| Common Name: | HEET GAS LINE ANTIFREEZE LINE |
| Manufacturer: | GOLD EAGLE |
| SDS Revision Date: | 9/11/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2AEP6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HEET(R*) GAS LINE ANTIFREEZE LINE
SAFETY DATA SHEET
GOLD EAGLE(R*)
| SECTION 1 - IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: HEET(R*) GAS LINE ANTIFREEZE LINE
SYNONYMS: 584402
PRODUCT CODE: 28201; 28203; 28205; 28213; 28219
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RECOMMENDED USE: GASOLINE FUEL ADDITIVE
RESTRICTIONS ON USE:
DO NOT USE IN DIESEL FUEL OR ADD TO GASOLINE/OIL MIXTURES USE IN 2 CYCLE
ENGINES
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
GOLD EAGLE CO.
4400 S. KILDARE AVENUE
CHICAGO, IL 606324372
UNITED STATES
HTTP://WWW.GOLDEAGLE.COM/
TELEPHONE (GENERAL): 773-376-4400
EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 1-800-535-5053 - (INFOTRAC #22283)
| SECTION 2 - HAZARD IDENTIFICATION | |
UNITED STATES (US):
ACCORDING TO: OSHA 29 CFR 1910.1200 HCS
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
FLAMMABLE LIQUIDS 2
SKIN IRRITATION 2
EYE IRRITATION 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE 3: NARCOTIC EFFECTS
REPRODUCTIVE TOXICITY 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE 1
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 1
LABEL ELEMENTS:
OSHA HCS 2012:
DANGER:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOUR
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS - EYES
CAUSES DAMAGE TO ORGANS - EYES THROUGH PROLONGED OR REPEATED EXPOSURE
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND/OR HOT SURFACES. - NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
GROUND AND/OR BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE MIST/VAPOURS/SPRAY.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
RESPONSE:
IN CASE OF FIRE: USE APPROPRIATE MEDIA FOR EXTINCTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT, SEE SUPPLEMENTAL FIRST AID INFORMATION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED: CALL POISON CENTER OR DOCTOR/PHYSICIAN.
STORAGE/DISPOSAL:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCES: MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE.
MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
METHANOL CAS: 67-56-1 100%
PROPRIETARY PROPRIETARY 0.0006% TO 0.0012%
PROPRIETARY PROPRIETARY 0.0001996% TO 0.0003996%
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING
TO REGULATION/DIRECTIVE
METHANOL INHALATION-RAT LC50: OSHA HCS 2012: FLAM. LIQ.
64000 PPM 4 HOUR(S) 2; EYE IRRIT. 2; SKIN
SKIN-RABBIT LD50: IRRIT. 2; STOT SE 1 (EYES);
15800 MG/KG STOT SE 3: NARC.; STOT RE 1
INGESTION/ORAL-RAT (EYES); REPR. 2
LD50: 5600 MG/KG
PROPRIETARY INGESTION/ORAL-RAT OSHA HCS 2012:
LD50: 4300 MG/KG EXPOSURE LIMIT(S)
INHALATION-RAT LC50:
5000 PPM 4 HOUR(S)
SKIN-RABBIT LD50:
>1700 MG/KG
PROPRIETARY SKIN-RABBIT LD50: OSHA HCS 2012:
17800 (MICRO)L/KG EXPOSURE LIMIT(S)
INGESTION/ORAL-RAT
LD50: 3500 MG/KG
INHALATION-RAT LC50:
55000 MG/M3 2 HOUR(S)
| SECTION 4 - FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
MOVE VICTIM TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.
GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.
SKIN:
IN CASE OF BURNS, IMMEDIATELY COOL AFFECTED SKIN FOR AS LONG AS POSSIBLE
WITH COLD WATER. DO NOT REMOVE CLOTHING IF ADHERING TO SKIN. IN CASE OF
CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH SKIN WITH RUNNING WATER FOR AT
LEAST 20 MINUTES. REMOVE AND ISOLATE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER.
EYE:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST FIVE MINUTES, THEN
CONTINUE RINSING EYE. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
INDUCE VOMITING (ONLY IN CONSCIOUS PERSONS) THEN GIVE 2 TEASPOONS OF
BAKING SODA IN A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
| SECTION 5 - FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE HALON REPLACEMENT OR CARBON DIOXIDE EXTINGUISHERS OR ALCOHOL FOAM FOR
SMALL FIRES. LARGE FIRES SHOULD BE EXTINGUISHED WITH ALCOHOL FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
WATER SPRAY OR FOG CAN COOL FIRE BUT MAY NOT BE EFFECTIVE IN EXTINGUISHING
FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN SEWERS.
HIGHLY FLAMMABLE:
WILL BE EASILY IGNITED BY HEAT, SPARKS OR FLAMES.
MANY LIQUIDS ARE LIGHTER THAN WATER.
MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND AND
COLLECT IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
LARGE FIRES:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE
IS OUT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
VENTILATE THE AREA. DO NOT WALK THROUGH SPILLED MATERIAL. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT (PPE) DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. DO NOT
BREATHE MIST, VAPOURS AND/OR SPRAY. AVOID CONTACT WITH SKIN, EYES, AND
CLOTHING.
EMERGENCY PROCEDURES:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 50 METERS (150 FEET) IN ALL DIRECTIONS. IF TANK, RAIL CAR OR TANK
TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800 METERS (1/2 MILE) IN ALL
DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR 800 METERS (1/2 MILE)
IN ALL DIRECTIONS.
LARGE SPILL:
CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST 300 METERS (1000 FEET)
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS OR FLAMES IN
IMMEDIATE AREA). KEEP UNAUTHORIZED PERSONNEL AWAY. STAY UPWIND. KEEP OUT
OF LOW AREAS. VENTILATE CLOSED SPACES BEFORE ENTERING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
ABSORB OR COVER WITH DRY EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL
AND TRANSFER TO CONTAINERS.
USE CLEAN NON-SPARKING TOOLS TO COLLECT ABSORBED MATERIAL.
A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS.
ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED.
LARGE SPILLS: DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
LARGE SPILLS:
WATER SPRAY MAY REDUCE VAPOR; BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, AND
FLAME. ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC CHARGES. DO NOT USE SPARKING
TOOLS. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS CHEMICAL.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT, AVOID DIRECT CONTACT. DO
NOT BREATHE MIST, VAPOURS AND/OR SPRAY. AVOID CONTACT WITH SKIN, EYES,
AND CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND
BEFORE EATING, DRINKING, OR USING TOBACCO.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING. STORE IN A COOL, DRY, WELLVENTILATED PLACE. EMPTY CONTAINERS
CONTAIN PRODUCT RESIDUES, ASSUME EMPTIED CONTAINERS TO HAVE SAME HAZARDS
AS FULL CONTAINERS.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH NIOSH OSHA
PROPRIETARY TWAS 20 PPM TWA 100 PPM TWA; 100 PPM TWA;
(PROPRIETARY) 435 MG/M3 TWA 435 MG/M3 TWA
STELS NOT ESTABLISHED 125 PPM STEL; NOT ESTABLISHED
545 MG/M3 STEL
PROPRIETARY TWAS 100 PPM TWA NOT ESTABLISHED 100 PPM TWA;
(PROPRIETARY) 435 MG/M3 TWA
STELS 150 PPM STEL NOT ESTABLISHED NOT ESTABLISHED
METHANOL TWAS 200 PPM TWA 200 PPM TWA; 200 PPM TWA;
(67-56-1) 260 MG/M3 TWA 260 MG/M3 TWA
STELS 250 PPM STEL 250 PPM STEL; NOT ESTABLISHED
325 MG/M3 STEL
EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT
BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. USE
ONLY APPROPRIATELY CLASSIFIED ELECTRICAL EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. USE A
NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS
ARE EXPERIENCED.
EYE/FACE: WEAR CHEMICAL SPLASH SAFETY GOGGLES.
SKIN/BODY: WEAR APPROPRIATE GLOVES. WEAR PROTECTIVE CLOTHING
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE
TO WATERWAYS. FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF
WASTE.
KEY TO ABBREVIATIONS:
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
STEL = SHORT TERM EXPOSURE LIMITS ARE BASED ON 15MINUTE EXPOSURES
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
TWA = TIMEWEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: LIQUID
APPEARANCE/DESCRIPTION: WATER-WHITE TO PALE YELLOW LIQUID.
COLOR: WATER-WHITE TO PALE YELLOW.
