| Common Name: | SANITIZER CONCENTRATE (PRODUCT NO. 16, CHEMICAL MANAGEMENT SYSTEMS) |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2BW55, 39CZ58 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) SANITIZER CONCENTRATE (PRODUCT NO. 16, 3M(TM) CHEMICAL MANAGEMENT
SYSTEMS)
05/28/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 06-6875-6
VERSION NUMBER: 22.02
ISSUE DATE: 05/28/15
SUPERCEDES DATE: 03/24/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SANITIZER CONCENTRATE (PRODUCT NO. 16, 3M(TM) CHEMICAL MANAGEMENT
SYSTEMS)
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
61-0000-6339-8
61-0000-6410-7
70-0710-0975-0 00-48011-34658-3
61-0000-6379-4
70-0708-4016-3 00-48011-20112-7
70-0716-5880-4
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
DISINFECTANT, EPA-REGISTERED SANITIZER FOR WALLS, FLOORS, AND OTHER HARD,
NON-POROUS SURFACES. SAFE FOR SANITIZING FOOD CONTACT SURFACES.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1C.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: CORROSION
PICTOGRAMS: CORROSION
HAZARD STATEMENTS: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
4% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 >95 TRADE SECRET *
DIDECYL DIMETHYL AMMONIUM CHLORIDE 7173-51-5 2.31
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM 68424-85-1 1.54
CHLORIDES
ETHYL ALCOHOL 64-17-5 0.1 - 1 TRADE SECRET *
METHYL ALCOHOL 67-56-1 <0.1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A METAL CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH WATER. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. THIS PRODUCT IS NOT INTENDED TO
BE USED WITHOUT PRIOR DILUTION AS SPECIFIED ON THE PRODUCT LABEL. GROUNDING
OR SAFETY SHOES WITH ELECTROSTATIC DISSIPATING SOLES (ESD) ARE NOT REQUIRED
WITH A CHEMICAL DISPENSING SYSTEM. KEEP OUT OF REACH OF CHILDREN. DO NOT
BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR
ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM AREAS WHERE PRODUCT MAY COME INTO CONTACT WITH FOOD OR
PHARMACEUTICALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
ETHYL ALCOHOL 64-17-5 ACGIH STEL: 1000 PPM A3:
CONFIRMED ANIMAL
CARCIN.
ETHYL ALCOHOL 64-17-5 OSHA TWA:
1900 MG/M3
(1000 PPM)
METHYL ALCOHOL 67-56-1 ACGIH TWA: 200 PPM SKIN NOTATION
STEL: 250 PPM
METHYL ALCOHOL 67-56-1 OSHA TWA:
260 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED. USE GENERAL DILUTION VENTILATION AND/OR LOCAL
EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF THE PRODUCT IS NOT USED WITH
A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE, WEAR
PROTECTIVE EYE/FACE PROTECTION. SELECT AND USE EYE/FACE PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF
AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR COLORLESS LIQUID WITH A MILD ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 4.8 - 7.6
BOILING POINT: >212 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 0.991 - 1.003 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 15.7 - 16.9 SEC [DETAILS: S-90 ZAHN #2]
HAZARDOUS AIR POLLUTANTS: NOT APPLICABLE
VOLATILE ORGANIC COMPOUNDS:
<1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: >95% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
130 - 140 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE
CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
ADDITIONAL INFORMATION:
THIS PRODUCT CONTAINS ETHANOL. ALCOHOLIC BEVERAGES AND ETHANOL IN ALCOHOLIC
BEVERAGES HAVE BEEN CLASSIFIED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER AS CARCINOGENIC TO HUMANS. THERE ARE ALSO DATA ASSOCIATING HUMAN
CONSUMPTION OF ALCOHOLIC BEVERAGES WITH DEVELOPMENTAL TOXICITY AND LIVER
TOXICITY. EXPOSURE TO ETHANOL DURING THE FORESEEABLE USE OF THIS PRODUCT IS
NOT EXPECTED TO CAUSE CANCER, DEVELOPMENTAL TOXICITY, OR LIVER TOXICITY.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR CALCULATED ATE:
(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
DIDECYL DIMETHYL INGESTION RAT LD50: 84 MG/KG
AMMONIUM CHLORIDE
BENZYL-C12-16-ALKYLDIMETHYL DERMAL RABBIT LD50: 645 MG/KG
AMMONIUM CHLORIDES
BENZYL-C12-16-ALKYLDIMETHYL INGESTION RAT LD50: 366 MG/KG
AMMONIUM CHLORIDES
ETHYL ALCOHOL DERMAL RABBIT LD50: >15,800 MG/KG
ETHYL ALCOHOL INHALATION- RAT LC50: 124.7 MG/L
VAPOR
(4 HOURS)
ETHYL ALCOHOL INGESTION RAT LD50: 17,800 MG/KG
METHYL ALCOHOL DERMAL LD50:
ESTIMATED TO BE
1,000 - 2,000 MG/KG
METHYL ALCOHOL INHALATION- LC50:
VAPOR ESTIMATED TO BE
10 - 20 MG/L
METHYL ALCOHOL INGESTION LD50:
ESTIMATED TO BE
50 - 300 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ETHYL ALCOHOL RABBIT NO SIGNIFICANT IRRITATION
METHYL ALCOHOL RABBIT MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ETHYL ALCOHOL RABBIT MODERATE IRRITANT
METHYL ALCOHOL RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
ETHYL ALCOHOL HUMAN SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
METHYL ALCOHOL GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ETHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
ETHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
METHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
METHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ETHYL ALCOHOL INGESTION MULTIPLE SOME POSITIVE DATA EXIST, BUT
ANIMAL THE DATA ARE NOT SUFFICIENT
SPECIES FOR CLASSIFICATION
METHYL ALCOHOL INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ETHYL ALCOHOL INHALATION NOT TOXIC TO DEVELOPMENT
ETHYL ALCOHOL INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INGESTION SOME POSITIVE MALE REPRODUCTIVE DATA
EXIST, BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INGESTION TOXIC TO DEVELOPMENT
METHYL ALCOHOL INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHYL ALCOHOL RAT NOAEL: 38 MG/L DURING GESTATION
ETHYL ALCOHOL RAT NOAEL: PREMATING & DURING
5,200 MG/KG/DAY GESTATION
METHYL ALCOHOL RAT NOAEL: 21 DAYS
1,600 MG/KG/DAY
METHYL ALCOHOL MOUSE LOAEL: DURING ORGANOGENESIS
4,000 MG/KG/DAY
METHYL ALCOHOL MOUSE NOAEL: 1.3 MG/L DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ETHYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ETHYL ALCOHOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INHALATION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INGESTION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHYL ALCOHOL HUMAN LOAEL: 2.6 MG/L 30 MINUTES
ETHYL ALCOHOL HUMAN LOAEL: 9.4 MG/L NOT AVAILABLE
ETHYL ALCOHOL MULTIPLE NOAEL:
ANIMAL NOT AVAILABLE
SPECIES
ETHYL ALCOHOL DOG NOAE:
3,000 MG/KG
METHYL ALCOHOL HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE
NOT AVAILABLE
METHYL ALCOHOL RAT NOAEL: 6 HOURS
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ALCOHOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHYL ALCOHOL INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYL ALCOHOL INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
IMMUNE SYSTEM ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYL ALCOHOL INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYL ALCOHOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INHALATION LIVER ALL DATA ARE NEGATIVE
METHYL ALCOHOL INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
METHYL ALCOHOL INGESTION LIVER SOME POSITIVE DATA
NERVOUS SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHYL ALCOHOL RABBIT LOAEL: 124 MG/L 365 DAYS
ETHYL ALCOHOL RAT NOAEL: 25 MG/L 14 DAYS
ETHYL ALCOHOL RAT LOAEL: 8,000 MG/KG/DAY 4 MONTHS
ETHYL ALCOHOL DOG NOAEL: 3,000 MG/KG/DAY 7 DAYS
METHYL ALCOHOL RAT NOAEL: 6.55 MG/L 4 WEEKS
METHYL ALCOHOL RAT NOAEL: 13.1 MG/L 6 WEEKS
METHYL ALCOHOL RAT NOAEL: 2,500 MG/KG/DAY 90 DAYS
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
A 3M PRODUCT ENVIRONMENTAL DATA SHEET (PED) IS AVAILABLE.
