| Common Name: | SCOTCH-WELD EPOXY ADHESIVE 2216 B/A GRAY |
| Manufacturer: | 3M |
| SDS Revision Date: | 7/17/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JBW3, 2JBY5, 2RUD2, 642R85 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 B/A GRAY 07/17/17
3M
SAFETY DATA SHEET
COPYRIGHT,2017,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 11-3168-9
VERSION NUMBER: 11.01
ISSUE DATE: 07/17/17
SUPERCEDES DATE: 04/16/15
PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 B/A GRAY
ID NUMBER(S):
62-2216-0530-6, 62-2216-0535-5, 62-2216-1430-8, 62-2216-1435-7,
62-2216-5430-4, 62-2216-6430-3, 62-2216-7430-2
RECOMMENDED USE: STRUCTURAL ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER,
ST. PAUL, MN 55144-1000,
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH
OF THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
10-3174-9, 10-3167-3
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE3MPRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A3MPRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL,IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 GRAY PART B 05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT,2018,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3167-3
VERSION NUMBER: 29.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 02/07/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 GRAY PART B
PRODUCT IDENTIFICATION NUMBERS:
62-2216-8530-8, 62-2216-8535-7, 62-2216-9530-7, 62-2216-9531-5
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER,
ST. PAUL, MN 55144-1000,
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS: EXCLAMATION MARK
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
EPOXY RESIN 25068-38-6 70 - 80 TRADE SECRET *
KAOLIN 1332-58-7 20 - 30 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 <1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE: USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY
COMBUSTIBLE MATERIAL SUCH AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CHLORIDE DURING COMBUSTION
KETONES DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL
AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE
DUST, INERT OR 1332-58-7 OSHA TWA(AS TOTAL DUST): 15
NUISANCE MG/M3;TWA(AS TOTAL DUST):
50 MILLIONS OF PARTICLES/
CU. FT.(15 MG/M3);TWA
(RESPIRABLE FRACTION):
15 MILLIONS OF
PARTICLES/CU. FT.(5 MG/M3);
TWA(RESPIRABLE FRACTION):
5 MG/M3
KAOLIN 1332-58-7 ACGIH TWA(RESPIRABLE FRACTION):
2 MG/M3
KAOLIN, TOTAL 1332-58-7 OSHA TWA(AS TOTAL DUST): 15
DUST MG/M3;TWA(RESPIRABLE
FRACTION): 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(AS TOTAL DUST):
15 MG/M3
INGREDIENT ADDITIONAL COMMENTS
DUST, INERT OR NUISANCE
KAOLIN A4: NOT CLASS. AS HUMAN CARCIN
KAOLIN, TOTAL DUST
TITANIUM DIOXIDE A4: NOT CLASS. AS HUMAN CARCIN
TITANIUM DIOXIDE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE VENTILATED ENCLOSURE FOR HEAT CURING. PROVIDE APPROPRIATE LOCAL
EXHAUST VENTILATION FOR CUTTING, GRINDING, SANDING OR MACHINING. USE
GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT
WITH YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: VISCOUS LIQUID
ODOR, COLOR, GRADE: GRAY VERY SLIGHT EPOXY ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: 248 DEG. C [TEST METHOD:PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: <=0.1 MMHg [@ 25 DEG. C]
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.33 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.33 [@ 20 DEG. C] [REF STD:WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 75,000 - 150,000 CENTIPOISE [TEST METHOD:BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0 % WEIGHT [TEST METHOD:CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
3.7 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: WHEN USED AS INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: AS SUPPLIED]
VOC LESS H2O & EXEMPT SOLVENTS:
<0.5 % [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: WHEN USED AS INTENDED WITH PART A]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS
IN A CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH
PRODUCTION OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING,
AND DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND
BLURRED OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA,
VOMITING AND DIARRHEA.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: POSSIBLE INTERNATIONAL AGENCY
HUMAN CARC. FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
EPOXY RESIN DERMAL RAT LD50 >1,600 MG/KG
EPOXY RESIN INGESTION RAT LD50 >1,000 MG/KG
KAOLIN DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
KAOLIN INGESTION HUMAN LD50 >15,000 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50 >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50 >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50 >10,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MILD IRRITANT
KAOLIN PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MODERATE IRRITANT
KAOLIN PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN AND SENSITIZING
ANIMAL
TITANIUM DIOXIDE HUMAN AND NOT CLASSIFIED
ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN NOT CLASSIFIED
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
EPOXY RESIN IN VIVO NOT MUTAGENIC
EPOXY RESIN IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
EPOXY RESIN DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
KAOLIN INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES
EPOXY RESIN INGESTION NOT CLASSIFIED RAT
FOR FEMALE
REPRODUCTION
EPOXY RESIN INGESTION NOT CLASSIFIED RAT
FOR MALE
REPRODUCTION
EPOXY RESIN DERMAL NOT CLASSIFIED RABBIT
FOR DEVELOPMENT
EPOXY RESIN INGESTION NOT CLASSIFIED RAT
FOR DEVELOPMENT
NAME TEST RESULT EXPOSURE DURATION
EPOXY RESIN NOAEL 750 2 GENERATION
MG/KG/DAY
EPOXY RESIN NOAEL 750 2 GENERATION
MG/KG/DAY
EPOXY RESIN NOAEL 300 DURING
MG/KG/DAY ORGANOGENESIS
EPOXY RESIN NOAEL 750 2 GENERATION
MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE
OR THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
EPOXY RESIN DERMAL LIVER NOT CLASSIFIED
EPOXY RESIN DERMAL NERVOUS SYSTEM NOT CLASSIFIED
EPOXY RESIN INGESTION AUDITORY NOT CLASSIFIED
SYSTEM |
HEART |
ENDOCRINE
SYSTEM |
HEMATOPOIETIC
SYSTEM |
LIVER | EYES |
KIDNEY AND/OR
BLADDER
KAOLIN INHALATION PNEUMOCONIOSIS CAUSES DAMAGE
TO ORGANS
THROUGH
PROLONGED OR
REPEATED
EXPOSURE
KAOLIN INHALATION PULMONARY NOT CLASSIFIED
FIBROSIS
TITANIUM DIOXIDE INHALATION RESPIRATORY SOME POSITIVE
SYSTEM DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY NOT CLASSIFIED
FIBROSIS
NAME SPECIES TEST RESULT EXPOSURE
DURATION
EPOXY RESIN RAT NOAEL 1,000 2 YEARS
MG/KG/DAY
EPOXY RESIN RAT NOAEL 1,000 13 WEEKS
MG/KG/DAY
EPOXY RESIN RAT NOAEL 1,000 28 DAYS
MG/KG/DAY
KAOLIN HUMAN NOAEL NA OCCUPATIONAL
EXPOSURE
KAOLIN RAT NOAEL NOT
AVAILABLE
TITANIUM DIOXIDE RAT LOAEL 0.01 2 YEARS
MG/L
TITANIUM DIOXIDE HUMAN NOAEL NOT OCCUPATIONAL
AVAILABLE EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
COMBUSTION PRODUCTS WILL INCLUDE HALOGEN ACID (HCL/HF/HBR). FACILITY
MUST BE CAPABLE OF HANDLING HALOGENATED MATERIALS. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS
OF FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY
BASED ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT
ALSO INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS
THAT ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3167-3
VERSION NUMBER: 29.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 02/07/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE3MPRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL,IT IS ESSENTIAL THAT THE USER EVALUATE THE3MPRODUCT
TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR
USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 GRAY PART A 05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT,2018,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3174-9
VERSION NUMBER: 34.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 02/07/18
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) EPOXY ADHESIVE 2216 GRAY PART A
PRODUCT IDENTIFICATION NUMBERS:
62-2217-8530-6, 62-2217-8535-5, 62-2217-9530-5, 62-2217-9531-3
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER,
ST. PAUL, MN 55144-1000,
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO CERTAIN OTHER AMINES.
60% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
60% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ALIPHATIC POLYMER DIAMINE 68911-25-1 30 - 60 TRADE SECRET *
KAOLIN 1332-58-7 30 - 60 TRADE SECRET *
BIS(3-AMINOPROPYL) ETHER OF 4246-51-9 1 - 10 TRADE SECRET *
DIETHYLENE GLYCOL
TITANIUM DIOXIDE 13463-67-7 <0.5 TRADE SECRET *
TOLUENE 108-88-3 <0.5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE: USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY
COMBUSTIBLE MATERIAL SUCH AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
AMINE COMPOUNDS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE
OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL
AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC
ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY.
REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH,
OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS
POSSIBLE. PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND
SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE
IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE
TOLUENE 108-88-3 ACGIH TWA: 20 PPM
TOLUENE 108-88-3 OSHA TWA: 200 PPM;CEIL: 300 PPM
KAOLIN 1332-58-7 ACGIH TWA(RESPIRABLE FRACTION):
2 MG/M3
KAOLIN, TOTAL 1332-58-7 OSHA TWA(AS TOTAL DUST): 15
DUST MG/M3;TWA(RESPIRABLE
FRACTION): 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS.
AS HUMAN CARCIN
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(AS TOTAL DUST):
15 MG/M3
INGREDIENT ADDITIONAL COMMENTS
TOLUENE A4: NOT CLASS. AS HUMAN CARCIN
TOLUENE
KAOLIN A4: NOT CLASS. AS HUMAN CARCIN
KAOLIN, TOTAL DUST
TITANIUM DIOXIDE A4: NOT CLASS. AS HUMAN CARCIN
TITANIUM DIOXIDE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT
WITH YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: VISCOUS
ODOR, COLOR, GRADE: PUNGENT ODOR, GRAY.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >=201 DEG. F [TEST METHOD:CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: <=0.1 MMHg [@ 25 DEG. C]
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.26 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.26 [@ 20 DEG. C] [REF STD:WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT:
N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
40,000 - 80,000 CENTIPOISE [@ 20 DEG. C] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: <1 % WEIGHT [TEST METHOD:CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
3.7 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: WHEN USED AS INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
< 0.5 % [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: WHEN USED AS INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
6.12 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: AS SUPPLIED]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS
IN A CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH
PRODUCTION OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL
BURNS, SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION
OR COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN,
STOMACH UPSET, NAUSEA, VOMITING AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: POSSIBLE INTERNATIONAL AGENCY
HUMAN CARC. FOR RESEARCH ON CANCER
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A CROSS-SENSITIZATION
REACTION TO CERTAIN OTHER AMINES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
KAOLIN DERMAL LD50 ESTIMATED TO BE
> 5,000 MG/KG
KAOLIN INGESTION HUMAN LD50 > 15,000 MG/KG
BIS(3-AMINOPROPYL) DERMAL RABBIT LD50 2,500 MG/KG
ETHER OF
DIETHYLENE GLYCOL
BIS(3-AMINOPROPYL) INGESTION RAT LD50 3,160 MG/KG
ETHER OF
DIETHYLENE GLYCOL
TOLUENE DERMAL RAT LD50 12,000 MG/KG
TOLUENE INHALATION- RAT LC50 30 MG/L
VAPOR (4
HOURS)
TOLUENE INGESTION RAT LD50 5,550 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50 > 10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50 > 6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50 > 10,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT IRRITANT
ALIPHATIC POLYMER DIAMINE RABBIT IRRITANT
KAOLIN PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
BIS(3-AMINOPROPYL) ETHER RABBIT CORROSIVE
OF DIETHYLENE GLYCOL
TOLUENE RABBIT IRRITANT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ALIPHATIC POLYMER DIAMINE SIMILAR HEALTH CORROSIVE
HAZARDS
KAOLIN PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
BIS(3-AMINOPROPYL) ETHER SIMILAR HEALTH CORROSIVE
OF DIETHYLENE GLYCOL HAZARDS
TOLUENE RABBIT MODERATE IRRITANT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
OVERALL PRODUCT SENSITIZING
ALIPHATIC POLYMER DIAMINE GUINEA PIG SENSITIZING
TOLUENE GUINEA PIG NOT CLASSIFIED
TITANIUM DIOXIDE HUMAN AND NOT CLASSIFIED
ANIMAL
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
KAOLIN INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES
TOLUENE INHALATION NOT CLASSIFIED HUMAN
FOR FEMALE
REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED RAT
FOR MALE
REPRODUCTION
TOLUENE INGESTION TOXIC TO RAT
DEVELOPMENT
TOLUENE INHALATION TOXIC TO HUMAN
DEVELOPMENT
NAME TEST RESULT EXPOSURE DURATION
TOLUENE NOAEL NOT OCCUPATIONAL EXPOSURE
AVAILABLE
TOLUENE NOAEL 2.3 1 GENERATION
MG/L
TOLUENE LOAEL 520 DURING
MG/KG/DAY GESTATION
TOLUENE NOAEL NOT POISONING
AVAILABLE AND/OR ABUSE
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
BIS(3-AMINOPROPYL) ETHER OF INHALATION RESPIRATORY SOME POSITIVE
DIETHYLENE GLYCOL IRRITATION DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE
IRRITATION DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE
DURATION
BIS(3-AMINOPROPYL) ETHER OF NOAEL NOT
DIETHYLENE GLYCOL AVAILABLE
TOLUENE HUMAN NOAEL NOT
AVAILABLE
TOLUENE HUMAN NOAEL NOT
AVAILABLE
TOLUENE MOUSE NOAEL 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL NOT POISONING
AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
KAOLIN INHALATION PNEUMOCONIOSIS CAUSES DAMAGE
TO ORGANS
THROUGH
PROLONGED OR
REPEATED
EXPOSURE
KAOLIN INHALATION PULMONARY NOT CLASSIFIED
FIBROSIS
TOLUENE INHALATION AUDITORY CAUSES DAMAGE
SYSTEM | TO ORGANS
NERVOUS THROUGH
SYSTEM | PROLONGED OR
EYES | REPEATED
OLFACTORY EXPOSURE
SYSTEM
TOLUENE INHALATION RESPIRATORY SOME POSITIVE
SYSTEM DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEART | LIVER | NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE NOT CLASSIFIED
SYSTEM
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR
HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM |
VASCULAR
SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER | KIDNEY NOT CLASSIFIED
AND/OR BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
TITANIUM DIOXIDE INHALATION RESPIRATORY SOME POSITIVE
SYSTEM DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY NOT CLASSIFIED
FIBROSIS
NAME SPECIES TEST RESULT EXPOSURE
DURATION
KAOLIN HUMAN NOAEL NA OCCUPATIONAL
EXPOSURE
KAOLIN RAT NOAEL NOT
AVAILABLE
TOLUENE HUMAN NOAEL NOT POISONING
AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL 2.3 15 MONTHS
MG/L
TOLUENE RAT NOAEL 11.3 15 WEEKS
MG/L
TOLUENE RAT NOAEL 1.1 4 WEEKS
MG/L
TOLUENE MOUSE NOAEL NOT 20 DAYS
AVAILABLE
TOLUENE MOUSE NOAEL 1.1 8 WEEKS
MG/L
TOLUENE HUMAN NOAEL NOT OCCUPATIONAL
AVAILABLE EXPOSURE
TOLUENE MULTIPLE NOAEL 11.3 15 WEEKS
ANIMAL MG/L
SPECIES
TOLUENE RAT NOAEL 625 13 WEEKS
MG/KG/DAY
TOLUENE RAT NOAEL 2,500 13 WEEKS
MG/KG/DAY
TOLUENE MULTIPLE NOAEL 2,500 13 WEEKS
ANIMAL MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL 600 14 DAYS
MG/KG/DAY
TOLUENE MOUSE NOAEL 105 28 DAYS
MG/KG/DAY
TOLUENE MOUSE NOAEL 105 4 WEEKS
MG/KG/DAY
TITANIUM DIOXIDE RAT LOAEL 0.01 2 YEARS
MG/L
TITANIUM DIOXIDE HUMAN NOAEL NOT OCCUPATIONAL
AVAILABLE EXPOSURE
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS
OF FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY
BASED ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT
ALSO INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS
THAT ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3174-9
VERSION NUMBER: 34.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 02/07/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
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A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND APPLICATION OF A
3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S KNOWLEDGE AND
CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE3MPRODUCT TO DETERMINE
WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD
OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
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INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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