| Common Name: | ALL-AROUND AUTOBODY SEALANT, PN 08500, 08510 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2JFH1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) ALL-AROUND AUTOBODY SEALANT, PN 08500, 08510
03/23/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-8276-7
VERSION NUMBER: 43.00
ISSUE DATE: 03/23/15
SUPERCEDES DATE: 01/16/08
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) ALL-AROUND AUTOBODY SEALANT, PN 08500, 08510
PRODUCT IDENTIFICATION NUMBERS: 62-5533-5219-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOBODY SEALANT, SEALANT
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
CARCINOGENICITY: CATEGORY 1A.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS: MAY CAUSE CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
22% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
LIMESTONE 1317-65-3 30 - 60 TRADE SECRET *
ACRYLIC LATEX POLYMER TRADE SECRET* 10 - 30 TRADE SECRET *
WATER 7732-18-5 10 - 30 TRADE SECRET *
DIISONONYL PHTHALATE 28553-12-0 7 - 13 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 1 - 5 TRADE SECRET *
POLYOXYETHYLENE MONOOCTYLPHENYL 9036-19-5 1 - 5 TRADE SECRET *
ETHER
STODDARD SOLVENT 8052-41-3 0.5 - 1.5 TRADE SECRET *
QUARTZ SILICA 14808-60-7 <0.5 TRADE SECRET *
FORMALDEHYDE 50-00-0 <0.1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX
IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN
ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL
HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A
CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES.
CLEAN UP RESIDUE WITH DETERGENT AND WATER. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
LIMESTONE 1317-65-3 OSHA TWA (AS TOTAL DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION): 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS.
AS HUMAN
CARCIN
TITANIUM DIOXIDE 13463-67-7 CMRG TWA (AS RESPIRABLE
DUST): 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 OSHA TWA (AS TOTAL DUST):
15 MG/M3
QUARTZ SILICA 14808-60-7 ACGIH TWA (RESPIRABLE A2:
FRACTION): SUSPECTED
0.025 MG/M3 HUMAN
CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS OF
PARTICLES/CU. FT.)
FORMALDEHYDE 50-00-0 ACGIH CEIL: 0.3 PPM A2:
SUSPECTED
HUMAN
CARCIN.,
SENSITIZER
FORMALDEHYDE 50-00-0 CMRG TWA: 0.5 PPM
FORMALDEHYDE 50-00-0 OSHA TWA: 0.75 PPM 29 CFR
STEL: 2 PPM 1910.1048
STODDARD SOLVENT 8052-41-3 ACGIH TWA: 100 PPM
STODDARD SOLVENT 8052-41-3 OSHA TWA:
2900 MG/M3
(500 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: MILD ACRYLIC-LIKE ODOR WHITE VISCOUS LIQUID
ODOR THRESHOLD: NO DATA AVAILABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: 212 DEG. F [TEST METHOD: ESTIMATED]
FLASH POINT: >212 DEG. F
EVAPORATION RATE: 0.3 [REF STD: BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: 18 MMHg [DETAILS: CONDITIONS: @ 25C]
VAPOR DENSITY: 0.8 [REF STD: AIR=1]
DENSITY: 1.56 - 1.61 G/ML
SPECIFIC GRAVITY: 1.60 [REF STD: WATER=1]
SOLUBILITY IN WATER: MODERATE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 120,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS:
0.00006 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
17 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
1.03 % WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 24 - 26% VOLUME
VOC LESS H2O & EXEMPT SOLVENTS:
21 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
VAPORS RELEASED DURING CURING MAY CAUSE EYE IRRITATION. SIGNS/SYMPTOMS MAY
INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS AIRRESP 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
FORMALDEHYDE 50-00-0 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON
HUMANS CANCER
FORMALDEHYDE 50-00-0 KNOWN HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
FORMALDEHYDE 50-00-0 CANCER HAZARD OSHA CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON
HUMANS CANCER
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON
CARC. CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3.0 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
DIISONONYL PHTHALATE DERMAL RABBIT LD50: >3,160 MG/KG
DIISONONYL PHTHALATE INHALATION- RAT LC50: >1.7 MG/L
DUST/MIST
(4 HOURS)
DIISONONYL PHTHALATE INGESTION RAT LD50: >10,000 MG/KG
POLYOXYETHYLENE DERMAL RABBIT LD50: >3,000 MG/KG
MONOOCTYLPHENYL ETHER
POLYOXYETHYLENE INGESTION RAT LD50: >500 MG/KG
MONOOCTYLPHENYL ETHER
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
STODDARD SOLVENT INHALATION- LC50:
VAPOR ESTIMATED TO BE
20 - 50 MG/L
STODDARD SOLVENT DERMAL RABBIT LD50: >3,000 MG/KG
STODDARD SOLVENT INGESTION RAT LD50: >5,000 MG/KG
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
FORMALDEHYDE DERMAL RABBIT LD50: 270 MG/KG
FORMALDEHYDE INHALATION- RAT LC50: 470 PPM
GAS
(4 HOURS)
FORMALDEHYDE INGESTION RAT LD50: 800 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
DIISONONYL PHTHALATE RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
STODDARD SOLVENT RABBIT IRRITANT
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
FORMALDEHYDE OFFICIAL CORROSIVE
CLASSIFICATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
DIISONONYL PHTHALATE RABBIT MILD IRRITANT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
STODDARD SOLVENT RABBIT NO SIGNIFICANT IRRITATION
FORMALDEHYDE OFFICIAL CORROSIVE
CLASSIFICATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
DIISONONYL PHTHALATE HUMAN AND ANIMAL NOT SENSITIZING
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT SENSITIZING
STODDARD SOLVENT GUINEA PIG NOT SENSITIZING
FORMALDEHYDE GUINEA PIG SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
FORMALDEHYDE HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIISONONYL PHTHALATE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
STODDARD SOLVENT IN VIVO NOT MUTAGENIC
STODDARD SOLVENT IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE IN VIVO MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIISONONYL PHTHALATE INGESTION MULTIPLE SOME POSITIVE DATA EXIST,
ANIMAL BUT THE DATA ARE NOT
SPECIES SUFFICIENT FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
STODDARD SOLVENT DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
STODDARD SOLVENT INHALATION HUMAN SOME POSITIVE DATA EXIST, BUT
AND THE DATA ARE NOT SUFFICIENT
ANIMAL FOR CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
FORMALDEHYDE NOT HUMAN CARCINOGENIC
SPECIFIED AND
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
DIISONONYL PHTHALATE INGESTION NOT TOXIC TO FEMALE REPRODUCTION
DIISONONYL PHTHALATE INGESTION NOT TOXIC TO MALE REPRODUCTION
DIISONONYL PHTHALATE INGESTION NOT TOXIC TO DEVELOPMENT
STODDARD SOLVENT INHALATION NOT TOXIC TO DEVELOPMENT
FORMALDEHYDE INGESTION SOME POSITIVE MALE REPRODUCTIVE DATA
EXIST, BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
FORMALDEHYDE INHALATION SOME POSITIVE DEVELOPMENTAL DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 625 MG/KG/DAY PREMATING &
DURING GESTATION
DIISONONYL PHTHALATE RAT NOAEL: 500 MG/KG/DAY 2 GENERATION
DIISONONYL PHTHALATE RAT NOAEL: 500 MG/KG/DAY 2 GENERATION
DIISONONYL PHTHALATE RAT NOAEL: 1,000 MG/KG/DAY DURING
ORGANOGENESIS
STODDARD SOLVENT RAT NOAEL: 2.4 MG/L DURING
ORGANOGENESIS
FORMALDEHYDE RAT NOAEL: 100 MG/KG NOT APPLICABLE
FORMALDEHYDE RAT NOAEL: 10 PPM DURING GESTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
STODDARD SOLVENT INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
STODDARD SOLVENT INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO ORGANS
FORMALDEHYDE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 0.812 MG/L 90 MINUTES
STODDARD SOLVENT HUMAN NOAEL: NOT AVAILABLE
AND ANIMAL
STODDARD SOLVENT NOAEL: NOT AVAILABLE
STODDARD SOLVENT DOG NOAEL: 6.5 MG/L 4 HOURS
FORMALDEHYDE RAT LOAEL: 128 PPM 6 HOURS
FORMALDEHYDE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
DIISONONYL PHTHALATE DERMAL BLOOD ALL DATA ARE NEGATIVE
LIVER
KIDNEY AND/OR
BLADDER
DIISONONYL PHTHALATE INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY ALL DATA ARE NEGATIVE
FIBROSIS
STODDARD SOLVENT INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
STODDARD SOLVENT INHALATION BONE, TEETH, ALL DATA ARE NEGATIVE
NAILS, AND/OR
HAIR
BLOOD
LIVER
MUSCLES
STODDARD SOLVENT INHALATION HEART ALL DATA ARE NEGATIVE
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
FORMALDEHYDE DERMAL RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
FORMALDEHYDE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INHALATION ENDOCRINE ALL DATA ARE NEGATIVE
SYSTEM
IMMUNE SYSTEM
MUSCLES
KIDNEY AND/OR
BLADDER
FORMALDEHYDE INHALATION EYES ALL DATA ARE NEGATIVE
VASCULAR SYSTEM
FORMALDEHYDE INHALATION HEART ALL DATA ARE NEGATIVE
FORMALDEHYDE INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
FORMALDEHYDE INGESTION HEART ALL DATA ARE NEGATIVE
ENDOCRINE
SYSTEM
HEMATOPOIETIC
SYSTEM
RESPIRATORY
SYSTEM
VASCULAR
SYSTEM
FORMALDEHYDE INGESTION SKIN ALL DATA ARE NEGATIVE
MUSCLES
EYES
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
DIISONONYL PHTHALATE RABBIT NOAEL: 2,425 MG/KG/DAY 6 WEEKS
DIISONONYL PHTHALATE RAT NOAEL: NOT AVAILABLE 13 WEEKS
TITANIUM DIOXIDE RAT LOAEL: 0.010 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
STODDARD SOLVENT RAT LOAEL: 4.6 MG/L 6 MONTHS
STODDARD SOLVENT RAT LOAEL: 1.9 MG/L 13 WEEKS
STODDARD SOLVENT MULTIPLE NOAEL: 0.6 MG/L 90 DAYS
ANIMAL
SPECIES
STODDARD SOLVENT RAT NOAEL: 5.6 MG/L 12 WEEKS
STODDARD SOLVENT MULTIPLE NOAEL: 1.3 MG/L 90 DAYS
ANIMAL
SPECIES
QUARTZ SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
FORMALDEHYDE MOUSE NOAEL: 80 MG/KG/DAY 60 WEEKS
FORMALDEHYDE RAT NOAEL: 0.3 PPM 28 MONTHS
FORMALDEHYDE RAT NOAEL: 20 PPM 13 WEEKS
FORMALDEHYDE MOUSE NOAEL: 15 PPM 3 WEEKS
FORMALDEHYDE MOUSE NOAEL: 10 PPM 13 WEEKS
FORMALDEHYDE RAT NOAEL: 15 PPM 28 MONTHS
FORMALDEHYDE RAT NOAEL: 14.3 PPM 2 YEARS
FORMALDEHYDE MOUSE NOAEL: 14.3 PPM 2 YEARS
FORMALDEHYDE RAT NOAEL: 300 MG/KG/DAY 2 YEARS
FORMALDEHYDE RAT NOAEL: 20 MG/KG/DAY 4 WEEKS
FORMALDEHYDE RAT NOAEL: 15 MG/KG/DAY 24 MONTHS
FORMALDEHYDE RAT NOAEL: 109 MG/KG/DAY 2 YEARS
FORMALDEHYDE RAT NOAEL: 300 MG/KG/DAY 2 YEARS
FORMALDEHYDE RAT NOAEL: 109 MG/KG/DAY 2 YEARS
ASPIRATION HAZARD
NAME VALUE
STODDARD SOLVENT ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE (AIRBORNE NONE CARCINOGEN
PARTICLES OF RESPIRABLE SIZE)
TITANIUM DIOXIDE 13463-67-7 CARCINOGEN
DIISONONYL PHTHALATE 28553-12-0 CARCINOGEN
FORMALDEHYDE 50-00-0 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-8276-7
VERSION NUMBER: 43.00
ISSUE DATE: 03/23/15
SUPERCEDES DATE: 01/16/08
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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