| Common Name: | SCOTCH-WELD LOW ODOR ACRYLIC ADHESIVE DP810 TAN |
| Manufacturer: | 3M |
| SDS Revision Date: | 8/11/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JBW7, 489K06 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN
08/11/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-6267-2
VERSION NUMBER: 12.00
ISSUE DATE: 08/11/17
SUPERCEDES DATE: 04/16/15
PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN
ID NUMBER(S):
62-3298-1430-5, 62-3298-1431-3, 62-3298-1435-4, 62-3298-1436-2,
62-3298-3530-0, 62-3298-3830-4
RECOMMENDED USE: STRUCTURAL ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
08-6252-4, 08-6239-1
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN AND LOW ODOR
ACRYLIC ADHESIVE 810 TAN, PART B 05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND (2) NEITHER THE COPY NOR THE ORIGINAL IS
RESOLD OR OTHERWISE DISTRIBUTED WITH THE INTENTION OF EARNING A PROFIT
THEREON.
DOCUMENT GROUP: 08-6239-1
VERSION NUMBER: 21.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 08/11/17
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN AND LOW ODOR
ACRYLIC ADHESIVE 810 TAN, PART B
PRODUCT IDENTIFICATION NUMBERS: 62-3298-8730-1
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
INTERNATIONAL OPERATIONS:
ADDRESS:
3M CENTER
ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
PHENOXYETHYL METHACRYLATE 10595-06-9 10 - 40 TRADE SECRET *
2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 30 TRADE SECRET *
HYDROXYPROPYL METHACRYLATE 27813-02-1 10 - 30 TRADE SECRET *
ACRYLATE OLIGOMER 41637-38-1 5 - 20 TRADE SECRET *
ACRYLONITRILE-BUTADIENE POLYMER 9010-81-5 5 - 20 TRADE SECRET *
2-HYDROXYETHYL METHACRYLATE 52628-03-2 <4 TRADE SECRET *
PHOSPHATE
4-METHOXYPHENOL 150-76-5 <1 TRADE SECRET *
PHENOTHIAZINE 92-84-2 <1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS (EG. ALUMINUM, ZINC
ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD CREATE AN EXPLOSION
HAZARD.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
4-METHOXYPHENOL 150-76-5 ACGIH TWA: 5 MG/M3
PHENOTHIAZINE 92-84-2 ACGIH TWA: 5 MG/M3 SKIN
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: SLIGHT FRAGRANCE, GREEN
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >93 DEG. C
FLASH POINT: >200 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: </=0.1 MMHg
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.07 G/ML
SPECIFIC GRAVITY: 1.07 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 20,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: <40% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
3.1 G/L [DETAILS: WHEN USED AS INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
0.3% [DETAILS: WHEN USED AS INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
319 G/L [TEST METHOD: TESTED PER EPA METHOD 24] [DETAILS: AS SUPPLIED]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION MAY OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN A
CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS:
AMINES
REDUCING AGENTS
REACTIVE METALS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
PHENOXYETHYL METHACRYLATE DERMAL LD50 ESTIMATED TO BE:
2,000 - 5,000 MG/KG
PHENOXYETHYL METHACRYLATE INGESTION LD50 ESTIMATED TO BE:
2,000 - 5,000 MG/KG
2-HYDROXYETHYL METHACRYLATE DERMAL RABBIT LD50: >5,000 MG/KG
2-HYDROXYETHYL METHACRYLATE INGESTION RAT LD50: 5,564 MG/KG
ACRYLONITRILE-BUTADIENE DERMAL LD50 ESTIMATED TO
POLYMER BE: >5,000 MG/KG
ACRYLONITRILE-BUTADIENE INGESTION LD50 ESTIMATED TO
POLYMER BE: 2,000 - 5,000 MG/KG
HYDROXYPROPYL METHACRYLATE DERMAL RABBIT LD50: >5,000 MG/KG
HYDROXYPROPYL METHACRYLATE INGESTION RAT LD50: >2,000 MG/KG
ACRYLATE OLIGOMER DERMAL PROFESS- LD50 ESTIMATED TO
IONAL BE: >5,000 MG/KG
JUDGMENT
ACRYLATE OLIGOMER INGESTION RAT LD50: >2,000 MG/KG
2-HYDROXYETHYL METHACRYLATE INGESTION RAT LD50: >2,000 MG/KG
PHOSPHATE
4-METHOXYPHENOL DERMAL RAT LD50: >2,000 MG/KG
4-METHOXYPHENOL INGESTION RAT LD50: 1,600 MG/KG
PHENOTHIAZINE DERMAL RAT LD50: >2,000 MG/KG
PHENOTHIAZINE INGESTION RAT LD50: 1,370 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
PHENOXYETHYL METHACRYLATE SIMILAR COMPOUNDS IRRITANT
2-HYDROXYETHYL METHACRYLATE RABBIT MINIMAL IRRITATION
ACRYLONITRILE-BUTADIENE POLYMER PROFESSIONAL NO SIGNIFICANT
JUDGMENT IRRITATION
HYDROXYPROPYL METHACRYLATE RABBIT MINIMAL IRRITATION
2-HYDROXYETHYL METHACRYLATE RABBIT CORROSIVE
PHOSPHATE
4-METHOXYPHENOL RABBIT MILD IRRITANT
PHENOTHIAZINE RABBIT NO SIGNIFICANT
IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
PHENOXYETHYL METHACRYLATE SIMILAR COMPOUNDS SEVERE IRRITANT
2-HYDROXYETHYL METHACRYLATE RABBIT MODERATE IRRITANT
ACRYLONITRILE-BUTADIENE PROFESSIONAL NO SIGNIFICANT IRRITATION
POLYMER JUDGMENT
HYDROXYPROPYL METHACRYLATE RABBIT MODERATE IRRITANT
2-HYDROXYETHYL METHACRYLATE SIMILAR HEALTH CORROSIVE
PHOSPHATE HAZARDS
4-METHOXYPHENOL RABBIT SEVERE IRRITANT
PHENOTHIAZINE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-HYDROXYETHYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
HYDROXYPROPYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
ACRYLATE OLIGOMER GUINEA PIG NOT CLASSIFIED
2-HYDROXYETHYL METHACRYLATE MOUSE SENSITIZING
PHOSPHATE
4-METHOXYPHENOL GUINEA PIG SENSITIZING
PHENOTHIAZINE GUINEA PIG SENSITIZING
PHOTOSENSITIZATION:
NAME SPECIES VALUE
PHENOTHIAZINE HUMAN SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
PHENOXYETHYL METHACRYLATE IN VITRO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VIVO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
HYDROXYPROPYL METHACRYLATE IN VIVO NOT MUTAGENIC
HYDROXYPROPYL METHACRYLATE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACRYLATE OLIGOMER IN VITRO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VITRO NOT MUTAGENIC
PHOSPHATE
PHENOTHIAZINE IN VITRO NOT MUTAGENIC
PHENOTHIAZINE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HYDROXYPROPYL METHACRYLATE INHALATION MULTIPLE ANIMAL NOT CARCINOGENIC
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2-HYDROXYETHYL METHACRYLATE INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
2-HYDROXYETHYL METHACRYLATE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
2-HYDROXYETHYL METHACRYLATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
2-HYDROXYETHYL METHACRYLATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
PHOSPHATE
PHENOTHIAZINE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE
DURATION
2-HYDROXYETHYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY PREMATING &
DURING
GESTATION
2-HYDROXYETHYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY 49 DAYS
2-HYDROXYETHYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY PREMATING &
DURING
GESTATION
HYDROXYPROPYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY PREMATING
INTO
LACTATION
HYDROXYPROPYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY 49 DAYS
HYDROXYPROPYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY DURING
GESTATION
2-HYDROXYETHYL METHACRYLATE RAT NOAEL: 1,000 MG/KG/DAY DURING
PHOSPHATE GESTATION
PHENOTHIAZINE RAT NOAEL: 150 MG/KG/DAY DURING
ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
METHACRYLATE IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
2-HYDROXYETHYL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
METHACRYLATE IRRITATION BUT THE DATA ARE NOT
PHOSPHATE SUFFICIENT FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
HYDROXYPROPYL SIMILAR HEALTH HAZARDS NOAEL NOT AVAILABLE
METHACRYLATE
2-HYDROXYETHYL SIMILAR HEALTH HAZARDS NOAEL NOT AVAILABLE
METHACRYLATE
PHOSPHATE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION BLOOD NOT CLASSIFIED
METHACRYLATE
HYDROXYPROPYL INGESTION HEMATOPOIETIC NOT CLASSIFIED
METHACRYLATE SYSTEM | HEART |
ENDOCRINE SYSTEM |
LIVER | IMMUNE
SYSTEM | NERVOUS
SYSTEM | KIDNEY
AND/OR BLADDER
2-HYDROXYETHYL INGESTION HEMATOPOIETIC NOT CLASSIFIED
METHACRYLATE SYSTEM | KIDNEY
PHOSPHATE AND/OR BLADDER |
HEART | LIVER |
IMMUNE SYSTEM |
EYES
PHENOTHIAZINE INGESTION HEMATOPOIETIC MAY CAUSE DAMAGE TO ORGANS
SYSTEM THOUGH PROLONGED OR
REPEATED EXPOSURE
PHENOTHIAZINE INGESTION HEART | ENDOCRINE NOT CLASSIFIED
SYSTEM | LIVER |
KIDNEY AND/OR
BLADDER |
RESPIRATORY
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL RAT NOAEL: 0.5 MG/L 21 DAYS
METHACRYLATE
HYDROXYPROPYL RAT NOAEL: 1,000 MG/KG/DAY 41 DAYS
METHACRYLATE
2-HYDROXYETHYL RAT NOAEL: 300 MG/KG/DAY 90 DAYS
METHACRYLATE
PHOSPHATE
PHENOTHIAZINE DOG NOAEL: 18 MG/KG/DAY 13 WEEKS
PHENOTHIAZINE DOG NOAEL: 67 MG/KG/DAY 13 WEEKS
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
PHENOXYETHYL METHACRYLATE (GLYCOL ETHERS) 10595-06-9 10 - 40
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 08-6239-1
VERSION NUMBER: 21.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 08/11/17
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE3MPRODUCT
TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR
USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN AND LOW ODOR
ACRYLIC ADHESIVE 810 TAN, PART A
05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-6252-4
VERSION NUMBER: 17.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 08/11/17
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) LOW ODOR ACRYLIC ADHESIVE DP810 TAN AND LOW ODOR
ACRYLIC ADHESIVE 810 TAN, PART A
PRODUCT IDENTIFICATION NUMBERS: 62-3398-8730-9
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION:
INDUSTRIAL ADHESIVES AND TAPES DIVISION
INTERNATIONAL OPERATIONS
ADDRESS:
3M CENTER
ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
CARCINOGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
PHENOXYETHYL METHACRYLATE 10595-06-9 10 - 40 TRADE SECRET *
2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 30 TRADE SECRET *
HYDROXYPROPYL METHACRYLATE 27813-02-1 10 - 30 TRADE SECRET *
ACRYLATE OLIGOMER 41637-38-1 5 - 20 TRADE SECRET *
ACRYLONITRILE-BUTADIENE POLYMER 9010-81-5 5 - 20 TRADE SECRET *
CUMENE HYDROPEROXIDE 80-15-9 1 - 5 TRADE SECRET *
2,2'-METHYLENEBIS[6-TERT- 119-47-1 <1 TRADE SECRET *
BUTYL-P-CRESOL]
CUMENE 98-82-8 <1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS (EG. ALUMINUM, ZINC
ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD CREATE AN EXPLOSION
HAZARD. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS
REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
CUMENE HYDROPEROXIDE 80-15-9 AIHA TWA: 6 MG/M3(1 PPM) SKIN
CUMENE 98-82-8 ACGIH TWA: 50 PPM
CUMENE 98-82-8 OSHA TWA: 245 MG/M3(50 PPM) SKIN
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
FLUOROELASTOMER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE, LOW ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >/=217 DEG. F
FLASH POINT: 216 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: </=0.1 MMHg
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.07 G/ML
SPECIFIC GRAVITY: 1.07 [REF STD: WATER=1]
SOLUBILITY IN WATER SLIGHT (LESS THAN 10%)
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 20,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: <40% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
3.1 G/L [DETAILS: WHEN USED AS INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
0.3% [DETAILS: WHEN USED AS INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
349 G/L [TEST METHOD: TESTED PER EPA METHOD 24] [DETAILS: AS SUPPLIED]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION MAY OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN A
CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS:
AMINES
REDUCING AGENTS
REACTIVE METALS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
CUMENE 98-82-8 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN RESEARCH ON CANCER
CARC.
CUMENE 98-82-8 ANTICIPATED NATIONAL TOXICOLOGY PROGRAM
HUMAN CARCINOGENS
CARCINOGEN
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED ATE:
2,000 - 5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED ATE:
VAPOR(4 HR) 20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE:
2,000 - 5,000 MG/KG
PHENOXYETHYL DERMAL LD50 ESTIMATED TO BE:
METHACRYLATE 2,000 - 5,000 MG/KG
PHENOXYETHYL INGESTION LD50 ESTIMATED TO BE:
METHACRYLATE 2,000 - 5,000 MG/KG
2-HYDROXYETHYL DERMAL RABBIT LD50: >5,000 MG/KG
METHACRYLATE
2-HYDROXYETHYL INGESTION RAT LD50: 5,564 MG/KG
METHACRYLATE
ACRYLONITRILE- DERMAL LD50 ESTIMATED TO BE: >5,000 MG/KG
BUTADIENE
POLYMER
ACRYLONITRILE- INGESTION LD50 ESTIMATED TO BE:
BUTADIENE 2,000 - 5,000 MG/KG
POLYMER
HYDROXYPROPYL DERMAL RABBIT LD50: >5,000 MG/KG
METHACRYLATE
HYDROXYPROPYL INGESTION RAT LD50: >2,000 MG/KG
METHACRYLATE
ACRYLATE DERMAL PROFES- LD50 ESTIMATED TO BE: >5,000 MG/KG
OLIGOMER SIONAL
JUDGEM-
ENT
ACRYLATE INGESTION RAT LD50: >2,000 MG/KG
OLIGOMER
CUMENE DERMAL RAT LD50: 500 MG/KG
HYDROPEROXIDE
CUMENE INHALATION- RAT LC50: 1.4 MG/L
HYDROPEROXIDE VAPOR (4
HOURS)
CUMENE INGESTION RAT LD50: 382 MG/KG
HYDROPEROXIDE
CUMENE DERMAL RABBIT LD50: >3,160 MG/KG
CUMENE INHALATION- RAT LC50: 39.4 MG/L
VAPOR (4
HOURS)
CUMENE INGESTION RAT LD50: 1,400 MG/KG
2,2'-METHYLENE- DERMAL RABBIT LD50: >10,000 MG/KG
BIS[6-TERT-
BUTYL-P-CRESOL]
2,2'-METHYLENE- INGESTION RAT LD50: >5,000 MG/KG
BIS[6-TERT-
BUTYL-P-CRESOL]
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
PHENOXYETHYL METHACRYLATE SIMILAR COMPOUNDS IRRITANT
2-HYDROXYETHYL METHACRYLATE RABBIT MINIMAL IRRITATION
ACRYLONITRILE-BUTADIENE POLYMER PROFESSIONAL NO SIGNIFICANT
JUDGMENT IRRITATION
HYDROXYPROPYL METHACRYLATE RABBIT MINIMAL IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
CUMENE RABBIT MINIMAL IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
PHENOXYETHYL METHACRYLATE SIMILAR COMPOUNDS SEVERE IRRITANT
2-HYDROXYETHYL METHACRYLATE RABBIT MODERATE IRRITANT
ACRYLONITRILE-BUTADIENE POLYMER PROFESSIONAL NO SIGNIFICANT
JUDGMENT IRRITATION
HYDROXYPROPYL METHACRYLATE RABBIT MODERATE IRRITANT
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
CUMENE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-HYDROXYETHYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
HYDROXYPROPYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
ACRYLATE OLIGOMER GUINEA PIG NOT CLASSIFIED
CUMENE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
PHENOXYETHYL METHACRYLATE IN VITRO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VIVO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
HYDROXYPROPYL METHACRYLATE IN VIVO NOT MUTAGENIC
HYDROXYPROPYL METHACRYLATE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
ACRYLATE OLIGOMER IN VITRO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VIVO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CUMENE IN VITRO NOT MUTAGENIC
CUMENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HYDROXYPROPYL METHACRYLATE INHALATION MULTIPLE ANIMAL NOT CARCINOGENIC
SPECIES
CUMENE INHALATION MULTIPLE ANIMAL CARCINOGENIC
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
2-HYDROXYETHYL INGESTION NOT CLASSIFIED RAT NOAEL: PREMATING
METHACRYLATE FOR FEMALE 1,000 & DURING
REPRODUCTION MG/KG/DAY GESTATION
2-HYDROXYETHYL INGESTION NOT CLASSIFIED RAT NOAEL: 49 DAYS
METHACRYLATE FOR MALE 1,000
REPRODUCTION MG/KG/DAY
2-HYDROXYETHYL INGESTION NOT CLASSIFIED RAT NOAEL: PREMATING
METHACRYLATE FOR 1,000 & DURING
DEVELOPMENT MG/KG/DAY GESTATION
HYDROXYPROPYL INGESTION NOT CLASSIFIED RAT NOAEL: PREMATING
METHACRYLATE FOR FEMALE 1,000 INTO
REPRODUCTION MG/KG/DAY LACTATION
HYDROXYPROPYL INGESTION NOT CLASSIFIED RAT NOAEL: 49 DAYS
METHACRYLATE FOR MALE 1,000
REPRODUCTION MG/KG/DAY
HYDROXYPROPYL INGESTION NOT CLASSIFIED RAT NOAEL: DURING
METHACRYLATE FOR 1,000 GESTATION
DEVELOPMENT MG/KG/DAY
CUMENE INHALATION NOT CLASSIFIED RABBIT NOAEL: DURING
FOR 11.3 MG/L ORGANOGE-
DEVELOPMENT NESIS
2,2'-METHYLEN- INGESTION NOT CLASSIFIED RAT NOAEL: PREMATING
EBIS[6-TERT- FOR FEMALE 50 & DURING
BUTYL-P- REPRODUCTION MG/KG/DAY GESTATION
CRESOL]
2,2'-METHYLEN- INGESTION TOXIC TO MALE RAT NOAEL: 50 DAYS
EBIS[6-TERT- REPRODUCTION 12.5
BUTYL-P- MG/KG/DAY
CRESOL]
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET VALUE
ORGAN(S)
HYDROXYPROPYL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST, BUT THE
METHACRYLATE IRRITATION DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CUMENE INHALATION CENTRAL MAY CAUSE DROWSINESS OR DIZZINESS
HYDROPEROXIDE NERVOUS
SYSTEM
DEPRESSION
CUMENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY IRRITATION
HYDROPEROXIDE IRRITATION
CUMENE INGESTION CENTRAL MAY CAUSE DROWSINESS OR DIZZINESS
HYDROPEROXIDE NERVOUS
SYSTEM
DEPRESSION
CUMENE INHALATION CENTRAL MAY CAUSE DROWSINESS OR DIZZINESS
NERVOUS
SYSTEM
DEPRESSION
CUMENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY IRRITATION
IRRITATION
CUMENE INGESTION CENTRAL MAY CAUSE DROWSINESS OR DIZZINESS
NERVOUS
SYSTEM
DEPRESSION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
HYDROXYPROPYL SIMILAR HEALTH HAZARDS NOAEL: NOT AVAILABLE
METHACRYLATE
CUMENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
HYDROPEROXIDE EXPOSURE
CUMENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
HYDROPEROXIDE EXPOSURE
CUMENE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
HYDROPEROXIDE
CUMENE MULTIPLE ANIMAL SPECIES NOAEL: NOT AVAILABLE NOT AVAILABLE
CUMENE HUMAN LOAEL: 0.2 MG/L OCCUPATIONAL
EXPOSURE
CUMENE MULTIPLE ANIMAL SPECIES NOAEL: NOT AVAILABLE NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION BLOOD NOT CLASSIFIED
METHACRYLATE
HYDROXYPROPYL INGESTION HEMATOPOIETIC NOT CLASSIFIED
METHACRYLATE SYSTEM | HEART |
ENDOCRINE SYSTEM |
LIVER | IMMUNE
SYSTEM | NERVOUS
SYSTEM | KIDNEY
AND/OR BLADDER
CUMENE INHALATION NERVOUS SYSTEM | CAUSES DAMAGE TO ORGANS
HYDROPEROXIDE RESPIRATORY SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
CUMENE INHALATION HEART | LIVER | NOT CLASSIFIED
HYDROPEROXIDE KIDNEY AND/OR
BLADDER
CUMENE INHALATION AUDITORY SYSTEM | NOT CLASSIFIED
ENDOCRINE SYSTEM |
HEMATOPOIETIC
SYSTEM | LIVER |
NERVOUS SYSTEM |
EYES
CUMENE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CUMENE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
CUMENE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER | HEART |
ENDOCRINE SYSTEM |
HEMATOPOIETIC
SYSTEM | LIVER |
RESPIRATORY SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL RAT NOAEL: 0.5 MG/L 21 DAYS
METHACRYLATE
HYDROXYPROPYL RAT NOAEL: 1,000 MG/KG/DAY 41 DAYS
METHACRYLATE
CUMENE RAT LOAEL: 0.2 MG/L 7 DAYS
HYDROPEROXIDE
CUMENE RAT NOAEL: 0.03 MG/L 90 DAYS
HYDROPEROXIDE
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RAT NOAEL: 4.9 MG/L 13 WEEKS
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RAT NOAEL: 769 MG/KG/DAY 6 MONTHS
ASPIRATION HAZARD:
NAME VALUE
CUMENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN THE SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
CARCINOGENICITY
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CUMENE HYDROPEROXIDE 80-15-9 TRADE SECRET 1 - 5
PHENOXYETHYL METHACRYLATE (GLYCOL ETHERS) 10595-06-9 10 - 40
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 08-6252-4
VERSION NUMBER: 17.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 08/11/17
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M