| Common Name: | STRUST SSPR 6PK MULTI-TEX RUSTIC UMBER, 239122 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 5/15/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2CEF8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 5/15/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: STRUST SSPR 6PK MULTI-TEX RUSTIC UMBER
PRODUCT IDENTIFIER: 239122
PRODUCT USE/CLASS: TOPCOAT/AEROSOLS
REVISION DATE: 5/15/2015
SUPERCEDES DATE: NEW SDS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY
CAUSE FLASH FIRE OR EXPLOSION. CONTENTS UNDER PRESSURE. HARMFUL IF INHALED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR
NAUSEA. MAY CAUSE EYE, SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP OUT OF
REACH OF CHILDREN. HARMFUL IF INHALED. CAUSES EYE IRRITATION. USE
VENTILATION NECESSARY TO KEEP EXPOSURES BELOW RECOMMENDED EXPOSURE LIMITS,
IF ANY. VAPOR HARMFUL. CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION.
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
FLAME
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
71% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY
GHS HAZARD STATEMENTS:
FLAMMABLE AEROSOL, CATEGORY 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
FLAMMABLE LIQUID, CATEGORY 1:
H224: EXTREMELY FLAMMABLE LIQUID AND VAPOR.
ACUTE TOXICITY, ORAL, CATEGORY 5:
H303: MAY BE HARMFUL IF SWALLOWED.
ACUTE TOXICITY, DERMAL, CATEGORY 5:
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ASPIRATION HAZARD, CATEGORY 2:
H305: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
FLAMMABLE AEROSOL, CATEGORY 1:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
GHS LABEL PRECAUTIONARY STATEMENTS:
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P375: FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH ... THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P374: FIGHT FIRE WITH NORMAL PRECAUTIONS FROM A REASONABLE DISTANCE.
P402: STORE IN A DRY PLACE.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P350: GENTLY WASH WITH PLENTY OF SOAP AND WATER.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
ACETONE 67-64-1 25-50 GHS02-GHS07 H225-336-319
PROPANE 74-98-6 10-25
N-BUTYL ACETATE 123-86-4 10-25 GHS02-GHS07 H225-336
HYDROUS MAGNESIUM 14807-96-6 2.5-10
SILICATE
N-BUTANE 106-97-8 2.5-10
XYLENE (MIXED 1330-20-7 2.5-10 GHS02-GHS07 H226-312-332-
ISOMERS) 315
ETHYLBENZENE 100-41-4 1.0-2.5 GHS02-GHS07 H225-332
CALCIUM CARBONATE 471-34-1 1.0-2.5
CARBON BLACK 1333-86-4 0.1-1.0 GHS02 H251
TITANIUM DIOXIDE 13463-67-7 0.1-1.0
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"16. OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY. REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL
ATTENTION. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS LESS THAN 20 DEG. F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. KEEP CONTAINERS TIGHTLY
CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME.
PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN.
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. FULL PROTECTIVE
EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED.
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS. ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND
UNPROTECTED PERSONNEL. VENTILATE AREA, ISOLATE SPILLED MATERIAL, AND REMOVE
WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY IN A
WELL-VENTILATED AREA. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING FUMES, VAPORS, OR MIST. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES,
SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE
120 DEG. F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR
STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT
EXPOSE TO HEAT OR STORE ABOVE 120 DEG. F. PRODUCT SHOULD BE STORED IN
TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
ACETONE 67-64-1 30.0
PROPANE 74-98-6 20.0
N-BUTYL ACETATE 123-86-4 15.0
HYDROUS MAGNESIUM SILICATE 14807-96-6 10.0
N-BUTANE 106-97-8 10.0
XYLENE (MIXED ISOMERS) 1330-20-7 10.0
ETHYLBENZENE 100-41-4 5.0
CALCIUM CARBONATE 471-34-1 5.0
CARBON BLACK 1333-86-4 1.0
TITANIUM DIOXIDE 13463-67-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
ACETONE 500 PPM 750 PPM 1000 PPM N.E.
PROPANE 1000 PPM N.E. 1000 PPM N.E.
N-BUTYL ACETATE 150 PPM 200 PPM 150 PPM N.E.
HYDROUS MAGNESIUM 2 MG/M3 N.E. 20 MPPCF N.E.
SILICATE (RESPIRABLE (MINERAL
DUST) DUST <1%
QUARTZ)
N-BUTANE 1000 PPM 1000 PPM N.E. N.E.
XYLENE (MIXED ISOMERS) 100 PPM 150 PPM 100 PPM N.E.
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
CALCIUM CARBONATE 10 MG/M3 N.E. 15 MG/M3 N.E.
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
(TOTAL DUST) [TOTAL
DUST]
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE
EXPLOSION-PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF VAPORS BY
OPENING ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION. PROVIDE GENERAL
DILUTION OF LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP TLV OF
HAZARDOUS INGREDIENTS BELOW ACCEPTABLE LIMITS.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOLIZED MIST
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 0.801
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT, N-OCTANOL/WATER: NO INFORMATION
DECOMPOSITION TEMP., DEG. C: NO INFORMATION
BOILING RANGE, DEG. C: -11 - 999
EXPLOSIVE LIMITS, VOL%: 0.7 - 13.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: -105
EVAPORATION RATE: FASTER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: NO INFORMATION
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION. AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS SOLVENTS
WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT
MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN IRRITATION. ALLERGIC REACTIONS
ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH
VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
PROLONGED OR EXCESSIVE INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. HARMFUL
IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG
FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY
EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON
BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN
OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR
CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH
EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. MAY CAUSE CENTRAL
NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS OF COORDINATION,
WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION) AND/OR DAMAGE.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH
CONCENTRATIONS MAY LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS,
DIZZINESS, NAUSEA, HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
74-98-6 PROPANE N.I. N.I. 658 MG/L RAT
123-86-4 N-BUTYL ACETATE N.I. >17600 MG/KG N.I.
RABBIT
1330-20-7 XYLENE (MIXED 4300 MG/KG N.I. 47635 MG/L
ISOMERS) RAT RAT
100-41-4 ETHYLBENZENE 3500 MG/KG 15354 MG/KG 17.2 MG/L
RAT RABBIT RAT
471-34-1 CALCIUM CARBONATE 6450 MG/KG N.I. N.I.
RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG N.I. N.I.
RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1950 1950 N.A.
PROPER SHIPPING PAINT PRODUCTS AEROSOLS AEROSOLS PAINT PRODUCTS
NAME IN LIMITED IN LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 2.1 2.1 N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, PRESSURE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
XYLENE (MIXED ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CHEMICAL NAME CAS-NO.
ETHYLBENZENE 100-41-4
CARBON BLACK 1333-86-4
TITANIUM DIOXIDE 13463-67-7
BENZENE 71-43-2
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CHEMICAL NAME CAS-NO.
N-METHYL 2-PYRROLIDONE 872-50-4
TOLUENE 108-88-3
BENZENE 71-43-2
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
CANADIAN WHMIS CLASS:
AB5
D2A
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 512
MSDS REVISION DATE: 5/15/2015
REASON FOR REVISION: NO INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H226: FLAMMABLE LIQUID AND VAPOUR.
H251:
SELF-HEATING: MAY CATCH FIRE.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS07: EXCLAMATION MARK
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AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
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