| Common Name: | SCOTCH-WELD URETHANE ADHESIVE 3549 B/A AND SCOTCH-WELD URETHANE ADHESIVE DP640 |
| Manufacturer: | 3M |
| SDS Revision Date: | 6/21/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JBL4, 2JCC2, 489K03 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640
06/21/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 11-3173-9
VERSION NUMBER: 15.01
ISSUE DATE: 06/21/17
SUPERCEDES DATE: 04/25/17
PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640
ID NUMBER(S):
62-3549-0501-0, 62-3549-1430-1, 62-3549-1431-9, 62-3549-1435-0,
62-3549-1436-8, 62-3549-3530-6, 62-3549-3830-0, 62-3549-6401-7
RECOMMENDED USE: 2-PART URETHANE ADHESIVE, INDUSTRIAL USE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET. THE DOCUMENT NUMBERS FOR COMPONENTS OF
THIS PRODUCT ARE: 10-3187-1, 10-3186-3
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE3MPRODUCT IS FIT FOR
A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND APPLICATION OF A
3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S KNOWLEDGE AND
CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M PRODUCT TO DETERMINE
WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD
OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640, PART B
04/24/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3186-3
VERSION NUMBER: 28.00
ISSUE DATE: 04/24/17
SUPERCEDES DATE: 08/11/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640, PART B
PRODUCT IDENTIFICATION NUMBERS: 62-3549-8501-2
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYESTER RESIN (NJTS REG. NO. TRADE SECRET* 40 - 70 TRADE SECRET *
04499600-7133)
POLYPROPYLENE GLYCOL 25322-69-4 10 - 30 TRADE SECRET *
TALC 14807-96-6 10 - 30 TRADE SECRET *
POLYOXYPROPYLENE TRIOL 25723-16-4 1 - 10 TRADE SECRET *
ZEOLITES 1318-02-1 1 - 10 TRADE SECRET *
O-DIETHYLBISANILINE 13680-35-8 1 - 5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT: NO NEED FOR FIRST AID IS ANTICIPATED.
EYE CONTACT: NO NEED FOR FIRST AID IS ANTICIPATED.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH OXIDIZING AGENTS (EG.
CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
ALUMINUM, 1318-02-1 ACGIH TWA(RESPIRABLE A4:
INSOLUBLE FRACTION): NOT CLASS. AS HUMAN
COMPOUNDS 1 MG/M3 CARCIN
TALC 14807-96-6 OSHA TWA: 2 MG/M3
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4:
FRACTION): NOT CLASS. AS HUMAN
2 MG/M3 CARCIN
POLYPROPYLENE 25322-69-4 AIHA TWA(AS AEROSOL):
GLYCOL 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION: NONE REQUIRED.
SKIN/HAND PROTECTION: NO CHEMICAL PROTECTIVE GLOVES ARE REQUIRED.
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: OFF-WHITE, SLIGHT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >/=179 DEG. C
FLASH POINT: >/=354 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL); NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.31 G/ML
SPECIFIC GRAVITY: 1.31 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
10,000 - 40,000 CENTIPOISE [@ 73.4 DEG. F] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
6.78 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION: NO KNOWN HEALTH EFFECTS.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
POLYPROPYLENE GLYCOL DERMAL RABBIT LD50: >10,000 MG/KG
POLYPROPYLENE GLYCOL INGESTION RAT LD50: >2,000 MG/KG
TALC DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
TALC INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
POLYOXYPROPYLENE DERMAL RAT LD50: >2,000 MG/KG
TRIOL
POLYOXYPROPYLENE INGESTION RAT LD50: >2,500 MG/KG
TRIOL
ZEOLITES DERMAL RABBIT LD50: >2,000 MG/KG
ZEOLITES INHALATION- RAT LC50: >4.57 MG/L
DUST/MIST
(4 HOURS)
ZEOLITES INGESTION RAT LD50: >5,000 MG/KG
O-DIETHYLBISANILINE INGESTION RAT LD50: 1,901 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
POLYOXYPROPYLENE TRIOL RABBIT NO SIGNIFICANT IRRITATION
ZEOLITES RABBIT NO SIGNIFICANT IRRITATION
O-DIETHYLBISANILINE RABBIT MINIMAL IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
POLYOXYPROPYLENE TRIOL RABBIT MILD IRRITANT
ZEOLITES RABBIT MILD IRRITANT
O-DIETHYLBISANILINE RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
O-DIETHYLBISANILINE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE DURATION
TALC INGESTION NOT TOXIC TO RAT NOAEL: DURING ORGANOGENESIS
DEVELOPMENT 1,600 MG/KG
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET VALUE SPECIES TEST EXPOSURE
ORGAN(S) RESULT DURATION
TALC INHALATION PNEUMOCONI- CAUSES DAMAGE HUMAN NOAEL OCCUPATI-
OSIS TO ORGANS NOT ONAL
THROUGH AVAILABLE EXPOSURE
PROLONGED OR
REPEATED
EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE RAT NOAEL: 113 WEEKS
FIBROSIS | DATA EXIST, 18 MG/M3
RESPIRATORY BUT THE DATA
SYSTEM ARE NOT
SUFFICIENT
FOR
CLASSIFICA-
TION
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
EPCRA 311/312 HAZARD CLASSIFICATIONS (EFFECTIVE JANUARY 1, 2018):
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3186-3
VERSION NUMBER: 28.00
ISSUE DATE: 04/24/17
SUPERCEDES DATE: 08/11/15
REASON FOR REISSUE: CONVERSION TO GHS FORMAT SDS.
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THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
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TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR
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3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
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INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640, PART A
04/24/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
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WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3187-1
VERSION NUMBER: 26.00
ISSUE DATE: 04/24/17
SUPERCEDES DATE: 04/16/15
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3549 B/A AND 3M(TM)
SCOTCH-WELD(TM) URETHANE ADHESIVE DP640, PART A
PRODUCT IDENTIFICATION NUMBERS: 62-3649-8501-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
ACCELERATOR FOR 2-PART POLYURETHANE ADHESIVE, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM |
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
URETHANE PREPOLYMER (NJTS TRADE SECRET* 15 - 40 TRADE SECRET *
REG. NO. 04499600-5770P)
HIGHER OLIGOMERS OF MDI 9016-87-9 10 - 30 TRADE SECRET *
P,P'-METHYLENEBIS(PHENYL 101-68-8 10 - 30 TRADE SECRET *
ISOCYANATE)
TALC 14807-96-6 10 - 30 TRADE SECRET *
DIPHENYLMETHANE 26447-40-5 1 - 10 TRADE SECRET *
DIISOCYANATE (MDI)
ZEOLITES 68989-22-0 1 - 5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8%
CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10
MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN 30
MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO
AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED, DO NOT
RESEAL CONTAINER. STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES.
STORE AWAY FROM OXIDIZING AGENTS. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
P,P'-METHYLENEBIS 101-68-8 ACGIH TWA: 0.005 PPM
(PHENYL ISOCYANATE)
P,P'-METHYLENEBIS 101-68-8 OSHA CEIL:
(PHENYL ISOCYANATE) 0.2 MG/M3(0.02
PPM)
FREE ISOCYANATES 101-68-8 MANUFACTURER TWA:
DETERMINED 0.005 PPM;
STEL: 0.02 PPM
TALC 14807-96-6 OSHA TWA: 2 MG/M3
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4:
FRACTION): NOT CLASS.
2 MG/M3 AS HUMAN
CARCIN
FREE ISOCYANATES 26447-40-5 MANUFACTURER TWA:
DETERMINED 0.005 PPM;
STEL: 0.02 PPM
ALUMINUM, 68989-22-0 ACGIH TWA(RESPIRABLE A4:
INSOLUBLE COMPOUNDS FRACTION): NOT CLASS.
1 MG/M3 AS HUMAN
CARCIN
FREE ISOCYANATES 9016-87-9 MANUFACTURER TWA:
DETERMINED 0.005 PPM;
STEL: 0.02 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
NEOPRENE
NITRILE RUBBER
NATURAL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BROWN, SLIGHT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >/=186 DEG. C
FLASH POINT: >/=367 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.35 G/ML
SPECIFIC GRAVITY: 1.35 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
15,000 - 32,000 CENTIPOISE [@ 73.4 DEG. F] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: </= 20% WEIGHT [TEST METHOD: CALCULATED]
HAZARDOUS AIR POLLUTANTS: 0.39 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN A
CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS:
AMINES
ALCOHOLS
WATER
REACTION WITH WATER, ALCOHOLS, AND AMINES IS NOT HAZARDOUS IF CONTAINER CAN
VENT TO THE ATMOSPHERE TO PREVENT PRESSURE BUILDUP.
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED
VAPOR(4 HR) ATE: >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
TALC DERMAL LD50 ESTIMATED TO BE: >5,000 MG/KG
TALC INGESTION LD50 ESTIMATED TO BE: >5,000 MG/KG
HIGHER OLIGOMERS DERMAL RABBIT LD50: >5,000 MG/KG
OF MDI
HIGHER OLIGOMERS INHALATION- RAT LC50: 0.368 MG/L
OF MDI DUST/MIST
(4 HOURS)
HIGHER OLIGOMERS INGESTION RAT LD50: 31,600 MG/KG
OF MDI
P,P'-METHYLENE- DERMAL RABBIT LD50: >5,000 MG/KG
BIS(PHENYL
ISOCYANATE)
P,P'-METHYLENE- INHALATION- RAT LC50: 0.368 MG/L
BIS(PHENYL DUST/MIST
ISOCYANATE) (4 HOURS)
P,P'-METHYLENE- INGESTION RAT LD50: 31,600 MG/KG
BIS(PHENYL
ISOCYANATE)
DIPHENYLMETHANE DERMAL RABBIT LD50: >5,000 MG/KG
DIISOCYANATE
(MDI)
DIPHENYLMETHANE INHALATION- RAT LC50: 0.368 MG/L
DIISOCYANATE DUST/MIST
(MDI) (4 HOURS)
DIPHENYLMETHANE INGESTION RAT LD50: 31,600 MG/KG
DIISOCYANATE
(MDI)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT
IRRITATION
HIGHER OLIGOMERS OF MDI OFFICIAL CLASSIFICATION IRRITANT
P,P'-METHYLENEBIS OFFICIAL CLASSIFICATION IRRITANT
(PHENYL ISOCYANATE)
DIPHENYLMETHANE OFFICIAL CLASSIFICATION IRRITANT
DIISOCYANATE (MDI)
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT
IRRITATION
HIGHER OLIGOMERS OF MDI OFFICIAL SEVERE IRRITANT
CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
DIPHENYLMETHANE DIISOCYANATE (MDI) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
HIGHER OLIGOMERS OF MDI OFFICIAL CLASSIFICATION SENSITIZING
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL CLASSIFICATION SENSITIZING
DIPHENYLMETHANE DIISOCYANATE (MDI) OFFICIAL CLASSIFICATION SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
HIGHER OLIGOMERS OF MDI HUMAN SENSITIZING
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) HUMAN SENSITIZING
DIPHENYLMETHANE DIISOCYANATE (MDI) HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
HIGHER OLIGOMERS OF MDI IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
P,P'-METHYLENEBIS IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
(PHENYL ISOCYANATE) ARE NOT SUFFICIENT FOR CLASSIFICATION
DIPHENYLMETHANE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
DIISOCYANATE (MDI) ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
HIGHER OLIGOMERS OF MDI INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
P,P'-METHYLENEBIS INHALATION RAT SOME POSITIVE DATA EXIST, BUT
(PHENYL ISOCYANATE) THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIPHENYLMETHANE INHALATION RAT SOME POSITIVE DATA EXIST, BUT
DIISOCYANATE (MDI) THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPEC- TEST EXPOSURE
IES RESULT DURATION
TALC INGESTION NOT TOXIC TO RAT NOAEL: DURING
DEVELOPMENT 1,600 ORGANOGENESIS
MG/KG
HIGHER OLIGOMERS INHALATION SOME POSITIVE RAT NOAEL: DURING
OF MDI DEVELOPMENTAL 0.004 ORGANOGENESIS
DATA EXIST, MG/L
BUT THE DATA
ARE NOT
SUFFICIENT
FOR CLASSIFI-
CATION
P,P'-METHYLENEBIS INHALATION SOME POSITIVE RAT NOAEL: DURING
(PHENYL DEVELOPMENTAL 0.004 ORGANOGENESIS
ISOCYANATE) DATA EXIST, MG/L
BUT THE DATA
ARE NOT
SUFFICIENT
FOR CLASSIFI-
CATION
DIPHENYLMETHANE INHALATION SOME POSITIVE RAT NOAEL: DURING
DIISOCYANATE DEVELOPMENTAL 0.004 ORGANOGENESIS
(MDI) DATA EXIST, MG/L
BUT THE DATA
ARE NOT
SUFFICIENT
FOR CLASSIFI-
CATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET VALUE
ORGAN(S)
HIGHER OLIGOMERS OF MDI INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
P,P'-METHYLENEBIS INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(PHENYL ISOCYANATE) IRRITATION IRRITATION
DIPHENYLMETHANE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
DIISOCYANATE (MDI) IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
HIGHER OLIGOMERS OF MDI OFFICIAL CLASSIFICATION NOAEL NOT
AVAILABLE
P,P'-METHYLENEBIS OFFICIAL CLASSIFICATION NOAEL NOT
(PHENYL ISOCYANATE) AVAILABLE
DIPHENYLMETHANE OFFICIAL CLASSIFICATION NOAEL NOT
DIISOCYANATE (MDI) AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA EXIST,
FIBROSIS | BUT THE DATA ARE NOT
RESPIRATORY SUFFICIENT FOR
SYSTEM CLASSIFICATION
HIGHER OLIGOMERS INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
OF MDI SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
P,P'-METHYLENEBIS INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(PHENYL ISOCYANATE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
DIPHENYLMETHANE INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
DIISOCYANATE (MDI) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
HIGHER OLIGOMERS RAT LOAEL: 0.004 MG/L 13 WEEKS
OF MDI
P,P'-METHYLENEBIS RAT LOAEL: 0.004 MG/L 13 WEEKS
(PHENYL ISOCYANATE)
DIPHENYLMETHANE RAT LOAEL: 0.004 MG/L 13 WEEKS
DIISOCYANATE (MDI)
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
EPCRA 311/312 HAZARD CLASSIFICATIONS (EFFECTIVE JANUARY 1, 2018):
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
HIGHER OLIGOMERS OF MDI 9016-87-9 TRADE SECRET 10 - 30
HIGHER OLIGOMERS OF MDI (DIISOCYANATES 9016-87-9 10 - 30
(CERTAIN CHEMICALS ONLY))
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 TRADE SECRET 10 - 30
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 10 - 30
(BENZENE, 1,1'-METHYLENEBIS
[4-ISOCYANATO-)
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 710 - 30
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3187-1
VERSION NUMBER: 26.00
ISSUE DATE: 04/24/17
SUPERCEDES DATE: 04/16/15
REASON FOR REISSUE: CONVERSION TO GHS FORMAT SDS.
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M