| Common Name: | 4055 AEROSOL WALL TEXTURE OIL BASED - ORANGE PEEL, 00384774 |
| Manufacturer: | PPG INDUSTRIES |
| SDS Revision Date: | 4/23/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 2AUT8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PPG
SAFETY DATA SHEET
DATE OF ISSUE/DATE OF REVISION: 23 APRIL 2019
VERSION: 9
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: 4055 AEROSOL WALL TEXTURE OIL BASED - ORANGE PEEL
PRODUCT CODE: 00384774
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PRODUCT USE:
CONSUMER APPLICATIONS, PROFESSIONAL APPLICATIONS, USED BY SPRAYING.
USE OF THE SUBSTANCE/MIXTURE: COATING.
USES ADVISED AGAINST: NOT APPLICABLE.
MANUFACTURER:
PPG INDUSTRIES, INC.
ONE PPG PLACE
PITTSBURGH, PA 15272
EMERGENCY TELEPHONE NUMBER:
(412) 434-4515 (U.S.)
(514) 645-1320 (CANADA)
01-800-00-21-400 OR + 52 55 5559 1588 (MEXICO)
TECHNICAL PHONE NUMBER: 1-800-441-9695 (8:00 AM TO 5:00 PM EST)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
| FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 1A
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
| PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN
| TOXICITY: 23.5% (ORAL), 53.1% (DERMAL), 24.3% (INHALATION)
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
| EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.
MAY DAMAGE THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
| OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
| PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
| EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT,
| HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING.
| DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT BREATHE
| DUST OR MIST. WASH HANDS THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
| CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
| PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE:
| GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
| IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
| IF ON SKIN:
| WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
| REUSE.
| IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
| IF IN EYES:
| RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
| IF PRESENT AND EASY TO DO. CONTINUE RINSING.
| IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
CONTENTS UNDER PRESSURE. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL
OCCUR AND THE CONTAINER MAY BURST OR EXPLODE. DO NOT PUNCTURE OR
INCINERATE. KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT. SANDING AND GRINDING
DUSTS MAY BE HARMFUL IF INHALED. THIS PRODUCT CONTAINS CRYSTALLINE SILICA
WHICH CAN CAUSE LUNG CANCER OR SILICOSIS. THE RISK OF CANCER DEPENDS ON THE
DURATION AND LEVEL OF EXPOSURE TO DUST FROM SANDING SURFACES OR MIST FROM
SPRAY APPLICATIONS. AVOID CONTACT WITH SKIN AND CLOTHING. WASH THOROUGHLY
AFTER HANDLING. EMITS TOXIC FUMES WHEN HEATED.
HAZARDS NOT OTHERWISE CLASSIFIED:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT NAME: 4055 AEROSOL WALL TEXTURE OIL BASED - ORANGE PEEL
INGREDIENT NAME % CAS NUMBER
LIMESTONE >/=20 - </=50 1317-65-3
ACETONE >/=5.0 - </=10 67-64-1
SOLVENT NAPHTHA (PETROLEUM), LIGHT >/=5.0 - </=9.2 64742-89-8
ALIPH.
ISOBUTANE >/=5.0 - </=10 75-28-5
WOLLASTONITE >/=5.0 - </=10 13983-17-0
PROPANE >/=1.0 - </=5.0 74-98-6
XYLENE >/=1.0 - </=5.0 1330-20-7
4-HYDROXY-4-METHYLPENTAN-2-ONE >/=1.0 - </=4.7 123-42-2
HEPTANE >/=1.0 - </=3.8 142-82-5
N-BUTYL ACETATE >/=1.0 - </=3.2 123-86-4
ETHYLBENZENE <1.0 100-41-4
FATTY ACIDS, C18-UNSATD., DIMERS, </=1.0 162627-17-0
REACTION PRODUCTS WITH N,N-DIMETHYL-1,
3-PROPANEDIAMINE AND 1,3-PROPANEDIAMINE
CRYSTALLINE SILICA, RESPIRABLE POWDER <1.0 14808-60-7
(<10 MICRONS)
N-METHYL-2-PYRROLIDONE <1.0 872-50-4
SUB CODES REPRESENT SUBSTANCES WITHOUT REGISTERED CAS NUMBERS.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
IF INGESTION, IRRITATION, ANY TYPE OF OVEREXPOSURE OR SYMPTOMS OF
OVEREXPOSURE OCCUR DURING OR PERSISTS AFTER USE OF THIS PRODUCT, CONTACT A
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE SAFETY
DATA SHEET INFORMATION AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS OR CONVULSING PERSON.
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
REMOVE CONTACT LENSES, IRRIGATE COPIOUSLY WITH CLEAN, FRESH WATER, HOLDING
THE EYELIDS APART FOR AT LEAST 10 MINUTES AND SEEK IMMEDIATE MEDICAL
ADVICE.
INHALATION:
REMOVE TO FRESH AIR. KEEP PERSON WARM AND AT REST. IF NOT BREATHING, IF
BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS, PROVIDE ARTIFICIAL
RESPIRATION OR OXYGEN BY TRAINED PERSONNEL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH SKIN THOROUGHLY WITH SOAP AND
WATER OR USE RECOGNIZED SKIN CLEANSER. DO NOT USE SOLVENTS OR THINNERS.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL. KEEP PERSON WARM AND AT REST. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION.
| INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING:
EXTREMELY FLAMMABLE AEROSOL. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND FROM THE CHEMICAL THE CONTAINER MAY BURST, WITH THE RISK OF
A SUBSEQUENT EXPLOSION. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR
TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. GAS
MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE
TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE OR EXPLOSION. BURSTING
AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT HIGH SPEED. RUNOFF TO
SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. THIS MATERIAL IS TOXIC TO
AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER CONTAMINATED WITH THIS
MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY
WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION. DO
NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION SOURCES.
NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID BREATHING VAPOR OR MIST.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED. PRESSURIZED CONTAINER: PROTECT FROM
SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C. DO NOT
PIERCE OR BURN, EVEN AFTER USE. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN
EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST.
AVOID BREATHING GAS. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM HEAT,
SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS.
SPECIAL PRECAUTIONS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS ARE HEAVIER THAN
AIR AND MAY SPREAD ALONG FLOORS. IF THIS MATERIAL IS PART OF A MULTIPLE
COMPONENT SYSTEM, READ THE SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT
OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE
HAZARDS OF ALL OF ITS PARTS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE ABOVE THE FOLLOWING TEMPERATURE: 50 DEG. C (122 DEG. F).
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT
SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. ELIMINATE ALL IGNITION
SOURCES. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
LIMESTONE OSHA PEL (UNITED STATES, 5/2018).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACETONE ACGIH TLV (UNITED STATES, 3/2018).
STEL: 500 PPM 15 MINUTES.
TWA: 250 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 2400 MG/M3 8 HOURS.
TWA: 1000 PPM 8 HOURS.
SOLVENT NAPHTHA (PETROLEUM), NONE.
LIGHT ALIPH.
ISOBUTANE ACGIH TLV (UNITED STATES, 3/2018).
STEL: 1000 PPM 15 MINUTES.
WOLLASTONITE ACGIH TLV (UNITED STATES, 3/2018).
TWA: 1 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
PROPANE OSHA PEL (UNITED STATES, 5/2018).
TWA: 1800 MG/M3 8 HOURS.
TWA: 1000 PPM 8 HOURS.
ACGIH TLV (UNITED STATES, 3/2018). OXYGEN
DEPLETION [ASPHYXIANT].
XYLENE ACGIH TLV (UNITED STATES, 3/2018).
STEL: 651 MG/M3 15 MINUTES.
STEL: 150 PPM 15 MINUTES.
TWA: 434 MG/M3 8 HOURS.
TWA: 100 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 435 MG/M3 8 HOURS.
TWA: 100 PPM 8 HOURS.
4-HYDROXY-4-METHYLPENTAN-2-ONE ACGIH TLV (UNITED STATES, 3/2018).
TWA: 238 MG/M3 8 HOURS.
TWA: 50 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 240 MG/M3 8 HOURS.
TWA: 50 PPM 8 HOURS.
HEPTANE ACGIH TLV (UNITED STATES, 3/2018).
STEL: 2050 MG/M3 15 MINUTES.
STEL: 500 PPM 15 MINUTES.
TWA: 1640 MG/M3 8 HOURS.
TWA: 400 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 2000 MG/M3 8 HOURS.
TWA: 500 PPM 8 HOURS.
N-BUTYL ACETATE OSHA PEL (UNITED STATES, 5/2018).
TWA: 710 MG/M3 8 HOURS.
TWA: 150 PPM 8 HOURS.
ACGIH TLV (UNITED STATES, 3/2018).
STEL: 150 PPM 15 MINUTES.
TWA: 50 PPM 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2018).
TWA: 20 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 435 MG/M3 8 HOURS.
TWA: 100 PPM 8 HOURS.
FATTY ACIDS, C18-UNSATD., NONE.
DIMERS, REACTION PRODUCTS WITH
N,N-DIMETHYL-1,3-
PROPANEDIAMINE AND
1,3-PROPANEDIAMINE
CRYSTALLINE SILICA, RESPIRABLE ACGIH TLV (UNITED STATES, 3/2018).
POWDER (<10 MICRONS) TWA: 0.025 MG/M3 8 HOURS.
FORM: RESPIRABLE
OSHA PEL Z3 (UNITED STATES, 6/2016).
TWA: 10 MG/M3 / (%SiO2+2) 8 HOURS.
FORM: RESPIRABLE
TWA: 250 MPPCF / (%SiO2+5) 8 HOURS.
FORM: RESPIRABLE
OSHA PEL (UNITED STATES, 5/2018).
TWA: 50 (MICRO)G/M3 8 HOURS.
FORM: RESPIRABLE DUST
N-METHYL-2-PYRROLIDONE IPEL (PPG). ABSORBED THROUGH SKIN.
TWA: 10 PPM
STEL: 20 PPM
KEY TO ABBREVIATIONS:
A: ACCEPTABLE MAXIMUM PEAK
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
C: CEILING LIMIT
F: FUME
IPEL: INTERNAL PERMISSIBLE EXPOSURE LIMIT
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
R: RESPIRABLE
S: POTENTIAL SKIN ABSORPTION
SR: RESPIRATORY SENSITIZATION
SS: SKIN SENSITIZATION
STEL: SHORT TERM EXPOSURE LIMIT VALUES
TD: TOTAL DUST
TLV: THRESHOLD LIMIT VALUE
TWA: TIME WEIGHTED AVERAGE
Z:
OSHA 29 CFR 1910.1200 SUBPART Z - TOXIC AND HAZARDOUS SUBSTANCES CONSULT
LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
RECOMMENDED MONITORING PROCEDURES:
IF THIS PRODUCT CONTAINS INGREDIENTS WITH EXPOSURE LIMITS, PERSONAL,
WORKPLACE ATMOSPHERE OR BIOLOGICAL MONITORING MAY BE REQUIRED TO DETERMINE
THE EFFECTIVENESS OF THE VENTILATION OR OTHER CONTROL MEASURES AND/OR THE
NECESSITY TO USE RESPIRATORY PROTECTIVE EQUIPMENT. REFERENCE SHOULD BE MADE
TO APPROPRIATE MONITORING STANDARDS. REFERENCE TO NATIONAL GUIDANCE
DOCUMENTS FOR METHODS FOR THE DETERMINATION OF HAZARDOUS SUBSTANCES WILL
ALSO BE REQUIRED.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
GLOVES: BUTYL RUBBER
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTI-STATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR. IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE
LIMIT, THEY MUST USE APPROPRIATE, CERTIFIED RESPIRATORS. USE A PROPERLY
FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH AN APPROVED
STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: WHITE.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: <35 DEG. C (<95 DEG. F)
FLASH POINT:
CLOSED CUP: -94.4 DEG. C (-137.9 DEG. F)
MATERIAL SUPPORTS COMBUSTION.: YES.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.2
DENSITY (LBS / GAL): 10.01
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): >0.21 CM2/S (>21 CST)
VOLATILITY: 72% (V/V), 42.855% (W/W)
% SOLID. (W/W): 57.145
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 13.45 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
WHEN EXPOSED TO HIGH TEMPERATURES MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS. REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
INCOMPATIBLE MATERIALS:
KEEP AWAY FROM THE FOLLOWING MATERIALS TO PREVENT STRONG EXOTHERMIC
REACTIONS: OXIDIZING AGENTS, STRONG ALKALIS, STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS: CARBON
MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF NITROGEN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
| LIMESTONE LD50 ORAL RAT 6450 MG/KG
ACETONE LC50 INHALATION RAT 76000 MG/M3 4 HOURS
VAPOR
LD50 DERMAL RABBIT 15.8 G/KG
LD50 ORAL RAT 5800 MG/KG
ISOBUTANE LC50 INHALATION RAT 658000 MG/M3 4 HOURS
VAPOR
XYLENE LD50 DERMAL RABBIT >1.7 G/KG
LD50 ORAL RAT 4.3 G/KG
4-HYDROXY-4- LD50 DERMAL RABBIT 13500 MG/KG
METHYLPENTAN-2-ONE LD50 ORAL RAT 2520 MG/KG
HEPTANE LC50 INHALATION RAT 48000 PPM 4 HOURS
GAS.
