| Common Name: | GORILLA GLUE WHITE |
| Manufacturer: | GORILLA GLUE |
| SDS Revision Date: | 7/9/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KKF2, 2KKF3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GORILLA(R*)
INCREDIBLY STRONG
100% TOUGH
SAFETY DATA SHEET
GORILLA GLUE WHITE
DATE REVISED: 07/09/2015
DATE ISSUED: 07/09/2015
VERSION: 1.0
FOR CHEMICAL EMERGENCY:
DURING BUSINESS HOURS: (800) 966-3458
OUTSIDE BUSINESS HOURS: (800) 420-7186
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
| SECTION 1: IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: GORILLA GLUE WHITE
SYNONYMS: POLYURETHANE ADHESIVE
INTENDED USE OF THE PRODUCT:
CONSUMER ADHESIVES FOR BUILDING, CARPENTRY, OR HOBBY PROJECTS.
NAME, ADDRESS, AND TELEPHONE OF THE RESPONSIBLE PARTY:
COMPANY:
THE GORILLA GLUE COMPANY
4550 RED BANK EXPRESSWAY
CINCINNATI, OHIO 45227
513-271-3300
WWW.GORILLATOUGH.COM
EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: 1-800-420-7186 (PROSAR)
| SECTION 2: HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
ACUTE TOX. 4 (INHALATION:DUST,MIST) H332
SKIN IRRIT. 2 H315
EYE IRRIT. 2B H320
RESP. SENS. 1 H334
SKIN SENS. 1 H317
STOT SE 3 H335
STOT RE 1 H372
FULL TEXT OF H-PHRASES: SEE SECTION 16
LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H320: CAUSES EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS (GHS-US):
P260: DO NOT BREATHE VAPORS, MIST, OR SPRAY.
P264:
WASH HANDS, FOREARMS, AND OTHER EXPOSED AREAS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE PROTECTION.
P284: [IN CASE OF INADEQUATE VENTILATION] WEAR RESPIRATORY PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P304+P340:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P312: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER OR DOCTOR.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
TERRITORIAL, PROVINCIAL, AND INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
OTHER HAZARDS: CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
UNKNOWN ACUTE TOXICITY (GHS-US): NOT AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
NAME PRODUCT IDENTIFIER % (W/W) CLASSIFICATION (GHS-US)
AROMATIC (CAS NO): 167883-19-4 60 - 100 ACUTE TOX. 4
POLYISOCYANATE (INHALATION:DUST,
BASED ON MDI MIST), H332
SKIN IRRIT. 2, H315
EYE IRRIT. 2B, H320
RESP. SENS. 1, H334
SKIN SENS. 1, H317
STOT SE 3, H335
STOT RE 1, H372
4,4'-
DIPHENYLMETHANE (CAS NO): 101-68-8 10 - 20 ACUTE TOX. 4
DIISOCYANATE (INHALATION:DUST,
(MDI) MIST), H332
SKIN IRRIT. 2, H315
EYE IRRIT. 2B, H320
RESP. SENS. 1, H334
SKIN SENS. 1, H317
STOT SE 3, H335
STOT RE 1, H372
2,4'- (CAS NO): 5873-54-1 10 - 20 ACUTE TOX. 4
DIPHENYLMETHANE (INHALATION:DUST,
DIISOCYANATE MIST), H332
(MDI) SKIN IRRIT. 2, H315
EYE IRRIT. 2B, H320
RESP. SENS. 1, H334
SKIN SENS. 1, H317
STOT SE 3, H335
STOT RE 1, H372
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL IF POSSIBLE).
INHALATION:
USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY MOVE THE EXPOSED PERSON TO
FRESH AIR. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. GENTLY WASH WITH PLENTY OF SOAP AND WATER
FOLLOWED BY RINSING WITH WATER FOR AT LEAST 15 MINUTES. CALL A POISON
CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. OBTAIN MEDICAL ATTENTION.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS BOTH ACUTE AND DELAYED:
GENERAL:
HARMFUL IF INHALED. EXPOSURE MAY PRODUCE AN ALLERGIC REACTION. INHALATION
MAY CAUSE ALLERGIC RESPIRATORY REACTION WITH ASTHMA-LIKE SYMPTOMS AND
DIFFICULTY BREATHING. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE
IRRITATION.
INHALATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION. HARMFUL IF INHALED.
SKIN CONTACT:
EXPOSURE MAY PRODUCE AN ALLERGIC REACTION. CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION: INGESTION IS LIKELY TO BE HARMFUL OR HAVE ADVERSE EFFECTS.
CHRONIC SYMPTOMS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
| SECTION 5: FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY POWDER, AND FOAM. IN CASES OF LARGE SCALE FIRES,
ALCOHOL-RESISTANT FOAMS ARE PREFERRED. IF WATER IS USED, IT SHOULD BE USED
IN VERY LARGE QUANTITIES. THE REACTION BETWEEN WATER AND ISOCYANATE MAY BE
VIGOROUS.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. USE OF HEAVY STREAM OF WATER MAY SPREAD
FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: NOT FLAMMABLE.
EXPLOSION HAZARD: PRODUCT IS NOT EXPLOSIVE.
REACTIVITY:
EXOTHERMIC REACTIONS WITH AMINES AND ALCOHOLS; REACTS WITH WATER FORMING
HEAT, CARBON DIOXIDE, AND INSOLUBLE POLYUREA.
THE COMBINED EFFECT OF CO2 AND HEAT CAN PRODUCE ENOUGH PRESSURE TO RUPTURE
A CLOSED CONTAINER.
ADVICE FOR FIREFIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
FIREFIGHTING INSTRUCTIONS:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES (CO, CO2). NITROGEN COMPOUNDS. DENSE BLACK SMOKE, ISOCYANATE,
ISOCYANIC ACID.
REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 9 FOR FLAMMABILITY PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT (PPE).
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
FOR EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
UPON ARRIVAL AT THE SCENE, A FIRST RESPONDER IS EXPECTED TO RECOGNIZE THE
PRESENCE OF DANGEROUS GOODS, PROTECT ONESELF AND THE PUBLIC, SECURE THE
AREA, AND CALL FOR THE ASSISTANCE OF TRAINED PERSONNEL AS SOON AS
CONDITIONS PERMIT.
ENVIRONMENTAL PRECAUTIONS: PREVENT ENTRY TO SEWERS AND PUBLIC WATERS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL, THEN PLACE IN SUITABLE
CONTAINER.
METHODS FOR CLEANING UP:
REMOVE MECHANICALLY; COVER REMAINDERS WITH WET ABSORBENT MATERIAL (E. G.
SAND, EARTH, SAWDUST). AFTER APPROX. 15 MIN. TRANSFER TO WASTE CONTAINER
AND DO NOT SEAL (EVOLUTION OF CO2). KEEP DAMP IN A SAFE VENTILATED AREA FOR
SEVERAL DAYS.
CLEAN UP SPILLS IMMEDIATELY AND DISPOSE OF WASTE SAFELY.
REFERENCE TO OTHER SECTIONS:
SEE HEADING 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. CONCERNING
DISPOSAL ELIMINATION AFTER CLEANING, SEE ITEM 13.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PROCEDURES.
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING, OR SMOKING AND AGAIN WHEN LEAVING WORK.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A DRY, COOL AND WELL-VENTILATED PLACE. KEEP CONTAINER CLOSED WHEN
NOT IN USE. STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP PRODUCT AWAY FROM
SOURCES OF ALCOHOLS, AMINES, OR OTHER MATERIALS THAT REACT WITH
ISOCYANATES. KEEP OUT OF REACH OF CHILDREN AND ANIMALS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. AMINES. ALCOHOLS. WATER,
COPPER ALLOYS.
SPECIFIC END USE(S):
CONSUMER ADHESIVES FOR BUILDING, CARPENTRY, OR HOBBY PROJECTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
FOR SUBSTANCES LISTED IN SECTION 3 THAT ARE NOT LISTED HERE, THERE ARE NO
ESTABLISHED EXPOSURE LIMITS FROM THE MANUFACTURER, SUPPLIER, IMPORTER, OR
THE APPROPRIATE ADVISORY AGENCY INCLUDING:
ACGIH (TLV), NIOSH (REL), OSHA (PEL), CANADIAN PROVINCIAL GOVERNMENTS, OR
THE MEXICAN GOVERNMENT.
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI):
USA ACGIH:
ACGIH TWA (PPM): 0.005 PPM
USA OSHA:
OSHA PEL (CEILING) (MG/M3): 0.2 MG/M3
USA OSHA:
OSHA PEL (CEILING) (PPM): 0.02 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 0.05 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 0.005 PPM
USA NIOSH:
NIOSH REL (CEILING) (MG/M3): 0.2 MG/M3
USA NIOSH:
NIOSH REL (CEILING) (PPM): 0.020 PPM
USA IDLH:
US IDLH (MG/M3): 75 MG/M3
ALBERTA:
OEL TWA (MG/M3): 0.05 MG/M3
ALBERTA:
OEL TWA (PPM): 0.005 PPM
BRITISH COLUMBIA:
OEL CEILING (PPM): 0.01 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 0.005 PPM
MANITOBA:
OEL TWA (PPM): 0.005 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 0.051 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 0.005 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 0.005 PPM
NOVA SCOTIA:
OEL TWA (PPM): 0.005 PPM
ONTARIO:
OEL CEILING (PPM): 0.02 PPM (DESIGNATED SUBSTANCES REGULATION)
ONTARIO:
OEL TWA (PPM):
0.005 PPM (DESIGNATED SUBSTANCES REGULATION)
0.005 PPM (APPLIES TO WORKPLACES TO WHICH THE DESIGNATED SUBSTANCES
REGULATION DOES NOT APPLY)
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 0.005 PPM
QUEBEC:
VEMP (MG/M3): 0.051 MG/M3
QUEBEC:
VEMP (PPM): 0.005 PPM
SASKATCHEWAN:
OEL STEL (PPM): 0.015 PPM
SASKATCHEWAN:
OEL TWA (PPM): 0.005 PPM
YUKON:
OEL CEILING (MG/M3): 0.2 MG/M3
YUKON:
OEL CEILING (PPM): 0.02 PPM
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE SUFFICIENT
VENTILATION TO KEEP VAPORS BELOW PERMISSIBLE EXPOSURE LIMIT. ENSURE ALL
NATIONAL/LOCAL REGULATIONS ARE OBSERVED.
PERSONAL PROTECTIVE EQUIPMENT: PROTECTIVE CLOTHING. SAFETY GLASSES. GLOVES.
INSUFFICIENT VENTILATION: WEAR RESPIRATORY PROTECTION.
MATERIALS FOR PROTECTIVE CLOTHING:
CHEMICALLY RESISTANT MATERIALS AND FABRICS.
HAND PROTECTION: WEAR CHEMICALLY RESISTANT PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
USE A NIOSH-APPROVED RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS
WHENEVER EXPOSURE MAY EXCEED ESTABLISHED OCCUPATIONAL EXPOSURE LIMITS.
OTHER INFORMATION: WHEN USING, DO NOT EAT, DRINK OR SMOKE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR/TRANSPARENT/YELLOWISH
ODOR: MUSTY
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
FREEZING POINT: NOT AVAILABLE
BOILING POINT: >300 DEG. C (572 DEG. F)
FLASH POINT: 198 DEG. C (388.4 DEG. F) @ 1,013 MBAR
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
LOWER FLAMMABLE LIMIT: NOT AVAILABLE
UPPER FLAMMABLE LIMIT: NOT AVAILABLE
VAPOR PRESSURE: <0.0001 MMHg @ 25 DEG. C (77 DEG. F)
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT AVAILABLE
RELATIVE DENSITY: 1.123 G/CM3
SPECIFIC GRAVITY / DENSITY: 1.123 G/CM3
SOLUBILITY: INSOLUBLE IN WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
VISCOSITY: 3800 - 6000 MPA.S AT 25 DEG. C (77 DEG. F)
EXPLOSION DATA - SENSITIVITY TO MECHANICAL IMPACT:
NOT EXPECTED TO PRESENT AN EXPLOSION HAZARD DUE TO MECHANICAL IMPACT.
EXPLOSION DATA - SENSITIVITY TO STATIC DISCHARGE:
NOT EXPECTED TO PRESENT AN EXPLOSION HAZARD DUE TO STATIC DISCHARGE.
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY:
EXOTHERMIC REACTIONS WITH AMINES AND ALCOHOLS; REACTS WITH WATER FORMING
HEAT, CARBON DIOXIDE, AND INSOLUBLE POLYUREA.
THE COMBINED EFFECT OF CO2 AND HEAT CAN PRODUCE ENOUGH PRESSURE TO RUPTURE
A CLOSED CONTAINER.
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED HANDLING AND STORAGE CONDITIONS (SEE SECTION 7).
POSSIBILITY OF HAZARDOUS REACTIONS:
CONTACT WITH MOISTURE, OTHER MATERIALS THAT REACT WITH ISOCYANATES, OR
TEMPERATURES ABOVE 350 DEG. F (177 DEG. C) MAY CAUSE POLYMERIZATION.
CONDITIONS TO AVOID: DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS. ACIDS. ALCOHOLS. WATER,
COPPER ALLOYS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES (CO, CO2). NITROGEN COMPOUNDS. ISOCYANATES. DENSE BLACK
SMOKE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS - PRODUCT:
ACUTE TOXICITY:
INHALATION: DUST
MIST: HARMFUL IF INHALED.
LD50 AND LC50 DATA:
GORILLA GLUE WHITE:
ATE US (DUST, MIST): 1.50 MG/L/4H
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PH: NOT APPLICABLE
SERIOUS EYE DAMAGE/IRRITATION: CAUSES EYE IRRITATION.
PH: NOT APPLICABLE
RESPIRATORY OR SKIN SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
TERATOGENICITY: NOT AVAILABLE
CARCINOGENICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION. HARMFUL IF INHALED.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
EXPOSURE MAY PRODUCE AN ALLERGIC REACTION. CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS LIKELY TO BE HARMFUL OR HAVE ADVERSE EFFECTS.
CHRONIC SYMPTOMS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
INFORMATION ON TOXICOLOGICAL EFFECTS - INGREDIENT(S):
LD50 AND LC50 DATA:
AROMATIC POLYISOCYANATE BASED ON MDI (167883-19-4):
ATE US (DUST, MIST): 1.50 MG/L/4H
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8):
LD50 ORAL RAT: 31600 MG/KG
LD50 DERMAL RABBIT: >9400 MG/KG
LC50 INHALATION RAT: 369 MG/M3 (EXPOSURE TIME: 4 H)
ATE US (DUST, MIST): 0.37 MG/L/4H
2,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (5873-54-1):
LD50 ORAL RAT: >2000 MG/KG
LD50 DERMAL RABBIT: >9400 MG/KG
ATE US (DUST, MIST): 1.50 MG/L/4H
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8):
IARC GROUP: 3
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY DATA BASED ON POLYMERIC MDI (A MIXTURE OF MONOMERS AND HIGHER
MOLECULAR WEIGHT OLIGOMERS).
TOXICITY: NOT CLASSIFIED
PERSISTENCE AND DEGRADABILITY:
GORILLA GLUE WHITE:
BIODEGRADATION: 0% AFTER 28 DAYS
BIOACCUMULATIVE POTENTIAL: DOES NOT BIOACCUMULATE.
MOBILITY IN SOIL: NOT AVAILABLE
OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF WASTE MATERIAL IN ACCORDANCE WITH ALL LOCAL, REGIONAL, NATIONAL,
PROVINCIAL, TERRITORIAL AND INTERNATIONAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT: NOT REGULATED FOR TRANSPORT
IN ACCORDANCE WITH IMDG: NOT REGULATED FOR TRANSPORT
IN ACCORDANCE WITH IATA: NOT REGULATED FOR TRANSPORT
IN ACCORDANCE WITH TDG: NOT REGULATED FOR TRANSPORT
| SECTION 15: REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
GORILLA GLUE WHITE:
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
AROMATIC POLYISOCYANATE BASED ON MDI (167883-19-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON UNITED STATES SARA SECTION 313
US EPA CERCLA HAZARDOUS SUBSTANCE COMPONENT (40 CFR 302), REPORTABLE
QUANTITY: 5000 LBS
SARA SECTION 313 - EMISSION REPORTING: 1.0%
2,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (5873-54-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
US STATE REGULATIONS:
GORILLA GLUE WHITE:
THIS PRODUCT CONTAINS A TRACE (PPM) AMOUNT OF PHENYL ISOCYANATE
(CAS # 103-71-9) AND MONOCHLOROBENZENE (CAS # 108-90-7) AS IMPURITIES.
CALIFORNIA PROP 65:
TO THE BEST OF OUR KNOWLEDGE, THIS PRODUCT DOES NOT CONTAIN ANY OF THE
LISTED CHEMICALS, WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER,
BIRTH DEFECTS OR REPRODUCTIVE HARM.
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CANADIAN REGULATIONS:
GORILLA GLUE WHITE:
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
AROMATIC POLYISOCYANATE BASED ON MDI (167883-19-4):
LISTED ON THE CANADIAN NDSL (NON-DOMESTIC SUBSTANCES LIST)
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
IDL CONCENTRATION 0.1%
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
2,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) (5873-54-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY CPR.
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
REVISION DATE: 07/09/2015
OTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS OF
THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS FULL TEXT PHRASES:
ACUTE TOX. 4 (INHALATION:DUST,MIST):
ACUTE TOXICITY (INHALATION:DUST,MIST) CATEGORY 4
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2B
RESP. SENS. 1: RESPIRATORY SENSITISATION CATEGORY 1
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
SKIN SENS. 1: SKIN SENSITIZATION CATEGORY 1
STOT RE 1: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 1
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H320: CAUSES EYE IRRITATION
H332: HARMFUL IF INHALED
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
PARTY RESPONSIBLE FOR THE PREPARATION OF THIS DOCUMENT:
THE GORILLA GLUE COMPANY
+1 513-271-3300
THE INFORMATION PRESENTED IN THIS SAFETY DATA SHEET WAS PREPARED BY
QUALIFIED PERSONNEL AND TO THE BEST OF OUR KNOWLEDGE IS TRUE AND ACCURATE.
THE INFORMATION AND RECOMMENDATIONS ARE FURNISHED FOR THIS PRODUCT WITH THE
UNDERSTANDING THAT THE PURCHASER WILL INDEPENDENTLY DETERMINE THE
SUITABILITY OF THE PRODUCT FOR THIS PURPOSE. THIS DATA DOES NOT CONSTITUTE
A WARRANTY, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, NOR IS IT
REPRESENTATION FOR WHICH THE GORILLA GLUE COMPANY ASSUMES LEGAL
RESPONSIBILITY. THE DATA IS SUBMITTED FOR THE USER'S INFORMATION AND
CONSIDERATION ONLY. ANY USE OF THIS PRODUCT MUST BE DETERMINED BY THE USER
TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, PROVINCIAL AND LOCAL
LAWS AND REGULATIONS.
GORILLA GLUE NA GHS SDS