| Common Name: | HEAVY-BODIED SEAM SEALER, P.N. 08306, 08308, HEAVY-BODIED SEAM SEALER - ACCELERA |
| Manufacturer: | 3M |
| SDS Revision Date: | 8/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KUU4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) HEAVY-BODIED SEAM SEALER, P.N. 08306, 08308
08/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-6601-2
VERSION NUMBER: 3.03
ISSUE DATE: 08/24/15
SUPERCEDES DATE: 04/30/14
PRODUCT IDENTIFIER: 3M(TM) HEAVY-BODIED SEAM SEALER, P.N. 08306, 08308
ID NUMBER(S):
41-0003-8085-1, 41-3701-2154-7, 41-3701-3013-4, 60-9800-3490-8
RECOMMENDED USE: AUTOMOTIVE, TWO-PART EPOXY SEAM SEALER
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH
OF THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
08-6599-8, 08-6600-4
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) HEAVY-BODIED SEAM SEALER - ACCELERATOR, PN 08306, 08308
03/04/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-6599-8
VERSION NUMBER: 10.00
ISSUE DATE: 03/04/16
SUPERCEDES DATE: 10/15/14
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) HEAVY-BODIED SEAM SEALER - ACCELERATOR, PN 08306, 08308
PRODUCT IDENTIFICATION NUMBERS: LB-K100-0029-9
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AUTOMOTIVE, SEAM SEALER ACCELERATOR TO BE MIXED AT A 1:1 RATIO WITH SEALER
BASE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS: EXCLAMATION MARK
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
WEAR EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
9% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
MERCAPTAN-TERMINATED EPOXY TRADE SECRET* 60 - 100 TRADE SECRET*
CURING AGENT NJ 800938-5952
PROPRIETARY POLYAMINE- TRADE SECRET* 7 - 13 TRADE SECRET*
POLYMERCAPTAN BLEND
DIMETHYL SILOXANE, REACTION 67762-90-7 3 - 7 TRADE SECRET*
PRODUCT WITH SILICA
1,8-DIAZABICYCLO[5.4.0] 6674-22-2 <0.5 TRADE SECRET*
UNDEC-7-ENE
BIS(DIMETHYLAMINOETHYL) ETHER 3033-62-3 <0.5 TRADE SECRET*
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN
UP RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID EYE CONTACT. KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
BIS(DIMETHYLAMINOETHYL) 3033-62-3 ACGIH TWA: 0.05 PPM SKIN
ETHER STEL: 0.15 PPM NOTATION
DIMETHYL SILOXANE, 67762-90-7 CMRG CEIL: 5 MG/M3
REACTION PRODUCT WITH
SILICA
SILICA, AMORPHOUS 67762-90-7 OSHA TWA
CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: OFF WHITE, MERCAPTAN ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: >200 DEG. F
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.18 G/CM3
SPECIFIC GRAVITY: 1.180 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY - NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.14 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
1.7% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
20 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
PERCENT VOLATILE: 1.7% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
20 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN
A CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
OXIDES OF NITROGEN NOT SPECIFIED
OXIDES OF SULFUR NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
MERCAPTAN-TERMINATED EPOXY DERMAL RABBIT LD50: >10,200 MG/KG
CURING AGENT NJ 800938-5952
MERCAPTAN-TERMINATED EPOXY INGESTION RAT LD50: 2,600 MG/KG
CURING AGENT NJ 800938-5952
DIMETHYL SILOXANE, REACTION DERMAL RABBIT LD50: >5,000 MG/KG
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INHALATION- RAT LC50: >0.691 MG/L
PRODUCT WITH SILICA DUST/MIST
(4 HOURS)
DIMETHYL SILOXANE, REACTION INGESTION RAT LD50: >5,110 MG/KG
PRODUCT WITH SILICA
1,8-DIAZABICYCLO[5.4.0] DERMAL RABBIT LD50: 1,233 MG/KG
UNDEC-7-ENE
1,8-DIAZABICYCLO[5.4.0] INGESTION RAT LD50: 836 MG/KG
UNDEC-7-ENE
BIS(DIMETHYLAMINOETHYL) DERMAL RABBIT LD50: 238 MG/KG
ETHER
BIS(DIMETHYLAMINOETHYL) INHALATION- RAT LC50: 2.2 MG/L
ETHER VAPOR
(4 HOURS)
BIS(DIMETHYLAMINOETHYL) INGESTION RAT LD50: 570 MG/KG
ETHER
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
SKIN SENSITIZATION:
NAME SPECIES VALUE
DIMETHYL SILOXANE, REACTION HUMAN AND NOT SENSITIZING
PRODUCT WITH SILICA ANIMAL
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL SILOXANE, REACTION NOT MOUSE SOME POSITIVE DATA
PRODUCT WITH SILICA SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO FEMALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO MALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO DEVELOPMENT
PRODUCT WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 509 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 497 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: DURING
PRODUCT WITH SILICA 1,350 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL SILOXANE, INHALATION RESPIRATORY SYSTEM ALL DATA ARE
REACTION PRODUCT SILICOSIS NEGATIVE
WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL SILOXANE, REACTION HUMAN NOAEL: OCCUPATIONAL
PRODUCT WITH SILICA NOT AVAILABLE EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE
INCINERATION FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL
FUEL DURING INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED
FOR TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS
(CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER
APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF
AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE
REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO
DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
ETHYLENE GLYCOL 107-21-1 DEVELOPMENTAL TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 08-6599-8
VERSION NUMBER: 10.00
ISSUE DATE: 03/04/16
SUPERCEDES DATE: 10/15/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) HEAVY-BODIED SEAM SEALER - BASE (PART B) PN 08306, 08308
01/20/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-6600-4
VERSION NUMBER: 9.01
ISSUE DATE: 01/20/15
SUPERCEDES DATE: 10/15/14
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) HEAVY-BODIED SEAM SEALER - BASE (PART B) PN 08306, 08308
PRODUCT IDENTIFICATION NUMBERS: LB-K100-0030-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, TWO-PART EPOXY SEAM SEALER - BASE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN SENSITIZER: CATEGORY 1.
CARCINOGENICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
22% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
22% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
EPOXY RESIN 25068-38-6 40 - 80 TRADE SECRET *
EPOXY RESIN 30583-72-3 10 - 30 TRADE SECRET *
DIMETHYL SILOXANE, REACTION 67762-90-7 3 - 7 TRADE SECRET *
PRODUCT WITH SILICA
CARBON BLACK 1333-86-4 0.5 - 1.5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN
UP RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
CARBON BLACK 1333-86-4 CMRG TWA: 0.5 MG/M3
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
CARBON BLACK 1333-86-4 ACGIH TWA (INHALABLE A3:
FRACTION): 3 MG/M3 CONFIRMED
ANIMAL CARCIN.
SILICA, AMORPHOUS 67762-90-7 OSHA TWA CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
DIMETHYL 67762-90-7 CMRG CEIL: 5 MG/M3
SILOXANE,
REACTION PRODUCT
WITH SILICA
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM
THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BLACK, EPOXY ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: >239 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.16 G/CM3
SPECIFIC GRAVITY: 1.16 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.03 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
6 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.5% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.5% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
6 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT IS GENERATED DURING CURE. DO NOT CURE A MASS LARGER THAN 50 GRAMS IN
A CONFINED SPACE TO PREVENT A PREMATURE EXOTHERMIC REACTION WITH PRODUCTION
OF INTENSE HEAT AND SMOKE.
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS
AMINES
STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES NOT SPECIFIED
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
CARBON BLACK 1333-86-4 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN CARC. RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
EPOXY RESIN DERMAL RAT LD50: >1,600 MG/KG
EPOXY RESIN INGESTION RAT LD50: >1,000 MG/KG
DIMETHYL SILOXANE, DERMAL RABBIT LD50: >5,000 MG/KG
REACTION PRODUCT WITH
SILICA
DIMETHYL SILOXANE, INHALATION- RAT LC50: >0.691 MG/L
REACTION PRODUCT WITH DUST/MIST
SILICA (4 HOURS)
DIMETHYL SILOXANE, INGESTION RAT LD50: >5,110 MG/KG
REACTION PRODUCT WITH
SILICA
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MILD IRRITANT
DIMETHYL SILOXANE, REACTION PRODUCT RABBIT NO SIGNIFICANT IRRITATION
WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
EPOXY RESIN RABBIT MODERATE IRRITANT
DIMETHYL SILOXANE, REACTION PRODUCT RABBIT NO SIGNIFICANT IRRITATION
WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN SENSITIZING
AND
ANIMAL
DIMETHYL SILOXANE, REACTION HUMAN NOT SENSITIZING
PRODUCT WITH SILICA AND
ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
EPOXY RESIN HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
EPOXY RESIN IN VIVO NOT MUTAGENIC
EPOXY RESIN IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, REACTION PRODUCT IN VITRO NOT MUTAGENIC
WITH SILICA
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
EPOXY RESIN DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, NOT MOUSE SOME POSITIVE DATA EXIST,
REACTION PRODUCT WITH SPECIFIED BUT THE DATA ARE NOT
SILICA SUFFICIENT FOR
CLASSIFICATION
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
EPOXY RESIN INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
EPOXY RESIN INGESTION NOT TOXIC TO MALE
REPRODUCTION
EPOXY RESIN DERMAL NOT TOXIC TO DEVELOPMENT
EPOXY RESIN INGESTION NOT TOXIC TO DEVELOPMENT
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO FEMALE
PRODUCT WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO MALE
PRODUCT WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO DEVELOPMENT
PRODUCT WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
EPOXY RESIN RAT NOAEL: 750 MG/KG/DAY 2 GENERATION
EPOXY RESIN RAT NOAEL: 750 MG/KG/DAY 2 GENERATION
EPOXY RESIN RABBIT NOAEL: 300 MG/KG/DAY DURING
ORGANOGENESIS
EPOXY RESIN RAT NOAEL: 750 MG/KG/DAY 2 GENERATION
DIMETHYL SILOXANE, RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 1,350 MG/KG/DAY DURING
REACTION PRODUCT ORGANOGENESIS
WITH SILICA
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
EPOXY RESIN DERMAL LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPOXY RESIN DERMAL NERVOUS SYSTEM ALL DATA ARE
NEGATIVE
EPOXY RESIN INGESTION AUDITORY SYSTEM ALL DATA ARE
HEART NEGATIVE
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
LIVER
EYES
KIDNEY AND/OR BLADDER
DIMETHYL SILOXANE, INHALATION RESPIRATORY SYSTEM ALL DATA ARE
REACTION PRODUCT SILICOSIS NEGATIVE
WITH SILICA
CARBON BLACK INHALATION PNEUMOCONIOSIS SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
EPOXY RESIN RAT NOAEL: 1,000 MG/KG/DAY 2 YEARS
EPOXY RESIN RAT NOAEL: 1,000 MG/KG/DAY 13 WEEKS
EPOXY RESIN RAT NOAEL: 1,000 MG/KG/DAY 28 DAYS
DIMETHYL SILOXANE, HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
REACTION PRODUCT EXPOSURE
WITH SILICA
CARBON BLACK HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
LEAD 7439-92-1 FEMALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 MALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 CARCINOGEN
LEAD 7439-92-1 DEVELOPMENTAL TOXIN
CARBON BLACK 1333-86-4 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 08-6600-4
VERSION NUMBER: 9.01
ISSUE DATE: 01/20/15
SUPERCEDES DATE: 10/15/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM