| Common Name: | SILICONE PLUS PREMIUM KITCHEN & BATH SEALANT WHITE |
| Manufacturer: | DAP |
| SDS Revision Date: | 7/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 29RV14 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00008770004
REVISION DATE: 7/28/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS:
MEDICAL/POISON CONTROL:
IN U.S.:
CALL: 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSECENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE
EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE
OR ACCIDENT INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT.
THIS PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD
AND THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS
OF THIS STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER
DESCRIBED IN SECTION 16.
| 1. IDENTIFICATION |  |
THIS MATERIAL SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON
REQUEST.
PRODUCT NAME: SILICONE PLUS PREMIUM KITCHEN & BATH SEALANT WHITE
PRODUCT UPC NUMBER: 070798087705
PRODUCT USE/CLASS: CAULKING COMPOUND
REVISION DATE: 7/28/2015
SUPERCEDES DATE: 9/27/2011
SDS NO: 00008770004
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET
SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
HIGH CONCENTRATION OF VAPORS MAY CAUSE IRRITATION TO EYES AND RESPIRATORY
SYSTEM.
GHS CLASSIFICATION: SKIN SENS. 1, STOT RE 2
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: WARNING
GHS HAZARD STATEMENTS:
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT, REPEATED EXPOSURE, CATEGORY 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
GHS LABEL PRECAUTIONARY STATEMENTS:
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. %
SILICA, AMORPHOUS 7631-86-9 2.5-10
METHYLTRI(ETHYLMETHYLKETOXIME)SILANE 22984-54-9 2.5-10
TITANIUM DIOXIDE 13463-67-7 0.1-1.0
METHYL ETHYL KETOXIME 96-29-7 0.1-1.0
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
SILICA, AMORPHOUS GHS03-GHS07 H270-332
METHYLTRI GHS03-GHS07-GHS08 H270-317-319-373
(ETHYLMETHYLKETOXIME)
SILANE
TITANIUM DIOXIDE NO INFORMATION NO INFORMATION
METHYL ETHYL KETOXIME GHS03-GHS05-GHS06-GHS08 H270-317-318-331-351
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
MATERIAL IS NOT LIKELY TO PRESENT AN INHALATION HAZARD AT AMBIENT
CONDITIONS. IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE
AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED,
GET MEDICAL ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF
SYMPTOMS PERSIST.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF
WATER FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL
ATTENTION IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE KNOWN.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED
OR EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED
MATERIAL AND PLACE INTO CONTAINERS. USE PERSONAL PROTECTIVE EQUIPMENT
AS NECESSARY. IN CASE OF SPILLAGE, ABSORB WITH INERT MATERIAL AND
DISPOSE OF IN ACCORDANCE WITH APPLICABLE REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. AVOID BREATHING VAPOR AND CONTACT WITH EYES, SKIN
AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTACT LENSES BEFORE USING. DO NOT HANDLE CONTACT
LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM FINGERTIPS, NAILS AND
CUTICLES. RESIDUAL SEALANT MAY TRANSFER TO CONTACT LENSES AND CAUSE
SEVERE EYE IRRITATION.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE
120 DEGREES F. STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV- ACGIH-TLV OSHA PEL- OSHA PEL-
TWA STEL TWA CEILING
SILICA, AMORPHOUS N.E. N.E. N.E. N.E.
METHYLTRI N.E. N.E. N.E. N.E.
(ETHYLMETHYLKETOXIME)
SILANE
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
TWA TWA TOTAL
DUST
METHYL ETHYL KETOXIME N.E. N.E. N.E. N.E.
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
SKIN PROTECTION: WEAR NITRILE OR NEOPRENE GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL USE.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: WHITE
PHYSICAL STATE: PASTE
ODOR: SLIGHT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 1.04 - 1.04
PH: NOT ESTABLISHED
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: N.I. - N.I.
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 93.3
VAPOR PRESSURE, MMHg: NO INFORMATION
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY:
THIS PRODUCT IS CONSIDERED STABLE UNDER NORMAL AND ANTICIPATED STORAGE AND
HANDLING CONDITIONS.
CONDITIONS TO AVOID: OXIDIZING AGENTS. EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY:
KEEP AWAY FROM STRONG OXIDIZING AGENTS. INCOMPATIBLE WITH STRONG BASES AND
OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
DURING APPLICATION AND CURE, THIS PRODUCT RELEASES METHANOL. INHALATION
MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT (NOSE, MOUTH, MUCOUS
MEMBRANES). MAY CAUSE ALLERGIC RESPIRATORY REACTION.
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
DIRECT SKIN CONTACT MAY CAUSE IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION.
EFFECT OF OVEREXPOSURE - EYE CONTACT: MAY CAUSE MILD EYE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
SINGLE DOSE ORAL TOXICITY IS VERY LOW. AMOUNTS INGESTED INCIDENTAL TO
INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION
OF LARGE AMOUNTS MAY CAUSE INJURY. INGESTION OF LARGE AMOUNTS MAY CAUSE
NAUSEA, GASTROINTESTINAL UPSET, AND PAIN. MAY CAUSE LIVER AND KIDNEY
DAMAGE, AND CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION MAY RESULT IN
OBSTRUCTION WHEN MATERIAL HARDENS.
CARCINOGENICITY: NO INFORMATION
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
7631-86-9 SILICA, AMORPHOUS >3300 MG/KG >5000 >20 MG/L
RAT MG/KG RABBIT
22984-54-9 METHYLTRI >2520 MG/KG >2000 MG/KG >50 MG/L
(ETHYLMETHYLKETOXIME) RAT RAT RAT
SILANE
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
96-29-7 METHYL ETHYL KETOXIME 2326 MG/KG 2702 MG/KG >4.83 MG/L
RAT RABBIT RAT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING
TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261.
DISPOSE AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE
COMPLEX AND MAY DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR
PROPER WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE. DO NOT FLUSH
INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPORODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: CONSUMER COMMODITY
| 16. OTHER INFORMATION | |
REVISION DATE: 7/28/2015
SUPERSEDES DATE: 9/27/2011
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 31.0
VOC MATERIAL, G/L: 31
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 3.0
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H331: TOXIC IF INHALED.
H332: HARMFUL IF INHALED.
H351:
SUSPECTED OF CAUSING CANCER. CLASSIFIED AS CATEGORY 2 BASED ON LIMITED
EVIDENCE ON HUMAN AND/OR ANIMAL STUDIES. MIXTURES WITH CONCENTRATIONS
OF SUSPECTED CARCINOGENS INGREDIENTS AT CONCENTRATION PRESENT BETWEEN
0.1% AND 1.0% LABELLING THE SDS WILL BE OPTIONAL DEPENDING ON AUTHORITIES.
IF CATEGORY 2 CARCINOGENIC PRESENT AT A CONCENTRATION OF 1% OR ABOVE
LABELLING THE SDS WILL BE EXPECTED. ROUTES OF EXPOSURE ARE DEPENDANT ON
INGREDIENT FORM.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS03: FLAME OVER CIRCLE
GHS05: CORROSION
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THISDOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.