| Common Name: | DEODORIZER - MOUNTAIN SPICE - CONCENTRATE (PRODUCT NO. 14, TWIST 'N FILL SYSTEM) |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/21/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2BW60 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) DEODORIZER - MOUNTAIN SPICE - CONCENTRATE (PRODUCT NO. 14,
TWIST'N FILL(TM) SYSTEM)
05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT,2018,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 06-8476-1
VERSION NUMBER: 20.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 07/13/17
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) DEODORIZER - MOUNTAIN SPICE - CONCENTRATE (PRODUCT NO. 14, TWIST'N
FILL(TM) SYSTEM)
PRODUCT IDENTIFICATION NUMBERS:
61-0000-6337-2, 70-0708-4014-8, 70-0716-6114-7, 70-0716-8288-7
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
DEODORIZER, LONG-LASTING DEODORIZER LEAVES A FRAGRANT, SPICY SCENT.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS: EXCLAMATION MARK
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR EYE/FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
53% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYALKOXY ALCOHOLS 69013-18-9 30 - 60 TRADE SECRET*
SORBITAN POLYETHOXY MONOLAURATE 9005-64-5 10 - 30 TRADE SECRET*
WATER 7732-18-5 10 - 30 TRADE SECRET*
CINNAMIC ALDEHYDE 104-55-2 1 - 5 TRADE SECRET*
EUCALYPTUS OIL 8000-48-4 1 - 5 TRADE SECRET*
1-METHOXY-2-PROPANOL 107-98-2 1 - 5 TRADE SECRET*
4-ALLYL-2-METHOXYPHENOL 97-53-0 0.1 - 1.5 TRADE SECRET*
TRANS-3,7-DIMETHYL-2,6-OCTADIENOL 106-24-1 0.1 - 1.5 TRADE SECRET*
TERPENES AND TERPENOIDS, SWEET 68647-72-3 0.1 - 1.5 TRADE SECRET*
ORANGE-OIL
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED
TO KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH WATER. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. THIS PRODUCT IS NOT INTENDED TO
BE USED WITHOUT PRIOR DILUTION AS SPECIFIED ON THE PRODUCT LABEL.
GROUNDING OR SAFETY SHOES WITH ELECTROSTATIC DISSIPATING SOLES (ESD) ARE
NOT REQUIRED WITH A CHEMICAL DISPENSING SYSTEM. KEEP OUT OF REACH OF
CHILDREN. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT.
WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING
AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
1-METHOXY-2-PROPANOL 107-98-2 ACGIH TWA: 50 PPM A4:
STEL: 100 PPM NOT CLASS.
AS HUMAN
CARCIN
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF THE PRODUCT IS NOT USED WITH
A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE, WEAR
PROTECTIVE EYE/FACE PROTECTION. SELECT AND USE EYE/FACE PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY
AND DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER
USE CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING
MANUFACTURER FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE
CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL
FOR EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF
AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - NITRILE
RESPIRATORY PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: STRONG SPICY ODOR GREEN LIQUID
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 6.5 - 8.5
MELTING POINT: NOT APPLICABLE
BOILING POINT: APPROXIMATELY 200 DEG. F
FLASH POINT: >200 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.019 - 1.039 G/ML
SPECIFIC GRAVITY: 1.019 - 1.039 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 26 - 38 SEC
VOLATILE ORGANIC COMPOUNDS:
1 - 5% [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOC LESS H2O & EXEMPT SOLVENTS:
25 - 35 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
SORBITAN POLYETHOXY DERMAL LD50 ESTIMATED TO BE
MONOLAURATE >5,000 MG/KG
SORBITAN POLYETHOXY INGESTION RAT LD50: 40,600 MG/KG
MONOLAURATE
EUCALYPTUS OIL DERMAL LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
CINNAMIC ALDEHYDE DERMAL RABBIT LD50: >2,000 MG/KG
CINNAMIC ALDEHYDE INGESTION RAT LD50: 2,200 MG/KG
