| Common Name: | LANDAU TOP & TRIM ADHESIVE |
| Manufacturer: | DAP |
| SDS Revision Date: | 6/19/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 29RU98, 29RU99, 29RV01 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00030519001
REVISION DATE: 6/19/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS:
MEDICAL/POISON CONTROL:
IN U.S.:
CALL: 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSE CENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE EVENT
OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT. THIS
PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND THIS
DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER DESCRIBED
IN SECTION 16.
| 1. IDENTIFICATION |  |
THIS SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON REQUEST.
PRODUCT NAME: LANDAU TOP & TRIM ADHESIVE
PRODUCT UPC NUMBER: 00233, 00234, 00235, 00237
PRODUCT USE/CLASS: CONTACT ADHESIVE
REVISION DATE: 6/19/2015
SUPERCEDES DATE: NEW SDS
SDS NO: 00030519001
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET
SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR
EXPLOSION. VAPORS CAN FORM AN IGNITABLE MIXTURE WITH AIR. VAPORS CAN
FLOW ALONG SURFACES TO A DISTANT IGNITION SOURCE AND FLASH BACK. DO NOT
SMOKE. EXTINGUISH ALL FLAMES AND PILOT LIGHTS, AND TURN OFF STOVES,
HEATERS, ELECTRIC MOTORS AND OTHER SOURCES OF IGNITION DURING USE AND
UNTIL ALL VAPORS ARE GONE. KEEP CONTAINER CLOSED AND AWAY FROM HEAT,
SPARKS, AND OPEN FLAME. STORE AWAY FROM CAUSTICS AND OXIDIZERS. AVOID
BREATHING VAPOR. AVOID SKIN AND EYE CONTACT. USE ONLY WITH ADEQUATE
VENTILATION. PREVENT BUILD-UP OF VAPORS BY OPENING ALL WINDOWS AND DOORS
TO ACHIEVE CROSS-VENTILATION. IRRITATING TO EYES, RESPIRATORY SYSTEM AND
SKIN. HARMFUL OR FATAL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED - CAN
ENTER LUNGS AND CAUSE DAMAGE. MAY AFFECT THE BRAIN OR NERVOUS SYSTEM
CAUSING DIZZINESS, HEADACHE OR NAUSEA.
GHS CLASSIFICATION:
EYE IRRIT. 2, FLAM. LIQ. 2, SKIN IRRIT. 2, STOT RE 2, STOT SE 3 NE
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT, REPEATED EXPOSURE, CATEGORY 2:
H373:
MAY CAUSE DAMAGE TO ORGANS <OR STATE ALL ORGANS AFFECTED, IF KNOWN>
THROUGH PROLONGED OR REPEATED EXPOSURE <STATE ROUTE OF EXPOSURE IF IT IS
CONCLUSIVELY PROVEN THAT NO OTHER ROUTES OF EXPOSURE CAUSE THE HAZARD>.
GHS LABEL PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/.../EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. % GHS SYMBOLS GHS STATEMENTS
ACETONE 67-64-1 10-25 GHS02-GHS03- H225-270-319-336
GHS07
TOLUENE 108-88-3 10-25 GHS02-GHS03- H225-270-302-
GHS07-GHS08 304-315-332-335-
336-373
N-HEXANE 110-54-3 10-25 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336-373
2-METHYLPENTANE 107-83-5 2.5-10 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336
3-METHYLPENTANE 96-14-0 2.5-10 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336
METHYLCYCLOPENTANE 96-37-7 2.5-10 GHS03-GHS08 H270-304
ISOHEPTANE 591-76-4 1.0-2.5 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336
2,3-DIMETHYLBUTANE 79-29-8 1.0-2.5 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336
MAGNESIUM OXIDE FUME 1309-48-4 1.0-2.5 GHS03 H270
2,4-DIMETHYLPENTANE 108-08-7 1.0-2.5 GHS02-GHS03- H225-270-304-
GHS07-GHS08 315-336
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION
IMMEDIATELY.
NOTE:
ONLY TRAINED PERSONNEL SHOULD ADMINISTER ARTIFICIAL RESPIRATION OR GIVE
OXYGEN.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST. REMOVE AND WASH CONTAMINATED CLOTHING. DO NOT TRY TO PEEL THE
SOLIDIFIED MATERIAL FROM THE SKIN OR USE SOLVENTS OR THINNERS TO DISSOLVE
IT. THE USE OF VEGETABLE OIL OR MINERAL OIL IS RECOMMENDED FOR REMOVAL OF
THIS MATERIAL FROM THE SKIN. FLUSH EXPOSED AREA WITH WATER WHILE REMOVING
CONTAMINATED CLOTHING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. TO
REMOVE FROM SKIN, REMOVE COMPLETELY WITH A DRY CLOTH OR PAPER TOWEL,
BEFORE WASHING WITH DETERGENT AND WATER.
FIRST AID - EYE CONTACT:
IF MATERIAL GETS INTO EYES, FLUSH WITH WATER IMMEDIATELY FOR 15 MINUTES.
CONSULT A PHYSICIAN.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS:
ELIMINATE SOURCES OF IGNITION:
HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAMES. VAPORS CAN FORM AN IGNITABLE
MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO A DISTANT IGNITION
SOURCE AND FLASH BACK. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (LIQUID AND/OR VAPOR). VAPOR CAN IGNITE POTENTIALLY CAUSING
AN EXPLOSION.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES. COOL FIRE-EXPOSED CONTAINERS USING WATER SPRAY.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
NOTE:
REVIEW FIRE HAZARDS BEFORE PROCEEDING WITH CLEAN UP. IMMEDIATELY ELIMINATE
SOURCES OF IGNITION. KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK.
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. PREVENT PRODUCT FROM ENTERING DRAINS. SOAK UP WITH INERT
ABSORBENT MATERIAL AND DISPOSE OF AS HAZARDOUS WASTE. READ ALL PRODUCT
INSTRUCTIONS BEFORE USING. PERSONAL PROTECTIVE EQUIPMENT SHOULD INCLUDE
IMPERVIOUS GLOVES, PROTECTIVE EYE WEAR, AND SUITABLE WORK CLOTHES.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. REMOVE ALL SOURCES OF IGNITION. MAKE SURE NOZZLE IS
DIRECTED AWAY FROM YOURSELF PRIOR TO DISCHARGE. KEEP AWAY FROM OPEN FLAMES,
HOT SURFACES AND SOURCES OF IGNITION. PROVIDE ADEQUATE VENTILATION. AVOID
HEAT, SPARKS AND OPEN FLAMES. WEAR APPROPRIATE PERSONAL PROTECTION. USE IN
WELL VENTILATED AREA. OPEN ALL WINDOWS AND DOORS OR USE OTHER MEANS TO
ENSURE CROSS-VENTILATION AND FRESH AIR ENTRY DURING APPLICATION AND DRYING.
ODOR IS NOT AN ADEQUATE WARNING FOR HAZARDOUS CONDITIONS. AVOID CONTACT
WITH EYES, SKIN AND CLOTHING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE
(LIQUID AND/OR VAPOR). VAPOR CAN IGNITE POTENTIALLY CAUSING AN EXPLOSION.
WASH THOROUGHLY AFTER HANDLING. DO NOT USE IN AREAS WHERE STATIC SPARKS MAY
BE GENERATED. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING
VAPORS MAY BE HARMFUL OR FATAL. CONSTRUCTION AND REPAIR ACTIVITIES CAN
ADVERSELY AFFECT INDOOR AIR QUALITY. CONSULT WITH OCCUPANTS OR A
REPRESENTATIVE (I.E. MAINTENANCE, BUILDING MANAGER, INDUSTRIAL HYGIENIST,
OR SAFETY OFFICER) TO DETERMINE WAYS TO MINIMIZE IMPACT.
STORAGE:
STORE AWAY FROM SOURCES OF IGNITION AND HEAT. PROTECT MATERIAL FROM DIRECT
SUNLIGHT. DO NOT STORE AT TEMPERATURES ABOVE 120 DEGREES F. STORE
CONTAINERS AWAY FROM EXCESSIVE HEAT AND FREEZING. STORE AWAY FROM CAUSTICS
AND OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH ACGIH-TLV OSHA OSHA
TLV-TWA STEL PEL-TWA PEL-CEILING
ACETONE 500 PPM TWA 750 PPM STEL 1000 PPM N.E.
TWA,
2400 MG/M3
TWA
TOLUENE 20 PPM TWA N.E. 200 PPM TWA 300 PPM
CEILING
N-HEXANE 50 PPM TWA N.E. 500 PPM TWA, N.E.
1800 MG/M3
TWA
2-METHYLPENTANE N.E. N.E. N.E. N.E.
3-METHYLPENTANE N.E. N.E. N.E. N.E.
METHYLCYCLOPENTANE N.E. N.E. N.E. N.E.
ISOHEPTANE 400 PPM TWA 500 PPM STEL N.E. N.E.
HEPTANE, ALL HEPTANE, ALL
ISOMERS ISOMERS
2,3-DIMETHYLBUTANE N.E. N.E. N.E. N.E.
MAGNESIUM OXIDE FUME 10 MG/M3 TWA N.E. 15 MG/M3 TWA N.E.
INHALABLE FUME, TOTAL
FRACTION PARTICULATE
2,4-DIMETHYLPENTANE 400 PPM TWA 500 PPM STEL N.E. N.E.
HEPTANE, ALL HEPTANE, ALL
ISOMERS ISOMERS
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
A NIOSH-APPROVED AIR PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
OR CANISTER B# MAY BE NECESSARY UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. IF CONCENTRATIONS
EXCEED THE EXPOSURE LIMITS SPECIFIED, USE OF A NIOSH-APPROVED SUPPLIED AIR
RESPIRATOR IS RECOMMENDED. WHERE THE PROTECTION FACTOR IS EXCEEDED, USE OF
A SELF CONTAINED BREATHING APPARATUS (SCBA) MAY BE NECESSARY. IF YOU
EXPERIENCE EYE WATERING, HEADACHE OR DIZZINESS OR IF AIR MONITORING
DEMONSTRATES VAPOR/MIST LEVELS ARE ABOVE APPLICABLE LIMITS, WEAR AND
APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH APPROVED) DURING AND AFTER
APPLICATION. A RESPIRATORY PROTECTION PROGRAM THAT MEETS THE OSHA 1910.134
AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE.
SKIN PROTECTION: SOLVENT-RESISTANT GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT:
PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF BODY CONTACT MAY OCCUR.
HYGIENIC PRACTICES: REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: TAN
PHYSICAL STATE: LIQUID
ODOR: STRONG SOLVENT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 0.80 - 0.80
PH: NOT ESTABLISHED
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: 54.4 - 60
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: -45.5
VAPOR PRESSURE, MMHg: NO INFORMATION
EVAPORATION RATE: FASTER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
FLAMMABILITY: NO INFORMATION
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. KEEP
AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE AND STRONGLY ACID MATERIALS
IN ORDER TO AVOID EXOTHERMIC REACTIONS. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT SMOKE.
INCOMPATIBILITY:
OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. KEEP AWAY FROM STRONG
OXIDIZING AGENTS, HEAT AND OPEN FLAMES. EXOTHERMIC REACTION WITH STRONG
ACIDS. STRONG BASES.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
INHALATION OF VAPORS MAY CAUSE IRRITATION OF THE NOSE, THROAT, LUNGS AND
RESPIRATORY TRACT. INHALATION OF VAPORS IN HIGH CONCENTRATION MAY CAUSE
SHORTNESS OF BREATH (LUNG EDEMA). INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. PROLONGED,
REPEATED OR HIGH EXPOSURES MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION
LEADING TO HEADACHES, NAUSEA, DROWSINESS, DIZZINESS, AND POSSIBLY
NARCOSIS. IN EXTREME CASES, MAY CAUSE LOSS OF CONSCIOUSNESS.
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
HARMFUL IF ABSORBED THROUGH THE SKIN. MAY CAUSE SKIN IRRITATION. PROLONGED
AND REPEATED SKIN CONTACT MAY CAUSE DERMATITIS, DRYING AND DEFATTING DUE TO
THE SOLVENT PROPERTIES.
EFFECT OF OVEREXPOSURE - EYE CONTACT: MAY CAUSE EYE IRRITATION.
SIGNS AND SYMPTOMS MAY INCLUDE:
PAIN, TEARS, SWELLING, REDNESS AND BLURRED VISION.
EFFECT OF OVEREXPOSURE - INGESTION:
HARMFUL OR FATAL IF SWALLOWED. INGESTION MAY CAUSE GASTROINTESTINAL
IRRITATION, NAUSEA, VOMITING AND DIARRHEA. MAY CAUSE GASTROINTESTINAL
DISTURBANCES WITH DIZZINESS AND CENTRAL NERVOUS SYSTEM DEPRESSION. IF
INGESTED, MAY CAUSE DEPRESSED RESPIRATION. ASPIRATION HAZARD IF SWALLOWED.
ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL
PNEUMONITIS, WHICH CAN BE FATAL.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED OR PROLONGED EXPOSURE MAY CAUSE IRREGULAR HEARTBEAT AND HEART
FAILURE AS WELL AS RESPIRATORY SYSTEM, KIDNEY, CARDIOVASCULAR AND LIVER
DAMAGE. MAY CAUSE KIDNEY AND LIVER DAMAGE AS WELL AS DEVELOPMENTAL AND
REPRODUCTIVE TOXICITY.
NOTICE:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
SYMPTOMS INCLUDE:
LOSS OF MEMORY, LOSS OF INTELLECTUAL ABILITY AND LOSS OF COORDINATION.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
MAY BE HARMFUL OR FATAL. OVEREXPOSURE OR MISUSE OF TOLUENE CAN CAUSE LIVER,
KIDNEY, AND BRAIN DAMAGE AS WELL AS CARDIAC ABNORMALITIES. THERE HAVE BEEN
CASES OF APLASTIC ANEMIA FROM TOLUENE IN INDUSTRIAL EXPOSURES
(ACGIH, 1992). INCREASED COAGULATION TIME AND REDUCED CLOTTING FACTORS
HAVE ALSO BEEN FOUND, WHICH ARE INDICATORS OF DAMAGE TO THE BONE MARROW
(CLAYTON & CLAYTON, 1994). N-HEXANE EXPOSURE CAN CAUSE NERVE DAMAGE TO
ARMS AND LEGS CAUSING NUMBNESS OF THE FINGERS AND TOES, EFFECT MAY BE
PERMANENT.
SYMPTOMS INCLUDE:
LOSS OF MEMORY, LOSS OF INTELLECTUAL ABILITY AND LOSS OF COORDINATION.
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
67-64-1 ACETONE 5250 MG/KG >15688 MG/KG 50 MG/L RAT
MOUSE RABBIT
108-88-3 TOLUENE 636 MG/KG RAT 8390 MG/KG 12.5 MG/L
RABBIT RAT
110-54-3 N-HEXANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
107-83-5 2-METHYLPENTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
96-14-0 3-METHYLPENTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
96-37-7 METHYLCYCLOPENTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
591-76-4 ISOHEPTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
79-29-8 2,3-DIMETHYLBUTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
1309-48-4 MAGNESIUM OXIDE >2000 MG/KG >2000 MG/KG >20 MG/L
FUME
108-08-7 2,4-DIMETHYLPENTANE 28710 MG/KG 3000 MG/KG >31.86 MG/L
RAT RABBIT RAT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
RESIDUES AND SPILLED MATERIAL ARE HAZARDOUS WASTE DUE TO IGNITABILITY.
DISPOSE OF MATERIAL IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE COMPLEX AND MAY
DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER WASTE DISPOSAL
IS WITH THE OWNER OF THE WASTE. DO NOT FLUSH INTO SURFACE WATER OR SANITARY
SEWER SYSTEM. DO NOT EMPTY INTO DRAINS. DO NOT BURN OR USE A CUTTING TORCH
ON THE EMPTY CONTAINER. DO NOT RE-USE EMPTY CONTAINERS. THE CONTAINER FOR
THIS PRODUCT CAN PRESENT EXPLOSION OR FIRE HAZARDS, EVEN WHEN EMPTIED. TO
AVOID RISK OF INJURY, DO NOT CUT, PUNCTURE, OR WELD ON OR NEAR THIS
CONTAINER.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: UN1133
DOT PROPER SHIPPING NAME: ADHESIVES, CONTAINING A FLAMMABLE LIQUID
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: 3
HAZARD SUBCLASS: N.A.
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA-SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
TOLUENE 108-88-3
N-HEXANE 110-54-3
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPRODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65: NO INFORMATION
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS: CLASS NO INFORMATION
| 16. OTHER INFORMATION | |
REVISION DATE: 6/19/2015
SUPERSEDES DATE: NEW MSDS
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 619.4
VOC MATERIAL, G/L: 498
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 62.2
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H302: HARMFUL IF SWALLOWED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS03: FLAME OVER CIRCLE
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THIS DOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.