LC50 INHALATION RAT 103 G/M3 4 HOURS
VAPOR
N-BUTYL ACETATE LC50 INHALATION RAT >21.1 MG/L 4 HOURS
VAPOR
LC50 INHALATION RAT 2000 PPM 4 HOURS
VAPOR
LD50 DERMAL RABBIT >17600 MG/KG
LD50 ORAL RAT 10.768 G/KG
ETHYLBENZENE LC50 INHALATION RAT 17.8 MG/L 4 HOURS
VAPOR
LD50 DERMAL RABBIT 17.8 G/KG
LD50 ORAL RAT 3.5 G/KG
N-METHYL-2-PYRROLIDONE LC50 INHALATION RAT >5100 MG/M3 4 HOURS
DUSTS AND MISTS
LD50 DERMAL RABBIT 8 G/KG
LD50 ORAL RAT 3.914 G/KG
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
IRRITATION/CORROSION:
PRODUCT/INGREDIENT NAME RESULT SPECIES SCORE EXPOSURE OBSERVATION
XYLENE SKIN - RABBIT 24 HOURS
MODERATE 500 MG
IRRITANT
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
EYES: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SENSITIZATION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
MUTAGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CARCINOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
WOLLASTONITE - 3 -
XYLENE - 3 -
ETHYLBENZENE - 2B -
CRYSTALLINE SILICA, RESPIRABLE - 1 KNOWN TO BE A HUMAN
POWDER (<10 MICRONS) CARCINOGEN.
CARCINOGEN CLASSIFICATION CODE:
IARC: 1, 2A, 2B, 3, 4
NTP:
KNOWN TO BE A HUMAN CARCINOGEN; REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN
OSHA: +
NOT LISTED/NOT REGULATED: -
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
TERATOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY
ACETONE CATEGORY 3
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. CATEGORY 3
XYLENE CATEGORY 3
4-HYDROXY-4-METHYLPENTAN-2-ONE CATEGORY 3
HEPTANE CATEGORY 3
N-BUTYL ACETATE CATEGORY 3
N-METHYL-2-PYRROLIDONE CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY
ISOBUTANE CATEGORY 2
PROPANE CATEGORY 2
ETHYLBENZENE CATEGORY 2
CRYSTALLINE SILICA, RESPIRABLE POWDER (<10 MICRONS) CATEGORY 1
N-METHYL-2-PYRROLIDONE CATEGORY 2
TARGET ORGANS:
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
BRAIN, CENTRAL NERVOUS SYSTEM (CNS).
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
BLOOD, KIDNEYS, LUNGS, THE NERVOUS SYSTEM, LIVER, HEART, GASTROINTESTINAL
TRACT, UPPER RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA.
ASPIRATION HAZARD:
NAME RESULT
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. ASPIRATION HAZARD - CATEGORY 1
XYLENE ASPIRATION HAZARD - CATEGORY 1
HEPTANE ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION.
| INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
CONCLUSION/SUMMARY:
HERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF. THIS PRODUCT CONTAINS
CRYSTALLINE SILICA WHICH CAN CAUSE LUNG CANCER OR SILICOSIS. THE RISK OF
CANCER DEPENDS ON THE DURATION AND LEVEL OF EXPOSURE TO DUST FROM SANDING
SURFACES OR MIST FROM SPRAY APPLICATIONS. EXPOSURE TO COMPONENT SOLVENT
VAPOR CONCENTRATIONS IN EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMIT
MAY RESULT IN ADVERSE HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND
RESPIRATORY SYSTEM IRRITATION AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND
CENTRAL NERVOUS SYSTEM. SYMPTOMS AND SIGNS INCLUDE HEADACHE, DIZZINESS,
FATIGUE, MUSCULAR WEAKNESS, DROWSINESS AND, IN EXTREME CASES, LOSS OF
CONSCIOUSNESS. SOLVENTS MAY CAUSE SOME OF THE ABOVE EFFECTS BY ABSORPTION
THROUGH THE SKIN. THERE IS SOME EVIDENCE THAT REPEATED EXPOSURE TO ORGANIC
SOLVENT VAPORS IN COMBINATION WITH CONSTANT LOUD NOISE CAN CAUSE GREATER
HEARING LOSS THAN EXPECTED FROM EXPOSURE TO NOISE ALONE. IF SPLASHED IN THE
EYES, THE LIQUID MAY CAUSE IRRITATION AND REVERSIBLE DAMAGE. INGESTION MAY
CAUSE NAUSEA, DIARRHEA AND VOMITING. THIS TAKES INTO ACCOUNT, WHERE KNOWN,
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS OF COMPONENTS FROM
SHORT-TERM AND LONG-TERM EXPOSURE BY ORAL, INHALATION AND DERMAL ROUTES OF
EXPOSURE AND EYE CONTACT.
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
CARCINOGENICITY:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
MAY CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
| ORAL 4767.9 MG/KG
DERMAL 11680 MG/KG
INHALATION (VAPORS) 188.7 MG/L
INHALATION (DUSTS AND MISTS) 25.73 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
| LIMESTONE ACUTE LC50 >56000 MG/L FISH 96 HOURS
ETHYLBENZENE ACUTE LC50: FISH - LEPOMIS 96 HOURS
150 TO 200 MG/L MACROCHIRUS - YOUNG
FRESH WATER OF THE YEAR
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
ACETONE READILY
XYLENE READILY
ETHYLBENZENE READILY
N-METHYL-2-PYRROLIDONE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
ACETONE -0.24 3 LOW
ISOBUTANE 2.8 LOW
PROPANE 2.36 LOW
XYLENE 3.16 7.4 TO 18.5 LOW
4-HYDROXY-4-METHYLPENTAN-2-ONE -0.14 TO 1.03 LOW
HEPTANE 4.66 HIGH
N-BUTYL ACETATE 1.78 LOW
ETHYLBENZENE 3.15 79.43 LOW
N-METHYL-2-PYRROLIDONE -0.38 3.16 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
REFER TO SECTION 7: HANDLING AND STORAGE AND SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION FOR ADDITIONAL HANDLING INFORMATION AND
PROTECTION OF EMPLOYEES. SECTION 6. ACCIDENTAL RELEASE MEASURES
| SECTION 14. TRANSPORT INFORMATION | |
DOT IMDG IATA
UN NUMBER UN1950 UN1950 UN1950
UN PROPER AEROSOLS AEROSOLS AEROSOLS, FLAMMABLE
SHIPPING NAME
TRANSPORT 2.1 2.1 2.1
HAZARD CLASS
(ES)
PACKING GROUP
ENVIRONMENTAL NO. YES. YES. THE ENVIRONMENTALLY
HAZARDS HAZARDOUS SUBSTANCE MARK
IS NOT REQUIRED.
MARINE NOT APPLICABLE. (HEPTANE) NOT APPLICABLE.
POLLUTANT
SUBSTANCES
PRODUCT RQ 2266.2 NOT APPLICABLE. NOT APPLICABLE.
(LBS)
RQ (XYLENE) NOT APPLICABLE. NOT APPLICABLE.
SUBSTANCES
ADDITIONAL INFORMATION:
DOT:
PACKAGE SIZES SHIPPED IN QUANTITIES LESS THAN THE PRODUCT REPORTABLE
QUANTITY ARE NOT SUBJECT TO THE RQ (REPORTABLE QUANTITY) TRANSPORTATION
REQUIREMENTS.
IMDG:
THE MARINE POLLUTANT MARK IS NOT REQUIRED WHEN TRANSPORTED IN SIZES OF </=5
L OR </=5 KG.
IATA:
THE ENVIRONMENTALLY HAZARDOUS SUBSTANCE MARK MAY APPEAR IF REQUIRED BY
OTHER TRANSPORTATION REGULATIONS.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
UNITED STATES - TSCA 5(A)2 - PROPOSED SIGNIFICANT NEW USE RULES:
N-METHYL-2-PYRROLIDONE: LISTED
SARA 302/304:
SARA 304 RQ: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 311/312:
CLASSIFICATION:
| FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 1A
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
HNOC: DEFATTING IRRITANT
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % CLASSIFICATION
ACETONE >/=5.0 - </=10 FLAMMABLE LIQUIDS -
CATEGORY 2
EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(NARCOTIC EFFECTS) -
CATEGORY 3
HNOC - DEFATTING IRRITANT
SOLVENT NAPHTHA (PETROLEUM), >/=5.0 - </=9.2 ACUTE TOXICITY (ORAL) -
LIGHT ALIPH. CATEGORY 4
EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(RESPIRATORY TRACT
IRRITATION) - CATEGORY 3
ASPIRATION HAZARD -
CATEGORY 1
HNOC - DEFATTING IRRITANT
ISOBUTANE >/=5.0 - </=10 FLAMMABLE GASES - CATEGORY 1
GASES UNDER PRESSURE -
COMPRESSED GAS
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) - CATEGORY 2
PROPANE >/=1.0 - </=5.0 FLAMMABLE GASES - CATEGORY 1
GASES UNDER PRESSURE -
COMPRESSED GAS
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) - CATEGORY 2
XYLENE >/=1.0 - </=5.0 FLAMMABLE LIQUIDS -
CATEGORY 3
ACUTE TOXICITY (DERMAL) -
CATEGORY 4
ACUTE TOXICITY (INHALATION)
- CATEGORY 4
SKIN IRRITATION - CATEGORY 2
EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(RESPIRATORY TRACT
IRRITATION) - CATEGORY 3
ASPIRATION HAZARD -
CATEGORY 1
4-HYDROXY-4-METHYLPENTAN- >/=1.0 - </=4.7 FLAMMABLE LIQUIDS -
2-ONE CATEGORY 3
EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(RESPIRATORY TRACT
IRRITATION) - CATEGORY 3
HEPTANE >/=1.0 - </=3.8 FLAMMABLE LIQUIDS -
CATEGORY 2
SKIN IRRITATION - CATEGORY 2
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(NARCOTIC EFFECTS) -
CATEGORY 3
ASPIRATION HAZARD -
CATEGORY 1
HNOC - DEFATTING IRRITANT
N-BUTYL ACETATE >/=1.0 - </=3.2 FLAMMABLE LIQUIDS -
CATEGORY 2
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(NARCOTIC EFFECTS) -
CATEGORY 3
HNOC - DEFATTING IRRITANT
ETHYLBENZENE <1.0 FLAMMABLE LIQUIDS -
CATEGORY 2
ACUTE TOXICITY (INHALATION)
- CATEGORY 4
CARCINOGENICITY - CATEGORY 2
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) (HEARING ORGANS)
- CATEGORY 2
ASPIRATION HAZARD -
CATEGORY 1
HNOC - DEFATTING IRRITANT
FATTY ACIDS, C18-UNSATD., </=1.0 SKIN SENSITIZATION -
DIMERS, REACTION PRODUCTS CATEGORY 1A
WITH N,N-DIMETHYL-1,3-
PROPANEDIAMINE AND
1,3-PROPANEDIAMINE
CRYSTALLINE SILICA, <1.0 CARCINOGENICITY -
RESPIRABLE POWDER (<10 CATEGORY 1A
MICRONS) SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) - CATEGORY 1
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) (INHALATION) -
CATEGORY 1
N-METHYL-2-PYRROLIDONE <1.0 SKIN IRRITATION - CATEGORY 2
EYE IRRITATION - CATEGORY 2A
TOXIC TO REPRODUCTION
(UNBORN CHILD) - CATEGORY 1B
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(RESPIRATORY TRACT
IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) - CATEGORY 2
HNOC - DEFATTING IRRITANT
SARA 313:
SUPPLIER NOTIFICATION:
CHEMICAL NAME CAS NUMBER CONCENTRATION
XYLENE 1330-20-7 1 - 5
ETHYLBENZENE 100-41-4 0.1 - 1
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
ADDITIONAL ENVIRONMENTAL INFORMATION IS CONTAINED ON THE ENVIRONMENTAL DATA
SHEET FOR THIS PRODUCT, WHICH CAN BE OBTAINED FROM YOUR PPG REPRESENTATIVE.
CALIFORNIA PROP. 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARDS 0
(*) - CHRONIC EFFECTS
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON
MSDSS OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER
MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
DATE OF PREVIOUS ISSUE: 12/13/2018
ORGANIZATION THAT PREPARED THE MSDS: EHS
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS,
1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON PRESENT SCIENTIFIC
AND TECHNICAL KNOWLEDGE. THE PURPOSE OF THIS INFORMATION IS TO DRAW
ATTENTION TO THE HEALTH AND SAFETY ASPECTS CONCERNING THE PRODUCTS SUPPLIED
BY PPG, AND TO RECOMMEND PRECAUTIONARY MEASURES FOR THE STORAGE AND
HANDLING OF THE PRODUCTS. NO WARRANTY OR GUARANTEE IS GIVEN IN RESPECT OF
THE PROPERTIES OF THE PRODUCTS. NO LIABILITY CAN BE ACCEPTED FOR ANY
FAILURE TO OBSERVE THE PRECAUTIONARY MEASURES DESCRIBED IN THIS DATA SHEET
OR FOR ANY MISUSE OF THE PRODUCTS.
UNITED STATES