| Common Name: | SCOTCH-WELD URETHANE ADHESIVE 3535 B/A |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/16/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JBH4, 2JBZ1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A
04/16/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 11-3171-3
VERSION NUMBER: 13.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 09/22/14
PRODUCT IDENTIFIER: 3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A
ID NUMBER(S): 62-3535-0515-9, 62-3535-0535-7, 62-3535-6430-5
RECOMMENDED USE: TWO PART URETHANE ADHESIVE, INDUSTRIAL USE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
10-3184-8, 19-8532-4
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A, PART A
04/16/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-3184-8
VERSION NUMBER: 50.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 07/12/12
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A, PART A
PRODUCT IDENTIFICATION NUMBERS: 62-3635-8530-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
URETHANE PREPOLYMER TRADE SECRET* 30 - 50 TRADE SECRET *
(NJTS REG. NO.
14499600-5770P)
POLYMETHYLENE POLYPHENYLENE 9016-87-9 10 - 30 TRADE SECRET *
ISOCYANATE
TALC 14807-96-6 10 - 30 TRADE SECRET *
P,P'-METHYLENEBIS(PHENYL 101-68-8 1 - 15 TRADE SECRET *
ISOCYANATE)
DIPHENYLMETHANE DIISOCYANATE 26447-40-5 1 - 10 TRADE SECRET *
(MDI)
GLASS SPHERES 68989-22-0 1 - 5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE: USE A CARBON DIOXIDE OR DRY CHEMICAL EXTINGUISHER TO
EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8% CONCENTRATED AMMONIA,
2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10 MINUTES. OR POUR WATER ON
SPILL AND ALLOW TO REACT FOR MORE THAN 30 MINUTES. COVER WITH ABSORBENT
MATERIAL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO AVOID PRESSURE
BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED, DO NOT
RESEAL CONTAINER. STORE AWAY FROM HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
P,P'-METHYLENEBIS 101-68-8 ACGIH TWA: 0.005 PPM
(PHENYL ISOCYANATE)
FREE ISOCYANATES 101-68-8 MANUFACTURER TWA: 0.005 PPM;
DETERMINED STEL: 0.02 PPM
P,P'-METHYLENEBIS 101-68-8 OSHA CEIL:
(PHENYL ISOCYANATE) 0.2 MG/M3(0.02
PPM)
TALC 14807-96-6 CMRG TWA(AS
RESPIRABLE
DUST):
0.5 MG/M3
TALC 14807-96-6 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3;
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3(2.4
MILLIONS OF
PARTICLES/CU.
FT.);
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
TALC 14807-96-6 ACGIH TWA A4: NOT
(RESPIRABLE CLASS. AS
FRACTION): HUMAN
2 MG/M3 CARCIN
FREE ISOCYANATES 26447-40-5 MANUFACTURER TWA: 0.005 PPM;
DETERMINED STEL: 0.02 PPM
ALUMINUM, INSOLUBLE 68989-22-0 ACGIH TWA A4: NOT
COMPOUNDS (RESPIRABLE CLASS. AS
FRACTION): HUMAN
1 MG/M3 CARCIN
BENZENE, 1,1'- 9016-87-9 ACGIH TWA: 0.005 PPM
METHYLENEBIS
[4-ISOCYANATO-
BENZENE, 1,1'- 9016-87-9 OSHA CEIL:
METHYLENEBIS 0.2 MG/M3(0.02
[4-ISOCYANATO- PPM)
FREE ISOCYANATES 9016-87-9 MANUFACTURER TWA: 0.005 PPM;
DETERMINED STEL: 0.02 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
NEOPRENE
NITRILE RUBBER
NATURAL RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - NEOPRENE APRON - NITRILE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BROWN, SLIGHT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=186 DEG. C
FLASH POINT: >=367 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.34 G/ML
SPECIFIC GRAVITY: 1.34 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
15,000 - 32,000 CENTIPOISE [@ 73.4 DEG. F] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: <= 20% WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART B]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
VOC LESS H2O & EXEMPT SOLVENTS:
0% [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART B]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
AMINES
ALCOHOLS
WATER
REACTION WITH WATER, ALCOHOLS, AND AMINES IS NOT HAZARDOUS IF CONTAINER CAN
VENT TO THE ATMOSPHERE TO PREVENT PRESSURE BUILDUP.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED ATE
VAPOR(4 HR) 20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE
>5,000 MG/KG
TALC DERMAL LD50 NOT AVAILABLE
TALC INGESTION LD50 NOT AVAILABLE
POLYMETHYLENE INHALATION- LC50 ESTIMATED TO BE 10 - 20 MG/L
POLYPHENYLENE VAPOR
ISOCYANATE
POLYMETHYLENE DERMAL RABBIT LD50 >5,000 MG/KG
POLYPHENYLENE
ISOCYANATE
POLYMETHYLENE INHALATION- RAT LC50 0.369 MG/L
POLYPHENYLENE DUST/MIST
ISOCYANATE (4 HOURS)
POLYMETHYLENE INGESTION RAT LD50 31,600 MG/KG
POLYPHENYLENE
ISOCYANATE
P,P'- INHALATION- LC50 ESTIMATED TO BE 10 - 20 MG/L
METHYLENEBIS VAPOR
(PHENYL
ISOCYANATE)
P,P'- DERMAL RABBIT LD50 >5,000 MG/KG
METHYLENEBIS
(PHENYL
ISOCYANATE)
P,P'- INHALATION- RAT LC50 0.369 MG/L
METHYLENEBIS DUST/MIST
(PHENYL (4 HOURS)
ISOCYANATE)
P,P'- INGESTION RAT LD50 31,600 MG/KG
METHYLENEBIS
(PHENYL
ISOCYANATE)
DIPHENYLMETHANE INHALATION- LC50 ESTIMATED TO BE 10 - 20 MG/L
DIISOCYANATE VAPOR
(MDI)
DIPHENYLMETHANE DERMAL RABBIT LD50 >5,000 MG/KG
DIISOCYANATE
(MDI)
DIPHENYLMETHANE INHALATION- RAT LC50 0.369 MG/L
DIISOCYANATE DUST/MIST
(MDI) (4 HOURS)
DIPHENYLMETHANE INGESTION RAT LD50 31,600 MG/KG
DIISOCYANATE
(MDI)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT
IRRITATION
POLYMETHYLENE POLYPHENYLENE OFFICIAL CLASSIFICATION IRRITANT
ISOCYANATE
P,P'-METHYLENEBIS(PHENYL OFFICIAL CLASSIFICATION IRRITANT
ISOCYANATE)
DIPHENYLMETHANE OFFICIAL CLASSIFICATION IRRITANT
DIISOCYANATE (MDI)
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT
IRRITATION
POLYMETHYLENE OFFICIAL CLASSIFICATION SEVERE IRRITANT
POLYPHENYLENE ISOCYANATE
P,P'-METHYLENEBIS(PHENYL OFFICIAL CLASSIFICATION SEVERE IRRITANT
ISOCYANATE)
DIPHENYLMETHANE OFFICIAL CLASSIFICATION SEVERE IRRITANT
DIISOCYANATE (MDI)
SKIN SENSITIZATION:
NAME SPECIES VALUE
POLYMETHYLENE OFFICIAL CLASSIFICATION SENSITIZING
POLYPHENYLENE ISOCYANATE
P,P'-METHYLENEBIS(PHENYL OFFICIAL CLASSIFICATION SENSITIZING
ISOCYANATE)
DIPHENYLMETHANE OFFICIAL CLASSIFICATION SENSITIZING
DIISOCYANATE (MDI)
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
POLYMETHYLENE POLYPHENYLENE ISOCYANATE HUMAN SENSITIZING
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) HUMAN SENSITIZING
DIPHENYLMETHANE DIISOCYANATE (MDI) HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
POLYMETHYLENE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
POLYPHENYLENE NOT SUFFICIENT FOR CLASSIFICATION
ISOCYANATE
P,P'-METHYLENEBIS IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
(PHENYL ISOCYANATE) NOT SUFFICIENT FOR CLASSIFICATION
DIPHENYLMETHANE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE
DIISOCYANATE (MDI) NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
POLYMETHYLENE INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
POLYPHENYLENE DATA ARE NOT SUFFICIENT FOR
ISOCYANATE CLASSIFICATION
P,P'-METHYLENEBIS INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
(PHENYL ISOCYANATE) DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
DIPHENYLMETHANE INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
DIISOCYANATE (MDI) DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
TALC INGESTION NOT TOXIC TO RAT NOAEL 1,600 DURING
DEVELOPMENT MG/KG ORGANOG-
ENESIS
POLYMETHYLENE INHALATION SOME POSITIVE RAT NOAEL 0.004 DURING
POLYPHENYLENE DEVELOPMENTAL MG/L ORGANOG-
ISOCYANATE DATA EXIST, ENESIS
BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
P,P'- INHALATION SOME POSITIVE RAT NOAEL 0.004 DURING
METHYLENEBIS DEVELOPMENTAL MG/L ORGANOG-
(PHENYL DATA EXIST, ENESIS
ISOCYANATE) BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
DIPHENYLMETHANE INHALATION SOME POSITIVE RAT NOAEL 0.004 DURING
DIISOCYANATE DEVELOPMENTAL MG/L ORGANOG-
(MDI) DATA EXIST, ENESIS
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
POLYMETHYLENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
POLYPHENYLENE IRRITATION IRRITATION
ISOCYANATE
P,P'-METHYLENEBIS INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(PHENYL IRRITATION IRRITATION
ISOCYANATE)
DIPHENYLMETHANE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
DIISOCYANATE (MDI) IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
POLYMETHYLENE OFFICIAL CLASSIFICATION NOAEL NOT AVAILABLE
POLYPHENYLENE
ISOCYANATE
P,P'-METHYLENEBIS OFFICIAL CLASSIFICATION NOAEL NOT AVAILABLE
(PHENYL
ISOCYANATE)
DIPHENYLMETHANE OFFICIAL CLASSIFICATION NOAEL NOT AVAILABLE
DIISOCYANATE (MDI)
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA EXIST,
FIBROSIS | BUT THE DATA ARE NOT
RESPIRATORY SUFFICIENT FOR
SYSTEM CLASSIFICATION
POLYMETHYLENE INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
POLYPHENYLENE SYSTEM THROUGH PROLONGED OR
ISOCYANATE REPEATED EXPOSURE
P,P'-METHYLENEBIS INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(PHENYL ISOCYANATE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
DIPHENYLMETHANE INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
DIISOCYANATE (MDI) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL 18 MG/M3 113 WEEKS
POLYMETHYLENE RAT LOAEL 0.004 MG/L 13 WEEKS
POLYPHENYLENE
ISOCYANATE
P,P'-METHYLENEBIS RAT LOAEL 0.004 MG/L 3 WEEKS
(PHENYL ISOCYANATE)
DIPHENYLMETHANE RAT LOAEL 0.004 MG/L 13 WEEKS
DIISOCYANATE (MDI)
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 10 - 30
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 10 - 30
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 10 - 30
(BENZENE, 1,1'-METHYLENEBIS
[4-ISOCYANATO-)
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 1 - 15
(BENZENE, 1,1'-METHYLENEBIS
[4-ISOCYANATO-)
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 1 - 15
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 1 - 15
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-3184-8
VERSION NUMBER: 50.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 07/12/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A, PART B
04/16/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 19-8532-4
VERSION NUMBER: 3.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 12/03/10
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) URETHANE ADHESIVE 3535 B/A, PART B
PRODUCT IDENTIFICATION NUMBERS: 62-3535-8530-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: BASE OF 2-PART URETHANE ADHESIVE, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYESTER RESIN TRADE SECRET* 30 - 60 TRADE SECRET *
(NJTS REG. NO.
04499600-7132)
TALC 14807-96-6 10 - 30 TRADE SECRET *
POLYPROPYLENE GLYCOL 25322-69-4 10 - 30 TRADE SECRET *
POLYOXYPROPYLENE TRIOL 25723-16-4 1 - 10 TRADE SECRET *
GLASS SPHERES 1318-02-1 1 - 10 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 1 - 10 TRADE SECRET *
O-DIETHYLBISANILINE 13680-35-8 1 - 5 TRADE SECRET *
DIBUTYLTIN BIS(2-ETHYLHEXYL 10584-98-2 <=0.8 TRADE SECRET *
MERCAPTOACETATE)
2-ETHYLHEXANOIC ACID 149-57-5 <=0.3 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE: USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY
COMBUSTIBLE MATERIAL SUCH AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) USE
PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TIN, ORGANIC 10584-98-2 ACGIH TWA(AS Sn): 0.1 MG/M3; A4: NOT CLASS.
COMPOUNDS STEL(AS Sn): 0.2 MG/M3 AS HUMAN
CARCIN, SKIN
NOTATION
TIN, ORGANIC 10584-98-2 OSHA TWA(AS Sn): 0.1 MG/M3
COMPOUNDS
ALUMINUM, 1318-02-1 ACGIH TWA(RESPIRABLE A4: NOT CLASS.
INSOLUBLE FRACTION): 1 MG/M3 AS HUMAN
COMPOUNDS CARCIN
TITANIUM 13463-67-7 ACGIH TWA: 10 MG/M3 A4: NOT CLASS.
DIOXIDE AS HUMAN
CARCIN
TITANIUM 13463-67-7 CMRG TWA(AS RESPIRABLE
DIOXIDE DUST): 5 MG/M3
TITANIUM 13463-67-7 OSHA TWA(AS TOTAL DUST):
DIOXIDE 15 MG/M3
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4: NOT CLASS.
