| Common Name: | 3.0 KITCHEN, BATH & PLUMBING SEALANT - CRYSTAL CLEAR |
| Manufacturer: | DAP |
| SDS Revision Date: | 6/19/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 29RV15 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00010079001
REVISION DATE: 6/19/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS:
MEDICAL/POISON CONTROL:
IN U.S.:
CALL: 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSECENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE
EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE
OR ACCIDENT INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT.
THIS PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER DESCRIBED
IN SECTION 16.
| 1. IDENTIFICATION |  |
THIS MATERIAL SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH
UPON REQUEST.
PRODUCT NAME: 3.0 KITCHEN, BATH & PLUMBING SEALANT - CRYSTAL CLEAR
PRODUCT UPC NUMBER: 00795
PRODUCT USE/CLASS: CAULKING COMPOUND
REVISION DATE: 6/19/2015
SUPERCEDES DATE: 6/25/2012
SDS NO: 00010079001
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET
SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. HIGH CONCENTRATION OF VAPORS MAY CAUSE IRRITATION TO EYES
AND RESPIRATORY SYSTEM.
GHS CLASSIFICATION: EYE IRRIT. 2, SKIN IRRIT. 2
SYMBOL(S) OF PRODUCT: EXCLAMATION MARK
SIGNAL WORD: WARNING
GHS HAZARD STATEMENTS:
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. %
PROPRIETARY PHTHALATE ESTERS PROPRIETARY 25-50
CYCLOTETRASILOXANE, OCTAMETHYL-, 68583-49-3 2.5-10
REACTION PRODS. WITH SILICA
3-(TRIMETHOXYSILYL)PROPYLAMINE 13822-56-5 1.0-2.5
ORGANOSILANE ESTER 2768-02-7 1.0-2.5
PROPRIETARY PHTHALATE ESTERS PROPRIETARY 1.0-2.5
SILICA, AMORPHOUS 7631-86-9 1.0-2.5
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
PROPRIETARY PHTHALATE ESTERS GHS03-GHS07 H270-332
CYCLOTETRASILOXANE, OCTAMETHYL-, GHS03-GHS07 H270-315-319-335
REACTION PRODS. WITH SILICA
3-(TRIMETHOXYSILYL)PROPYLAMINE GHS03-GHS07 H270-315-319
ORGANOSILANE ESTER GHS03-GHS07 H270-332
PROPRIETARY PHTHALATE ESTERS GHS03-GHS06 H270-331
SILICA, AMORPHOUS GHS03-GHS07 H270-332
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
MATERIAL IS NOT LIKELY TO PRESENT AN INHALATION HAZARD AT AMBIENT
CONDITIONS. IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO
OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL
ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE KNOWN.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED
OR EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. IN CASE
OF SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN ACCORDANCE WITH
APPLICABLE REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. AVOID BREATHING VAPOR AND CONTACT WITH EYES, SKIN
AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. ENSURE FRESH AIR ENTRY
DURING APPLICATION AND DRYING. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH ACGIH-TLV OSHA OSHA PEL-
TLV-TWA STEL PEL-TWA CEILING
PROPRIETARY PHTHALATE ESTERS N.E. N.E. N.E. N.E.
CYCLOTETRASILOXANE, OCTAMETHYL-, N.E. N.E. N.E. N.E.
REACTION PRODS. WITH SILICA
3-(TRIMETHOXYSILYL)PROPYLAMINE N.E. N.E. N.E. N.E.
ORGANOSILANE ESTER N.E. N.E. N.E. N.E.
PROPRIETARY PHTHALATE ESTERS N.E. N.E. N.E. N.E.
SILICA, AMORPHOUS N.E. N.E. N.E. N.E.
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
SKIN PROTECTION:
WEAR NITRILE OR NEOPRENE GLOVES. NATURAL RUBBER, BUTYL RUBBER AND
POLYVINYL CHLORIDE GLOVES ARE NOT SUITABLE PROTECTION AGAINST
PHTHALATES SUCH AS DIISODECYL PHTHALATE AND DIISONONYL PHTHALATE;
NEOPRENE IS RECOMMENDED.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL USE.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: PASTE
ODOR: SLIGHT
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 1.03 - 1.04
PH: NOT APPLICABLE
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.I. - N.I.
BOILING RANGE, DEG. C: N.I. - N.I.
AUTO-IGNITION TEMPERATURE, DEG. C NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 93.3
VAPOR PRESSURE, MMHg: NO INFORMATION
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: INCOMPATIBLE WITH STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE
ADVERSE HEALTH EFFECTS. DURING APPLICATION AND CURE, THIS PRODUCT
RELEASES METHANOL. METHANOL MAY AFFECT THE BRAIN OR NERVOUS SYSTEM
CAUSING DIZZINESS, HEADACHE OR NAUSEA. INHALATION OF VAPORS IN HIGH
CONCENTRATION MAY CAUSE MILD IRRITATION OF RESPIRATORY SYSTEM (NOSE,
MOUTH, MUCOUS MEMBRANES).
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD
IRRITATION.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DIRECT EYE CONTACT MAY CAUSE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. SINGLE DOSE ORAL TOXICITY IS VERY LOW. AMOUNTS INGESTED
INCIDENTAL TO INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER,
INGESTION OF LARGE AMOUNTS MAY CAUSE INJURY. INGESTION MAY RESULT IN
OBSTRUCTION WHEN MATERIAL HARDENS.
CARCINOGENICITY: NO INFORMATION
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL DERMAL VAPOR
LD50 LD50 LC50
68515-49-1 PROPRIETARY >60000 MG/KG 16000 MG/KG >12.54 MG/L
PHTHALATE ESTERS RAT RABBIT RAT
68583-49-3 CYCLOTETRASILOXANE, >5000 MG/KG N.I. N.I.
OCTAMETHYL-, REACTION RAT
PRODS. WITH SILICA
13822-56-5 3-(TRIMETHOXYSILYL) 2968 MG/KG 11292 MG/KG N.I.
PROPYLAMINE RAT RABBIT
2768-02-7 ORGANOSILANE ESTER 11000 MG/KG 3259.2 MG/KG >20 MG/L
RAT RABBIT
68515-48-0 PROPRIETARY PHTHALATE 2550 MG/KG >3160 MG/KG >4.4 MG/L
ESTERS RAT RABBIT RAT
7631-86-9 SILICA, AMORPHOUS >3300 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED
UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING
TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261.
DISPOSE AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE
COMPLEX AND MAY DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER
WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE. LIQUIDS CANNOT BE DISPOSED
OF IN A LANDFILL.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED.
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT. THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES
SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM
THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: CONSUMER COMMODITY
| 16. OTHER INFORMATION | |
REVISION DATE: 6/19/2015
SUPERSEDES DATE: 6/25/2012
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 24.7
VOC MATERIAL, G/L: 25
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 2.4
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H331: TOXIC IF INHALED.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS03: FLAME OVER CIRCLE
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS
OF THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES
AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY,
WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY,
EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN
PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. SINCE
THISDOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE USE AND
PRECAUTIONARY HANDLING OF THE REFERENCED PRODUCT BY A PROPERLY TRAINED
PERSON, IT IS THEREFORE THE RESPONSIBILITY OF THE USER TO (I) REVIEW THE
RECOMMENDATIONS WITH DUE CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE
INTENDED USE AND (II) DETERMINE IF THEY ARE APPROPRIATE.