EUCALYPTUS OIL INGESTION RAT LD50: 2,480 MG/KG
1-METHOXY-2-PROPANOL DERMAL RABBIT LD50:
11,000-13,800 MG/KG
1-METHOXY-2-PROPANOL INHALATION- RAT LC50: 56 MG/L
VAPOR
(4 HOURS)
1-METHOXY-2-PROPANOL INGESTION RAT LD50: 6,100 MG/KG
4-ALLYL-2-METHOXYPHENOL DERMAL LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
4-ALLYL-2-METHOXYPHENOL INGESTION LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
TERPENES AND TERPENOIDS, INHALATION- MOUSE LC50 >3.14 MG/L
SWEET ORANGE-OIL VAPOR
(4 HOURS)
TERPENES AND TERPENOIDS, DERMAL RABBIT LD50: >5,000 MG/KG
SWEET ORANGE-OIL
TRANS-3,7-DIMETHYL- DERMAL RABBIT LD50: >5,000 MG/KG
2,6-OCTADIENOL
4-ALLYL-2-METHOXYPHENOL INHALATION- RAT LC50: >2.58 MG/L
DUST/MIST
(4 HOURS)
TERPENES AND TERPENOIDS, INGESTION RAT LD50: 4,400 MG/KG
SWEET ORANGE-OIL
TRANS-3,7-DIMETHYL- INGESTION RAT LD50: 3,600 MG/KG
2,6-OCTADIENOL
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT MINIMAL IRRITATION
CINNAMIC ALDEHYDE HUMAN MILD IRRITANT
EUCALYPTUS OIL NOT AVAILABLE MINIMAL IRRITATION
1-METHOXY-2-PROPANOL NOT AVAILABLE MINIMAL IRRITATION
4-ALLYL-2-METHOXYPHENOL PROFESSIONAL MINIMAL IRRITATION
JUDGMENT
TERPENES AND TERPENOIDS, RABBIT MILD IRRITANT
SWEET ORANGE-OIL
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT SEVERE IRRITANT
CINNAMIC ALDEHYDE HUMAN MODERATE IRRITANT
EUCALYPTUS OIL NOT AVAILABLE MILD IRRITANT
1-METHOXY-2-PROPANOL NOT AVAILABLE MILD IRRITANT
4-ALLYL-2-METHOXYPHENOL PROFESSIONAL MILD IRRITANT
JUDGMENT
TERPENES AND TERPENOIDS, RABBIT MILD IRRITANT
SWEET ORANGE-OIL
SKIN SENSITIZATION:
NAME SPECIES VALUE
CINNAMIC ALDEHYDE HUMAN AND SENSITIZING
ANIMAL
EUCALYPTUS OIL HUMAN NOT CLASSIFIED
1-METHOXY-2-PROPANOL GUINEA PIG NOT CLASSIFIED
4-ALLYL-2-METHOXYPHENOL MULTIPLE SENSITIZING
ANIMAL
SPECIES
TERPENES AND TERPENOIDS, MOUSE SENSITIZING
SWEET ORANGE-OIL
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
CTNNAMIC ALDEHYDE IN VIVO NOT MUTAGENIC
CINNAMIC ALDEHYDE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1-METHOXY-2-PROPANOL IN VITRO NOT MUTAGENIC
4-ALLYL-2-METHOXYPHENOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TERPENES AND TERPENOIDS, IN VITRO NOT MUTAGENIC
SWEET ORANGE-OIL
TERPENES AND TERPENOIDS, IN VIVO NOT MUTAGENIC
SWEET ORANGE-OIL
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
1-METHOXY-2-PROPANOL INHALATION MULTIPLE SOME POSITIVE DATA
ANIMAL EXIST, BUT THE DATA
SPECIES ARE NOT SUFFICIENT
FOR CLASSIFICATION
4-ALLYL-2-METHOXYPHENOL INGESTION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TERPENES AND TERPENOIDS, INGESTION RAT SOME POSITIVE DATA
SWEET ORANGE-OIL EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
CINNAMIC ALDEHYDE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
1-METHOXY-2-PROPANOL INHALATION NOT CLASSIFIED FOR MALE
REPRODUCTION
1-METHOXY-2-PROPANOL INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
1-METHOXY-2-PROPANOL INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
1-METHOXY-2-PROPANOL INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
1-METHOXY-2-PROPANOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
1-METHOXY-2-PROPANOL INHALATION NOT CLASSIFIED FOR DEVELOPMENT
TERPENES AND TERPENOIDS, INGESTION NOT CLASSIFIED FOR FEMALE
SWEET ORANGE-OIL REPRODUCTION
TERPENES AND TERPENOIDS, INGESTION NOT CLASSIFIED FOR DEVELOPMENT
SWEET ORANGE-OIL
NAME SPECIES TEST RESULT EXPOSURE DURATION
CINNAMIC ALDEHYDE RAT NOAEL: DURING
250 MG/KG/DAY ORGANOGENESIS
1-METHOXY-2-PROPANOL RAT NOAEL: 11 MG/L 2 GENERATION
1-METHOXY-2-PROPANOL MOUSE NOAEL: 2 GENERATION
3,328 MG/KG/DAY
1-METHOXY-2-PROPANOL RAT NOAEL: 3.7 MG/L 2 GENERATION
1-METHOXY-2-PROPANOL MOUSE NOAEL: 2 GENERATION
3,328 MG/KG
1-METHOXY-2-PROPANOL RAT NOAEL: DURING GESTATION
370 MG/KG
1-METHOXY-2-PROPANOL RAT NOAEL: 3.7 MGL 2 GENERATION
TERPENES AND TERPENOIDS, RAT NOAEL: PREMATING &
SWEET ORANGE-OIL 750 MG/KG/DAY DURING GESTATION
TERPENES AND TERPENOIDS, MULTIPLE NOAEL: DURING
SWEET ORANGE-OIL ANIMAL 591 MG/KG/DAY ORGANOGENESIS
SPECIES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
EUCALYPTUS OIL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
EUCALYPTUS OIL INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
EUCALYPTUS OIL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
1-METHOXY-2-PROPANOL DERMAL CENTRAL NERVOUS NOT CLASSIFIED
SYSTEM DEPRESSION
1-METHOXY-2-PROPANOL INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
TERPENES AND INGESTION NERVOUS SYSTEM NOT CLASSIFIED
TERPENOIDS, SWEET
ORANGE-OIL
NAME SPECIES TEST RESULT EXPOSURE DURATION
EUCALYPTUS OIL HUMAN NOAEL: ENVIRONMENTAL
NOT AVAILABLE EXPOSURE
EUCALYPTUS OIL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
EUCALYPTUS OIL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
1-METHOXY-2-PROPANOL RABBIT NOAEL: 13 WEEKS
1,800 MG/KG
1-METHOXY-2-PROPANOL HUMAN NOAEL:
NOT AVAILABLE
TERPENES AND TERPENOIDS, NOAEL:
SWEET ORANGE-OIL NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CINNAMIC ALDEHYDE INGESTION LIVER NOT CLASSIFIED
CINNAMIC ALDEHYDE INGESTION BLOOD NOT CLASSIFIED
CINNAMIC ALDEHYDE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
1-METHOXY-2-PROPANOL DERMAL KIDNEY AND/OR NOT CLASSIFIED
BLADDER
1-METHOXY-2-PROPANOL DERMAL HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
1-METHOXY-2-PROPANOL INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
1-METHOXY-2-PROPANOL INHALATION LIVER NOT CLASSIFIED
1-METHOXY-2-PROPANOL INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
1-METHOXY-2-PROPANOL INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
1-METHOXY-2-PROPANOL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
4-ALLYL- INGESTION LIVER NOT CLASSIFIED
2-METHOXYPHENOL
4-ALLYL- INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
2-METHOXYPHENOL
4-ALLYL- INGESTION BLOOD NOT CLASSIFIED
2-METHOXYPHENOL
TERPENES AND INGESTION KIDNEY AND/OR NOT CLASSIFIED
TERPENOIDS, SWEET BLADDER
ORANGE-OIL
TERPENES AND INGESTION LIVER NOT CLASSIFIED
TERPENOIDS, SWEET
ORANGE-OIL
TERPENES AND INGESTION HEART NOT CLASSIFIED
TERPENOIDS, SWEET ENDOCRINE SYSTEM
ORANGE-OIL BONE, TEETH,
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
RESPIRATORY
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
CINNAMIC ALDEHYDE RAT NOAEL: 16 WEEKS
500 MG/KG/DAY
CINNAMIC ALDEHYDE RAT NOAEL: 13 WEEKS
5,000 MG/KG/DAY
CINNAMIC ALDEHYDE RAT NOAEL: 12 WEEKS
227 MG/KG/DAY
1-METHOXY-2-PROPANOL RABBIT NOAEL: 13 WEEKS
1,800 MG/KG/DAY
1-METHOXY-2-PROPANOL RABBIT NOAEL: 3 WEEKS
1,000 MG/KG/DAY
1-METHOXY-2-PROPANOL RAT NOAEL: 3.7 MG/L 13 WEEKS
1-METHOXY-2-PROPANOL RAT NOAEL: 11 MG/L 13 WEEKS
1-METHOXY-2-PROPANOL RAT NOAEL: 2.2 MG/L 10 DAYS
1-METHOXY-2-PROPANOL RAT NOAEL: 13 WEEKS
920 MG/KG/DAY
1-METHOXY-2-PROPANOL RAT NOAEL: 13 WEEKS
920 MG/KG/DAY
4-ALLYL-2-METHOXYPHENOL RAT NOAEL: 4 DAYS
900 MG/KG/DAY
4-ALLYL-2-METHOXYPHENOL RAT LOAEL: 34 DAYS
1,400 MG/KG
4-ALLYL-2-METHOXYPHENOL RAT NOAEL: 19 WEEKS
500 MG/KG/DAY
TERPENES AND TERPENOIDS, RAT LOAEL: 103 WEEKS
SWEET ORANGE-OIL 75 MG/KG/DAY
TERPENES AND TERPENOIDS, MOUSE NOAEL: 103 WEEKS
SWEETORANGE-OIL 1,000 MG/KG/DAY
TERPENES AND TERPENOIDS, RAT NOAEL: 103 WEEKS
SWEET ORANGE-OIL 600 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
EUCALYPTUS OIL SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TERPENES AND TERPENOIDS, SWEET ORANGE-OIL ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS: SERIOUS EYE DAMAGE OR EYE IRRITATION
15.2. STATE REGULATIONS:
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
JAPAN CHEMICAL SUBSTANCE CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
THIS PRODUCT COMPLIES WITH THE NEW ZEALAND HAZARDOUS SUBSTANCES AND NEW
ORGANISMS ACT (1996).
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 06-8476-1
VERSION NUMBER: 20.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 07/13/17
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