| Common Name: | LOCTITE 7900 CERAMISHIELD KNOWN AS LOCTITE SF 7900 CERAMIC SHIELD, 1616692 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/3/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 29FX35 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 05/03/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE 7900 CERAMISHIELD KNOWN AS LOCTITE SF 7900 CERAMIC SHIELD
PRODUCT TYPE: LUBRICANT
IDH NUMBER: 1616692
ITEM NUMBER: 1616692
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTENTS UNDER PRESSURE.
EXTREMELY FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE AEROSOL. 1
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - 3
SINGLE EXPOSURE
PICTOGRAM(S):
FLAME
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN,
EVEN AFTER USE. AVOID BREATHING MIST OR SPRAY. WASH AFFECTED AREA
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
PROPANE/ISOBUTANE 68476-86-8 40 - 50
ACETONE 67-64-1 20 - 30
METHYL ETHYL KETONE 78-93-3 10 - 20
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
DANGEROUS WHEN EXPOSED TO HEAT OR FLAME. THIS MATERIAL CAN BE IGNITED BY
FLAME OR SPARK UNDER ALL NORMAL ATMOSPHERIC CONDITIONS. VAPORS ARE HEAVIER
THAN AIR AND MAY TRAVEL TO IGNITION SOURCES AND FLASH BACK. CLOSED
CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS. TOXIC AND IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. REFER TO SECTION 8 "EXPOSURE
CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
FOR INDUSTRIAL USE ONLY. USE ONLY WITH ADEQUATE VENTILATION. PREVENT
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH
THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE. DO NOT STORE WITH
OXIDIZING MATERIALS.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS ACGIH TLV OSHA PEL AIHA OTHER
COMPONENT(S) WEEL
PROPANE/ISOBUTANE NONE NONE NONE NONE
ACETONE 250 PPM TWA 1,000 PPM NONE NONE
500 PPM STEL (2,400 MG/M3)
PEL
METHYL ETHYL 200 PPM TWA 200 PPM NONE NONE
KETONE 300 PPM STEL (590 MG/M3)
PEL
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED
ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: WHITE
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: 6 - 8
VAPOR PRESSURE: 231 MM Hg
BOILING POINT/RANGE: 56 DEG. C (132.8 DEG. F)
MELTING POINT/RANGE: -95 DEG. C (-139 DEG. F)
SPECIFIC GRAVITY: 1.2
VAPOR DENSITY: 2.0
FLASH POINT: -20 DEG. C (-4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 2.2%
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 13%
AUTOIGNITION TEMPERATURE: 465 DEG. C (869 DEG. F)
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: 14.4
SOLUBILITY IN WATER: SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 778 G/L (CALCULATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS. IRRITATING ORGANIC VAPORS.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
HIGH TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS WITH NAUSEA, DIZZINESS AND HEADACHE.
SKIN CONTACT:
CAUSES SKIN IRRITATION. PROLONGED OR REPEATED CONTACT WITH THIS PRODUCT MAY
DRY AND/OR DEFAT THE SKIN.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED. MAY CAUSE
DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
HAZARDOUS LD50S AND LC50S IMMEDIATE AND DELAYED
COMPONENT(S) HEALTH EFFECTS
PROPANE/ISOBUTANE NONE NO RECORDS
ACETONE ORAL LD50 (MOUSE): CENTRAL NERVOUS
5.2 G/KG SYSTEM, IRRITANT
ORAL LD50 (MOUSE):
3,000 MG/KG
ORAL LD50 (RABBIT):
5,340 MG/KG
ORAL LD50 (RAT):
5,800 MG/KG
ORAL LD50 (RAT):
9,800 MG/KG
DERMAL LD50
(RABBIT):
20,000 MG/KG
INHALATION LC50
(RAT, 4 H): 76 MG/L
METHYL ETHYL ORAL LD50 (MOUSE): IRRITANT, CENTRAL
KETONE 670 MG/KG NERVOUS SYSTEM
ORAL LD50 (RAT):
2,300 - 3,500 MG/KG
ORAL LD50 (RAT):
4,500 - 6,800 MG/KG
DERMAL LD50 (RABBIT):
>8,000 MG/KG
INHALATION LC50
(RAT, 4 H): 11700 PPM
HAZARDOUS NTP IARC OSHA CARCINOGEN
COMPONENT(S) CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
PROPANE/ISOBUTANE NO NO NO
ACETONE NO NO NO
METHYL ETHYL NO NO NO
KETONE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
D001: IGNITABLE.
D035: METHYL ETHYL KETONE.
THIS PRODUCT MAY CONTAIN TRACES OF:
D018: BENZENE (CHECK TCLP LEVEL).
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
DOT HAZARDOUS SUBSTANCE(S): ACETONE, METHYL ETHYL KETONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312:
IMMEDIATE HEALTH, DELAYED HEALTH, FIRE, SUDDEN RELEASE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). METHYL ETHYL KETONE (CAS#
78-93-3).
CERCLA REPORTABLE QUANTITY:
ACETONE (CAS# 67-64-1) 5,000 LBS. (2,270 KG)
METHYL ETHYL KETONE (CAS# 78-93-3) 5,000 LBS. (2,270 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CARA R. RIVERA, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 05/03/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.