FRACTION): 2 MG/M3 AS HUMAN
CARCIN
TALC 14807-96-6 CMRG TWA(AS RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3;
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3(2.4
MILLIONS OF
PARTICLES/CU. FT.);
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
2-ETHYLHEXANOIC 149-57-5 ACGIH TWA(INHALABLE
ACID FRACTION AND
VAPOR): 5 MG/M3
POLYPROPYLENE 25322-69-4 AIHA TWA(AS AEROSOL):
GLYCOL 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE, RESINOUS ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >=179 DEG. C
FLASH POINT: >=354 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.31 G/ML
SPECIFIC GRAVITY: 1.31 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
5,000 - 40,000 CENTIPOISE [@ 73.4 DEG. F] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
PERCENT VOLATILE: 1 - 2% WEIGHT [TEST METHOD: ACS METHOD]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART A]
VOC LESS H2O & EXEMPT SOLVENTS:
6.24 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: AS SUPPLIED]
VOC LESS H2O & EXEMPT SOLVENTS:
0% [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: WHEN USED AS
INTENDED WITH PART A]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION: NO KNOWN HEALTH EFFECTS.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS REGULATION
DESCRIPTION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE RESEARCH ON CANCER
HUMAN
CARC.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE
>5,000 MG/KG
POLYPROPYLENE DERMAL RABBIT LD50 >10,000 MG/KG
GLYCOL
POLYPROPYLENE INGESTION RAT LD50 >2,000 MG/KG
GLYCOL
TALC DERMAL LD50 NOT AVAILABLE
TALC INGESTION LD50 NOT AVAILABLE
TITANIUM DIOXIDE DERMAL RABBIT LD50 >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50 >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50 >10,000 MG/KG
POLYOXYPROPYLENE DERMAL RAT LD50 >2,000 MG/KG
TRIOL
POLYOXYPROPYLENE INGESTION RAT LD50 >2,500 MG/KG
TRIOL
GLASS SPHERES DERMAL RABBIT LD50 >2,000 MG/KG
GLASS SPHERES INHALATION- RAT LC50 >4.57 MG/L
DUST/MIST
(4 HOURS)
GLASS SPHERES INGESTION RAT LD50 >5,000 MG/KG
O-DIETHYLBISA- INGESTION RAT LD50 1,901 MG/KG
NILINE
2-ETHYLHEXANOIC DERMAL RAT LD50 >2,000 MG/KG
ACID
2-ETHYLHEXANOIC INHALATION- RAT LC50 >3.54 MG/L
ACID DUST/MIST
(4 HOURS)
2-ETHYLHEXANOIC INGESTION RAT LD50 1,600 MG/KG
ACID
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
POLYOXYPROPYLENE TRIOL RABBIT NO SIGNIFICANT IRRITATION
GLASS SPHERES RABBIT NO SIGNIFICANT IRRITATION
O-DIETHYLBISANILINE RABBIT MINIMAL IRRITATION
2-ETHYLHEXANOIC ACID RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLYPROPYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
POLYOXYPROPYLENE TRIOL RABBIT MILD IRRITANT
GLASS SPHERES RABBIT MILD IRRITANT
O-DIETHYLBISANILINE RABBIT NO SIGNIFICANT IRRITATION
2-ETHYLHEXANOIC ACID RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
O-DIETHYLBISANILINE IN VITRO NOT MUTAGENIC
2-ETHYLHEXANOIC ACID IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
TALC INGESTION NOT TOXIC TO RAT NOAEL 1,600 DURING
DEVELOPMENT MG/KG ORGANOGEN-
ESIS
2-ETHYLHEXANOIC INGESTION TOXIC TO RAT NOAEL 300 1
ACID FEMALE MG/KG/DAY GENERATION
REPRODUCTION
2-ETHYLHEXANOIC INGESTION TOXIC TO RAT NOAEL 300 1
ACID MALE MG/KG/DAY GENERATION
REPRODUCTION
2-ETHYLHEXANOIC INGESTION TOXIC TO MULTIPLE NOAEL 100 DURING
ACID DEVELOPMENT ANIMAL MG/KG/DAY ORGANOGEN-
SPECIES ESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-ETHYLHEXANOIC INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
ACID IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-ETHYLHEXANOIC ACID NOAEL NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA EXIST,
FIBROSIS | BUT THE DATA ARE NOT
RESPIRATORY SUFFICIENT FOR
SYSTEM CLASSIFICATION
TITANIUM DIOXIDE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY ALL DATA ARE NEGATIVEL
FIBROSIS
2-ETHYLHEXANOIC INGESTION BLOOD | LIVER SOME POSITIVE DATA EXIST,
ACID BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-ETHYLHEXANOIC INGESTION SKIN | KIDNEY SOME POSITIVE DATA EXIST,
ACID AND/OR BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL 18 MG/M3 113 WEEKS
TITANIUM DIOXIDE RAT LOAEL 0.010 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL EXPOSURE
2-ETHYLHEXANOIC RAT NOAEL 1,068 MG/KG/DAY 13 WEEKS
ACID
2-ETHYLHEXANOIC MOUSE NOAEL 3,139 MG/KG/DAY 13 WEEKS
ACID
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 19-8532-4
VERSION NUMBER: 3.00
ISSUE DATE: 04/16/15
SUPERCEDES DATE: 12/03/10
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM