| Common Name: | SCOTCH-WELD EPOXY ADHESIVE 1751 B/A GRAY |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/16/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JBH3, 2JBV7, 2JBV8, 2JCD7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 B/A GRAY
04/16/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 11-3162-2
VERSION NUMBER: 13.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 02/06/08
PRODUCT IDENTIFIER: 3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 B/A GRAY
ID NUMBER(S):
62-1751-0530-3, 62-1751-0535-2, 62-1751-5430-1, 62-1751-6430-0,
62-1751-7430-9
RECOMMENDED USE: STRUCTURAL ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
10-3135-0, 10-3128-5
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 GRAY PART B
09/30/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3128-5
VERSION NUMBER: 27.00
ISSUE DATE: 09/30/15
SUPERCEDES DATE: 04/16/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 GRAY PART B
PRODUCT IDENTIFICATION NUMBERS: 62-1751-8530-5
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1B.
REPRODUCTIVE TOXICITY: CATEGORY 2.
GERM CELL MUTAGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING GENETIC DEFECTS.
CAUSES DAMAGE TO ORGANS: NERVOUS SYSTEM
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
LIVER
KIDNEY/URINARY TRACT
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
10% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
59% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
EPOXY RESIN 25068-38-6 40 - 70 TRADE SECRET *
ALUMINUM PIGMENTS 7429-90-5 15 - 40 TRADE SECRET *
N-BUTYL GLYCIDYL ETHER 2426-08-6 1 - 20 TRADE SECRET *
CLAY (NJTS REG NO 04499600-7160) TRADE SECRET* 1 - 10 TRADE SECRET *
AMORPHOUS SILICA 112945-52-5 1 - 5 TRADE SECRET *
RESORCINOL 108-46-3 0.5 - 1.5 TRADE SECRET *
QUARTZ SILICA 14808-60-7 <0.3 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM
OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
RESORCINOL 108-46-3 ACGIH TWA: 10 PPM; A4: NOT CLASS. AS
STEL: 20 PPM HUMAN CARCIN
SILICA, AMORPHOUS 112945-52-5 OSHA TWA
CONCENTRATION:
0.8 MG/M3;
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
QUARTZ SILICA 14808-60-7 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3;
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS
OF
PARTICLES/CU.
FT.)
QUARTZ SILICA 14808-60-7 ACGIH TWA(RESPIRABLE A2: SUSPECTED HUMAN
FRACTION): CARCIN.
0.025 MG/M3
N-BUTYL GLYCIDYL 2426-08-6 OSHA TWA:
ETHER 270 MG/M3(50
PPM)
N-BUTYL GLYCIDYL 2426-08-6 ACGIH TWA: 3 PPM SKIN NOTATION; SKIN
ETHER SENSITIZER
ALUMINUM PIGMENTS 7429-90-5 ACGIH TWA(RESPIRABLE A4: NOT CLASS. AS
FRACTION): HUMAN CARCIN
1 MG/M3
ALUMINUM PIGMENTS 7429-90-5 OSHA TWA(AS Al
RESPIRABLE
DUST):
5 MG/M3;
TWA(AS Al
TOTAL
DUST):
15 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: GRAY, LITTLE ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=164 DEG. C [DETAILS: N-BUTYL GLYCIDYL ETHER]
FLASH POINT: 201 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.3 G/ML
SPECIFIC GRAVITY: 1.3 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 CENTIPOISE [@ 73.4 DEG. F]
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
8.6 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
231 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
VOC LESS H2O & EXEMPT SOLVENTS:
0.7% [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART A]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN A
CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
KIDNEY/BLADDER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE CHANGES IN URINE PRODUCTION, ABDOMINAL OR LOWER
BACK PAIN, INCREASED PROTEIN IN URINE, INCREASED BLOOD UREA NITROGEN (BUN),
BLOOD IN URINE, AND PAINFUL URINATION.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
GENOTOXICITY:
GENOTOXICITY AND MUTAGENICITY:
MAY INTERACT WITH GENETIC MATERIAL AND POSSIBLY ALTER GENE EXPRESSION.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS REGULATION
DESCRIPTION
SILICA, CRYS 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY PROGRAM
AIRRESP CARCINOGEN CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY FOR RESEARCH
CARCINOGENIC ON CANCER
TO HUMANS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED ATE
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED ATE
VAPOR(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE
>5,000 MG/KG
EPOXY RESIN DERMAL RAT LD50 >1,600 MG/KG
EPOXY RESIN INGESTION RAT LD50 >1,000 MG/KG
ALUMINUM DERMAL LD50 ESTIMATED TO BE >5,000 MG/KG
PIGMENTS
ALUMINUM INGESTION LD50 ESTIMATED TO BE >5,000 MG/KG
PIGMENTS
ALUMINUM INHALATION- RAT LC50 >0.888 MG/L
PIGMENTS DUST/MIST
(4 HOURS)
N-BUTYL DERMAL RABBIT LD50 ESTIMATED TO BE 1,000 - 2,000
GLYCIDYL ETHER MG/KG
N-BUTYL INHALATION- RAT LC50 >21.3 MG/L
GLYCIDYL ETHER VAPOR (4
HOURS)
N-BUTYL INGESTION RAT LD50 1,800 MG/KG
GLYCIDYL ETHER
CLAY (NJTS REG DERMAL LD50 ESTIMATED TO BE >5,000 MG/KG
NO
04499600-7160)
CLAY (NJTS REG INHALATION- RAT LC50 >12.6 MG/L
NO DUST/MIST
04499600-7160) (4 HOURS)
CLAY (NJTS REG INGESTION RAT LD50 >5,000 MG/KG
NO
04499600-7160)
AMORPHOUS DERMAL RABBIT LD50 >5,000 MG/KG
SILICA
AMORPHOUS INHALATION- RAT LC50 >0.691 MG/L
SILICA DUST/MIST
(4 HOURS)
AMORPHOUS INGESTION RAT LD50 >5,110 MG/KG
SILICA
RESORCINOL DERMAL RABBIT LD50 3,360 MG/KG
RESORCINOL INHALATION- RAT LC50 >1.95 MG/L
DUST/MIST
(4 HOURS)
RESORCINOL INGESTION RAT LD50 489 MG/KG
QUARTZ SILICA DERMAL LD50 ESTIMATED TO BE >5,000 MG/KG
QUARTZ SILICA INGESTION LD50 ESTIMATED TO BE >5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MILD IRRITANT
ALUMINUM PIGMENTS RABBIT NO SIGNIFICANT IRRITATION
N-BUTYL GLYCIDYL ETHER RABBIT MILD IRRITANT
CLAY (NJTS REG NO 04499600-7160) RAT NO SIGNIFICANT IRRITATION
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
RESORCINOL RABBIT MINIMAL IRRITATION
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MODERATE IRRITANT
ALUMINUM PIGMENTS RABBIT NO SIGNIFICANT IRRITATION
N-BUTYL GLYCIDYL ETHER RABBIT MILD IRRITANT
CLAY (NJTS REG NO 04499600-7160) RABBIT NO SIGNIFICANT IRRITATION
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
RESORCINOL RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN AND ANIMAL SENSITIZING
ALUMINUM PIGMENTS GUINEA PIG NOT SENSITIZING
N-BUTYL GLYCIDYL ETHER MOUSE SENSITIZING
AMORPHOUS SILICA HUMAN AND ANIMAL NOT SENSITIZING
RESORCINOL MULTIPLE ANIMAL SPECIES SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN SOME POSITIVE DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
ALUMINUM PIGMENTS HUMAN SOME POSITIVE DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
EPOXY RESIN IN VIVO NOT MUTAGENIC
EPOXY RESIN IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
ALUMINUM PIGMENTS IN VITRO NOT MUTAGENIC
N-BUTYL GLYCIDYL ETHER IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
N-BUTYL GLYCIDYL ETHER IN VIVO MUTAGENIC
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
RESORCINOL IN VIVO NOT MUTAGENIC
RESORCINOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
EPOXY RESIN DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
AMORPHOUS SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
RESORCINOL INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
QUARTZ SILICA INHALATION HUMAN AND CARCINOGENIC
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
EPOXY RESIN INGESTION NOT TOXIC TO RAT NOAEL 750 2 GENERATION
FEMALE MG/KG/DAY
REPRODUCTION
EPOXY RESIN INGESTION NOT TOXIC TO RAT NOAEL 750 2 GENERATION
MALE MG/KG/DAY
REPRODUCTION
EPOXY RESIN DERMAL NOT TOXIC TO RABBIT NOAEL 300 DURING
DEVELOPMENT MG/KG/DAY ORGANOGEN-
ESIS
EPOXY RESIN INGESTION NOT TOXIC TO RAT NOAEL 750 2 GENERATION
DEVELOPMENT MG/KG/DAY
N-BUTYL INHALATION SOME RAT NOAEL 0.2 10 WEEKS
GLYCIDYL POSITIVE MG/L
ETHER MALE
REPRODUCTIVE
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
N-BUTYL INGESTION TOXIC TO RAT NOAEL 100 DURING
GLYCIDYL DEVELOPMENT MG/KG/DAY GESTATION
ETHER
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 509 1 GENERATION
SILICA FEMALE MG/KG/DAY
REPRODUCTION
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 497 1 GENERATION
SILICA MALE MG/KG/DAY
REPRODUCTION
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 1,350 DURING
SILICA DEVELOPMENT MG/KG/DAY ORGANOGEN-
ESIS
RESORCINOL INGESTION NOT TOXIC TO RAT NOAEL 304 2 GENERATION
FEMALE MG/KG/DAY
REPRODUCTION
RESORCINOL INGESTION NOT TOXIC TO RAT NOAEL 223 2 GENERATION
MALE MG/KG/DAY
REPRODUCTION
RESORCINOL INGESTION NOT TOXIC TO RAT NOAEL 250 DURING
DEVELOPMENT MG/KG/DAY GESTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
N-BUTYL GLYCIDYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
ETHER SYSTEM DEPRESSION DIZZINESS
N-BUTYL GLYCIDYL INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
ETHER IRRITATION IRRITATION
RESORCINOL DERMAL HEART | ENDOCRINE SOME POSITIVE DATA EXIST,
SYSTEM | BLOOD | BUT THE DATA ARE NOT
METHEMOGLOBINEMIA SUFFICIENT FOR
| LIVER | NERVOUS CLASSIFICATION
SYSTEM | KIDNEY
AND/OR BLADDER |
RESPIRATORY
SYSTEM
RESORCINOL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
RESORCINOL INGESTION NERVOUS SYSTEM CAUSES DAMAGE TO ORGANS
RESORCINOL INGESTION METHEMOGLOBINEMIA SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
N-BUTYL GLYCIDYL MULTIPLE ANIMAL SPECIES NOAEL NOT AVAILABLE
ETHER
N-BUTYL GLYCIDYL OFFICIAL CLASSIFICATION NOAEL NOT AVAILABLE
ETHER
RESORCINOL HUMAN NOAEL NOT AVAILABLE
RESORCINOL SIMILAR HEALTH HAZARDS NOAEL NOT AVAILABLE
RESORCINOL RAT NOAEL 27.5 MG/KG
RESORCINOL HUMAN NOAEL NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
EPOXY RESIN DERMAL LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPOXY RESIN DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
EPOXY RESIN INGESTION AUDITORY SYSTEM | ALL DATA ARE NEGATIVE
HEART | ENDOCRINE
SYSTEM |
HEMATOPOIETIC
SYSTEM | LIVER |
EYES | KIDNEY
AND/OR BLADDER
ALUMINUM PIGMENTS INHALATION NERVOUS SYSTEM | SOME POSITIVE DATA EXIST,
RESPIRATORY BUT THE DATA ARE NOT
SYSTEM SUFFICIENT FOR
CLASSIFICATION
N-BUTYL GLYCIDYL DERMAL LIVER SOME POSITIVE DATA EXIST,
ETHER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-BUTYL GLYCIDYL INHALATION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
ETHER BLADDER | BUT THE DATA ARE NOT
RESPIRATORY SUFFICIENT FOR
SYSTEM CLASSIFICATION
N-BUTYL GLYCIDYL INHALATION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
ETHER SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-BUTYL GLYCIDYL INHALATION LIVER SOME POSITIVE DATA EXIST,
ETHER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
AMORPHOUS SILICA INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
SYSTEM |
SILICOSIS
RESORCINOL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
RESORCINOL INGESTION HEART | SKIN | ALL DATA ARE NEGATIVE
ENDOCRINE SYSTEM
| BONE, TEETH,
NAILS, AND/OR
HAIR |
HEMATOPOIETIC
SYSTEM | LIVER |
IMMUNE SYSTEM |
MUSCLES | NERVOUS
SYSTEM | EYES |
KIDNEY AND/OR
BLADDER |
RESPIRATORY
SYSTEM | VASCULAR
SYSTEM
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
EPOXY RESIN RAT NOAEL 1,000 MG/KG/DAY 2 YEARS
EPOXY RESIN RAT NOAEL 1,000 MG/KG/DAY 13 WEEKS
EPOXY RESIN RAT NOAEL 1,000 MG/KG/DAY 28 DAYS
ALUMINUM PIGMENTS HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
N-BUTYL GLYCIDYL RAT LOAEL 100 MG/KG/DAY 28 DAYS
ETHER
N-BUTYL GLYCIDYL RAT NOAEL 1.6 MG/L 50 DAYS
ETHER
N-BUTYL GLYCIDYL RAT NOAEL 1 MG/L 28 DAYS
ETHER
N-BUTYL GLYCIDYL RAT NOAEL 0.8 MG/L 50 DAYS
ETHER
AMORPHOUS SILICA HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
RESORCINOL RAT NOAEL 1 MG/L 14 DAYS
RESORCINOL RAT NOAEL 250 MG/KG/DAY 13 WEEKS
QUARTZ SILICA HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ALUMINUM PIGMENTS 7429-90-5 TRADE SECRET 15 - 40
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3128-5
VERSION NUMBER: 27.00
ISSUE DATE: 09/30/15
SUPERCEDES DATE: 04/16/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 GRAY PART A
04/16/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3135-0
VERSION NUMBER: 27.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 01/15/09
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 1751 GRAY PART A
PRODUCT IDENTIFICATION NUMBERS: 62-1752-8530-3
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1A.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
10% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYAMIDE RESIN 68410-23-1 80 - 95 TRADE SECRET *
CLAY (NJTS REG NO 04499600-7160) TRADE SECRET* 1 - 10 TRADE SECRET *
TRIETHYLENETETRAMINE 112-24-3 1 - 10 TRADE SECRET *
AMORPHOUS SILICA 112945-52-5 1 - 5 TRADE SECRET *
QUARTZ SILICA 14808-60-7 <0.3 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM
STRONG BASES. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TRIETHYLENETETRAMINE 112-24-3 AIHA TWA: SKIN NOTATION
6 MG/M3(1 PPM)
SILICA, AMORPHOUS 112945-52-5 OSHA TWA
CONCENTRATION:
0.8 MG/M3;
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
QUARTZ SILICA 14808-60-7 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3;
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3(2.4
MILLIONS OF
PARTICLES/CU.
FT.)
QUARTZ SILICA 14808-60-7 ACGIH TWA A2: SUSPECTED
(RESPIRABLE HUMAN CARCIN.
FRACTION):
0.025 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NEOPRENE
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: AMBER, AMINE ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=260 DEG. C
FLASH POINT: >=500 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 0.95 G/ML
SPECIFIC GRAVITY: 0.95 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 - 400,000 CENTIPOISE [@ 73.4 DEG. F]
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
8.6 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
VOC LESS H2O & EXEMPT SOLVENTS:
0.7% [TEST METHOD: CALCULATED PER CARB TITLE 2] [DETAILS: WHEN USED AS
INTENDED WITH PART B]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN A
CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS REGULATION
DESCRIPTION
SILICA, CRYS 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY PROGRAM
AIRRESP CARCINOGEN CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY FOR RESEARCH
CARCINOGENIC ON CANCER
TO HUMANS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED
ATE >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE >5,000 MG/KG
POLYAMIDE RESIN INGESTION RAT LD50 >8,000 MG/KG
CLAY (NJTS REG NO DERMAL LD50 ESTIMATED TO BE >5,000
04499600-7160) MG/KG
CLAY (NJTS REG NO INHALATION- RAT LC50 >12.6 MG/L
04499600-7160) DUST/MIST
(4 HOURS)
CLAY (NJTS REG NO INGESTION RAT LD50 >5,000 MG/KG
04499600-7160)
TRIETHYLENETETRAMINE DERMAL RABBIT LD50 550 MG/KG
TRIETHYLENETETRAMINE INGESTION RAT LD50 2,500 MG/KG
AMORPHOUS SILICA DERMAL RABBIT LD50 >5,000 MG/KG
AMORPHOUS SILICA INHALATION- RAT LC50 >0.691 MG/L
DUST/MIST
(4 HOURS)
AMORPHOUS SILICA INGESTION RAT LD50 >5,110 MG/KG
QUARTZ SILICA DERMAL LD50 ESTIMATED TO BE >5,000
MG/KG
QUARTZ SILICA INGESTION LD50 ESTIMATED TO BE >5,000
MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
CLAY (NJTS REG NO 04499600-7160) RAT NO SIGNIFICANT IRRITATION
TRIETHYLENETETRAMINE RABBIT CORROSIVE
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
CLAY (NJTS REG NO 04499600-7160) RABBIT NO SIGNIFICANT IRRITATION
TRIETHYLENETETRAMINE RABBIT CORROSIVE
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
TRIETHYLENETETRAMINE GUINEA PIG SENSITIZING
AMORPHOUS SILICA HUMAN AND ANIMAL NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
AMORPHOUS SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN AND ANIMAL CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE DURATION
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 509 1 GENERATION
SILICA FEMALE MG/KG/DAY
REPRODUCTION
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 497 1 GENERATION
SILICA MALE MG/KG/DAY
REPRODUCTION
AMORPHOUS INGESTION NOT TOXIC TO RAT NOAEL 1,350 DURING
SILICA DEVELOPMENT MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
AMORPHOUS SILICA INHALATION RESPIRATORY SYSTEM | ALL DATA ARE NEGATIVE
SILICOSIS
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
AMORPHOUS SILICA HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
QUARTZ SILICA HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3135-0
VERSION NUMBER: 27.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 01/15/09
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM