP.
PRECAUTIONARY STATEMENT(S) DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.
| SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS | |
SUBSTANCES: SEE SECTION BELOW FOR COMPOSITION OF MIXTURES
MIXTURES:
CAS NO %[WEIGHT] NAME
7664-93-9 80-90 SULFURIC ACID WITH >51% ACID
7783-35-9 0.1-0.3 MERCURIC SULFATE
10294-26-5 0.1-1 SILVER SULFATE
7732-18-5 <19 WATER
| SECTION 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
EYE CONTACT:
IF THIS PRODUCT COMES IN CONTACT WITH THE EYES:
IMMEDIATELY HOLD EYELIDS APART AND FLUSH THE EYE CONTINUOUSLY WITH RUNNING
WATER.
ENSURE COMPLETE IRRIGATION OF THE EYE BY KEEPING EYELIDS APART AND AWAY
FROM EYE AND MOVING THE EYELIDS BY OCCASIONALLY LIFTING THE UPPER AND LOWER
LIDS.
CONTINUE FLUSHING UNTIL ADVISED TO STOP BY THE POISONS INFORMATION CENTRE
OR A DOCTOR, OR FOR AT LEAST 15 MINUTES.
TRANSPORT TO HOSPITAL OR DOCTOR WITHOUT DELAY.
REMOVAL OF CONTACT LENSES AFTER AN EYE INJURY SHOULD ONLY BE UNDERTAKEN
BY SKILLED PERSONNEL.
SKIN CONTACT:
IF SKIN OR HAIR CONTACT OCCURS:
IMMEDIATELY FLUSH BODY AND CLOTHES WITH LARGE AMOUNTS OF WATER, USING
SAFETY SHOWER IF AVAILABLE.
QUICKLY REMOVE ALL CONTAMINATED CLOTHING, INCLUDING FOOTWEAR.
WASH SKIN AND HAIR WITH RUNNING WATER. CONTINUE FLUSHING WITH WATER UNTIL
ADVISED TO STOP BY THE POISONS INFORMATION CENTRE.
TRANSPORT TO HOSPITAL, OR DOCTOR.
INHALATION:
IF FUMES OR COMBUSTION PRODUCTS ARE INHALED REMOVE FROM CONTAMINATED AREA.
LAY PATIENT DOWN. KEEP WARM AND RESTED.
PROSTHESES SUCH AS FALSE TEETH, WHICH MAY BLOCK AIRWAY, SHOULD BE REMOVED,
WHERE POSSIBLE, PRIOR TO INITIATING FIRST AID PROCEDURES.
APPLY ARTIFICIAL RESPIRATION IF NOT BREATHING, PREFERABLY WITH A DEMAND
VALVE RESUSCITATOR, BAG-VALVE MASK DEVICE, OR POCKET MASK AS TRAINED.
PERFORM CPR IF NECESSARY.
TRANSPORT TO HOSPITAL, OR DOCTOR, WITHOUT DELAY.
INHALATION OF VAPOURS OR AEROSOLS (MISTS, FUMES) MAY CAUSE LUNG OEDEMA.
CORROSIVE SUBSTANCES MAY CAUSE LUNG DAMAGE (E.G. LUNG OEDEMA, FLUID IN THE
LUNGS).
AS THIS REACTION MAY BE DELAYED UP TO 24 HOURS AFTER EXPOSURE, AFFECTED
INDIVIDUALS NEED COMPLETE REST (PREFERABLY IN SEMI-RECUMBENT POSTURE) AND
MUST BE KEPT UNDER MEDICAL OBSERVATION EVEN IF NO SYMPTOMS ARE (YET)
MANIFESTED.
BEFORE ANY SUCH MANIFESTATION, THE ADMINISTRATION OF A SPRAY CONTAINING A
DEXAMETHASONE DERIVATIVE OR BECLOMETHASONE DERIVATIVE MAY BE CONSIDERED.
THIS MUST DEFINITELY BE LEFT TO A DOCTOR OR PERSON AUTHORISED BY HIM/HER.
(ICSC13719)
INGESTION:
FOR ADVICE, CONTACT A POISONS INFORMATION CENTRE OR A DOCTOR AT ONCE.
URGENT HOSPITAL TREATMENT IS LIKELY TO BE NEEDED.
IF SWALLOWED DO NOT INDUCE VOMITING.
IF VOMITING OCCURS, LEAN PATIENT FORWARD OR PLACE ON LEFT SIDE (HEAD-DOWN
POSITION, IF POSSIBLE) TO MAINTAIN OPEN AIRWAY AND PREVENT ASPIRATION.
OBSERVE THE PATIENT CAREFULLY.
NEVER GIVE LIQUID TO A PERSON SHOWING SIGNS OF BEING SLEEPY OR WITH REDUCED
AWARENESS; I.E. BECOMING UNCONSCIOUS.
GIVE WATER TO RINSE OUT MOUTH, THEN PROVIDE LIQUID SLOWLY AND AS MUCH AS
CASUALTY CAN COMFORTABLY DRINK.
TRANSPORT TO HOSPITAL OR DOCTOR WITHOUT DELAY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: SEE SECTION 11
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
FOR ACUTE OR SHORT TERM REPEATED EXPOSURES TO STRONG ACIDS:
AIRWAY PROBLEMS MAY ARISE FROM LARYNGEAL EDEMA AND INHALATION EXPOSURE.
TREAT WITH 100% OXYGEN INITIALLY.
RESPIRATORY DISTRESS MAY REQUIRE CRICOTHYROIDOTOMY IF ENDOTRACHEAL
INTUBATION IS CONTRAINDICATED BY EXCESSIVE SWELLING
INTRAVENOUS LINES SHOULD BE ESTABLISHED IMMEDIATELY IN ALL CASES WHERE
THERE IS EVIDENCE OF CIRCULATORY COMPROMISE.
STRONG ACIDS PRODUCE A COAGULATION NECROSIS CHARACTERISED BY FORMATION OF
A COAGULUM (ESCHAR) AS A RESULT OF THE DESSICATING ACTION OF THE ACID ON
PROTEINS IN SPECIFIC TISSUES.
INGESTION:
IMMEDIATE DILUTION (MILK OR WATER) WITHIN 30 MINUTES POST INGESTION IS
RECOMMENDED.
DO NOT ATTEMPT TO NEUTRALISE THE ACID SINCE EXOTHERMIC REACTION MAY EXTEND
THE CORROSIVE INJURY.
BE CAREFUL TO AVOID FURTHER VOMIT SINCE RE-EXPOSURE OF THE MUCOSA TO THE
ACID IS HARMFUL. LIMIT FLUIDS TO ONE OR TWO GLASSES IN AN ADULT.
CHARCOAL HAS NO PLACE IN ACID MANAGEMENT.
SOME AUTHORS SUGGEST THE USE OF LAVAGE WITHIN 1 HOUR OF INGESTION.
SKIN:
SKIN LESIONS REQUIRE COPIOUS SALINE IRRIGATION. TREAT CHEMICAL BURNS AS
THERMAL BURNS WITH NON-ADHERENT GAUZE AND WRAPPING.
DEEP SECOND-DEGREE BURNS MAY BENEFIT FROM TOPICAL SILVER SULFADIAZINE.
EYE:
EYE INJURIES REQUIRE RETRACTION OF THE EYELIDS TO ENSURE THOROUGH
IRRIGATION OF THE CONJUCTIVAL CUL-DE-SACS. IRRIGATION SHOULD LAST AT
LEAST 20-30 MINUTES. DO NOT USE NEUTRALISING AGENTS OR ANY OTHER ADDITIVES.
SEVERAL LITRES OF SALINE ARE REQUIRED.
CYCLOPLEGIC DROPS, (1% CYCLOPENTOLATE FOR SHORT-TERM USE OR 5% HOMATROPINE
FOR LONGER TERM USE) ANTIBIOTIC DROPS, VASOCONSTRICTIVE AGENTS OR
ARTIFICIAL TEARS MAY BE INDICATED DEPENDENT ON THE SEVERITY OF THE INJURY.
STEROID EYE DROPS SHOULD ONLY BE ADMINISTERED WITH THE APPROVAL OF A
CONSULTING OPHTHALMOLOGIST).
[ELLENHORN AND BARCELOUX: MEDICAL TOXICOLOGY]
| SECTION 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY OR FOG.
FOAM.
DRY CHEMICAL POWDER.
BCF (WHERE REGULATIONS PERMIT).
CARBON DIOXIDE.
SPECIAL HAZARDS ARISING FROM THE SUBSTRATE OR MIXTURE:
FIRE INCOMPATIBILITY: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIRE FIGHTING:
ALERT FIRE BRIGADE AND TELL THEM LOCATION AND NATURE OF HAZARD.
WEAR FULL BODY PROTECTIVE CLOTHING WITH BREATHING APPARATUS.
PREVENT, BY ANY MEANS AVAILABLE, SPILLAGE FROM ENTERING DRAINS OR WATER
COURSE.
USE FIRE FIGHTING PROCEDURES SUITABLE FOR SURROUNDING AREA.
DO NOT APPROACH CONTAINERS SUSPECTED TO BE HOT.
COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY FROM A PROTECTED LOCATION.
IF SAFE TO DO SO, REMOVE CONTAINERS FROM PATH OF FIRE.
EQUIPMENT SHOULD BE THOROUGHLY DECONTAMINATED AFTER USE.
FIRE/EXPLOSION HAZARD:
NON COMBUSTIBLE.
NOT CONSIDERED TO BE A SIGNIFICANT FIRE RISK.
ACIDS MAY REACT WITH METALS TO PRODUCE HYDROGEN, A HIGHLY FLAMMABLE AND
EXPLOSIVE GAS.
HEATING MAY CAUSE EXPANSION OR DECOMPOSITION LEADING TO VIOLENT RUPTURE
OF CONTAINERS.
MAY EMIT CORROSIVE, POISONOUS FUMES. MAY EMIT ACRID SMOKE.
DECOMPOSITION MAY PRODUCE TOXIC FUMES OF: SULFUR OXIDES (SOX)
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
SEE SECTION 8
ENVIRONMENTAL PRECAUTIONS: SEE SECTION 12
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
MINOR SPILLS:
DRAINS FOR STORAGE OR USE AREAS SHOULD HAVE RETENTION BASINS FOR PH
ADJUSTMENTS AND DILUTION OF SPILLS BEFORE DISCHARGE OR DISPOSAL OF
MATERIAL.
CHECK REGULARLY FOR SPILLS AND LEAKS.
CLEAN UP ALL SPILLS IMMEDIATELY.
AVOID BREATHING VAPOURS AND CONTACT WITH SKIN AND EYES.
CONTROL PERSONAL CONTACT WITH THE SUBSTANCE, BY USING PROTECTIVE EQUIPMENT.
CONTAIN AND ABSORB SPILL WITH SAND, EARTH, INERT MATERIAL OR VERMICULITE.
WIPE UP.
PLACE IN A SUITABLE, LABELLED CONTAINER FOR WASTE DISPOSAL.
MAJOR SPILLS:
DO NOT TOUCH THE SPILL MATERIAL
CLEAR AREA OF PERSONNEL AND MOVE UPWIND.
ALERT FIRE BRIGADE AND TELL THEM LOCATION AND NATURE OF HAZARD.
MAY BE VIOLENTLY OR EXPLOSIVELY REACTIVE.
WEAR FULL BODY PROTECTIVE CLOTHING WITH BREATHING APPARATUS.
PREVENT, BY ANY MEANS AVAILABLE, SPILLAGE FROM ENTERING DRAINS OR WATER
COURSE.
CONSIDER EVACUATION (OR PROTECT IN PLACE).
STOP LEAK IF SAFE TO DO SO.
CONTAIN SPILL WITH SAND, EARTH OR VERMICULITE.
COLLECT RECOVERABLE PRODUCT INTO LABELLED CONTAINERS FOR RECYCLING.
NEUTRALISE/DECONTAMINATE RESIDUE (SEE SECTION 13 FOR SPECIFIC AGENT).
COLLECT SOLID RESIDUES AND SEAL IN LABELLED DRUMS FOR DISPOSAL.
WASH AREA AND PREVENT RUNOFF INTO DRAINS.
AFTER CLEAN UP OPERATIONS, DECONTAMINATE AND LAUNDER ALL PROTECTIVE
CLOTHING AND EQUIPMENT BEFORE STORING AND RE-USING.
IF CONTAMINATION OF DRAINS OR WATERWAYS OCCURS, ADVISE EMERGENCY SERVICES.
PERSONAL PROTECTIVE EQUIPMENT ADVICE IS CONTAINED IN SECTION 8 OF THE SDS.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
SAFE HANDLING:
AVOID ALL PERSONAL CONTACT, INCLUDING INHALATION.
WEAR PROTECTIVE CLOTHING WHEN RISK OF EXPOSURE OCCURS.
USE IN A WELL-VENTILATED AREA.
WARNING:
TO AVOID VIOLENT REACTION, ALWAYS ADD MATERIAL TO WATER AND NEVER WATER TO
MATERIAL.
AVOID SMOKING, NAKED LIGHTS OR IGNITION SOURCES.
AVOID CONTACT WITH INCOMPATIBLE MATERIALS.
WHEN HANDLING, DO NOT EAT, DRINK OR SMOKE.
KEEP CONTAINERS SECURELY SEALED WHEN NOT IN USE.
AVOID PHYSICAL DAMAGE TO CONTAINERS.
ALWAYS WASH HANDS WITH SOAP AND WATER AFTER HANDLING.
WORK CLOTHES SHOULD BE LAUNDERED SEPARATELY. LAUNDER CONTAMINATED CLOTHING
BEFORE RE-USE.
USE GOOD OCCUPATIONAL WORK PRACTICE.
OBSERVE MANUFACTURER'S STORAGE AND HANDLING RECOMMENDATIONS CONTAINED
WITHIN THIS SDS.
ATMOSPHERE SHOULD BE REGULARLY CHECKED AGAINST ESTABLISHED EXPOSURE
STANDARDS TO ENSURE SAFE WORKING CONDITIONS ARE MAINTAINED.
OTHER INFORMATION:
STORE IN ORIGINAL CONTAINERS.
KEEP CONTAINERS SECURELY SEALED.
STORE IN A COOL, DRY, WELL-VENTILATED AREA.
STORE AWAY FROM INCOMPATIBLE MATERIALS AND FOODSTUFF CONTAINERS.
PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE AND CHECK REGULARLY FOR LEAKS.
OBSERVE MANUFACTURER'S STORAGE AND HANDLING RECOMMENDATIONS CONTAINED
WITHIN THIS SDS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
SUITABLE CONTAINER:
DO NOT USE MILD STEEL OR GALVANISED CONTAINERS
DO NOT USE ALUMINIUM OR GALVANISED CONTAINERS
CHECK REGULARLY FOR SPILLS AND LEAKS
LINED METAL CAN, LINED METAL PAIL/CAN.
PLASTIC PAIL.
POLYLINER DRUM.
PACKING AS RECOMMENDED BY MANUFACTURER.
CHECK ALL CONTAINERS ARE CLEARLY LABELLED AND FREE FROM LEAKS.
FOR LOW VISCOSITY MATERIALS:
DRUMS AND JERRICANS MUST BE OF THE NON-REMOVABLE HEAD TYPE.
WHERE A CAN IS TO BE USED AS AN INNER PACKAGE, THE CAN MUST HAVE A SCREWED
ENCLOSURE.
FOR MATERIALS WITH A VISCOSITY OF AT LEAST 2680 CST. (23 DEG. C) AND SOLIDS
(BETWEEN 15 C DEG. AND 40 DEG C.):
REMOVABLE HEAD PACKAGING;
CANS WITH FRICTION CLOSURES AND
LOW PRESSURE TUBES AND CARTRIDGES
MAY BE USED.
WHERE COMBINATION PACKAGES ARE USED, AND THE INNER PACKAGES ARE OF GLASS,
PORCELAIN OR STONEWARE, THERE MUST BE SUFFICIENT INERT CUSHIONING MATERIAL
IN CONTACT WITH INNER AND OUTER PACKAGES UNLESS THE OUTER PACKAGING IS A
CLOSE FITTING MOULDED PLASTIC BOX AND THE SUBSTANCES ARE NOT INCOMPATIBLE
WITH THE PLASTIC.
STORAGE INCOMPATIBILITY:
INORGANIC ACIDS ARE GENERALLY SOLUBLE IN WATER WITH THE RELEASE OF HYDROGEN
IONS. THE RESULTING SOLUTIONS HAVE PH'S OF LESS THAN 7.0.
INORGANIC ACIDS NEUTRALISE CHEMICAL BASES (FOR EXAMPLE: AMINES AND
INORGANIC HYDROXIDES) TO FORM SALTS - NEUTRALISATION CAN GENERATE
DANGEROUSLY LARGE AMOUNTS OF HEAT IN SMALL SPACES.
THE DISSOLUTION OF INORGANIC ACIDS IN WATER OR THE DILUTION OF THEIR
CONCENTRATED SOLUTIONS WITH ADDITIONAL WATER MAY GENERATE SIGNIFICANT HEAT.
THE ADDITION OF WATER TO INORGANIC ACIDS OFTEN GENERATES SUFFICIENT HEAT IN
THE SMALL REGION OF MIXING TO CAUSE SOME OF THE WATER TO BOIL EXPLOSIVELY.
THE RESULTING "BUMPING" CAN SPATTER THE ACID.
INORGANIC ACIDS REACT WITH ACTIVE METALS, INCLUDING SUCH STRUCTURAL METALS
AS ALUMINUM AND IRON, TO RELEASE HYDROGEN, A FLAMMABLE GAS.
INORGANIC ACIDS CAN INITIATE THE POLYMERISATION OF CERTAIN CLASSES OF
ORGANIC COMPOUNDS.
INORGANIC ACIDS REACT WITH CYANIDE COMPOUNDS TO RELEASE GASEOUS HYDROGEN
CYANIDE.
INORGANIC ACIDS GENERATE FLAMMABLE AND/OR TOXIC GASES IN CONTACT WITH
DITHIOCARBAMATES, ISOCYANATES, MERCAPTANS, NITRIDES, NITRILES, SULFIDES,
AND STRONG REDUCING AGENTS. ADDITIONAL GAS-GENERATING REACTIONS OCCUR WITH
SULFITES, NITRITES, THIOSULFATES (TO GIVE H2S AND SO3), DITHIONITES (SO2),
AND EVEN CARBONATES.
ACIDS OFTEN CATALYSE (INCREASE THE RATE OF) CHEMICAL REACTIONS.
REACTS WITH MILD STEEL, GALVANISED STEEL / ZINC PRODUCING HYDROGEN GAS
WHICH MAY FORM AN EXPLOSIVE MIXTURE WITH AIR.
AVOID ANY CONTAMINATION OF THIS MATERIAL AS IT IS VERY REACTIVE AND ANY
CONTAMINATION IS POTENTIALLY HAZARDOUS
SULFURIC ACID:
IS A STRONG OXIDISER
REACTS WITH WATER OR STEAM
REACTS VIOLENTLY WITH MANY SUBSTANCES INCLUDING REDUCING AGENTS,
COMBUSTIBLE MATERIALS, ORGANIC SUBSTANCES, ALKALIS, AMMONIUM
TETRAPEROXOCHROMATE, ANILINE, 1,2-ETHANEDIAMINE, ETHANOLAMINE, ISOPRENE,
MESITYL OXIDE, ENDO--NORBANECARBOXYLIC ACID ETHYL ESTER, PERCHLORATES,
SODIUM CARBONATE, ZINC CHLORATE
REACTS, POSSIBLY CAUSING IGNITION OR EXPLOSION, WITH MANY SUBSTANCES,
INCLUDING NON-OXIDISING MINERAL ACIDS, ORGANIC ACIDS, BASES, REDUCING
AGENTS, ACETIC ANHYDRIDE, ACETONE CYANOHYDRIN, ACETONITRILE, ACROLEIN,
ACRYLATES, ACRYLONITRILE, ALCOHOLS, ALDEHYDES, ALKYLENE OXIDES, ALLYL
ALCOHOL, ALLYL CHLORIDE, SUBSTITUTED ALLYLS, 2-AMINOETHANOL, AMMONIUM
HYDROXIDE, BROMINE PENTAFLUORIDE, N-BUTYRALDEHYDE, CAPROLACTAM SOLUTION,
CARBIDES, CAESIUM ACETYLENE CARBIDE, CHLORINE TRIFLUORIDE, CHLORATES,
CHLOROSULFONIC ACID, CRESOLS, CUPROUS NITRIDE, DIISOBUTYLENE, ETHYLENE
CYANOHYDRIN, ETHYLENE DIAMINE, ETHYLENE GLYCOL, ETHYLENEIMINE, FULMINATES,
GLYCOLS, HYDROCHLORIC ACID, IODINE HEPTAFLUORIDE, IRON, ISOCYANATES,
KETONES, LITHIUM SILICIDE, MERCURIC NITRIDE, 2-METHYLLACTONITRILE,
POWDERED METALS, NITRIC ACID, P-NITROTOLUENE, PENTASILVER
TRIHYDROXYDIAMINOPHOSPHATE, PERCHLORIC ACID, PHENOLS, PHOSPHORUS,
PICRATES, POTASSIUM CHLORATE, POTASSIUM PERMANGANATE, BETA-PROPIOLACTONE,
PROPYLENE OXIDE, PYRIDINE, RUBIDIUM ACETYLENE, SILVER PERMANGANATE, SODIUM,
SODIUM CHLORATE, SODIUM HYDROXIDE, STYRENE MONOMER, ZINC PHOSPHIDE
INCREASES THE EXPLOSIVE SENSITIVITY OF NITROMETHANE
INCOMPATIBLE WITH 2-AMINO-5-NITROTHIAZOLE, 2-AMINOTHIAZOLE, AMMONIA,
ALIPHATIC AMINES, ALKANOLAMINES, AMIDES, ORGANIC ANHYDRIDES, ISOCYANATE,
VINYL ACETATE, ALKYLENE OXIDES, EPICHLOROHYDRIN
ATTACKS SOME PLASTICS, RUBBER AND COATINGS
REACTS WITH METALS TO PRODUCE FLAMMABLE HYDROGEN GAS
+: FLAME
X: EXPLODING BOMB
+: SKULLS AND CROSSBONES
O: FLAME OVER CIRCLE
+: HEALTH HAZARD
+: EXCLAMATION MARK
+: CORROSION
X - MUST NOT BE STORED TOGETHER
0 - MAY BE STORED TOGETHER WITH SPECIFIC PREVENTIONS
+ - MAY BE STORED TOGETHER
| SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
| OCCUPATIONAL EXPOSURE LIMITS (OEL):
| INGREDIENT DATA:
SOURCE INGREDIENT MATERIAL NAME
US NIOSH RECOMMENDED SULFURIC ACID BATTERY ACID, HYDROGEN
EXPOSURE LIMITS (RELS) WITH >51% ACID SULFATE, OIL OF VITRIOL,
SULFURIC ACID (AQUEOUS)
US ACGIH THRESHOLD SULFURIC ACID SULFURIC ACID
LIMIT VALUES (TLV) WITH >51% ACID
US OSHA PERMISSIBLE SULFURIC ACID SULFURIC ACID
EXPOSURE LEVELS WITH >51% ACID
(PELS) - TABLE Z1
US ACGIH THRESHOLD MERCURIC SULFATE MERCURY, ALL FORMS EXCEPT
LIMIT VALUES (TLV) ALKYL, AS Hg - ELEMENTAL
AND INORGANIC FORMS
US OSHA PERMISSIBLE MERCURIC SULFATE MERCURY (ARYL AND
EXPOSURE LEVELS INORGANIC) (AS Hg)
(PELS) - TABLE Z1
US ACGIH THRESHOLD SILVER SULFATE SILVER, AND
LIMIT VALUES (TLV) COMPOUNDS - METAL, DUST
AND FUME
US ACGIH THRESHOLD SILVER SULFATE SILVER, AND
LIMIT VALUES (TLV) COMPOUNDS - SOLUBLE
COMPOUNDS, AS Ag
US OSHA PERMISSIBLE SILVER SULFATE SILVER, METAL AND SOLUBLE
EXPOSURE LEVELS COMPOUNDS (AS Ag)
(PELS) - TABLE Z1
INGREDIENT TWA STEL PEAK NOTES
SULFURIC ACID 1 MG/M3 NOT NOT NOT AVAILABLE
WITH >51% ACID AVAILABLE AVAILABLE
SULFURIC ACID 0.2 MG/M3 NOT NOT TLV(R*) BASIS:
WITH >51% ACID AVAILABLE AVAILABLE PULM FUNC
SULFURIC ACID 1 MG/M3 NOT NOT NOT AVAILABLE
WITH >51% ACID AVAILABLE AVAILABLE
MERCURIC SULFATE 0.025 MG/M3 NOT NOT TLV(R*) BASIS:
AVAILABLE AVAILABLE CNS IMPAIR;
KIDNEY DAM; BEI
MERCURIC SULFATE NOT NOT NOT SEE TABLE Z-2
AVAILABLE AVAILABLE AVAILABLE
SILVER SULFATE 0.1 MG/M3 NOT NOT TLV(R*) BASIS:
AVAILABLE AVAILABLE ARGYRIA
SILVER SULFATE 0.01 MG/M3 NOT NOT TLV(R*) BASIS:
AVAILABLE AVAILABLE ARGYRIA
SILVER SULFATE 0.01 MG/M3 NOT NOT NOT AVAILABLE
AVAILABLE AVAILABLE
| EMERGENCY LIMITS:
INGREDIENT MATERIAL NAME TEEL-1 TEEL-2 TEEL-3
SULFURIC ACID SULFURIC ACID NOT NOT NOT
WITH >51% ACID AVAILABLE AVAILABLE AVAILABLE
MERCURIC SULFATE MERCURIC SULFATE; 0.11 MG/M3 0.15 MG/M3 41 MG/M3
(MERCURY(II)
SULFATE)
INGREDIENT ORIGINAL IDLH REVISED IDLH
SULFURIC ACID WITH >51% ACID 15 MG/M3 NOT AVAILABLE
MERCURIC SULFATE 10 MG/M3 NOT AVAILABLE
SILVER SULFATE 10 MG/M3 NOT AVAILABLE
WATER NOT AVAILABLE NOT AVAILABLE
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS ARE USED TO REMOVE A HAZARD OR PLACE A BARRIER BETWEEN
THE WORKER AND THE HAZARD. WELL-DESIGNED ENGINEERING CONTROLS CAN BE HIGHLY
EFFECTIVE IN PROTECTING WORKERS AND WILL TYPICALLY BE INDEPENDENT OF WORKER
INTERACTIONS TO PROVIDE THIS HIGH LEVEL OF PROTECTION.
THE BASIC TYPES OF ENGINEERING CONTROLS ARE:
PROCESS CONTROLS WHICH INVOLVE CHANGING THE WAY A JOB ACTIVITY OR PROCESS
IS DONE TO REDUCE THE RISK.
ENCLOSURE AND/OR ISOLATION OF EMISSION SOURCE WHICH KEEPS A SELECTED HAZARD
"PHYSICALLY" AWAY FROM THE WORKER AND VENTILATION THAT STRATEGICALLY "ADDS"
AND "REMOVES" AIR IN THE WORK ENVIRONMENT. VENTILATION CAN REMOVE OR DILUTE
AN AIR CONTAMINANT IF DESIGNED PROPERLY. THE DESIGN OF A VENTILATION SYSTEM
MUST MATCH THE PARTICULAR PROCESS AND CHEMICAL OR CONTAMINANT IN USE.
EMPLOYERS MAY NEED TO USE MULTIPLE TYPES OF CONTROLS TO PREVENT EMPLOYEE
OVEREXPOSURE.
LOCAL EXHAUST VENTILATION USUALLY REQUIRED. IF RISK OF OVEREXPOSURE EXISTS,
WEAR APPROVED RESPIRATOR. CORRECT FIT IS ESSENTIAL TO OBTAIN ADEQUATE
PROTECTION.
SUPPLIED-AIR TYPE RESPIRATOR MAY BE REQUIRED IN SPECIAL CIRCUMSTANCES.
CORRECT FIT IS ESSENTIAL TO ENSURE ADEQUATE PROTECTION.
AN APPROVED SELF CONTAINED BREATHING APPARATUS (SCBA) MAY BE REQUIRED IN
SOME SITUATIONS.
PROVIDE ADEQUATE VENTILATION IN WAREHOUSE OR CLOSED STORAGE AREA. AIR
CONTAMINANTS GENERATED IN THE WORKPLACE POSSESS VARYING "ESCAPE" VELOCITIES
WHICH, IN TURN, DETERMINE THE "CAPTURE VELOCITIES" OF FRESH CIRCULATING
AIR REQUIRED TO EFFECTIVELY REMOVE THE CONTAMINANT.
TYPE OF CONTAMINANT AIR SPEED
SOLVENT, VAPOURS, DEGREASING ETC., EVAPORATING 0.25-0.5 M/S
FROM TANK (IN STILL AIR). (50-100 F/MIN.)
AEROSOLS, FUMES FROM POURING OPERATIONS, INTERMITTENT 0.5-1 M/S
CONTAINER FILLING, LOW SPEED CONVEYER TRANSFERS, (100-200 F/MIN.)
WELDING, SPRAY DRIFT, PLATING ACID FUMES, PICKLING
(RELEASED AT LOW VELOCITY INTO ZONE OF ACTIVE
GENERATION)
DIRECT SPRAY, SPRAY PAINTING IN SHALLOW BOOTHS, DRUM 1-2.5 M/S
FILLING, CONVEYER LOADING, CRUSHER DUSTS, GAS DISCHARGE (200-500 F/MIN.)
(ACTIVE GENERATION INTO ZONE OF RAPID AIR MOTION)
GRINDING, ABRASIVE BLASTING, TUMBLING, HIGH SPEED WHEEL 2.5-10 M/S
GENERATED DUSTS (RELEASED AT HIGH INITIAL VELOCITY INTO (500-2000 F/MIN.)
ZONE OF VERY HIGH RAPID AIR MOTION).
WITHIN EACH RANGE THE APPROPRIATE VALUE DEPENDS ON:
LOWER END OF THE RANGE UPPER END OF THE RANGE
1: 1: DISTURBING ROOM AIR CURRENTS
ROOM AIR CURRENTS MINIMAL
OR FAVOURABLE TO CAPTURE
2: 2: CONTAMINANTS OF HIGH TOXICITY
CONTAMINANTS OF LOW TOXICITY
OR OF NUISANCE VALUE ONLY.
3: INTERMITTENT, LOW PRODUCTION. 3: HIGH PRODUCTION, HEAVY USE
4: 4: SMALL HOOD-LOCAL CONTROL ONLY
LARGE HOOD OR LARGE AIR MASS
IN MOTION
SIMPLE THEORY SHOWS THAT AIR VELOCITY FALLS RAPIDLY WITH DISTANCE AWAY FROM
THE OPENING OF A SIMPLE EXTRACTION PIPE. VELOCITY GENERALLY DECREASES WITH
THE SQUARE OF DISTANCE FROM THE EXTRACTION POINT (IN SIMPLE CASES).
THEREFORE THE AIR SPEED AT THE EXTRACTION POINT SHOULD BE ADJUSTED,
ACCORDINGLY, AFTER REFERENCE TO DISTANCE FROM THE CONTAMINATING SOURCE.
THE AIR VELOCITY AT THE EXTRACTION FAN, FOR EXAMPLE, SHOULD BE A MINIMUM
OF 1-2 M/S (200-400 F/MIN) FOR EXTRACTION OF SOLVENTS GENERATED IN A TANK
2 METERS DISTANT FROM THE EXTRACTION POINT. OTHER MECHANICAL
CONSIDERATIONS, PRODUCING PERFORMANCE DEFICITS WITHIN THE EXTRACTION
APPARATUS, MAKE IT ESSENTIAL THAT THEORETICAL AIR VELOCITIES ARE MULTIPLIED
BY FACTORS OF 10 OR MORE WHEN EXTRACTION SYSTEMS ARE INSTALLED OR USED.
PERSONAL PROTECTION:
FACE SHIELD
GLOVES
FULL SUIT
BOOTS
FULL-FACE RESPIRATOR
EYE AND FACE PROTECTION:
SAFETY GLASSES WITH UNPERFORATED SIDE SHIELDS MAY BE USED WHERE CONTINUOUS
EYE PROTECTION IS DESIRABLE, AS IN LABORATORIES; SPECTACLES ARE NOT
SUFFICIENT WHERE COMPLETE EYE PROTECTION IS NEEDED SUCH AS WHEN HANDLING
BULK-QUANTITIES, WHERE THERE IS A DANGER OF SPLASHING, OR IF THE MATERIAL
MAY BE UNDER PRESSURE.
CHEMICAL GOGGLES. WHENEVER THERE IS A DANGER OF THE MATERIAL COMING IN
CONTACT WITH THE EYES; GOGGLES MUST BE PROPERLY FITTED.
FULL FACE SHIELD (20 CM, 8 IN MINIMUM) MAY BE REQUIRED FOR SUPPLEMENTARY
BUT NEVER FOR PRIMARY PROTECTION OF EYES; THESE AFFORD FACE PROTECTION.
ALTERNATIVELY A GAS MASK MAY REPLACE SPLASH GOGGLES AND FACE SHIELDS.
CONTACT LENSES MAY POSE A SPECIAL HAZARD; SOFT CONTACT LENSES MAY ABSORB
AND CONCENTRATE IRRITANTS. A WRITTEN POLICY DOCUMENT, DESCRIBING THE
WEARING OF LENSES OR RESTRICTIONS ON USE, SHOULD BE CREATED FOR EACH
WORKPLACE OR TASK. THIS SHOULD INCLUDE A REVIEW OF LENS ABSORPTION AND
ADSORPTION FOR THE CLASS OF CHEMICALS IN USE AND AN ACCOUNT OF INJURY
EXPERIENCE. MEDICAL AND FIRST-AID PERSONNEL SHOULD BE TRAINED IN THEIR
REMOVAL AND SUITABLE EQUIPMENT SHOULD BE READILY AVAILABLE. IN THE EVENT
OF CHEMICAL EXPOSURE, BEGIN EYE IRRIGATION IMMEDIATELY AND REMOVE CONTACT
LENS AS SOON AS PRACTICABLE. LENS SHOULD BE REMOVED AT THE FIRST SIGNS OF
EYE REDNESS OR IRRITATION - LENS SHOULD BE REMOVED IN A CLEAN ENVIRONMENT
ONLY AFTER WORKERS HAVE WASHED HANDS THOROUGHLY. [CDC NIOSH CURRENT
INTELLIGENCE BULLETIN 59], [AS/NZS 1336 OR NATIONAL EQUIVALENT]
SKIN PROTECTION: SEE HAND PROTECTION BELOW
HANDS/FEET PROTECTION:
ELBOW LENGTH PVC GLOVES
WHEN HANDLING CORROSIVE LIQUIDS, WEAR TROUSERS OR OVERALLS OUTSIDE OF
BOOTS, TO AVOID SPILLS ENTERING BOOTS.
BODY PROTECTION: SEE OTHER PROTECTION BELOW
OTHER PROTECTION:
OVERALLS.
PVC APRON.
PVC PROTECTIVE SUIT MAY BE REQUIRED IF EXPOSURE SEVERE.
EYEWASH UNIT.
ENSURE THERE IS READY ACCESS TO A SAFETY SHOWER.
RECOMMENDED MATERIAL(S):
| GLOVE SELECTION INDEX:
GLOVE SELECTION IS BASED ON A MODIFIED PRESENTATION OF THE:
"FORSBERG CLOTHING PERFORMANCE INDEX".
THE EFFECT(S) OF THE FOLLOWING SUBSTANCE(S) ARE TAKEN INTO ACCOUNT IN THE
COMPUTER-GENERATED SELECTION: 251991Y - COD REAGENT VARIO MR
RESPIRATORY PROTECTION:
MATERIAL CPI
NEOPRENE A
BUTYL C
NATURAL RUBBER C
NATURAL+NEOPRENE C
NEOPRENE/NATURAL C
NITRILE C
PE C
PVA C
PVC C
SARANEX-23 C
VITON C
* CPI - CHEMWATCH PERFORMANCE INDEX
A: BEST SELECTION
B: SATISFACTORY; MAY DEGRADE AFTER 4 HOURS CONTINUOUS IMMERSION
C: POOR TO DANGEROUS CHOICE FOR OTHER THAN SHORT TERM IMMERSION
NOTE:
AS A SERIES OF FACTORS WILL INFLUENCE THE ACTUAL PERFORMANCE OF THE GLOVE,
A FINAL SELECTION MUST BE BASED ON DETAILED OBSERVATION.
* WHERE THE GLOVE IS TO BE USED ON A SHORT TERM, CASUAL OR INFREQUENT
BASIS, FACTORS SUCH AS "FEEL" OR CONVENIENCE (E.G. DISPOSABILITY), MAY
DICTATE A CHOICE OF GLOVES WHICH MIGHT OTHERWISE BE UNSUITABLE FOLLOWING
LONG-TERM OR FREQUENT USE. A QUALIFIED PRACTITIONER SHOULD BE CONSULTED.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: BROWN
PHYSICAL STATE: LIQUID
ODOUR: NOT AVAILABLE
ODOUR THRESHOLD: NOT AVAILABLE
PH (AS SUPPLIED): 1
MELTING POINT / FREEZING POINT (DEG. C): NOT AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE (DEG. C): NOT AVAILABLE
FLASH POINT (DEG. C): NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY: NOT AVAILABLE
UPPER EXPLOSIVE LIMIT (%): NOT AVAILABLE
LOWER EXPLOSIVE LIMIT (%): NOT AVAILABLE
VAPOUR PRESSURE (KPA): NOT AVAILABLE
SOLUBILITY IN WATER (G/L): MISCIBLE
VAPOUR DENSITY (AIR = 1): NOT AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.758
PARTITION COEFFICIENT N-OCTANOL / WATER: NOT AVAILABLE
AUTO-IGNITION TEMPERATURE (DEG. C): NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY (CST): NOT AVAILABLE
MOLECULAR WEIGHT (G/MOL): NOT AVAILABLE
TASTE: NOT AVAILABLE
EXPLOSIVE PROPERTIES: NOT AVAILABLE
OXIDISING PROPERTIES: NOT AVAILABLE
SURFACE TENSION (DYN/CM OR MN/M): NOT AVAILABLE
VOLATILE COMPONENT (%VOL): NOT AVAILABLE
GAS GROUP: NOT AVAILABLE
PH AS A SOLUTION (1%): NOT AVAILABLE
VOC G/L: NOT AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY: SEE SECTION 7
CHEMICAL STABILITY:
CONTACT WITH ALKALINE MATERIAL LIBERATES HEAT
UNSTABLE IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
PRODUCT IS CONSIDERED STABLE.
HAZARDOUS POLYMERISATION WILL NOT OCCUR.
POSSIBILITY OF HAZARDOUS REACTIONS: SEE SECTION 7
CONDITIONS TO AVOID: SEE SECTION 7
INCOMPATIBLE MATERIALS: SEE SECTION 7
HAZARDOUS DECOMPOSITION PRODUCTS: SEE SECTION 5
| SECTION 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
INHALED:
INHALATION OF VAPOURS OR AEROSOLS (MISTS, FUMES), GENERATED BY THE MATERIAL
DURING THE COURSE OF NORMAL HANDLING, MAY BE HARMFUL.
THE MATERIAL CAN CAUSE RESPIRATORY IRRITATION IN SOME PERSONS. THE BODY'S
RESPONSE TO SUCH IRRITATION CAN CAUSE FURTHER LUNG DAMAGE.
CORROSIVE ACIDS CAN CAUSE IRRITATION OF THE RESPIRATORY TRACT, WITH
COUGHING, CHOKING AND MUCOUS MEMBRANE DAMAGE. THERE MAY BE DIZZINESS,
HEADACHE, NAUSEA AND WEAKNESS.
HIGH CONCENTRATIONS CAUSE INFLAMED AIRWAYS AND WATERY SWELLING OF THE
LUNGS WITH OEDEMA.
INGESTION:
ACCIDENTAL INGESTION OF THE MATERIAL MAY BE HARMFUL; ANIMAL EXPERIMENTS
INDICATE THAT INGESTION OF LESS THAN 150 GRAM MAY BE FATAL OR MAY PRODUCE
SERIOUS DAMAGE TO THE HEALTH OF THE INDIVIDUAL.
INGESTION OF ACIDIC CORROSIVES MAY PRODUCE BURNS AROUND AND IN THE MOUTH,
THE THROAT AND OESOPHAGUS. IMMEDIATE PAIN AND DIFFICULTIES IN SWALLOWING
AND SPEAKING MAY ALSO BE EVIDENT.
SKIN CONTACT:
SKIN CONTACT WITH THE MATERIAL MAY BE HARMFUL; SYSTEMIC EFFECTS MAY RESULT
FOLLOWING ABSORPTION.
SKIN CONTACT WITH ACIDIC CORROSIVES MAY RESULT IN PAIN AND BURNS; THESE MAY
BE DEEP WITH DISTINCT EDGES AND MAY HEAL SLOWLY WITH THE FORMATION OF SCAR
TISSUE.
OPEN CUTS, ABRADED OR IRRITATED SKIN SHOULD NOT BE EXPOSED TO THIS MATERIAL
ENTRY INTO THE BLOOD-STREAM, THROUGH, FOR EXAMPLE, CUTS, ABRASIONS OR
LESIONS, MAY PRODUCE SYSTEMIC INJURY WITH HARMFUL EFFECTS. EXAMINE THE
SKIN PRIOR TO THE USE OF THE MATERIAL AND ENSURE THAT ANY EXTERNAL DAMAGE
IS SUITABLY PROTECTED.
EYE:
IF APPLIED TO THE EYES, THIS MATERIAL CAUSES SEVERE EYE DAMAGE.
DIRECT EYE CONTACT WITH ACID CORROSIVES MAY PRODUCE PAIN, TEARS,
SENSITIVITY TO LIGHT AND BURNS. MILD BURNS OF THE EPITHELIA GENERALLY
RECOVER RAPIDLY AND COMPLETELY.
CHRONIC:
REPEATED OR PROLONGED EXPOSURE TO ACIDS MAY RESULT IN THE EROSION OF TEETH,
SWELLING AND/OR ULCERATION OF MOUTH LINING. IRRITATION OF AIRWAYS TO LUNG,
WITH COUGH, AND INFLAMMATION OF LUNG TISSUE OFTEN OCCURS.
REPEATED OR LONG-TERM OCCUPATIONAL EXPOSURE IS LIKELY TO PRODUCE CUMULATIVE
HEALTH EFFECTS INVOLVING ORGANS OR BIOCHEMICAL SYSTEMS.
LONG-TERM EXPOSURE TO RESPIRATORY IRRITANTS MAY RESULT IN AIRWAYS DISEASE,
INVOLVING DIFFICULTY BREATHING AND RELATED WHOLE-BODY PROBLEMS.
THERE IS SOME EVIDENCE THAT INHALING THIS PRODUCT IS MORE LIKELY TO CAUSE A
SENSITISATION REACTION IN SOME PERSONS COMPARED TO THE GENERAL POPULATION.
251991Y - COD REAGENT VARIO MR:
TOXICITY IRRITATION
NOT AVAILABLE NOT AVAILABLE
SULFURIC ACID WITH >51% ACID:
TOXICITY IRRITATION
INHALATION (GUINEA PIG) LC50: 0.036 MG/L/8H[2] NOT AVAILABLE
ORAL (RAT) LD50: 2140 MG/KG[2]
MERCURIC SULFATE:
TOXICITY IRRITATION
DERMAL (RAT) LD50: 625 MG/KG[2] NOT AVAILABLE
ORAL (RAT) LD50: 57 MG/KG[2]
SILVER SULFATE:
TOXICITY IRRITATION
NOT AVAILABLE NOT AVAILABLE
WATER:
TOXICITY IRRITATION
NOT AVAILABLE NOT AVAILABLE
LEGEND:
1. VALUE OBTAINED FROM EUROPE ECHA REGISTERED SUBSTANCES - ACUTE TOXICITY
2.* VALUE OBTAINED FROM MANUFACTURER'S SDS. UNLESS OTHERWISE SPECIFIED DATA
EXTRACTED FROM RTECS - REGISTER OF TOXIC EFFECT OF CHEMICAL SUBSTANCES
251991Y - COD REAGENT VARIO MR:
FOR ACID MISTS, AEROSOLS, VAPOURS
TEST RESULTS SUGGEST THAT EUKARYOTIC CELLS ARE SUSCEPTIBLE TO GENETIC
DAMAGE WHEN THE PH FALLS TO ABOUT 6.5. CELLS FROM THE RESPIRATORY TRACT
HAVE NOT BEEN EXAMINED IN THIS RESPECT. MUCOUS SECRETION MAY PROTECT THE
CELLS OF THE AIRWAY FROM DIRECT EXPOSURE TO INHALED ACIDIC MISTS
(WHICH ALSO PROTECTS THE STOMACH LINING FROM THE HYDROCHLORIC ACID SECRETED
THERE).
251991Y - COD REAGENT VARIO MR & SILVER SULFATE:
ASTHMA-LIKE SYMPTOMS MAY CONTINUE FOR MONTHS OR EVEN YEARS AFTER EXPOSURE
TO THE MATERIAL ENDS. THIS MAY BE DUE TO A NON-ALLERGIC CONDITION KNOWN AS
REACTIVE AIRWAYS DYSFUNCTION SYNDROME (RADS) WHICH CAN OCCUR AFTER EXPOSURE
TO HIGH LEVELS OF HIGHLY IRRITATING COMPOUND. MAIN CRITERIA FOR DIAGNOSING
RADS INCLUDE THE ABSENCE OF PREVIOUS AIRWAYS DISEASE IN A NON-ATOPIC
INDIVIDUAL, WITH SUDDEN ONSET OF PERSISTENT ASTHMA-LIKE SYMPTOMS WITHIN
MINUTES TO HOURS OF A DOCUMENTED EXPOSURE TO THE IRRITANT. OTHER CRITERIA
FOR DIAGNOSIS OF RADS INCLUDE A REVERSIBLE AIRFLOW PATTERN ON LUNG FUNCTION
TESTS, MODERATE TO SEVERE BRONCHIAL HYPERREACTIVITY ON METHACHOLINE
CHALLENGE TESTING, AND THE LACK OF MINIMAL LYMPHOCYTIC INFLAMMATION,
WITHOUT EOSINOPHILIA. RADS (OR ASTHMA) FOLLOWING AN IRRITATING INHALATION
IS AN INFREQUENT DISORDER WITH RATES RELATED TO THE CONCENTRATION OF AND
DURATION OF EXPOSURE TO THE IRRITATING SUBSTANCE. ON THE OTHER HAND,
INDUSTRIAL BRONCHITIS IS A DISORDER THAT OCCURS AS A RESULT OF EXPOSURE
DUE TO HIGH CONCENTRATIONS OF IRRITATING SUBSTANCE (OFTEN PARTICLES) AND IS
COMPLETELY REVERSIBLE AFTER EXPOSURE CEASES. THE DISORDER IS CHARACTERIZED
BY DIFFICULTY BREATHING, COUGH AND MUCUS PRODUCTION.
SILVER SULFATE & WATER:
NO SIGNIFICANT ACUTE TOXICOLOGICAL DATA IDENTIFIED IN LITERATURE SEARCH.
ACUTE TOXICITY: #
CARCINOGENICITY: $
SKIN IRRITATION/CORROSION: #
REPRODUCTIVITY: $
SERIOUS EYE DAMAGE/IRRITATION: #
STOT - SINGLE EXPOSURE: $
RESPIRATORY OR SKIN SENSITISATION: $
STOT - REPEATED EXPOSURE: #
MUTAGENICITY: $
ASPIRATION HAZARD: $
LEGEND:
X - DATA AVAILABLE BUT DOES NOT FILL THE CRITERIA FOR CLASSIFICATION
# - DATA AVAILABLE TO MAKE CLASSIFICATION
$ - DATA NOT AVAILABLE TO MAKE CLASSIFICATION
| SECTION 12 ECOLOGICAL INFORMATION | |
TOXICITY:
251991Y - COD REAGENT VARIO MR:
ENDPOINT TEST DURATION SPECIES VALUE SOURCE
(HR)
NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
SULFURIC ACID WITH >51% ACID:
ENDPOINT TEST DURATION SPECIES VALUE SOURCE
(HR)
LC50 96 FISH =8 MG/L 1
EC50 48 CRUSTACEA =42.5 MG/L 1
EC0 24 CRUSTACEA =30 MG/L 1
NOEC 16 CRUSTACEA 88 MG/L 4
MERCURIC SULFATE:
ENDPOINT TEST DURATION SPECIES VALUE SOURCE
(HR)
NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
SILVER SULFATE:
ENDPOINT TEST DURATION SPECIES VALUE SOURCE
(HR)
LC50 96 FISH 0.0031 MG/L 2
EC50 48 CRUSTACEA 0.0006 MG/L 2
NOEC 480 CRUSTACEA 0.00031 MG/L 2
WATER:
ENDPOINT TEST DURATION SPECIES VALUE SOURCE
(HR)
NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
LEGEND:
EXTRACTED FROM
1. IUCLID TOXICITY DATA
2. EUROPE ECHA REGISTERED SUBSTANCES - ECOTOXICOLOGICAL
INFORMATION - AQUATIC TOXICITY
3. EPIWIN SUITE V3.12 (QSAR) - AQUATIC TOXICITY DATA (ESTIMATED)
4. US EPA, ECOTOX DATABASE - AQUATIC TOXICITY DATA
5. ECETOC AQUATIC HAZARD ASSESSMENT DATA
6. NITE (JAPAN) - BIOCONCENTRATION DATA
7. METI (JAPAN) - BIOCONCENTRATION DATA
8. VENDOR DATA
HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
DO NOT ALLOW PRODUCT TO COME IN CONTACT WITH SURFACE WATERS OR TO
INTERTIDAL AREAS BELOW THE MEAN HIGH WATER MARK. DO NOT CONTAMINATE WATER
WHEN CLEANING EQUIPMENT OR DISPOSING OF EQUIPMENT WASH-WATERS.
WASTES RESULTING FROM USE OF THE PRODUCT MUST BE DISPOSED OF ON SITE OR
AT APPROVED WASTE SITES.
ECOTOXICITY:
THE TOLERANCE OF WATER ORGANISMS TOWARDS PH MARGIN AND VARIATION IS
DIVERSE. RECOMMENDED PH VALUES FOR TEST SPECIES LISTED IN OECD GUIDELINES
ARE BETWEEN 6.0 AND ALMOST 9. ACUTE TESTING WITH FISH SHOWED 96H-LC50 AT
ABOUT PH 3.5
PREVENT, BY ANY MEANS AVAILABLE, SPILLAGE FROM ENTERING DRAINS OR WATER
COURSES.
FOR SULFURIC ACID:
ENVIRONMENTAL FATE:
LARGE DISCHARGES OF SULFURIC ACID MAY CONTRIBUTE TO THE ACIDIFICATION OF
WATER AND BE FATAL TO AQUATIC LIFE AND SOIL MICRO-ORGANISMS, AND MAY
CONTRIBUTE TO THE ACIDIFICATION OF EFFLUENT TREATMENT SYSTEMS AND INJURE
SEWAGE TREATMENT ORGANISMS. THE SUBSTANCE WILL REACT VIOLENTLY WITH A
VARIETY OF OTHER CHEMICALS, AS WELL AS WATER.
ATMOSPHERIC FATE:
SULFURIC ACID IS REMOVED FROM THE AIR BY DRY/WET DEPOSITION. IN THE
STRATOSPHERE, SULFURIC ACID AEROSOLS HAVE LIFETIMES OF ABOUT 14 AND 2.4
DAYS, AT ALTITUDES OF 15 AND 20 KM, RESPECTIVELY. AT CLOUD LEVEL, THE
RESIDENCE TIME IS ABOUT 6 DAYS, WITH SHORTER RESIDENCE TIMES IN SURFACE
AIR. THE SUBSTANCE WILL REACT WITH ATMOSPHERIC WATER, (HYGROSCOPIC). THE
SUBSTANCE IS A STRONG OXIDIZER, (REACTS WITH OXYGEN), AND IS HIGHLY
CORROSIVE TO STAINLESS STEEL.
TERRESTRIAL FATE:
SOIL - IN SOIL, THE IONS FROM SULFURIC ACID CAN ADSORB TO SOIL PARTICLES
OR LEACH INTO SURFACE WATER AND GROUNDWATER. THE IONS, (SULFATE, HYDROGEN),
CAN ADSORB TO SOIL PARTICLES OR BE CONVERTED TO GASES. LOW OXYGEN BACTERIA
IN SEDIMENTS AND SOIL CAN REDUCE SULFATE TO SULFUR AND HYDROGEN SULFIDE.
PLANTS - SULFATES CAN BE TAKEN UP BY PLANTS AND BE INCORPORATED INTO THE
PARENCHYMA OF THE PLANT.
AQUATIC FATE:
IN WATER, SULFURIC ACID BREAKS APART INTO LESS COMPLEX GROUPS OF ATOMS,
(DISSOCIATES), AND THE NEGATIVELY CHARGES SULFATE ATOMS MAY COMBINE WITH
OTHER POSITIVELY CHARGES ATOMS.
SULFURIC ACID WILL REACT VIOLENTLY IN ALCOHOL AND WATER, ESPECIALLY IF
WATER IS ADDED TO THE PRODUCT.
ECOTOXICITY:
SHORT TERM DEGRADATION PRODUCTS ARE NOT LIKELY. HOWEVER, LONG TERM
DEGRADATION PRODUCTS MAY ARISE. THE PRODUCTS OF DEGRADATION ARE LESS
TOXIC THAN THE PRODUCT ITSELF. SULFURIC ACID IS MODERATELY TOXIC TO
BLUEGILL/SUNFISH, AESOP SHRIMP, AND WESTERN MOSQUITOFISH.
DO NOT DISCHARGE INTO SEWER OR WATERWAYS.
PERSISTENCE AND DEGRADABILITY:
INGREDIENT PERSISTENCE: WATER/SOIL PERSISTENCE: AIR
WATER LOW LOW
BIOACCUMULATIVE POTENTIAL:
INGREDIENT BIOACCUMULATION
WATER LOW (LOGKOW = -1.38)
MOBILITY IN SOIL:
INGREDIENT MOBILITY
WATER LOW (KOC = 14.3)
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
PRODUCT / PACKAGING DISPOSAL:
CONTAINERS MAY STILL PRESENT A CHEMICAL HAZARD/DANGER WHEN EMPTY.
RETURN TO SUPPLIER FOR REUSE/RECYCLING IF POSSIBLE.
OTHERWISE:
IF CONTAINER CAN NOT BE CLEANED SUFFICIENTLY WELL TO ENSURE THAT RESIDUALS
DO NOT REMAIN OR IF THE CONTAINER CANNOT BE USED TO STORE THE SAME PRODUCT,
THEN PUNCTURE CONTAINERS, TO PREVENT RE-USE, AND BURY AT AN AUTHORISED
LANDFILL.
WHERE POSSIBLE RETAIN LABEL WARNINGS AND SDS AND OBSERVE ALL NOTICES
PERTAINING TO THE PRODUCT.
RECYCLE WHEREVER POSSIBLE.
CONSULT MANUFACTURER FOR RECYCLING OPTIONS OR CONSULT LOCAL OR REGIONAL
WASTE MANAGEMENT AUTHORITY FOR DISPOSAL IF NO SUITABLE TREATMENT OR
DISPOSAL FACILITY CAN BE IDENTIFIED.
TREAT AND NEUTRALISE AT AN APPROVED TREATMENT PLANT. TREATMENT SHOULD
INVOLVE:
NEUTRALISATION WITH SODA-ASH OR SODA-LIME FOLLOWED BY:
BURIAL IN A LAND-FILL SPECIFICALLY LICENSED TO ACCEPT CHEMICAL AND / OR
PHARMACEUTICAL WASTES OR INCINERATION IN A LICENSED APPARATUS
(AFTER ADMIXTURE WITH SUITABLE COMBUSTIBLE MATERIAL).
DECONTAMINATE EMPTY CONTAINERS WITH 5% AQUEOUS SODIUM HYDROXIDE OR SODA
ASH, FOLLOWED BY WATER. OBSERVE ALL LABEL SAFEGUARDS UNTIL CONTAINERS ARE
CLEANED AND DESTROYED.
| SECTION 14 TRANSPORT INFORMATION | |
LABELS REQUIRED:
CLASS 8, CORROSIVES
CLASS 6.1, TOXIC
MARINE POLLUTANT: NO
LAND TRANSPORT (DOT):
UN NUMBER: 2922
UN PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, TOXIC, N.O.S. SULPHURIC ACID, MERCURY SULPHATE
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBRISK: 6.1
PACKING GROUP: II
ENVIRONMENTAL HAZARD: NOT APPLICABLE
SPECIAL PRECAUTIONS FOR USER:
HAZARD LABEL: 8, 6.1
SPECIAL PROVISIONS: B3, IB2, T7, TP2
AIR TRANSPORT (ICAO-IATA / DGR):
UN NUMBER: 2922
UN PROPER SHIPPING NAME:
CORROSIVE LIQUID, TOXIC, N.O.S. * SULPHURIC ACID, MERCURY SULPHATE
TRANSPORT HAZARD CLASS(ES):
ICAO/IATA CLASS: 8
ICAO / IATA SUBRISK: 6.1
ERG CODE: 8P
PACKING GROUP: II
ENVIRONMENTAL HAZARD: NOT APPLICABLE
SPECIAL PRECAUTIONS FOR USER:
SPECIAL PROVISIONS: A3 A803
CARGO ONLY PACKING INSTRUCTIONS: 855
CARGO ONLY MAXIMUM QTY / PACK: 30 L
PASSENGER AND CARGO PACKING INSTRUCTIONS: 851
PASSENGER AND CARGO MAXIMUM QTY / PACK: 1 L
PASSENGER AND CARGO LIMITED QUANTITY PACKING INSTRUCTIONS: Y840
PASSENGER AND CARGO LIMITED MAXIMUM QTY / PACK: 0.5 L
SEA TRANSPORT (IMDG-CODE / GGVSEE):
UN NUMBER: 2922
UN PROPER SHIPPING NAME:
CORROSIVE LIQUID, TOXIC, N.O.S. SULPHURIC ACID, MERCURY SULPHATE
TRANSPORT HAZARD CLASS(ES):
IMDG CLASS: 8
IMDG SUBRISK: 6.1
PACKING GROUP: II
ENVIRONMENTAL HAZARD: NOT APPLICABLE
SPECIAL PRECAUTIONS FOR USER:
EMS NUMBER: F-A, S-B
SPECIAL PROVISIONS: 274
LIMITED QUANTITIES: 1 L
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
SOURCE PRODUCT NAME POLLUTION CATEGORY SHIP TYPE
SULPHURIC ACID Y 3
| SECTION 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS / LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
| SULFURIC ACID WITH >51% ACID(7664-93-9) IS FOUND ON THE FOLLOWING
| REGULATORY LISTS:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) - AGENTS CLASSIFIED BY
THE IARC MONOGRAPHS
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) DANGEROUS GOODS
REGULATIONS - PROHIBITED LIST
PASSENGER AND CARGO AIRCRAFT
US - ALASKA LIMITS FOR AIR CONTAMINANTS
US - CALIFORNIA OEHHA/ARB - ACUTE REFERENCE EXPOSURE LEVELS AND TARGET
ORGANS (RELS)
US - CALIFORNIA OEHHA/ARB - CHRONIC REFERENCE EXPOSURE LEVELS AND TARGET
ORGANS (CRELS)
US - CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
US - HAWAII AIR CONTAMINANT LIMITS
US - IDAHO - LIMITS FOR AIR CONTAMINANTS
US - MASSACHUSETTS - RIGHT TO KNOW LISTED CHEMICALS
US - MICHIGAN EXPOSURE LIMITS FOR AIR CONTAMINANTS
US - MINNESOTA PERMISSIBLE EXPOSURE LIMITS (PELS)
US - NEW JERSEY RIGHT TO KNOW - SPECIAL HEALTH HAZARD SUBSTANCE LIST
(SHHSL): CARCINOGENS
US - OREGON PERMISSIBLE EXPOSURE LIMITS (Z-1)
US - PENNSYLVANIA - HAZARDOUS SUBSTANCE LIST
US - RHODE ISLAND HAZARDOUS SUBSTANCE LIST
US - TENNESSEE OCCUPATIONAL EXPOSURE LIMITS - LIMITS FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A FINAL RULE LIMITS
FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A TRANSITIONAL LIMITS
FOR AIR CONTAMINANTS
US - WASHINGTON PERMISSIBLE EXPOSURE LIMITS OF AIR CONTAMINANTS
US - WASHINGTON TOXIC AIR POLLUTANTS AND THEIR ASIL, SQER AND DE MINIMIS
EMISSION VALUES
US - WYOMING TOXIC AND HAZARDOUS SUBSTANCES TABLE Z1 LIMITS FOR AIR
CONTAMINANTS
US ACGIH THRESHOLD LIMIT VALUES (TLV)
US ACGIH THRESHOLD LIMIT VALUES (TLV) - CARCINOGENS
US CWA (CLEAN WATER ACT) - LIST OF HAZARDOUS SUBSTANCES
US DRUG ENFORCEMENT ADMINISTRATION (DEA) LIST I AND II REGULATED CHEMICALS
US EPCRA SECTION 313 CHEMICAL LIST
US NATIONAL TOXICOLOGY PROGRAM (NTP) 14TH REPORT PART A KNOWN TO BE HUMAN
CARCINOGENS
US NIOSH RECOMMENDED EXPOSURE LIMITS (RELS)
US OSHA PERMISSIBLE EXPOSURE LEVELS (PELS) - TABLE Z1
US SARA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES
US TOXIC SUBSTANCES CONTROL ACT (TSCA) - CHEMICAL SUBSTANCE INVENTORY
US TSCA CHEMICAL SUBSTANCE INVENTORY - INTERIM LIST OF ACTIVE SUBSTANCES
| MERCURIC SULFATE(7783-35-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) - AGENTS CLASSIFIED BY
THE IARC MONOGRAPHS
US - ALASKA LIMITS FOR AIR CONTAMINANTS
US - CALIFORNIA OEHHA/ARB - ACUTE REFERENCE EXPOSURE LEVELS AND TARGET
ORGANS (RELS)
US - CALIFORNIA OEHHA/ARB - CHRONIC REFERENCE EXPOSURE LEVELS AND TARGET
ORGANS (CRELS)
US - CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
US - CALIFORNIA PROPOSITION 65 - REPRODUCTIVE TOXICITY
US - HAWAII AIR CONTAMINANT LIMITS
US - IDAHO - LIMITS FOR AIR CONTAMINANTS
US - MASSACHUSETTS - RIGHT TO KNOW LISTED CHEMICALS
US - MICHIGAN EXPOSURE LIMITS FOR AIR CONTAMINANTS
US - MINNESOTA PERMISSIBLE EXPOSURE LIMITS (PELS)
US - PENNSYLVANIA - HAZARDOUS SUBSTANCE LIST
US - TENNESSEE OCCUPATIONAL EXPOSURE LIMITS - LIMITS FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A FINAL RULE LIMITS
FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A TRANSITIONAL LIMITS
FOR AIR CONTAMINANTS
US - WASHINGTON PERMISSIBLE EXPOSURE LIMITS OF AIR CONTAMINANTS
US - WYOMING TOXIC AND HAZARDOUS SUBSTANCES TABLE Z1 LIMITS FOR AIR
CONTAMINANTS
US ACGIH THRESHOLD LIMIT VALUES (TLV)
US ACGIH THRESHOLD LIMIT VALUES (TLV) - CARCINOGENS
US CLEAN AIR ACT - HAZARDOUS AIR POLLUTANTS
US CWA (CLEAN WATER ACT) - LIST OF HAZARDOUS SUBSTANCES
US CWA (CLEAN WATER ACT) - PRIORITY POLLUTANTS
US CWA (CLEAN WATER ACT) - TOXIC POLLUTANTS
US EPCRA SECTION 313 CHEMICAL LIST
US LIST OF ACTIVE SUBSTANCES EXEMPT FROM THE TSCA INVENTORY NOTIFICATIONS
(ACTIVE-INACTIVE) RULE
US OSHA PERMISSIBLE EXPOSURE LEVELS (PELS) - TABLE Z1
US TOXIC SUBSTANCES CONTROL ACT (TSCA) - CHEMICAL SUBSTANCE INVENTORY
| SILVER SULFATE(10294-26-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS:
US - CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
US - HAWAII AIR CONTAMINANT LIMITS
US - IDAHO - LIMITS FOR AIR CONTAMINANTS
US - MICHIGAN EXPOSURE LIMITS FOR AIR CONTAMINANTS
US - MINNESOTA PERMISSIBLE EXPOSURE LIMITS (PELS)
US - OREGON PERMISSIBLE EXPOSURE LIMITS (Z-1)
US - TENNESSEE OCCUPATIONAL EXPOSURE LIMITS - LIMITS FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A FINAL RULE LIMITS
FOR AIR CONTAMINANTS
US - VERMONT PERMISSIBLE EXPOSURE LIMITS TABLE Z-1-A TRANSITIONAL LIMITS
FOR AIR CONTAMINANTS
US - WASHINGTON PERMISSIBLE EXPOSURE LIMITS OF AIR CONTAMINANTS
US - WYOMING TOXIC AND HAZARDOUS SUBSTANCES TABLE Z1 LIMITS FOR AIR
CONTAMINANTS
US ACGIH THRESHOLD LIMIT VALUES (TLV)
US CWA (CLEAN WATER ACT) - PRIORITY POLLUTANTS
US CWA (CLEAN WATER ACT) - TOXIC POLLUTANTS
US EPCRA SECTION 313 CHEMICAL LIST
US LIST OF ACTIVE SUBSTANCES EXEMPT FROM THE TSCA INVENTORY NOTIFICATIONS
(ACTIVE-INACTIVE) RULE
US OSHA PERMISSIBLE EXPOSURE LEVELS (PELS) - TABLE Z1
US TOXIC SUBSTANCES CONTROL ACT (TSCA) - CHEMICAL SUBSTANCE INVENTORY
| WATER(7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS:
US TOXIC SUBSTANCES CONTROL ACT (TSCA) - CHEMICAL SUBSTANCE INVENTORY
US TSCA CHEMICAL SUBSTANCE INVENTORY - INTERIM LIST OF ACTIVE SUBSTANCES
ECHA SUMMARY:
INGREDIENT CAS NUMBER INDEX NO ECHA DOSSIER
SULFURIC ACID 7664-93-9 016-020-00-8 01-2119458838-20-XXXX
WITH >51% ACID 01-2119969649-13-XXXX
01-2120080820-60-XXXX
HARMONISATION HAZARD CLASS AND PICTOGRAMS SIGNAL HAZARD STATEMENT
(C&L INVENTORY) CATEGORY CODE(S) WORD CODE(S) CODE(S)
1 SKIN CORR. 1A GHS05; DGR H314
1 SKIN IRRIT. 2; GHS07; WNG H315; H319
EYE IRRIT. 2
HARMONISATION CODE 1 = THE MOST PREVALENT CLASSIFICATION.
HARMONISATION CODE 2 = THE MOST SEVERE CLASSIFICATION.
INGREDIENT CAS NUMBER INDEX NO ECHA DOSSIER
MERCURIC SULFATE 7783-35-9 080-002-00-6 01-2120118583-59-XXXX
HARMONISATION HAZARD CLASS AND PICTOGRAMS SIGNAL HAZARD STATEMENT
(C&L INVENTORY) CATEGORY CODE(S) WORD CODE(S) CODE(S)
1 ACUTE TOX. 2; GHS09; GHS08; H300; H310;
ACUTE TOX. 1; GHS06; DGR H330; H373; H410
STOT RE 2;
AQUATIC ACUTE 1;
AQUATIC CHRONIC 1
HARMONISATION CODE 1 = THE MOST PREVALENT CLASSIFICATION.
HARMONISATION CODE 2 = THE MOST SEVERE CLASSIFICATION.
INGREDIENT CAS NUMBER INDEX NO ECHA DOSSIER
SILVER SULFATE 10294-26-5 NOT AVAILABLE 01-2119918297-31-XXXX
HARMONISATION HAZARD CLASS AND PICTOGRAMS SIGNAL HAZARD STATEMENT
(C&L INVENTORY) CATEGORY CODE(S) WORD CODE(S) CODE(S)
1 EYE DAM. 1; GHS09; GHS05; DGR H318; H410
AQUATIC ACUTE 1;
AQUATIC CHRONIC 1
HARMONISATION CODE 1 = THE MOST PREVALENT CLASSIFICATION.
HARMONISATION CODE 2 = THE MOST SEVERE CLASSIFICATION.
INGREDIENT CAS NUMBER INDEX NO ECHA DOSSIER
WATER 7732-18-5 NOT AVAILABLE NOT AVAILABLE
HARMONISATION HAZARD CLASS AND PICTOGRAMS SIGNAL HAZARD STATEMENT
(C&L INVENTORY) CATEGORY CODE(S) WORD CODE(S) CODE(S)
1 NOT CLASSIFIED NOT AVAILABLE NOT AVAILABLE
HARMONISATION CODE 1 = THE MOST PREVALENT CLASSIFICATION.
HARMONISATION CODE 2 = THE MOST SEVERE CLASSIFICATION.
FEDERAL REGULATIONS:
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
| SECTION 311/312 HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS): NO
GAS UNDER PRESSURE: NO
EXPLOSIVE: NO
SELF-HEATING: NO
PYROPHORIC (LIQUID OR SOLID): NO
PYROPHORIC GAS: NO
CORROSIVE TO METAL: YES
OXIDIZER (LIQUID, SOLID OR GAS): NO
ORGANIC PEROXIDE: NO
SELF-REACTIVE: NO
IN CONTACT WITH WATER EMITS FLAMMABLE GAS: NO
COMBUSTIBLE DUST: NO
CARCINOGENICITY: NO
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE): YES
REPRODUCTIVE TOXICITY: NO
SKIN CORROSION OR IRRITATION: YES
RESPIRATORY OR SKIN SENSITIZATION: NO
SERIOUS EYE DAMAGE OR EYE IRRITATION: YES
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE): YES
ASPIRATION HAZARD: NO
GERM CELL MUTAGENICITY: NO
SIMPLE ASPHYXIANT: NO
| US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES
| (40 CFR 302.4):
NAME REPORTABLE QUANTITY REPORTABLE QUANTITY
IN POUNDS (LB) IN KG
SULFURIC ACID 1000 454
MERCURIC SULFATE 10 4.54
STATE REGULATIONS:
| US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM
| US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & LISTED SUBSTANCE
| REPRODUCTIVE TOXICITY (CRT)
MERCURY AND MERCURY COMPOUNDS LISTED
NATIONAL INVENTORY STATUS:
NATIONAL INVENTORY STATUS
AUSTRALIA - AICS Y
CANADA - DSL Y
CANADA - NDSL N (WATER; SULFURIC ACID WITH >51% ACID;
SILVER SULFATE; MERCURIC SULFATE)
CHINA - IECSC Y
EUROPE - EINEC / ELINCS / NLP Y
JAPAN - ENCS Y
KOREA - KECI Y
NEW ZEALAND - NZIOC Y
PHILIPPINES - PICCS Y
USA - TSCA Y
LEGEND:
Y: ALL INGREDIENTS ARE ON THE INVENTORY
N:
NOT DETERMINED OR ONE OR MORE INGREDIENTS ARE NOT ON THE INVENTORY
AND ARE NOT EXEMPT FROM LISTING(SEE SPECIFIC INGREDIENTS IN BRACKETS)
| SECTION 16 OTHER INFORMATION | |
REVISION DATE: 10/15/2018
INITIAL DATE: 10/15/2018
OTHER INFORMATION:
CLASSIFICATION OF THE PREPARATION AND ITS INDIVIDUAL COMPONENTS HAS DRAWN
ON OFFICIAL AND AUTHORITATIVE SOURCES AS WELL AS INDEPENDENT REVIEW BY THE
CHEMWATCH CLASSIFICATION COMMITTEE USING AVAILABLE LITERATURE REFERENCES.
THE SDS IS A HAZARD COMMUNICATION TOOL AND SHOULD BE USED TO ASSIST IN THE
RISK ASSESSMENT. MANY FACTORS DETERMINE WHETHER THE REPORTED HAZARDS ARE
RISKS IN THE WORKPLACE OR OTHER SETTINGS. RISKS MAY BE DETERMINED BY
REFERENCE TO EXPOSURES SCENARIOS. SCALE OF USE, FREQUENCY OF USE AND
CURRENT OR AVAILABLE ENGINEERING CONTROLS MUST BE CONSIDERED.
DEFINITIONS AND ABBREVIATIONS:
PC-TWA: PERMISSIBLE CONCENTRATION-TIME WEIGHTED AVERAGE
PC-STEL: PERMISSIBLE CONCENTRATION-SHORT TERM EXPOSURE LIMIT
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
STEL: SHORT TERM EXPOSURE LIMIT
TEEL: TEMPORARY EMERGENCY EXPOSURE LIMIT?
IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATIONS
OSF: ODOUR SAFETY FACTOR
NOAEL: NO OBSERVED ADVERSE EFFECT LEVEL
LOAEL: LOWEST OBSERVED ADVERSE EFFECT LEVEL
TLV: THRESHOLD LIMIT VALUE
LOD: LIMIT OF DETECTION
OTV: ODOUR THRESHOLD VALUE
BCF: BIOCONCENTRATION FACTORS
BEI: BIOLOGICAL EXPOSURE INDEX
YSI SELLS THIS PRODUCT UNDER AGREEMENT WITH THE ORIGINAL MANUFACTURER. YSI
ASSUMES NO LEGAL LIABILITY OR RESPONSIBILITY FOR THE ACCURACY, COMPLETENESS
OR USEFULNESS OF ANY INFORMATION SET FORTH IN THIS SDS. YSI, A XYLEM BRAND
CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS INFORMATION AND ITS
PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN COMBINATION WITH ITS
PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY TO ENSURE SAFE
CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE PRODUCT, AND TO ASSUME
LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO IMPROPER USE. THE
INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE.
POWERED BY: AUTHORITE, FROM CHEMWATCH.
CHEMWATCH: 9-600189