| Common Name: | SCOTCHCAST WET-NICHE POTTING COMPOUND 2136 (PARTS A & B) |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/10/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 25L049 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PARTS A & B)
04/10/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 30-1547-6
VERSION NUMBER: 4.01
ISSUE DATE: 04/10/17
SUPERCEDES DATE: 11/11/14
PRODUCT IDENTIFIER:
SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PARTS A & B)
ID NUMBER(S): 80-6116-1278-1
RECOMMENDED USE: ELECTRICAL, WET-NICHE POTTING COMPOUND
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
30-1314-1, 29-4839-6
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PART B)
05/22/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 30-1314-1
VERSION NUMBER: 3.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/04/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER
3M(TM) SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PART B)
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ELECTRICAL, PART B OF TWO-PART ELECTRICAL RESIN SYSTEM.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
CARCINOGENICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
HEALTH HAZARD
PICTOGRAMS:
CORROSION
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR EYE/FACE PROTECTION.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
1,3-BUTADIENE, HOMOPOLYMER, HYDROXY- 69102-90-5 35 - 45
TERMINATED
DIUNDECYL PHTHALATE 3648-20-2 15 - 25
POLYPROPYLENE GLYCOL 25322-69-4 10 - 20 TRADE SECRET *
N,N-DI(2-HYDROXYPROPYL)ANILINE 3077-13-2 5 - 15 TRADE SECRET *
DIPROPYLENE GLYCOL 25265-71-8 5 - 10
4,4'-METHYLENEBIS(2,6-DIETHYLANILINE) 13680-35-8 1 - 6 TRADE SECRET *
ALUMINUM POTASSIUM SODIUM SILICATE 12736-96-8 1 - 5
CARBON BLACK 1333-86-4 1 - 5
CASTOR OIL 8001-79-4 1 - 5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU ARE CONCERNED, GET MEDICAL ADVICE.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. USE
PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
CARBON BLACK 1333-86-4 ACGIH TWA(INHALABLE A3: CONFIRMED ANIMAL
FRACTION): CARCIN.
3 MG/M3
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
POLYPROPYLENE 25322-69-4 AIHA TWA(AS AEROSOL):
GLYCOL 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION: NO CHEMICAL PROTECTIVE GLOVES ARE REQUIRED.
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: SMOOTH BLACK LIQUID WITH CHARACTERISTIC ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >300 DEG. F
FLASH POINT: >300 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: <27 PSIA [@ 131 DEG. F]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 0.98 [DETAILS:REF STD: WATER = 1]
SOLUBILITY IN WATER: NOT APPLICABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 1,600 CENTIPOISE - 2,000 CENTIPOISE
AVERAGE PARTICLE SIZE: NOT APPLICABLE
BULK DENSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: NO DATA AVAILABLE
PERCENT VOLATILE: NO DATA AVAILABLE
SOFTENING POINT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
NOT DETERMINED
NO DATA AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
VAPORS RELEASED DURING CURING MAY CAUSE IRRITATION OF THE RESPIRATORY
SYSTEM. SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE,
HEADACHE, HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
CARBON BLACK 1333-86-4 GRP. 2B: POSSIBLE INTERNATIONAL AGENCY FOR
HUMAN CARC. RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
1,3-BUTADIENE, DERMAL LD50: ESTIMATED TO
HOMOPOLYMER, BE >5,000 MG/KG
HYDROXYTERMINATED
1,3-BUTADIENE, INGESTION LD50: ESTIMATED TO
HOMOPOLYMER, BE 2,000 - 5,000 MG/KG
HYDROXYTERMINATED
DIUNDECYL PHTHALATE DERMAL RABBIT LD50: >7,900 MG/KG
DIUNDECYL PHTHALATE INGESTION RAT LD50: >15,000 MG/KG
POLYPROPYLENE GLYCOL DERMAL RABBIT LD50: >10,000 MG/KG
POLYPROPYLENE GLYCOL INGESTION RAT LD50: >2,000 MG/KG
N,N-DI(2- DERMAL RABBIT LD50: >2,000 MG/KG
HYDROXYPROPYL)-
ANILINE INGESTION RAT LD50: 3,800 MG/KG
N,N-DI(2-
HYDROXYPROPYL)-
ANILINE
DIPROPYLENE GLYCOL DERMAL RABBIT LD50: >5,010 MG/KG
DIPROPYLENE GLYCOL INHALATION- RAT LC50: >2.34 MG/L
DUST/MIST
(4 HOURS)
DIPROPYLENE GLYCOL INGESTION RAT LD50: >5,010 MG/KG
4,4'-METHYLENEBIS- INGESTION RAT LD50: 1,901 MG/KG
(2,6-DIETHYLANILINE)
CASTOR OIL DERMAL LD50: ESTIMATED TO
BE >5,000
CASTOR OIL INGESTION LD50: ESTIMATED TO
BE >5,000
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
N,N-DI(2-HYDROXYPROPYL)ANILINE PROFESSIONAL MINIMAL IRRITATION
JUDGMENT
DIPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
4,4'-METHYLENEBIS(2,6- RABBIT MINIMAL IRRITATION
DIETHYLANILINE)
CASTOR OIL HUMAN MINIMAL IRRITATION
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
N,N-DI(2-HYDROXYPROPYL)ANILINE PROFESSIONAL CORROSIVE
JUDGMENT
DIPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
4,4'-METHYLENEBIS(2,6- RABBIT NO SIGNIFICANT IRRITATION
DIETHYLANILINE)
CASTOR OIL RABBIT MILD IRRITANT
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
DIPROPYLENE GLYCOL GUINEA PIG NOT CLASSIFIED
CASTOR OIL HUMAN NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIPROPYLENE GLYCOL IN VITRO NOT MUTAGENIC
DIPROPYLENE GLYCOL IN VIVO NOT MUTAGENIC
4,4'-METHYLENEBIS(2,6-DIETHYLANILINE) IN VITRO NOT MUTAGENIC
CASTOR OIL IN VITRO NOT MUTAGENIC
CASTOR OIL IN VIVO NOT MUTAGENIC
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIPROPYLENE GLYCOL INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
DIPROPYLENE INGESTION NOT CLASSIFIED RAT NOAEL: 5,000 DURING
GLYCOL FOR DEVELOPMENT MG/KG/DAY ORGANO-
GENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIPROPYLENE INGESTION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
GLYCOL BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIPROPYLENE INGESTION HEART NOT CLASSIFIED
GLYCOL
DIPROPYLENE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
GLYCOL LIVER
DIPROPYLENE INGESTION KIDNEY AND/OR NOT CLASSIFIED
GLYCOL BLADDER
DIPROPYLENE INGESTION SKIN | BONE, TEETH, NOT CLASSIFIED
GLYCOL NAILS, AND/OR HAIR |
HEMATOPOIETIC
SYSTEM | IMMUNE
SYSTEM | NERVOUS
SYSTEM | VASCULAR
SYSTEM
CASTOR OIL INGESTION HEART | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | LIVER
CASTOR OIL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CARBON BLACK INHALATION PNEUMOCONIOSIS NOT CLASSIFIED
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIPROPYLENE GLYCOL RAT NOAEL: 470 MG/KG/DAY 105 WEEKS
DIPROPYLENE GLYCOL RAT NOAEL: 470 MG/KG/DAY 105 WEEKS
DIPROPYLENE GLYCOL RAT NOAEL: 3,040 MG/KG/DAY 105 WEEKS
DIPROPYLENE GLYCOL RAT NOAEL: 115 MG/KG/DAY 105 WEEKS
DIPROPYLENE GLYCOL RAT NOAEL: 3,040 MG/KG/DAY 105 WEEKS
CASTOR OIL RAT NOAEL: 4,800 MG/KG/DAY 13 WEEKS
CASTOR OIL MOUSE NOAEL: 13,000 MG/KG/DAY 13 WEEKS
CARBON BLACK HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. AS A
DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
CARCINOGENICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 30-1314-1
VERSION NUMBER: 3.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/04/18
REASON FOR REISSUE: CONVERSION TO GHS FORMAT SDS.
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PART A)
05/22/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 29-4839-6
VERSION NUMBER: 5.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/04/18
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCHCAST(TM) WET-NICHE POTTING COMPOUND 2136 (PART A)
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ELECTRICAL, PART A OF TWO-PART ELECTRICAL RESIN.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR EYE/FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
25% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYETHER-HYDROCARBON-URETHANE 154517-54-1 35 - 45 TRADE SECRET *
POLYMER
P,P'-METHYLENEBIS(PHENYL 101-68-8 25 - 35 TRADE SECRET *
ISOCYANATE)
BENZENE, 1,1'-METHYLENEBIS- 39310-05-9 5 - 15 TRADE SECRET *
[ISOCYANATO-, HOMOPOLYMER
DIUNDECYL PHTHALATE 3648-20-2 0 - 15
DIUNDECYL PHTHALATE, BRANCHED 85507-79-5 0 - 15
AND LINEAR
1,1'-METHYLENEBIS(ISOCYANATO- 26447-40-5 <2 TRADE SECRET *
BENZENE)
4-VINYLCYCLOHEXENE 100-40-3 <0.0005 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8%
CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10
MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN 30
MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO
AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH
APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT USE IN A CONFINED AREA WITH
MINIMAL AIR EXCHANGE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO
NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE
ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED
TO PREVENT CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED,
DO NOT RESEAL CONTAINER. PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE
AWAY FROM STRONG BASES. STORE AWAY FROM AREAS WHERE PRODUCT MAY COME INTO
CONTACT WITH FOOD OR PHARMACEUTICALS. STORE IN A DRY PLACE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
4-VINYLCYCLOHEXENE 100-40-3 ACGIH TWA: 0.1 PPM A3: CONFIRMED
ANIMAL CARCIN.
4-VINYLCYCLOHEXENE 100-40-3 AIHA TWA: 4.4 MG/M3
(1 PPM)
P,P'- 101-68-8 ACGIH TWA:0.005 PPM
METHYLENEBIS(PHENYL
ISOCYANATE)
P,P'- 101-68-8 OSHA CEIL: 0.2 MG/M3
METHYLENEBIS(PHENYL (0.02 PPM)
ISOCYANATE)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
FLUOROELASTOMER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: LIGHT STRAW COLORED LIQUID WITH PUNGENT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=300 DEG. F
FLASH POINT: >=300 DEG. F [TEST METHOD:CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.08 [REF STD:WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 700 - 900 CENTIPOISE
AVERAGE PARTICLE SIZE: NO DATA AVAILABLE
BULK DENSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
SOFTENING POINT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS: 10.5 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION MAY OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
STRONG BASES
ALCOHOLS
WATER
NO DATA AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
4-VINYLCYCLOHEXENE 100-40-3 GRP. 2B: POSSIBLE INTERNATIONAL AGENCY
HUMAN CARC. FOR RESEARCH ON CANCER
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
POLYETHER-HYDROCARBON- DERMAL LD50: ESTIMATED TO BE
URETHANE POLYMER >5,000 MG/KG
POLYETHER-HYDROCARBON- INGESTION LD50: ESTIMATED TO BE
URETHANE POLYMER 2,000 - 5,000 MG/KG
P,P'-METHYLENEBIS- DERMAL RABBIT LD50: >5,000 MG/KG
(PHENYL ISOCYANATE)
P,P'-METHYLENEBIS- INHALATION- RAT LC50: 0.368 MG/L
(PHENYL ISOCYANATE) DUST/MIST
(4 HOURS)
P,P'-METHYLENEBIS- INGESTION RAT LD50: 31,600 MG/KG
(PHENYL ISOCYANATE)
DIUNDECYL PHTHALATE DERMAL RABBIT LD50: >7,900 MG/KG
DIUNDECYL PHTHALATE INGESTION RAT LD50: >15,000 MG/KG
1,1'-METHYLENEBIS- DERMAL RABBIT LD50: >5,000 MG/KG
(ISOCYANATOBENZENE)
1,1'-METHYLENEBIS- INHALATION- RAT LC50: 0.368 MG/L
(ISOCYANATOBENZENE) DUST/MIST
(4 HOURS)
1,1'-METHYLENEBIS- INGESTION RAT LD50: 31,600 MG/KG
(ISOCYANATOBENZENE)
4-VINYLCYCLOHEXENE DERMAL LD50: ESTIMATED TO
BE >5,000 MG/KG
4-VINYLCYCLOHEXENE INGESTION RAT LD50: 6,300 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL IRRITANT
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL IRRITANT
CLASSIFICATION
4-VINYLCYCLOHEXENE RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
4-VINYLCYCLOHEXENE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SENSITIZING
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL SENSITIZING
CLASSIFICATION
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) HUMAN SENSITIZING
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
P,P'-METHYLENEBIS- IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
(PHENYL ISOCYANATE) NOT SUFFICIENT FOR CLASSIFICATION
1,1'-METHYLENEBIS- IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
(ISOCYANATOBENZENE) NOT SUFFICIENT FOR CLASSIFICATION
4-VINYLCYCLOHEXENE IN VITRO NOT MUTAGENIC
4-VINYLCYCLOHEXENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
P,P'-METHYLENEBIS- INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
(PHENYL ISOCYANATE) DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
1,1'-METHYLENEBIS- INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
(ISOCYANATOBENZENE) DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
4-VINYLCYCLOHEXENE INGESTION MOUSE CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES
P,P'-METHYLENEBIS- INHALATION NOT CLASSIFIED RAT
(PHENYLISOCYANATE) FOR DEVELOPMENT
1,1'-METHYLENEBIS- INHALATION NOT CLASSIFIED RAT
(ISOCYANATOBENZENE) FOR DEVELOPMENT
4-VINYLCYCLOHEXENE INGESTION NOT CLASSIFIED MOUSE
FOR MALE
REPRODUCTION
4-VINYLCYCLOHEXENE INGESTION TOXIC TO FEMALE MOUSE
REPRODUCTION
4-VINYLCYCLOHEXENE INHALATION TOXIC TO FEMALE MOUSE
REPRODUCTION
NAME TEST RESULT EXPOSURE DURATION
P,P'-METHYLENEBIS- NOAEL: 0.004 MG/L DURING ORGANOGENESIS
(PHENYLISOCYANATE)
1,1'-METHYLENEBIS- NOAEL: 0.004 MG/L DURING ORGANOGENESIS
(ISOCYANATOBENZENE)
4-VINYLCYCLOHEXENE NOAEL: 500 MG/KG/DAY 13 WEEKS
4-VINYLCYCLOHEXENE NOAEL: 600 MG/KG/DAY 13 WEEKS
4-VINYLCYCLOHEXENE NOAEL: 1.1 MG/L 13 WEEKS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
P,P'-METHYLENEBIS- INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(PHENYL ISOCYANATE) IRRITATION IRRITATION
1,1'-METHYLENEBIS- INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(ISOCYANATOBENZENE) IRRITATION IRRITATION
4-VINYLCYCLOHEXENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
P,P'-METHYLENEBIS- OFFICIAL NOAEL: NOT AVAILABLE
(PHENYL ISOCYANATE) CLASSIFICATION
1,1'-METHYLENEBIS- OFFICIAL NOAEL: NOT AVAILABLE
(ISOCYANATOBENZENE) CLASSIFICATION
4-VINYLCYCLOHEXENE SIMILAR NOAEL: NA
HEALTH
HAZARDS
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
P,P'-METHYLENEBIS- INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(PHENYL ISOCYANATE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
1,1'-METHYLENEBIS- INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(ISOCYANATOBENZENE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
4-VINYLCYCLOHEXENE INHALATION LIVER | KIDNEY NOT CLASSIFIED
AND/OR BLADDER
4-VINYLCYCLOHEXENE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
P,P'-METHYLENEBIS- RAT LOAEL: 0.004 MG/L 13 WEEKS
(PHENYL ISOCYANATE)
1,1'-METHYLENEBIS- RAT LOAEL: 0.004 MG/L 13 WEEKS
(ISOCYANATOBENZENE)
4-VINYLCYCLOHEXENE RAT NOAEL: 4.4 MG/L 13 WEEKS
4-VINYLCYCLOHEXENE RAT NOAEL: 800 MG/KG/DAY 13 WEEKS
ASPIRATION HAZARD:
NAME VALUE
4-VINYLCYCLOHEXENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 TRADE SECRET 25 - 35
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS
ARE DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE.
THESE RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL
UNDER EXPECTED CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE
IN EMERGENCY SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A
FULLY IMPLEMENTED HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE AMERICAN COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 29-4839-6
VERSION NUMBER: 5.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/04/18
REASON FOR REISSUE: CONVERSION TO GHS FORMAT SDS.
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
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REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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