| Common Name: | BLUE CREAM HARDENER 05766 |
| Manufacturer: | 3M |
| SDS Revision Date: | 6/8/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2CTR1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) BLUE CREAM HARDENER 05766
06/08/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 28-0172-8
VERSION NUMBER: 6.03
ISSUE DATE: 06/08/18
SUPERCEDES DATE: 05/24/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) BLUE CREAM HARDENER 05766
PRODUCT IDENTIFICATION NUMBERS: 60-9800-3723-2
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
ORGANIC PEROXIDE: TYPE E.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1B.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
FLAME
EXCLAMATION MARK
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
HEATING MAY CAUSE A FIRE.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
KEEP AWAY FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
KEEP ONLY IN ORIGINAL CONTAINER.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
PROTECT FROM SUNLIGHT.
STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP COOL.
STORE AWAY FROM OTHER MATERIALS.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
8% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
BENZOYL PEROXIDE 94-36-0 30 - 60 TRADE SECRET *
BENZOIC ACID, C9-11-BRANCHED 131298-44-7 10 - 30 TRADE SECRET *
ALKYL ESTERS
WATER 7732-18-5 10 - 30 TRADE SECRET *
ZINC STEARATE 557-05-1 5 - 10 TRADE SECRET *
CALCIUM SULFATE 7778-18-9 3 - 7 TRADE SECRET *
OXIRANE, POLYMER WITH 9038-95-3 1 - 5 TRADE SECRET *
METHYLOXIRANE, MONOBUTYL ETHER
FERRIC AMMONIUM FERROCYANIDE 25869-00-5 <=1 TRADE SECRET *
FERRIC FERROCYANIDE 14038-43-8 <=1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
PART OF THE OXYGEN FOR COMBUSTION IS SUPPLIED BY THE PEROXIDE ITSELF.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING
TOOLS. PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE. SEAL THE CONTAINER. DISPOSE
OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO
NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE
ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
PROTECT FROM SUNLIGHT. STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP
COOL. KEEP ONLY IN ORIGINAL CONTAINER. STORE AWAY FROM OTHER MATERIALS.
KEEP/STORE AWAY FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
ZINC STEARATE 557-05-1 OSHA TWA (AS TOTAL DUST):
15 MG/M3
TWA (RESPIRABLE FRACTION):
5 MG/M3
CALCIUM 7778-18-9 ACGIH TWA (INHALABLE FRACTION):
SULFATE 10 MG/M3
CALCIUM 7778-18-9 OSHA TWA (AS TOTAL DUST):
SULFATE 15 MG/M3
TWA (RESPIRABLE FRACTION):
5 MG/M3
BENZOYL 94-36-0 ACGIH TWA: 5 MG/M3 A4:
PEROXIDE NOT CLASS.
AS HUMAN
CARCIN
BENZOYL 94-36-0 OSHA TWA: 5 MG/M3
PEROXIDE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
WEAR RESPIRATORY PROTECTION IF VENTILATION IS INADEQUATE TO PREVENT
OVEREXPOSURE. AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A
RESPIRATOR IS REQUIRED. IF A RESPIRATOR IS NEEDED, USE RESPIRATORS
AS PART OF A FULL RESPIRATORY PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES FOR QUESTIONS ABOUT SUITABILITY
FOR A SPECIFIC APPLICATION, CONSULT WITH YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BLUE PASTE WITH SLIGHT ESTER ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: 111 DEG. C [TEST METHOD: ESTIMATED]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS):
ORGANIC PEROXIDE: TYPE E.
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.2 G/ML
SPECIFIC GRAVITY: 1.2 [REF STD:WATER=1] [DETAILS:@ 25 C]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: 410 DEG. C [TEST METHOD.ESTIMATED]
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 70,000 CENTIPOISE - 150,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS:
0.0308 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
0% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS: 0 G/L [TESTMETHOD:CALCULATED SCAQMD RULE 443.1]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TESTMETHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: ACCELERATORS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MAY BE HARMFUL IN CONTACT WITH SKIN.
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON - PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE >12.5 MG/L
(4 HR)
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
>5,000 MG/KG
BENZOYL PEROXIDE DERMAL LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
BENZOYL PEROXIDE INHALATION- RAT LC50: >24.3 MG/L
DUST/MIST
(4 HOURS)
BENZOYL PEROXIDE INGESTION RAT LD50: >5,000 MG/KG
BENZOIC ACID, DERMAL RABBIT LD50: >2,000 MG/KG
C9-11-BRANCHED
ALKYL ESTERS
BENZOIC ACID, INHALATION- RAT LC50: >5 MG/L
C9-11-BRANCHED DUST/MIST
ALKYL ESTERS (4 HOURS)
BENZOIC ACID, INGESTION RAT LD50: >5,000 MG/KG
C9-11-BRANCHED
ALKYL ESTERS
ZINC STEARATE DERMAL RABBIT LD50: >2,000 MG/KG
ZINC STEARATE INHALATION- RAT LC50: >50 MG/L
DUST/MIST
(4 HOURS)
ZINC STEARATE INGESTION RAT LD50: >5,000 MG/KG
CALCIUM SULFATE DERMAL PROFESSIONAL LD50 ESTIMATED TO BE
JUDGMENT >5,000 MG/KG
CALCIUM SULFATE INGESTION RAT LD50: >5,000 MG/KG
OXIRANE, POLYMER DERMAL RABBIT LD50: >16,960 MG/KG
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER INHALATION- RAT LC50: >5 MG/L
WITH METHYLOXIRANE, DUST/MIST
MONOBUTYL ETHER (4 HOURS)
OXIRANE, POLYMER INGESTION RAT LD50: 4,240 MG/KG
WITH METHYLOXIRANE,
MONOBUTYL ETHER
FERRIC AMMONIUM DERMAL LD50 ESTIMATED TO BE
FERROCYANIDE >5,000 MG/KG
FERRIC FERROCYANIDE DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
FERRIC AMMONIUM INGESTION RAT LD50: >5,110 MG/KG
FERROCYANIDE
FERRIC FERROCYANIDE INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT MINIMAL IRRITATION
ZINC STEARATE RABBIT NO SIGNIFICANT IRRITATION
OXIRANE, POLYMER WITH RABBIT MINIMAL IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT SEVERE IRRITANT
ZINC STEARATE RABBIT NO SIGNIFICANT IRRITATION
OXIRANE, POLYMER WITH RABBIT NO SIGNIFICANT IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
SKIN SENSITIZATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE GUINEA SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
BENZOYL PEROXIDE IN VITRO NOT MUTAGENIC
BENZOYL PEROXIDE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
BENZOYL PEROXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
BENZOYL PEROXIDE DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
OXIRANE, POLYMER INGESTION RAT NOT CARCINOGENIC
WITH METHYLOXIRANE,
MONOBUTYL ETHER
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
BENZOYL PEROXIDE INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
BENZOYL PEROXIDE INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
BENZOYL PEROXIDE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
OXIRANE, POLYMER WITH INHALATION NOT CLASSIFIED FOR MALE REPRODUCTION
METHYLOXIRANE,
MONOBUTYL ETHER
NAME SPECIES TEST RESULT EXPOSURE DURATION
BENZOYL PEROXIDE RAT NOAEL: 1,000 MG/KG/DAY PREMATING & DURING
GESTATION
BENZOYL PEROXIDE RAT NOAEL: 500 MG/KG/DAY PREMATING & DURING
GESTATION
BENZOYL PEROXIDE RAT NOAEL: 500 MG/KG/DAY PREMATING & DURING
GESTATION
OXIRANE, POLYMER RAT NOAEL: 1 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER WITH INGESTION NERVOUS SYSTEM NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL
ETHER
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER WITH RAT NOAEL:
METHYLOXIRANE, MONOBUTYL NOT AVAILABLE
ETHER
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER WITH INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL HEMATOPOIETIC SYSTEM
ETHER LIVER
NERVOUS SYSTEM
OXIRANE, POLYMER WITH INHALATION KIDNEY AND/OR NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL BLADDER
ETHER
OXIRANE, POLYMER WITH INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH INHALATION HEART NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH INGESTION LIVER SOME POSITIVE
METHYLOXIRANE, MONOBUTYL KIDNEY AND/OR BLADDER DATA EXIST,
ETHER BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
OXIRANE, POLYMER WITH INGESTION HEMATOPOIETIC SYSTEM NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH INGESTION HEART NOT CLASSIFIED
METHYLOXIRANE, MONOBUTYL ENDOCRINE SYSTEM
ETHER RESPIRATORY SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER WITH RAT NOAEL: 1 MG/L 2 WEEKS
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH RAT NOAEL: 0.005 MG/L 2 WEEKS
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH RAT LOAEL: 0.001 MG/L 2 WEEKS
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH RAT NOAEL: 0.5 MG/L 2 WEEKS
METHYLOXIRANE, MONOBUTYL
ETHER
OXIRANE, POLYMER WITH RAT NOAEL: 90 DAYS
METHYLOXIRANE, MONOBUTYL 145 MG/KG/DAY
ETHER
OXIRANE, POLYMER WITH RAT NOAEL: 2 YEARS
METHYLOXIRANE, MONOBUTYL 500 MG/KG/DAY
ETHER
OXIRANE, POLYMER WITH RAT NOAEL: 90 DAYS
METHYLOXIRANE, MONOBUTYL 3,770 MG/KG/DAY
ETHER SYSTEM
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE
INCINERATION FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL
FUEL DURING INCINERATION PROCESSES.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: ORGANIC PEROXIDE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 5 - 10
BENZOYL PEROXIDE 94-36-0 TRADE SECRET 30 - 60
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS OXIDIZER
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 28-0172-8
VERSION NUMBER: 6.03
ISSUE DATE: 06/08/18
SUPERCEDES DATE: 05/24/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM