| Common Name: | HIGH PERFORMANCE INDUSTRIAL PLASTIC ADHESIVE 4693 |
| Manufacturer: | 3M |
| SDS Revision Date: | 6/25/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2GKL6, 56KA62 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) HIGH PERFORMANCE INDUSTRIAL PLASTIC ADHESIVE 4693
06/25/21
3M
SAFETY DATA SHEET
COPYRIGHT,2021, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 11-4283-5
VERSION NUMBER: 24.00
ISSUE DATE: 06/25/21
SUPERCEDES DATE: 06/25/21
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) HIGH PERFORMANCE INDUSTRIAL PLASTIC ADHESIVE 4693
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
62-4493-6530-3 00-21200-83759-3
62-4493-7530-2 00-21200-83760-9
62-4493-9530-0 00-21200-83762-3
62-4493-6535-2
62-4493-8530-1 00-21200-83761-1
7000046574, 7000121405, 7000046575, 7000000923, 7010310264
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, INDUSTRIAL USE
THIS CHEMICAL/PRODUCT IS NOT AND CANNOT BE DISTRIBUTED IN COMMERCE
(AS DEFINED IN TSCA SECTION 3(13)) FOR CONSUMER PAINT OR COATING REMOVAL.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
CARCINOGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
SENSORY ORGANS
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
CYCLOHEXANE 110-82-7 60 - 80 TRADE SECRET *
POLYTERPENE RESIN 31393-98-3 5 - 20 TRADE SECRET *
STYRENE-BUTADIENE POLYMER 9003-55-8 7 - 13 TRADE SECRET *
ACETONE 67-64-1 <3 TRADE SECRET *
METHYL ETHYL KETONE 78-93-3 <2 TRADE SECRET *
TOLUENE 108-88-3 <=2 TRADE SECRET *
METHYL ISBUTYL KETONE 108-10-1 <1 TRADE SECRET *
METHYLENE CHLORIDE 75-09-2 <0.01 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHE, DIZZINESS, DROWSINESS,
INCOORDINATION, NAUSEA, SLURRED SPEECH, GIDDINESS, AND UNCONSCIOUSNESS).
TARGET ORGAN EFFECTS FOLLOWING PROLONGED OR REPEATED EXPOSURE. SEE
SECTION 11 FOR ADDITIONAL DETAILS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. WORKING
FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX
IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING
TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND
SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE
IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL/OCCUPATIONAL USE ONLY. NOT FOR CONSUMER SALE OR USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP
AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW
STATIC OR PROPERLY GROUNDED SHOES. USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE THE RISK OF IGNITION,
DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS USING THIS
PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID
FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
IF THERE IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
METHYL ISBUTYL KETONE 108-10-1 ACGIH TWA: 20 PPM A3:
STEL: 75 PPM CONFIRMED
ANIMAL
CARCIN.
METHYL ISBUTYL KETONE 108-10-1 OSHA TWA:
410 MG/M3
(100 PPM)
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS.
AS HUMAN
CARCIN,
OTOTOXICANT
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
CYCLOHEXANE 110-82-7 ACGIH TWA: 100 PPM
CYCLOHEXANE 110-82-7 OSHA TWA:
1050 MG/M3
(300 PPM)
ACETONE 67-64-1 ACGIH TWA: 250 PPM A4:
STEL: 500 PPM NOT CLASS.
AS HUMAN
CARCIN
ACETONE 67-64-1 OSHA TWA:
2400 MG/M3
(1000 PPM)
METHYLENE CHLORIDE 75-09-2 ACGIH TWA: 50 PPM A3:
CONFIRMED
ANIMAL
CARCIN.
METHYLENE CHLORIDE 75-09-2 OSHA TWA: 25 PPM 29 CFR
STEL: 125 PPM 1910.1052,
SKIN
METHYL ETHYL KETONE 78-93-3 ACGIH TWA: 200 PPM
STEL: 300 PPM
METHYL ETHYL KETONE 78-93-3 OSHA TWA:
590 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYVINYL ALCOHOL (PVA)
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: LIQUID
COLOR: LIGHT AMBER
ODOR: SOLVENT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=81 DEG. C [DETAILS:CYCLOHEXANE]
FLASH POINT: -4 DEG. F [TEST METHOD:CLOSED CUP]
EVAPORATION RATE: >=2 [REF STD:WATER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 1.1% VOLUME
FLAMMABLE LIMITS (UEL): 8.0% VOLUME
VAPOR PRESSURE: <=95 MMHg [@ 68 DEG. F]
VAPOR DENSITY: 0.8 [REF STD:AIR=1]
DENSITY: 0.82 G/ML
SPECIFIC GRAVITY: 0.82 [REF STD:WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: 245 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 150 - 300 CENTIPOISE [@ 73.4 DEG. F ]
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD:CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
<=597 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
SOLIDS CONTENT: 20 - 40%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
REDUCING AGENTS
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT: MAY BE HARMFUL IN CONTACT WITH SKIN.
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
OLFACTORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE DECREASED ABILITY TO DETECT ODORS AND/OR
COMPLETE LOSS OF SMELL.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
METHYL ISBUTYL KETONE 108-10-1 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON
CARC. CANCER
METHYLENE CHLORIDE 75-09-2 GRP. 2A: INTERNATIONAL AGENCY
PROBABLE HUMAN FOR RESEARCH ON
CARC. CANCER
METHYLENE CHLORIDE 75-09-2 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
METHYLENE CHLORIDE 75-09-2 CANCER HAZARD OSHA CARCINOGENS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
CYCLOHEXANE DERMAL RAT LD50: >2,000 MG/KG
CYCLOHEXANE INHALATION- RAT LC50: >32.9 MG/L
VAPOR
(4 HOURS)
CYCLOHEXANE INGESTION RAT LD50: 6,200 MG/KG
POLYTERPENE RESIN DERMAL LD50 ESTIMATED TO
BE >5,000 MG/KG
POLYTERPENE RESIN INGESTION RAT LD50: >34,000 MG/KG
STYRENE-BUTADIENE POLYMER DERMAL RABBIT LD50: >2,000 MG/KG
STYRENE-BUTADIENE POLYMER INGESTION RAT LD50: >5,000 MG/KG
ACETONE DERMAL RABBIT LD50: >15,688 MG/KG
ACETONE INHALATION- RAT LC50: 76 MG/L
VAPOR
(4 HOURS)
ACETONE INGESTION RAT LD50: 5,800 MG/KG
METHYL ETHYL KETONE DERMAL RABBIT LD50: >8,050 MG/KG
METHYL ETHYL KETONE INHALATION- RAT LC50: 34.5 MG/L
VAPOR
(4 HOURS)
METHYL ETHYL KETONE INGESTION RAT LD50: 2,737 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
METHYL ISBUTYL KETONE DERMAL RABBIT LD50: >16,000 MG/KG
METHYL ISBUTYL KETONE INHALATION- RAT LC50:
VAPOR >8.2, <16.4 MG/L
(4 HOURS)
METHYL ISBUTYL KETONE INGESTION RAT LD50: 3,038 MG/KG
METHYLENE CHLORIDE DERMAL RAT LD50: >2,000 MG/KG
METHYLENE CHLORIDE INHALATION- RAT LC50: 63.7 MG/L
VAPOR
(4 HOURS)
METHYLENE CHLORIDE INGESTION RAT LD50: 1,410 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
CYCLOHEXANE RABBIT MILD IRRITANT
STYRENE-BUTADIENE POLYMER PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
ACETONE MOUSE MINIMAL IRRITATION
METHYL ETHYL KETONE RABBIT MINIMAL IRRITATION
TOLUENE RABBIT IRRITANT
METHYL ISBUTYL KETONE RABBIT MILD IRRITANT
METHYLENE CHLORIDE RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
CYCLOHEXANE RABBIT MILD IRRITANT
ACETONE RABBIT SEVERE IRRITANT
METHYL ETHYL KETONE RABBIT SEVERE IRRITANT
TOLUENE RABBIT MODERATE IRRITANT
METHYL ISBUTYL KETONE RABBIT MILD IRRITANT
METHYLENE CHLORIDE RABBIT SEVERE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
TOLUENE GUINEA PIG NOT CLASSIFIED
METHYL ISBUTYL KETONE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
CYCLOHEXANE IN VITRO NOT MUTAGENIC
CYCLOHEXANE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACETONE IN VIVO NOT MUTAGENIC
ACETONE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE IN VITRO NOT MUTAGENIC
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
METHYL ISBUTYL KETONE IN VITRO NOT MUTAGENIC
METHYLENE CHLORIDE IN VIVO NOT MUTAGENIC
METHYLENE CHLORIDE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ACETONE NOT SPECIFIED MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
METHYL ETHYL KETONE INHALATION HUMAN NOT CARCINOGENIC
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ISBUTYL KETONE INHALATION MULTIPLE CARCINOGENIC
ANIMAL
SPECIES
METHYLENE CHLORIDE INHALATION MULTIPLE CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR MALE
REPRODUCTION
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
ACETONE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
ACETONE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
METHYL ETHYL KETONE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
TOLUENE INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED FOR MALE
REPRODUCTION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
METHYL ISBUTYL KETONE INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
METHYL ISBUTYL KETONE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
METHYL ISBUTYL KETONE INHALATION NOT CLASSIFIED FOR MALE
REPRODUCTION
METHYL ISBUTYL KETONE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
METHYLENE CHLORIDE INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
METHYLENE CHLORIDE INHALATION NOT CLASSIFIED FOR MALE
REPRODUCTION
METHYLENE CHLORIDE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 6.9 MG/L 2 GENERATION
ACETONE RAT NOAEL: 13 WEEKS
1,700 MG/KG/DAY
ACETONE RAT NOAEL: 5.2 MG/L DURING
ORGANOGENESIS
METHYL ETHYL KETONE RAT LOAEL: 8.8 MG/L DURING GESTATION
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING GESTATION
520 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 8.2 MG/L 2 GENERATION
ANIMAL
SPECIES
METHYL ISBUTYL KETONE RAT NOAEL: 13 WEEKS
1,000 MG/KG/DAY
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 8.2 MG/L 2 GENERATION
ANIMAL
SPECIES
METHYL ISBUTYL KETONE MOUSE NOAEL: 12.3 MG/L DURING
ORGANOGENESIS
METHYLENE CHLORIDE RAT NOAEL: 5.2 MG/L 2 GENERATION
METHYLENE CHLORIDE RAT NOAEL: 5.2 MG/L 2 GENERATION
METHYLENE CHLORIDE MULTIPLE NOAEL: 4.3 MG/L DURING GESTATION
ANIMAL
SPECIES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CYCLOHEXANE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
CYCLOHEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
ACETONE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
ACETONE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION LIVER NOT CLASSIFIED
ACETONE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYL ETHYL KETONE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYL ETHYL KETONE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYL ETHYL KETONE INGESTION LIVER NOT CLASSIFIED
METHYL ETHYL KETONE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYL ISBUTYL INHALATION CENTRAL NERVOUS MAY CAUSE
KETONE SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYL ISBUTYL INHALATION RESPIRATORY MAY CAUSE
KETONE IRRITATION RESPIRATORY
IRRITATION
METHYL ISBUTYL INHALATION VASCULAR SYSTEM NOT CLASSIFIED
KETONE
METHYL ISBUTYL INGESTION CENTRAL NERVOUS MAY CAUSE
KETONE SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYLENE CHLORIDE DERMAL BLOOD SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
METHYLENE CHLORIDE INHALATION BLOOD SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
CYCLOHEXANE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
CYCLOHEXANE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
CYCLOHEXANE PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
ACETONE HUMAN NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL: 6 HOURS
1.19 MG/L
ACETONE GUINEA PIG NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ETHYL KETONE OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
METHYL ETHYL KETONE HUMAN NOAEL:
NOT AVAILABLE
METHYL ETHYL KETONE PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: NOT APPLICABLE
NOT AVAILABLE
METHYL ETHYL KETONE RAT LOAEL: NOT APPLICABLE
1,080 MG/KG
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ISBUTYL HUMAN LOAEL: 0.1 MG/L 2 HOURS
KETONE
METHYL ISBUTYL HUMAN NOAEL: 0.9 MG/L 7 MINUTES
KETONE
METHYL ISBUTYL DOG NOAEL: NOT AVAILABLE
KETONE NOT AVAILABLE
METHYL ISBUTYL RAT LOAEL: NOT APPLICABLE
KETONE 900 MG/KG
METHYLENE CHLORIDE RAT NOAEL: 4 HOURS
NOT AVAILABLE
METHYLENE CHLORIDE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
METHYLENE CHLORIDE HUMAN NOAEL:
NOT AVAILABLE
METHYLENE CHLORIDE NOAEL:
NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CYCLOHEXANE INHALATION LIVER NOT CLASSIFIED
CYCLOHEXANE INHALATION AUDITORY SYSTEM NOT CLASSIFIED
CYCLOHEXANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CYCLOHEXANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
CYCLOHEXANE INHALATION PERIPHERAL NOT CLASSIFIED
NERVOUS SYSTEM
ACETONE DERMAL EYES NOT CLASSIFIED
ACETONE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INHALATION HEART NOT CLASSIFIED
LIVER
ACETONE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INGESTION HEART NOT CLASSIFIED
ACETONE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INGESTION LIVER NOT CLASSIFIED
ACETONE INGESTION EYES NOT CLASSIFIED
ACETONE INGESTION RESPIRATORY NOT CLASSIFIED
SYSTEM
ACETONE INGESTION MUSCLES NOT CLASSIFIED
ACETONE INGESTION SKIN NOT CLASSIFIED
BONE, TEETH,
NAILS, AND/OR
HAIR
METHYL ETHYL KETONE DERMAL NERVOUS SYSTEM NOT CLASSIFIED
METHYL ETHYL KETONE INHALATION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
HEART
ENDOCRINE SYSTEM
GASTROINTESTINAL
TRACT
BONE, TEETH,
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
IMMUNE SYSTEM
MUSCLES
METHYL ETHYL KETONE INGESTION LIVER NOT CLASSIFIED
METHYL ETHYL KETONE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
EYES ORGANS THROUGH
OLFACTORY SYSTEM PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION NERVOUS SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR
HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
VASCULAR SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
METHYL ISBUTYL KETONE INHALATION LIVER NOT CLASSIFIED
METHYL ISBUTYL KETONE INHALATION HEART NOT CLASSIFIED
METHYL ISBUTYL KETONE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
METHYL ISBUTYL KETONE INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
METHYL ISBUTYL KETONE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM
METHYL ISBUTYL KETONE INHALATION NERVOUS SYSTEM NOT CLASSIFIED
METHYL ISBUTYL KETONE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM
LIVER
KIDNEY AND/OR
BLADDER
METHYL ISBUTYL KETONE INGESTION HEART NOT CLASSIFIED
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
RESPIRATORY
SYSTEM
METHYLENE CHLORIDE INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INHALATION HEART NOT CLASSIFIED
METHYLENE CHLORIDE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
METHYLENE CHLORIDE INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYLENE CHLORIDE INGESTION BLOOD NOT CLASSIFIED
METHYLENE CHLORIDE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
METHYLENE CHLORIDE INGESTION EYES NOT CLASSIFIED
NAME SPECIES TEST RESULT EXPOSURE DURATION
CYCLOHEXANE RAT NOAEL: 24 MG/L 90 DAYS
CYCLOHEXANE RAT NOAEL: 1.7 MG/L 90 DAYS
CYCLOHEXANE RABBIT NOAEL: 2.7 MG/L 10 WEEKS
CYCLOHEXANE MOUSE NOAEL: 24 MG/L 14 WEEKS
CYCLOHEXANE RAT NOAEL: 8.6 MG/L 30 WEEKS
ACETONE GUINEA NOAEL: 3 WEEKS
PIG NOT AVAILABLE
ACETONE HUMAN NOAEL: 3 MG/L 6 WEEKS
ACETONE HUMAN NOAEL: 1.19 MG/L 6 DAYS
ACETONE GUINEA NOAEL: 119 MG/L NOT AVAILABLE
PIG
ACETONE RAT NOAEL: 45 MG/L 8 WEEKS
ACETONE RAT NOAEL: 13 WEEKS
900 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
200 MG/KG/DAY
ACETONE MOUSE NOAEL: 14 DAYS
3,896 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
3,400 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG
ACETONE MOUSE NOAEL: 13 WEEKS
11,298 MG/KG/DAY
METHYL ETHYL KETONE GUINEA NOAEL: 31 WEEKS
PIG NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 14.7 MG/L 90 DAYS
METHYL ETHYL KETONE RAT NOAEL: 7 DAYS
NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
173 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE MULTIPLE NOAEL: 11.3 MG/L 15 WEEKS
ANIMAL
SPECIES
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
METHYL ISBUTYL KETONE RAT NOAEL: 0.41 MG/L 13 WEEKS
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 0.8 MG/L 2 WEEKS
ANIMAL
SPECIES
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 0.4 MG/L 90 DAYS
ANIMAL
SPECIES
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 4.1 MG/L 14 WEEKS
ANIMAL
SPECIES
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 0.41 MG/L 90 DAYS
ANIMAL
SPECIES
METHYL ISBUTYL KETONE MULTIPLE NOAEL: 0.41 MG/L 13 WEEKS
ANIMAL
SPECIES
METHYL ISBUTYL KETONE RAT NOAEL: 13 WEEKS
1,000 MG/KG/DAY
METHYL ISBUTYL KETONE RAT NOAEL: 120 DAYS
1,040 MG/KG/DAY
METHYLENE CHLORIDE RAT LOAEL: 6.95 MG/L 2 YEARS
METHYLENE CHLORIDE RAT NOAEL: 0.17 MG/L 2 YEARS
METHYLENE CHLORIDE MULTIPLE LOAEL: 35 MG/L 8 WEEKS
ANIMAL
SPECIES
METHYLENE CHLORIDE HUMAN NOAEL:
NOT AVAILABLE
METHYLENE CHLORIDE RAT NOAEL: 18 MG/L 28 DAYS
METHYLENE CHLORIDE RAT LOAEL: 3 MONTHS
1,200 MG/KG/DAY
METHYLENE CHLORIDE RAT NOAEL: 2 YEARS
249 MG/KG/DAY
METHYLENE CHLORIDE RAT NOAEL: 3 MONTHS
1,469 MG/KG/DAY
METHYLENE CHLORIDE RAT NOAEL: 104 WEEKS
249 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
CYCLOHEXANE ASPIRATION HAZARD
TOLUENE ASPIRATION HAZARD
METHYL ISBUTYL KETONE SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA):
D001 (IGNITABLE), D035 (METHYL ETHYL KETONE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARDS:
CARCINOGENICITY
REPRODUCTIVE TOXICITY
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CYCLOHEXANE 110-82-7 TRADE SECRET 60 - 80
TOLUENE 108-88-3 TRADE SECRET <=2
METHYL ISBUTYL KETONE 108-10-1 TRADE SECRET <1
THIS MATERIAL CONTAINS A CHEMICAL WHICH REQUIRES EXPORT NOTIFICATION UNDER
TSCA SECTION 12[B]:
INGREDIENT C.A.S. NO REGULATION STATUS
(CATEGORY IF APPLICABLE)
METHYLENE CHLORIDE 75-09-2 TOXIC SUBSTANCES APPLICABLE
CONTROL ACT (TSCA) 6
BANNED OR RESTRICTED
USE CHEMICALS
ADDITIONAL TSCA INFORMATION:
COMPONENTS CAS NO ADDITIONAL INFORMATION
METHYLENE CHLORIDE 75-09-2 THIS CHEMICAL/PRODUCT IS NOT AND
CANNOT BE DISTRIBUTED IN COMMERCE
(AS DEFINED IN TSCA SECTION 3(5))
OR PROCESSED (AS DEFINED IN TSCA
SECTION 3(13)) FOR CONSUMER PAINT
OR COATING REMOVAL.
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 11-4283-5
VERSION NUMBER: 24.00
ISSUE DATE: 06/25/21
SUPERCEDES DATE: 06/25/21
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M.
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM