| Common Name: | REARVIEW MIRROR ADHESIVE, PN08752 |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/4/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2CTF2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) REARVIEW MIRROR ADHESIVE, PN08752
09/04/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-7693-0
ISSUE DATE: 09/04/15
VERSION NUMBER: 7.00
SUPERCEDES DATE: 11/03/14
PRODUCT IDENTIFIER: 3M(TM) REARVIEW MIRROR ADHESIVE, PN08752
ID NUMBER(S): 60-4550-5186-6, 60-4550-6899-3
RECOMMENDED USE: AUTOMOTIVE, REARVIEW MIRROR ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
07-7689-8, 07-7690-6
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) REARVIEW MIRROR ADHESIVE / ADHESIVE, P/N 08752; 3M(TM) HIGH BOND
REARVIEW MIRROR ADHESIVE / ADHESIVE, PN08749
11/03/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-7689-8
ISSUE DATE: 11/03/14
VERSION NUMBER: 8.00
SUPERCEDES DATE: 10/11/11
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) REARVIEW MIRROR ADHESIVE / ADHESIVE, P/N 08752; 3M(TM) HIGH BOND
REARVIEW MIRROR ADHESIVE / ADHESIVE, PN08749
PRODUCT IDENTIFICATION NUMBERS: LB-K000-1110-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, REAR VIEW MIRROR ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
ACUTE TOXICITY (DERMAL): CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HARMFUL IN CONTACT WITH SKIN.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
RESPIRATORY SYSTEM
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE: SKIN
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
21% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
58% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ALIPHATIC URETHANE ACRYLATE RESIN TRADE SECRET* 30 - 60 TRADE SECRET*
BISPHENOL A POLYETHYLENE GLYCOL 41637-38-1 10 - 30 TRADE SECRET*
DIETHER DIMETHACRYLATE
HYDROXYPROPYL METHACRYLATE 27813-02-1 7 - 20 TRADE SECRET*
1,6-HEXANEDIOL DIACRYLATE 13048-33-4 7 - 15 TRADE SECRET*
ISOBORNYL ACRYLATE 5888-33-5 7 - 13 TRADE SECRET*
ACRYLIC ACID 79-10-7 1 - 10 TRADE SECRET*
POLYESTER RESIN TRADE SECRET* 5 - 10 TRADE SECRET*
3-(TRIMETHOXYSILYL)PROPYL 2530-83-8 0.1 - 1 TRADE SECRET*
GLYCIDYL ETHER
CUMENE HYDROPEROXIDE 80-15-9 0.1 - 1 TRADE SECRET*
SACCHARIN 81-07-2 0.1 - 1 TRADE SECRET*
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 0.1 - 1 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION.
WASH CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS OF THIS SDS FOR
INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION,
VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR.
READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
1,6-HEXANEDIOL 13048-33-4 AIHA TWA: DERMAL
DIACRYLATE 1 MG/M3 SENSITIZER
(0.11 PPM)
3-(TRIMETHOXYSILYL) 2530-83-8 CMRG TWA: 5 PPM
PROPYL GLYCIDYL
ETHER
HYDROXYPROPYL 27813-02-1 CMRG CEIL: 3 PPM
METHACRYLATE
ACRYLIC ACID 79-10-7 MANUFACTURER STEL:
DETERMINED 5 PPM
(15 MG/M3)
ACRYLIC ACID 79-10-7 ACGIH TWA: 2 PPM A4:
NOT CLASS. AS
HUMAN CARCIN,
SKIN NOTATION
CUMENE 80-15-9 AIHA TWA: SKIN NOTATION
HYDROPEROXIDE 6 MG/M3
(1 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: YELLOW LIQUID, SHARP ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >=300 DEG. F [@ 760 MMHG]
FLASH POINT >=200 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: >=5.0 MMHg [DETAILS: CONDITIONS: @ 75 F.]
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.1 G/ML
SPECIFIC GRAVITY: 1.1 [REF STD: WATER=1]
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 1.08 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
21.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
232 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
PERCENT VOLATILE: 21.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
232 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
AMINES
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE TARGET ORGAN EFFECTS AFTER INHALATION.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
MAY CAUSE TARGET ORGAN EFFECTS AFTER SKIN CONTACT.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
TARGET ORGAN EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
DERMAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, ITCHING, ACNE, OR BUMPS ON THE SKIN.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE
1,000 - 2,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
>5,000 MG/KG
BISPHENOL A INGESTION RAT LD50: >2,000 MG/KG
POLYETHYLENE GLYCOL
DIETHER DIMETHACRYLATE
1,6-HEXANEDIOL DERMAL RABBIT LD50: 3,636 MG/KG
DIACRYLATE
HYDROXYPROPYL DERMAL RABBIT LD50: >5,000 MG/KG
METHACRYLATE
1,6-HEXANEDIOL INGESTION RAT LD50: >5,000 MG/KG
DIACRYLATE
HYDROXYPROPYL INGESTION RAT LD50: 11,200 MG/KG
METHACRYLATE
ISOBORNYL ACRYLATE DERMAL RABBIT LD50: >5,000 MG/KG
ISOBORNYL ACRYLATE INGESTION RAT LD50: 4,350 MG/KG
ACRYLIC ACID DERMAL RABBIT LD50: 295 MG/KG
ACRYLIC ACID INHALATION- RAT LC50: 3.8 MG/L
DUST/MIST
(4 HOURS)
ACRYLIC ACID INGESTION RAT LD50: 1,250 MG/KG
1-ACETYL- DERMAL LD50 ESTIMATED TO BE:
2-PHENYLHYDRAZINE 200 - 1,000 MG/KG
1-ACETYL- INGESTION MOUSE LD50: 270 MG/KG
2-PHENYLHYDRAZINE
SACCHARIN INGESTION MOUSE LD50: 17,000 MG/KG
3-(TRIMETHOXYSILYL) DERMAL RABBIT LD50: 4,000 MG/KG
PROPYL GLYCIDYL ETHER
3-(TRIMETHOXYSILYL) INHALATION- RAT LC50: >5.3 MG/L
PROPYL GLYCIDYL ETHER DUST/MIST
(4 HOURS)
3-(TRIMETHOXYSILYL) INGESTION RAT LD50: 7,010 MG/KG
PROPYL GLYCIDYL ETHER
CUMENE HYDROPEROXIDE DERMAL RAT LD50: 500 MG/KG
CUMENE HYDROPEROXIDE INHALATION- RAT LC50: 1.4 MG/L
VAPOR
(4 HOURS)
CUMENE HYDROPEROXIDE INGESTION RAT LD50: 382 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
1,6-HEXANEDIOL DIACRYLATE RABBIT IRRITANT
ISOBORNYL ACRYLATE RABBIT MINIMAL IRRITATION
ACRYLIC ACID RABBIT CORROSIVE
3-(TRIMETHOXYSILYL)PROPYL RABBIT MILD IRRITANT
GLYCIDYL ETHER
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
1,6-HEXANEDIOL DIACRYLATE RABBIT MODERATE IRRITANT
ISOBORNYL ACRYLATE RABBIT MILD IRRITANT
ACRYLIC ACID RABBIT CORROSIVE
3-(TRIMETHOXYSILYL)PROPYL RABBIT CORROSIVE
GLYCIDYL ETHER
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
BISPHENOL A POLYETHYLENE GLYCOL GUINEA PIG NOT SENSITIZING
DIETHER DIMETHACRYLATE
1,6-HEXANEDIOL DIACRYLATE GUINEA PIG SENSITIZING
ISOBORNYL ACRYLATE MOUSE SENSITIZING
ACRYLIC ACID GUINEA PIG SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL GUINEA PIG SOME POSITIVE DATA EXIST,
GLYCIDYL ETHER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
BISPHENOL A POLYETHYLENE GLYCOL IN VITRO NOT MUTAGENIC
DIETHER DIMETHACRYLATE
1,6-HEXANEDIOL DIACRYLATE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
ISOBORNYL ACRYLATE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
ACRYLIC ACID IN VIVO NOT MUTAGENIC
ACRYLIC ACID IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL IN VIVO NOT MUTAGENIC
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL IN VITRO SOME POSITIVE DATA EXIST,
GLYCIDYL ETHER BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
CUMENE HYDROPEROXIDE IN VIVO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
1,6-HEXANEDIOL DIACRYLATE DERMAL MOUSE NOT CARCINOGENIC
ACRYLIC ACID INGESTION RAT NOT CARCINOGENIC
ACRYLIC ACID DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL DERMAL MOUSE NOT CARCINOGENIC
GLYCIDYL ETHER
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
1,6-HEXANEDIOL DIACRYLATE NOT SPECIFIED NOT TOXIC TO DEVELOPMENT
ACRYLIC ACID INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
ACRYLIC ACID INGESTION NOT TOXIC TO MALE
REPRODUCTION
ACRYLIC ACID INHALATION NOT TOXIC TO DEVELOPMENT
ACRYLIC ACID INGESTION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT TOXIC TO FEMALE
GLYCIDYL ETHER REPRODUCTION
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT TOXIC TO MALE
GLYCIDYL ETHER REPRODUCTION
3-(TRIMETHOXYSILYL)PROPYL INGESTION SOME POSITIVE DEVELOPMENTAL
GLYCIDYL ETHER DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
1,6-HEXANEDIOL DIACRYLATE RAT NOAEL: DURING
750 MG/KG/DAY ORGANOGENESIS
ACRYLIC ACID RAT NOAEL: 2 GENERATION
460 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: 2 GENERATION
460 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: 1.1 MG/L DURING
ORGANOGENESIS
ACRYLIC ACID RAT NOAEL: 2 GENERATION
53 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: DURING
GLYCIDYL ETHER 3,000 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
1,6-HEXANEDIOL DIACRYLATE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOBORNYL ACRYLATE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACRYLIC ACID INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE HYDROPEROXIDE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
CUMENE HYDROPEROXIDE INHALATION RESPIRATORY MAY CAUSE
IRRITATION RESPIRATORY
NAME SPECIES TEST RESULT EXPOSURE
DURATION
1,6-HEXANEDIOL DIACRYLATE HUMAN NOAEL:
NOT AVAILABLE
ISOBORNYL ACRYLATE OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
ACRYLIC ACID HUMAN NOAEL:
NOT AVAILABLE
CUMENE HYDROPEROXIDE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
CUMENE HYDROPEROXIDE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
1,6-HEXANEDIOL DIACRYLATE DERMAL SKIN MAY CAUSE DAMAGE TO
ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
3-(TRIMETHOXYSILYL)PROPYL INGESTION HEART ALL DATA ARE
GLYCIDYL ETHER ENDOCRINE NEGATIVE
SYSTEM
BONE, TEETH
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
CUMENE HYDROPEROXIDE INHALATION NERVOUS SYSTEM CAUSES DAMAGE TO
RESPIRATORY ORGANS THROUGH
SYSTEM PROLONGED OR
REPEATED EXPOSURE
CUMENE HYDROPEROXIDE INHALATION HEART SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA
KIDNEY ARE NOT SUFFICIENT
AND/OR BLADDER FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
1,6-HEXANEDIOL DIACRYLATE MOUSE LOAEL: 80 WEEKS
70 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 28 DAYS
GLYCIDYL ETHER 1,000 MG/KG/DAY
CUMENE HYDROPEROXIDE RAT LOAEL: 0.2 MG/L 7 DAYS
CUMENE HYDROPEROXIDE RAT NOAEL: 0.03 MG/L 90 DAYS
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
IF NO OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ACRYLIC ACID 79-10-7 1 - 10
CUMENE HYDROPEROXIDE 80-15-9 0.1 - 1
SACCHARIN 81-07-2 0.1 - 1
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 2
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 07-7689-8
ISSUE DATE: 11/03/14
VERSION NUMBER: 8.00
SUPERCEDES DATE: 10/11/11
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) REARVIEW MIRROR ADHESIVE (PRIMER), PN08752; 3M(TM) HIGH BOND
REARVIEW MIRROR ADHESIVE (PRIMER), PN08749
10/06/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-7690-6
ISSUE DATE: 10/06/15
VERSION NUMBER: 7.00
SUPERCEDES DATE: 06/11/12
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) REARVIEW MIRROR ADHESIVE (PRIMER), PN08752; 3M(TM) HIGH BOND
REARVIEW MIRROR ADHESIVE (PRIMER), PN08749
PRODUCT IDENTIFICATION NUMBERS: LB-K000-1119-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, REAR VIEW MIRROR ADHESIVE - PRIMER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ISOPROPYL ALCOHOL 67-63-0 60 - 100 TRADE SECRET*
STODDARD SOLVENT 8052-41-3 1 - 5 TRADE SECRET*
CARBOXYLIC ACIDS, C3-10, 85737-14-0 <=1 TRADE SECRET*
COPPER(1+) SALTS, OXIDIZED
ORGANO COPPER COMPOUND 22221-10-9 <=1 TRADE SECRET*
NEODECANOIC ACID, COPPER(2+) 68084-48-0 <=1 TRADE SECRET*
SALT
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM DESIGNED FOR
USE ON SOLVENTS, SUCH AS ALCOHOLS AND ACETONE, THAT CAN DISSOLVE IN WATER.
AN AR - AFFF TYPE FOAM IS RECOMMENDED. WORKING FROM AROUND THE EDGES OF THE
SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE
INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS
DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL,
HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS
POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR
TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH DETERGENT
AND WATER. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGE. AVOID BREATHING DUST/FUME/GAS/MIST/
VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
AVOID RELEASE TO THE ENVIRONMENT. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW STATIC OR PROPERLY GROUNDED
SHOES. TO MINIMIZE THE RISK OF IGNITION, DETERMINE APPLICABLE ELECTRICAL
CLASSIFICATIONS FOR THE PROCESS USING THIS PRODUCT AND SELECT SPECIFIC
LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID FLAMMABLE VAPOR ACCUMULATION.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT IF THERE IS POTENTIAL FOR
STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS. STORE AWAY FROM
AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
COPPER COMPOUNDS 22221-10-9 ACGIH TWA
(AS Cu DUST
OR MIST): 1 MG/M3
TWA
(AS Cu, FUME):
0.2 MG/M3
ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA: 200 PPM A4:
STEL: 400 PPM NOT CLASS. AS
HUMAN CARCIN
ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:
980 MG/M3
(400 PPM)
COPPER COMPOUNDS 68084-48-0 ACGIH TWA(AS Cu DUST
OR MIST):
1 MG/M3
TWA(AS Cu, FUME):
0.2 MG/M3
STODDARD SOLVENT 8052-41-3 ACGIH TWA: 100 PPM
STODDARD SOLVENT 8052-41-3 OSHA TWA:
2900 MG/M3
(500 PPM)
COPPER COMPOUNDS 85737-14-0 ACGIH TWA(AS Cu DUST
OR MIST):
1 MG/M3
TWA(AS Cu, FUME):
0.2 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR LIQUID, MILD ORGANIC ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: 180 DEG. F
FLASH POINT: 53.0 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: 7.7
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): 2.0%
FLAMMABLE LIMITS(UEL): 12.0%
VAPOR PRESSURE: 32.0 MMHg [DETAILS: CONDITIONS: @ 68 F.]
DENSITY: 0.79 G/ML
SPECIFIC GRAVITY: 0.79 [REF STD: WATER=1]
SOLUBILITY IN WATER: 95 - 100%
SOLUBILITY IN WATER: MODERATE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 3 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: 0 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
783 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
99.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 98.51% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
783 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
AMINES
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE
>50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
ISOPROPYL ALCOHOL DERMAL RABBIT LD50: 12,870 MG/KG
ISOPROPYL ALCOHOL INHALATION- RAT LC50: 72.6 MG/L
VAPOR
(4 HOURS)
ISOPROPYL ALCOHOL INGESTION RAT LD50: 4,710 MG/KG
STODDARD SOLVENT INHALATION- LC50:
VAPOR ESTIMATED TO BE
20 - 50 MG/L
STODDARD SOLVENT DERMAL RABBIT LD50: >3,000 MG/KG
STODDARD SOLVENT INGESTION RAT LD50: >5,000 MG/KG
CARBOXYLIC ACIDS, C3-10, INGESTION LD50:
COPPER(1+) SALTS, ESTIMATED TO BE
OXIDIZED 300 - 2,000 MG/KG
NEODECANOIC ACID, INGESTION LD50:
COPPER(2+) SALT ESTIMATED TO BE
2,000 - 5,000 MG/KG
ORGANO COPPER COMPOUND INGESTION LD50:
ESTIMATED TO BE
300 - 2,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ISOPROPYL ALCOHOL MULTIPLE ANIMAL SPECIES NO SIGNIFICANT IRRITATION
STODDARD SOLVENT RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ISOPROPYL ALCOHOL RABBIT SEVERE IRRITANT
STODDARD SOLVENT RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
ISOPROPYL ALCOHOL GUINEA PIG NOT SENSITIZING
STODDARD SOLVENT GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ISOPROPYL ALCOHOL IN VITRO NOT MUTAGENIC
ISOPROPYL ALCOHOL IN VIVO NOT MUTAGENIC
STODDARD SOLVENT IN VIVO NOT MUTAGENIC
STODDARD SOLVENT IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ISOPROPYL ALCOHOL INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT INHALATION HUMAN SOME POSITIVE DATA EXIST, BUT
AND THE DATA ARE NOT SUFFICIENT
ANIMAL FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ISOPROPYL ALCOHOL INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
ISOPROPYL ALCOHOL INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
STODDARD SOLVENT INHALATION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
ISOPROPYL ALCOHOL RAT NOAEL: 400 MG/KG/DAY DURING
ORGANOGENESIS
ISOPROPYL ALCOHOL RAT LOAEL: 9 MG/L DURING
GESTATION
STODDARD SOLVENT RAT NOAEL: 2.4 MG/L DURING
ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ISOPROPYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ISOPROPYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOPROPYL ALCOHOL INHALATION AUDITORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOPROPYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
STODDARD SOLVENT INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
STODDARD SOLVENT INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
ISOPROPYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE
ISOPROPYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE
ISOPROPYL ALCOHOL GUINEA PIG NOAEL: 13.4 MG/L 24 HOURS
ISOPROPYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
STODDARD SOLVENT HUMAN NOAEL: NOT AVAILABLE
AND ANIMAL
STODDARD SOLVENT NOAEL: NOT AVAILABLE
STODDARD SOLVENT DOG NOAEL: 6.5 MG/L 4 HOURS
STODDARD SOLVENT PROFESSIONAL NOAEL: NOT AVAILABLE
JUDGEMENT
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ISOPROPYL ALCOHOL INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ISOPROPYL ALCOHOL INHALATION NERVOUS SYSTEM ALL DATA ARE NEGATIVE
ISOPROPYL ALCOHOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT INHALATION BONE, TEETH, ALL DATA ARE NEGATIVE
NAILS, AND/OR
HAIR
BLOOD
LIVER
MUSCLES
STODDARD SOLVENT INHALATION HEART ALL DATA ARE NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
ISOPROPYL ALCOHOL RAT NOAEL: 12.3 MG/L 24 MONTHS
ISOPROPYL ALCOHOL RAT NOAEL: 12 MG/L 13 WEEKS
ISOPROPYL ALCOHOL RAT NOAEL: 12 WEEKS
400 MG/KG/DAY
STODDARD SOLVENT RAT LOAEL: 4.6 MG/L 6 MONTHS
STODDARD SOLVENT RAT LOAEL: 1.9 MG/L 13 WEEKS
STODDARD SOLVENT MULTIPLE NOAEL: 0.6 MG/L 90 DAYS
ANIMAL
SPECIES
STODDARD SOLVENT RAT NOAEL: 5.6 MG/L 12 WEEKS
STODDARD SOLVENT MULTIPLE NOAEL: 1.3 MG/L 90 DAYS
ANIMAL
SPECIES
ASPIRATION HAZARD:
NAME VALUE
STODDARD SOLVENT ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 07-7690-6
ISSUE DATE: 10/06/15
VERSION NUMBER: 7.00
SUPERCEDES DATE: 06/11/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM