| Common Name: | ETHYL ACETATE [FOR SPECTROPHOTOMETRY] |
| Manufacturer: | TCI AMERICA |
| SDS Revision Date: | 10/1/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 26WD36 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TCI
TCI AMERICA
SAFETY DATA SHEET
REVISION NUMBER: 1
REVISION DATE: 10/01/2018
| 1. IDENTIFICATION |  |
PRODUCT NAME: ETHYL ACETATE [FOR SPECTROPHOTOMETRY]
PRODUCT CODE: A0030
PRODUCT USE: FOR LABORATORY RESEARCH PURPOSES.
RESTRICTIONS ON USE: NOT FOR DRUG OR HOUSEHOLD USE.
COMPANY:
TCI AMERICA
9211 N. HARBORGATE STREET
PORTLAND, OR 97203
U.S.A.
TELEPHONE: +1-800-423-8616 / +1-503-283-1681
FAX: +1-888-520-1075 / +1-503-283-1987
E-MAIL: SALES-US@TCICHEMICALS.COM
WWW.TCICHEMICALS.COM
EMERGENCY TELEPHONE NUMBER:
CHEMICAL EMERGENCIES:
TCI AMERICA (8:00 AM - 5:00 PM) PST: +1-503-286-7624
TRANSPORTATION EMERGENCIES:
CHEMTREC 24-HOUR:
+1-800-424-9300 (U.S.A.)
+1-703-527-3887 (INTERNATIONAL)
RESPONSIBLE DEPARTMENT: TCI AMERICA
ENVIRONMENTAL HEALTH SAFETY AND SECURITY: +1- 503-286-7624
| 2. HAZARD(S) IDENTIFICATION | |
OSHA HAZ COM: CFR 1910.1200:
EYE DAMAGE/IRRITATION [CATEGORY 2B]
WHMIS 2015:
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [CATEGORY 1]
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [CATEGORY 3]
FLAMMABLE LIQUIDS [CATEGORY 2]
SIGNAL WORD: DANGER!
HAZARD STATEMENT(S):
HIGHLY FLAMMABLE LIQUID AND VAPOR
CAUSES EYE IRRITATION
CAUSES DAMAGE TO: RESPIRATORY SYSTEM
MAY CAUSE DROWSINESS OR DIZZINESS.
PICTOGRAM(S) OR SYMBOL(S):
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PRECAUTIONARY STATEMENT(S):
[PREVENTION]:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED. GROUND AND BOND CONTAINER AND RECEIVING
EQUIPMENT. USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. DO NOT BREATHE MIST, VAPORS OR SPRAY. USE ONLY OUTDOORS
OR IN A WELL-VENTILATED AREA. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH HANDS AND FACE THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE
GLOVES, EYE PROTECTION.
[RESPONSE]:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE OR ATTENTION.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR.
IN CASE OF FIRE: USE DRY CHEMICAL, DRY SAND OR FOAM TO EXTINGUISH.
[STORAGE]:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
[DISPOSAL]:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL REGULATIONS (E.G. US: 40 CFR PART 261, EU:91/156/EEC, JP: WASTE
DISPOSAL AND CLEANING ACT, ETC.).
HAZARDS NOT OTHERWISE CLASSIFIED [HNOC]: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: SUBSTANCE
COMPONENTS: ETHYL ACETATE [FOR SPECTROPHOTOMETRY]
PERCENT: >99.5%(GC)
CAS RN: 141-78-6
MOLECULAR WEIGHT: 88.11
CHEMICAL FORMULA: C4H8O2
SYNONYMS: ACETIC ACID ETHYL ESTER
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. GENTLY WASH WITH
PLENTY OF SOAP AND WATER. CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
INGESTION: CALL A POISON CENTER OR DOCTOR/PHYSICIAN. RINSE MOUTH.
SYMPTOMS/EFFECTS:
ACUTE: DIZZINESS. REDNESS. DROWSINESS.
DELAYED: NO DATA AVAILABLE
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION: NOT AVAILABLE.
NOTES TO PHYSICIAN: NO DATA AVAILABLE
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: WATER (IT MAY SCATTER AND SPREAD FIRE.)
HAZARDOUS COMBUSTION PRODUCTS:
THESE PRODUCTS INCLUDE: CARBON OXIDES
OTHER SPECIFIC HAZARDS: CLOSED CONTAINERS MAY EXPLODE FROM HEAT OF A FIRE.
ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS IF POSSIBLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE EXTRA PERSONAL PROTECTIVE EQUIPMENT (SELF-CONTAINED BREATHING
APPARATUS). KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. ENTRY TO NON-INVOLVED PERSONNEL SHOULD BE CONTROLLED AROUND
THE LEAKAGE AREA BY ROPING OFF, ETC.
ENVIRONMENTAL PRECAUTIONS: PREVENT PRODUCT FROM ENTERING DRAINS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ABSORB SPILLED MATERIAL IN DRY SAND OR INERT ABSORBENT BEFORE RECOVERING IT
INTO AN AIRTIGHT CONTAINER. IN CASE OF LARGE AMOUNT OF SPILLAGE, CONTAIN A
SPILL BY BUNDING. ADHERED OR COLLECTED MATERIAL SHOULD BE PROMPTLY DISPOSED
OF, IN ACCORDANCE WITH APPROPRIATE LAWS AND REGULATIONS.
PREVENTION OF SECONDARY HAZARDS:
REMOVE ALL SOURCES OF IGNITION. FIRE-EXTINGUISHING DEVICES SHOULD BE
PREPARED IN CASE OF A FIRE. USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF
EQUIPMENT.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING IS PERFORMED IN A WELL VENTILATED PLACE. WEAR SUITABLE PROTECTIVE
EQUIPMENT. PREVENT GENERATION OF VAPOR OR MIST. KEEP AWAY FROM
HEAT/SPARKS/OPEN FLAME/HOT SURFACES. -NO SMOKING. TAKE MEASURES TO PREVENT
THE BUILD UP OF ELECTROSTATIC CHARGE. USE EXPLOSION-PROOF EQUIPMENT. WASH
HANDS AND FACE THOROUGHLY AFTER HANDLING.
USE A CLOSED SYSTEM IF POSSIBLE. USE A VENTILATION, LOCAL EXHAUST IF VAPOR
OR AEROSOL WILL BE GENERATED. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DARK AND WELL-VENTILATED
PLACE.
STORE LOCKED UP.
STORE AWAY FROM INCOMPATIBLE MATERIALS SUCH AS OXIDIZING AGENTS.
PACKAGING MATERIAL: COMPLY WITH LAWS.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
ACGIH TLV(TWA): 400 PPM
OSHA PEL(TWA): 400 PPM
JSOH OELS(TWA): 200 PPM
APPROPRIATE ENGINEERING CONTROLS:
FOLLOW SAFE INDUSTRIAL ENGINEERING/LABORATORY PRACTICES WHEN HANDLING ANY
CHEMICAL. INSTALL A CLOSED SYSTEM OR LOCAL EXHAUST. ALSO INSTALL SAFETY
SHOWER AND EYE BATH.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
HALF OR FULL FACEPIECE RESPIRATOR, SELF-CONTAINED BREATHING
APPARATUS(SCBA), SUPPLIED AIR RESPIRATOR, ETC. USE RESPIRATORS APPROVED
UNDER APPROPRIATE GOVERNMENT STANDARDS AND FOLLOW LOCAL AND NATIONAL
REGULATIONS.
HAND PROTECTION: IMPERVIOUS GLOVES.
EYE PROTECTION: SAFETY GOGGLES. A FACE-SHIELD, IF THE SITUATION REQUIRES.
SKIN AND BODY PROTECTION:
IMPERVIOUS PROTECTIVE CLOTHING. PROTECTIVE BOOTS, IF THE SITUATION
REQUIRES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE (20 DEG. C): LIQUID
FORM: CLEAR
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/RANGE: 77 DEG. C (171 DEG. F)
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
RELATIVE DENSITY: 0.90
KINEMATIC VISCOSITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
FLASH POINT: -3 DEG. C (27 DEG. F)
FLAMMABILITY(SOLID, GAS): NO DATA AVAILABLE
PH: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE.
VAPOR DENSITY: 3.04
DYNAMIC VISCOSITY: NO DATA AVAILABLE
EVAPORATION RATE(BUTYL ACETATE=1): NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: 427 DEG. C (801 DEG. F)
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: 2.2%
UPPER: 11.5%
SOLUBILITY(IES):
[WATER]: SLIGHTLY SOLUBLE
[OTHER SOLVENTS]:
MISCIBLE: CHLOROFORM
SOLUBLE: ETHER, ALCOHOLS, BENZENE, ACETONE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER PROPER CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO SPECIAL REACTIVITY HAS BEEN REPORTED.
CONDITIONS TO AVOID: SPARK, OPEN FLAME, STATIC DISCHARGE
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS, ACIDS, BASES
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE
| 11. TOXICOLOGICAL INFORMATION | |
RTECS NUMBER: AH5425000
ACUTE TOXICITY:
IHL-RAT LC50: 200 G/M3
ORL-RAT LD50: 5620 MG/KG
ORL-MUS LD50: 4100 MG/KG
SKN-RBT LD50: >20 ML/KG
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION: EYE-HMN 400 PPM
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY:
CYT-HAM-FBR 9 G/L
SLN-SMC 24400 PPM
CARCINOGENICITY: NO DATA AVAILABLE
IARC: NO DATA AVAILABLE
NTP: NO DATA AVAILABLE
OSHA: NO DATA AVAILABLE
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TARGET ORGAN(S):
CAUSES DAMAGE TO: RESPIRATORY SYSTEM
MAY CAUSE DROWSINESS OR DIZZINESS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
FISH: NO DATA AVAILABLE
CRUSTACEA: NO DATA AVAILABLE
ALGAE: NO DATA AVAILABLE
PERSISTENCE / DEGRADABILITY:
66 - 112% (BY BOD) , 95% (BY TOC) , 100% (BY GC)
BIOACCUMULATIVE POTENTIAL(BCF): NO DATA AVAILABLE
MOBILITY IN SOIL:
LOG POW: 0.73
SOIL ADSORPTION (KOC): 59
HENRY'S LAW (PAM 3/MOL): 13.6
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF PRODUCT:
RECYCLE TO PROCESS IF POSSIBLE. IT IS THE GENERATOR'S RESPONSIBILITY TO
COMPLY WITH FEDERAL, STATE AND LOCAL RULES AND REGULATIONS. YOU MAY BE ABLE
TO DISSOLVE OR MIX MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER SYSTEM. THIS
SECTION IS INTENDED TO PROVIDE ASSISTANCE BUT DOES NOT REPLACE THESE LAWS,
NOR DOES COMPLIANCE IN ACCORDANCE WITH THIS SECTION ENSURE REGULATORY
COMPLIANCE ACCORDING TO THE LAW. US EPA GUIDELINES FOR IDENTIFICATION AND
LISTING OF HAZARDOUS WASTE ARE LISTED IN 40 CFR PARTS 261. THE PRODUCT
SHOULD NOT BE ALLOWED TO ENTER THE ENVIRONMENT, DRAINS, WATER WAYS, OR THE
SOIL.
DISPOSAL OF CONTAINER:
DISPOSE OF AS UNUSED PRODUCT. DO NOT RE-USE EMPTY CONTAINERS.
OTHER CONSIDERATIONS:
OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THE
SUBSTANCE.
| 14. TRANSPORT INFORMATION | |
DOT (US):
UN NUMBER: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
CLASS OR DIVISION: 3 FLAMMABLE LIQUID
PACKING GROUP: II
IATA:
UN NUMBER: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE, UNSTABILIZED
CLASS OR DIVISION: 3 FLAMMABLE LIQUID
PACKING GROUP: II
IMDG:
UN NUMBER: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
CLASS OR DIVISION: 3 FLAMMABLE LIQUID
PACKING GROUP: II
EMS NUMBER: F-E, S-D
REPORTABLE QUANTITY: 5000 POUNDS (2270 KILOGRAMS)
| 15. REGULATORY INFORMATION | |
TOXIC SUBSTANCE CONTROL ACT (TSCA 8B.):
THIS PRODUCT IS ON THE EPA TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
US FEDERAL REGULATIONS:
CERCLA HAZARDOUS SUBSTANCE AND REPORTABLE QUANTITY:
SARA 313: NOT LISTED
SARA 302: NOT LISTED
STATE REGULATIONS:
STATE RIGHT-TO-KNOW:
MASSACHUSETTS: LISTED
NEW JERSEY: LISTED
PENNSYLVANIA: LISTED
CALIFORNIA PROPOSITION 65: NOT LISTED
OTHER INFORMATION:
NFPA RATING:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 1
HMIS CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
PHYSICAL 1
INTERNATIONAL INVENTORIES:
CANADA:
DSL: ON DSL
EC-NO: 205-500-4
| 16. OTHER INFORMATION | |
REVISION DATE: 10/01/2018
REVISION NUMBER: 1
TCI CHEMICALS ARE FOR RESEARCH PURPOSES ONLY AND ARE NOT INTENDED FOR USE
AS DRUGS, FOOD ADDITIVES, HOUSEHOLDS, OR PESTICIDES. THE INFORMATION HEREIN
IS BELIEVED TO BE CORRECT, BUT DOES NOT CLAIM TO BE ALL INCLUSIVE AND
SHOULD BE USED ONLY AS A GUIDE. NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF
ITS AFFILIATES OR SUBSIDIARIES ASSUMES ANY LIABILITY WHATSOEVER FOR THE
ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN. FINAL
DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF
THE USER. ALL CHEMICAL REAGENTS MUST BE HANDLED WITH THE RECOGNITION THAT
THEIR CHEMICAL, PHYSIOLOGICAL, TOXICOLOGICAL, AND HAZARDOUS PROPERTIES HAVE
NOT BEEN FULLY INVESTIGATED OR DETERMINED. ALL CHEMICAL REAGENTS SHOULD BE
HANDLED ONLY BY INDIVIDUALS WHO ARE FAMILIAR WITH THEIR POTENTIAL HAZARDS
AND WHO HAVE BEEN FULLY TRAINED IN PROPER SAFETY, LABORATORY, AND CHEMICAL
HANDLING PROCEDURES. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN, WE CAN
NOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS WHICH EXIST. OUR SDS ARE
BASED ONLY ON DATA AVAILABLE AT THE TIME OF SHIPPING AND ARE SUBJECT TO
CHANGE WITHOUT NOTICE AS NEW INFORMATION IS OBTAINED. AVOID LONG STORAGE
PERIODS SINCE THE PRODUCT IS SUBJECT TO DEGRADATION WITH AGE AND MAY BECOME
MORE DANGEROUS OR HAZARDOUS. IT IS THE RESPONSIBILITY OF THE USER TO
REQUEST UPDATED SDS FOR PRODUCTS THAT ARE STORED FOR EXTENDED PERIODS.
DISPOSAL OF UNUSED PRODUCT MUST BE UNDERTAKEN BY QUALIFIED PERSONNEL WHO
ARE KNOWLEDGEABLE IN ALL APPLICABLE REGULATIONS AND FOLLOW ALL PERTINENT
SAFETY PRECAUTIONS INCLUDING THE USE OF APPROPRIATE PROTECTIVE EQUIPMENT
(E.G. PROTECTIVE GOGGLES, PROTECTIVE CLOTHING, BREATHING EQUIPMENT, FACE
MASK, FUME HOOD). FOR PROPER HANDLING AND DISPOSAL, ALWAYS COMPLY WITH
FEDERAL, STATE AND LOCAL REGULATIONS.