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
GENERAL PROPERTIES:
BOILING POINT: 147 F(63.8889 C)
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
SPECIFIC GRAVITY/RELATIVE DENSITY: = 0.791 WATER=1
WATER SOLUBILITY: SOLUBLE 100 %
VISCOSITY: 3 TO 5 CENTISTOKE (CST, CS) OR MM2/SEC @ 40 C(104 F)
VOLATILITY:
VAPOR PRESSURE: 96 MMHg (TORR)
VAPOR DENSITY: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
VOC (VOL.): 100 %
VOLATILES (VOL.): 100 %
FLAMMABILITY:
FLASH POINT: 56 F(13.3333 C)
UEL: 12.7 %
LEL: 2 %
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT RELEVANT.
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS, ALUMINUM, ZINC, OR METALS THAT DISPLACE HYDROGEN,
RUBBER AND RUBBER BASED COATINGS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE AND
PERCHLORIC ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
EXCESSIVE HEATING AND/OR INCOMPLETE COMBUSTION WILL PRODUCE CARBON
MONOXIDE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
METHANOL (100%): 67-56-1
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 5600 MG/KG
INHALATION-RAT LC50: 64000 PPM 4 HOUR(S)
SKIN-RABBIT LD50: 15800 MG/KG
IRRITATION:
EYE-RABBIT: 100 MG 24 HOUR(S) - MODERATE IRRITATION
SKIN-RABBIT: 20 MG 24 HOUR(S) - MODERATE IRRITATION
MUTAGEN:
CYTOGENETIC ANALYSIS - INGESTION/ORAL-MOUSE: 1 G/KG
DNA DAMAGE - INGESTION/ORAL-RAT: 10 (MICRO)MOL/KG
REPRODUCTIVE:
INHALATION-MOUSE TCLO:
5000 PPM 7 HOUR(S)(615D PREG); REPRODUCTIVE EFFECTS: SPECIFIC DEVELOPMENTAL
ABNORMALITIES: CENTRAL NERVOUS SYSTEM; REPRODUCTIVE EFFECTS: SPECIFIC
DEVELOPMENTAL ABNORMALITIES: CRANIOFACIAL (INCLUDING NOSE AND TONGUE)
INHALATION-MOUSE TCLO:
2000 PPM 7 HOUR(S)(615D PREG); REPRODUCTIVE EFFECTS: SPECIFIC DEVELOPMENTAL
ABNORMALITIES: MUSCULOSKELETAL SYSTEM
GHS PROPERTIES CLASSIFICATION
RESPIRATORY SENSITIZATION OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/IRRITATION OSHA HCS 2012: EYE IRRITATION 2
ACUTE TOXICITY OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD OSHA HCS 2012: DATA LACKING
CARCINOGENICITY OSHA HCS 2012: DATA LACKING
SKIN CORROSION/IRRITATION OSHA HCS 2012: SKIN IRRITATION 2
SKIN SENSITIZATION OSHA HCS 2012: DATA LACKING
STOT-RE OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY
REPEATED EXPOSURE 1
STOT-SE OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY SINGLE
EXPOSURE 1; SPECIFIC TARGET ORGAN
TOXICITY SINGLE EXPOSURE 3:
NARCOTIC EFFECTS
TOXICITY FOR REPRODUCTION OSHA HCS 2012: TOXIC TO REPRODUCTION 2
GERM CELL MUTAGENICITY OSHA HCS 2012: DATA LACKING
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
MAY AFFECT THE CENTRAL NERVOUS SYSTEM. SYMPTOMS MAY INCLUDE DIZZINESS,
DROWSINESS, LETHARGY, COMA AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
SKIN:
ACUTE (IMMEDIATE): CAUSES SKIN IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE.
EYE:
ACUTE (IMMEDIATE): CAUSES SERIOUS EYE IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE.
INGESTION:
ACUTE (IMMEDIATE):
MAY CAUSE HEADACHE, DIZZINESS, WEAKNESS, EUPHORIA, DROWSINESS, SHORTNESS
OF BREATH, VOMITING, AND LOSS OF VOLUNTARY MUSCLE CONTROL. CAN ALSO CAUSE
BLINDNESS AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
OTHER:
CHRONIC (DELAYED):
CHRONIC POISONING FROM REPEATED EXPOSURE TO METHANOL VAPOR WERE MANIFESTED
BY CONJUNCTIVITIS, HEADACHE, GIDDINESS, INSOMNIA, GASTRIC DISTURBANCES,
AND BILATERAL BLINDNESS.
CARCINOGENIC EFFECTS:
THIS PRODUCT DOES NOT CONTAIN ANY COMPONENTS ABOVE DE MINIMUS
CONCENTRATIONS THAT ARE CONSIDERED CARCINOGENIC BY OSHA , IARC OR NTP .
CARCINOGENIC EFFECTS:
CAS IARC
PROPRIETARY PROPRIETARY GROUP 2B-POSSIBLE CARCINOGEN
REPRODUCTIVE EFFECTS:
ANIMAL TESTS FOR COMPONENTS HAVE SHOWN ADVERSE REPRODUCTIVE EFFECTS.
KEY TO ABBREVIATIONS:
LD = LETHAL DOSE
TC = TOXIC CONCENTRATION
| SECTION 12 - ECOLOGICAL INFORMATION | |
TOXICITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
PERSISTENCE AND DEGRADABILITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
BIOACCUMULATIVE POTENTIAL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
MOBILITY IN SOIL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
OTHER ADVERSE EFFECTS:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
UN NUMBER UN PROPER TRANSPORT PACKING ENVIRONMENTAL
SHIPPING NAME HAZARD CLASS(ES) GROUP HAZARDS
DOT ORM-D CONSUMER NDA NDA NDA
COMMODITY
SPECIAL PRECAUTIONS FOR USER: NONE SPECIFIED.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NO DATA AVAILABLE
| SECTION 15 - REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: ACUTE, CHRONIC, FIRE
INVENTORY:
COMPONENT CAS TSCA
PROPRIETARY PROPRIETARY YES
METHANOL 67-56-1 YES
PROPRIETARY PROPRIETARY YES
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
PROPRIETARY PROPRIETARY (LISTED UNDER ETHYL BENZENE)
METHANOL 67-56-1
PROPRIETARY PROPRIETARY (ISOMERS AND MIXTURES)
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - FLAMMABLE
SUBSTANCES:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - TOXIC
SUBSTANCES:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
PROPRIETARY PROPRIETARY 1000 LB FINAL RQ; 454 KG FINAL RQ
METHANOL 67-56-1 5000 LB FINAL RQ; 2270 KG FINAL RQ
PROPRIETARY PROPRIETARY 100 LB FINAL RQ; 45.4 KG FINAL RQ
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 EMISSION REPORTING:
PROPRIETARY PROPRIETARY 0.1 % DE MINIMIS CONCENTRATION
METHANOL 67-56-1 1.0 % DE MINIMIS CONCENTRATION
PROPRIETARY PROPRIETARY 1.0 % DE MINIMIS CONCENTRATION
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CWA (CLEAN WATER ACT) - HAZARDOUS SUBSTANCES:
PROPRIETARY PROPRIETARY
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY
U.S. - CWA (CLEAN WATER ACT) - TOXIC POLLUTANTS:
PROPRIETARY PROPRIETARY
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
UNITED STATES CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
PROPRIETARY PROPRIETARY CARCINOGEN, INITIAL DATE 6/11/04
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 DEVELOPMENTAL TOXICITY, INITIAL
DATE 3/16/12
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
PROPRIETARY PROPRIETARY 54 (MICRO)G/DAY NSRL (INHALATION);
41 (MICRO)G/DAY NSRL (ORAL)
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67 -56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
PROPRIETARY PROPRIETARY NOT LISTED
METHANOL 67-56-1 NOT LISTED
PROPRIETARY PROPRIETARY NOT LISTED
OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
REVISION DATE: 11/SEPTEMBER/2015
PREPARATION DATE: 23/SEPTEMBER/2014
OTHER INFORMATION:
SCHEDULE B NUMBER: 3820.00.0000.
DISCLAIMER/STATEMENT OF LIABILITY:
INFORMATION PRESENTED HEREIN IS BELIEVED TO BE FACTUAL, AS IT HAS BEEN
DERIVED FROM THE WORKS AND OPINIONS OF PERSONS BELIEVED TO BE QUALIFIED
EXPERTS. HOWEVER, NOTHING CONTAINED IN THIS INFORMATION IS TO BE TAKEN
AS WARRANTY OR REPRESENTATION FOR WHICH THE GOLD EAGLE CO. BEARS LEGAL
RESPONSIBILITY. THE USER SHOULD REVIEW ANY RECOMMENDATIONS IN THE SPECIFIC
CONTEXT OF THE INTENDED USE TO DETERMINE WHETHER THEY ARE APPROPRIATE.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
FORMAT: GHS
LANGUAGE: ENGLISH (US)
OSHA HCS 2012