CHEMICAL FATE INFORMATION:
A 3M PRODUCT ENVIRONMENTAL DATA SHEET (PED) IS AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D018 (BENZENE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIFRA:
STATUS REGISTRATION NUMBER
REGISTERED 47371-147-10350
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE UNITED STATES
ENVIRONMENTAL PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING
REQUIREMENTS UNDER FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM
THE CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA
SHEETS (SDS), AND FOR WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS. THE
HAZARD INFORMATION REQUIRED ON THE PESTICIDE LABEL IS REPRODUCED BELOW.
THE PESTICIDE LABEL ALSO INCLUDES OTHER IMPORTANT INFORMATION, INCLUDING
DIRECTIONS FOR USE.
PRECAUTIONARY STATEMENTS:
HAZARDS TO HUMANS AND DOMESTIC ANIMALS:
DANGER. CORROSIVE.
CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. WEAR PROTECTIVE EYEWEAR (GOGGLES, FACE SHIELD OR
SAFETY GLASSES), PROTECTIVE CLOTHING AND RUBBER GLOVES. WASH THOROUGHLY
WITH SOAP AND WATER AFTER HANDLING. HARMFUL IF SWALLOWED. REMOVE
CONTAMINATED CLOTHING AND WASH CLOTHING BEFORE REUSE.
FIRST AID INFORMATION:
IF IN EYES:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING EYE.
IF ON SKIN OR CLOTHING:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES.
IF SWALLOWED:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
HAVE PERSON SIP A GLASS OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING
UNLESS TOLD TO DO SO BY THE POISON CONTROL CENTER OR DOCTOR. DO NOT GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A POISON CONTROL CENTER
OR DOCTOR FOR TREATMENT ADVICE. HAVE THE PRODUCT CONTAINER OR LABEL WITH
YOU WHEN CALLING A POISON CONTROL CENTER OR DOCTOR OR GOING FOR TREATMENT.
NOTE TO PHYSICIAN:
PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
MEASURES AGAINST CIRCULATORY SHOCK, RESPIRATORY DEPRESSION AND CONVULSION
MAY BE NEEDED.
ENVIRONMENTAL HAZARDS:
THIS PESTICIDE IS TOXIC TO FISH. DO NOT APPLY IN MARINE AND/OR ESTUARINE
OIL FIELDS.
PHYSICAL/CHEMICAL HAZARDS:
THIS PESTICIDE IS A CATIONIC GERMICIDE. DO NOT MIX WITH SOAP OR ANIONIC
MATERIALS. DO NOT USE OR STORE NEAR HEAT OR FLAME.
STORAGE AND DISPOSAL:
DO NOT CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR DISPOSAL.
PESTICIDE STORAGE:
OPEN DUMPING IS PROHIBITED. STORE IN ORIGINAL CONTAINER IN AREAS
INACCESSIBLE TO CHILDREN.
PESTICIDE DISPOSAL:
PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER DISPOSAL OF EXCESS
PESTICIDE, SPRAY MIXTURE OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF
THESE WASTES CANNOT BE DISPOSED OF BY USE ACCORDING TO LABEL INSTRUCTIONS,
CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE
HAZARDOUS WASTE REPRESENTATIVE AT THE NEAREST EPA REGIONAL OFFICE FOR
GUIDANCE.
CONTAINER DISPOSAL:
NONREFILLABLE CONTAINER. DO NOT REUSE OR REFILL THIS CONTAINER. WRAP EMPTY
CONTAINER AND PUT IN TRASH.
15.2. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
METHYL ALCOHOL 67-56-1 DEVELOPMENTAL TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
JAPAN CHEMICAL SUBSTANCE CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 06-6875-6
VERSION NUMBER: 22.02
ISSUE DATE: 05/28/15
SUPERCEDES DATE: 03/24/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM