| Common Name: | RIGID PILLAR FOAM PN 08458 |
| Manufacturer: | 3M |
| SDS Revision Date: | 2/20/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KUU5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) RIGID PILLAR FOAM PN 08458
02/20/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-3998-7
VERSION NUMBER: 8.01
ISSUE DATE: 02/20/17
SUPERCEDES DATE: 05/14/15
PRODUCT IDENTIFIER: 3M RIGID PILLAR FOAM PN 08458
ID NUMBER UPC
41-0003-6636-3
41-3701-2157-0
60-9800-4272-9
60-9800-4274-5
41-0003-8018-2
60-9800-3105-2
60-9800-4273-7
RECOMMENDED USE: AUTOMOTIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
07-3997-9, 07-3996-1
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY.
IN ADDITION, INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT
AS THE INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) RIGID PILLAR FOAM PN 08458 PART B
01/14/19
3M
SAFETY DATA SHEET
COPYRIGHT, 2019, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-3997-9
VERSION NUMBER: 12.04
ISSUE DATE: 01/14/19
SUPERCEDES DATE: 05/23/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) RIGID PILLAR FOAM PN 08458 PART B
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
LB-K100-0031-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AUTOMOTIVE, TWO COMPONENT RIGID FOAM
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
THIS INFORMATION MAY BE DIFFERENT FROM THE ACTUAL PRODUCT LABEL
INFORMATION FOR LABELS REGULATED BY OTHER AGENCIES.
2.1. HAZARD CLASSIFICATION:
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES DAMAGE TO ORGANS:
LIVER
NERVOUS SYSTEM
KIDNEY/URINARY TRACT
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
4% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLY[OXY(METHYL-1,2-ETHANEDIYL)], 25322-69-4 30 - 60 TRADE SECRET *
.ALPHA.-HYDRO-.OMEGA.-HYDROXY-
POLYPROPYLENE GLYCOL GLYCEROL 25791-96-2 15 - 40 TRADE SECRET *
TRIETHER
DIMETHYL SILOXANE, REACTION 67762-90-7 1 - 10 TRADE SECRET*
PRODUCT WITH SILICA
WATER 7732-18-5 1 - 10 TRADE SECRET*
DIETHYLENE GLYCOL 111-46-6 1 - 5 TRADE SECRET*
POTASSIUM ACETATE 127-08-2 1 - 5 TRADE SECRET*
POLYALKYLENE GLYCOL TRADE SECRET* 0.5 - 1.5 TRADE SECRET*
SILOXANE POLYALKYLENEOXIDE TRADE SECRET* 0.5 - 1.5 TRADE SECRET*
COPOLYMER
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL
TREATMENT REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND
EXPLODE.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
DIETHYLENE GLYCOL 111-46-6 AIHA TWA: 10 MG/M3
POLY[OXY(METHYL-1,2- 25322-69-4 AIHA TWA(AS AEROSOL):
ETHANEDIYL)], 10 MG/M3
.ALPHA.-HYDRO-
.OMEGA.-HYDROXY-
SILICA, AMORPHOUS 67762-90-7 OSHA TWA
CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION: EYE PROTECTION NOT REQUIRED.
SKIN/HAND PROTECTION: NO PROTECTIVE GLOVES REQUIRED.
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: OFF-WHITE LIQUID ODORLESS.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=390 DEG. F
FLASH POINT: >=200 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=27 PSIA [@ 131 DEG. F] [DETAILS: MITS DATA]
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1 - 1.08 G/ML
SPECIFIC GRAVITY: 1.04 [REF STD: WATER=1]
SOLUBILITY IN WATER: NOT APPLICABLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 4,000 - 8,000 CENTIPOISE [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS:
0.002 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
2 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
30 - 32 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
EYE CONTACT:
VAPORS RELEASED DURING CURING MAY CAUSE EYE IRRITATION. SIGNS/SYMPTOMS
MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR HAZY VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS,
TREMORS, AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
KIDNEY/BLADDER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE CHANGES IN URINE PRODUCTION, ABDOMINAL OR
LOWER BACK PAIN, INCREASED PROTEIN IN URINE, INCREASED BLOOD UREA
NITROGEN (BUN), BLOOD IN URINE, AND PAINFUL URINATION.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
>50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
300 - 2,000 MG/KG
POLY[OXY(METHYL- DERMAL RABBIT LD50: >10,000 MG/KG
1,2-ETHANEDIYL)],
.ALPHA.-HYDRO-.
OMEGA.-HYDROXY-
POLY[OXY(METHYL- INGESTION RAT LD50: >2,000 MG/KG
1,2-ETHANEDIYL)],
.ALPHA.-HYDRO-.
OMEGA.- HYDROXY-
POLYPROPYLENE DERMAL RAT LD50: >2,000 MG/KG
GLYCOL GLYCEROL
TRIETHER
POLYPROPYLENE INHALATION- RAT LC50: >50 MG/L
GLYCOL GLYCEROL DUST/MIST
TRIETHER (4 HOURS)
POLYPROPYLENE INGESTION RAT LD50: 4,600 MG/KG
GLYCOL GLYCEROL
TRIETHER
DIMETHYL SILOXANE, DERMAL RABBIT LD50: >5,000 MG/KG
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, INHALATION- RAT LC50: >0.691 MG/L
REACTION PRODUCT DUST/MIST
WITH SILICA (4 HOURS)
DIMETHYL SILOXANE, INGESTION RAT LD50: >5,110 MG/KG
REACTION PRODUCT
WITH SILICA
DIETHYLENE GLYCOL INGESTION HUMAN LD50 ESTIMATED TO BE
300 - 2,000 MG/KG
DIETHYLENE GLYCOL DERMAL RABBIT LD50: 13,300 MG/KG
DIETHYLENE GLYCOL INHALATION- RAT LC50: >4.6 MG/L
DUST/MIST
(4 HOURS)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLY[OXY(METHYL-1,2-ETHANEDIYL)], RABBIT NO SIGNIFICANT IRRITATION
.ALPHA.-HYDRO-.OMEGA.-HYDROXY-
POLYPROPYLENE GLYCOL GLYCEROL RABBIT NO SIGNIFICANT IRRITATION
TRIETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
DIETHYLENE GLYCOL RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLY[OXY(METHYL-1,2-ETHANEDIYL)], RABBIT NO SIGNIFICANT IRRITATION
.ALPHA.-HYDRO-.OMEGA.-HYDROXY-
POLYPROPYLENE GLYCOL GLYCEROL RABBIT MILD IRRITANT
TRIETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
DIETHYLENE GLYCOL RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
DIMETHYL SILOXANE, REACTION PRODUCT HUMAN AND ANIMAL NOT CLASSIFIED
WITH SILICA
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL SILOXANE, NOT SPECIFIED MOUSE SOME POSITIVE DATA EXIST,
REACTION PRODUCT BUT THE DATA ARE NOT
WITH SILICA SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
DIMETHYL SILOXANE, REACTION PRODUCT INGESTION NOT CLASSIFIED FOR FEMALE
WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION PRODUCT INGESTION NOT CLASSIFIED FOR MALE
WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION PRODUCT INGESTION NOT CLASSIFIED FOR
WITH SILICA DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL SILOXANE, RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 1,350 MG/KG/DAY DURING
REACTION PRODUCT ORGANOGENESIS
WITH SILICA
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIETHYLENE GLYCOL INGESTION LIVER CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
DIETHYLENE GLYCOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIETHYLENE GLYCOL HUMAN NOAEL: POISONING AND/OR
NOT AVAILABLE ABUSE
DIETHYLENE GLYCOL HUMAN NOAEL: POISONING AND/OR
NOT AVAILABLE ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL SILOXANE, INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
REACTION PRODUCT SILICOSIS
WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL
REACTION PRODUCT NOT AVAILABLE EXPOSURE
WITH SILICA
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
CADMIUM 7440-43-9 MALE REPRODUCTIVE TOXIN
CADMIUM AND CADMIUM COMPOUNDS 7440-43-9 CARCINOGEN
CADMIUM 7440-43-9 DEVELOPMENTAL TOXIN
ACETALDEHYDE 75-07-0 CARCINOGEN
ETHYLENE GLYCOL (INGESTED) 107-21-1 DEVELOPMENTAL TOXIN
FURAN 110-00-9 CARCINOGEN
MERCURY AND MERCURY COMPOUNDS 7439-97-6 DEVELOPMENTAL TOXIN
PROPYLENE OXIDE 75-56-9 CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE FEMALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE MALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE DEVELOPMENTAL TOXIN
LEAD 7439-92-1 FEMALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 MALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 CARCINOGEN
LEAD 7439-92-1 DEVELOPMENTAL TOXIN
COBALT METAL POWDER 7440-48-4 CARCINOGEN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 07-3997-9
VERSION NUMBER: 12.04
ISSUE DATE: 01/14/19
SUPERCEDES DATE: 05/23/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS
FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) RIGID PILLAR FOAM PN 08458 PART A
10/22/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-3996-1
VERSION NUMBER: 12.00
ISSUE DATE: 10/22/18
SUPERCEDES DATE: 05/23/18
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER: 3M(TM) RIGID PILLAR FOAM PN 08458 PART A
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, TWO COMPONENT RIGID FOAM
1.3. SUPPLIER' DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER, ST.
PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 30 - 60 TRADE SECRET*
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 15 - 40 TRADE SECRET*
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) 26447-40-5 7 - 30 TRADE SECRET*
DIMETHYL SILOXANE, REACTION PRODUCT 67762-90-7 1 - 5 TRADE SECRET*
WITH SILICA
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES
IF EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER IN CASE OF FIRE:
USE A CARBON DIOXIDE EXTINGUISHER TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL
AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER,
8% CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR
10 MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN
30 MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES
OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO
AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH
APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL/OCCUPATIONAL USE ONLY. NOT FOR CONSUMER SALE OR USE.
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED,
DO NOT RESEAL CONTAINER. STORE IN A DRY PLACE. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
P,P'-METHYLENEBIS 101-68-8 ACGIH TWA:
(PHENYL ISOCYANATE) 0.005 PPM
P,P'-METHYLENEBIS 101-68-8 OSHA CEIL:
(PHENYL ISOCYANATE) 0.2 MG/M3
(0.02 PPM)
SILICA, AMORPHOUS 67762-90-7 OSHA TWA
CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE APPROPRIATE LOCAL EXHAUST VENTILATION ON OPEN CONTAINERS.
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - NITRILE
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. AN EXPOSURE
ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED. IF A
RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: VISCOUS
ODOR, COLOR, GRADE: BROWN, NEGLIGIBLE ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=400 DEG. F
FLASH POINT: 390 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=27 PSIA [@ 131.0000000000 DEG. F] [DETAILS.MITS DATA]
VAPOR DENSITY: 8.50 [REF STD: AIR=1]
DENSITY: 1.24 G/ML
SPECIFIC GRAVITY: 1.24 [REF STD: WATER=1]
SOLUBILITY IN WATER: NOT APPLICABLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 5,000 - 14,000 CENTIPOISE [@ 80 DEG. F]
HAZARDOUS AIR POLLUTANTS:
13.6 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TESTMETHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
PERCENT VOLATILE: 0.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
AMINES
ALCOHOLS
WATER
REACTION WITH WATER, ALCOHOLS, AND AMINES IS NOT HAZARDOUS IF CONTAINER
CAN VENT TO THE ATMOSPHERE TO PREVENT PRESSURE BUILDUP.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES NOT SPECIFIED
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
HYDROGEN CYANIDE NOT SPECIFIED
OXIDES OF NITROGEN NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED
VAPOR(4 HR) ATE: >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
POLYMETHYLENE DERMAL RABBIT LD50: >5,000 MG/KG
POLYPHENYLENE
ISOCYANATE
POLYMETHYLENE INHALATION- RAT LC50: 0.368 MG/L
POLYPHENYLENE DUST/MIST
ISOCYANATE (4 HOURS)
POLYMETHYLENE INGESTION RAT LD50: 31,600 MG/KG
POLYPHENYLENE
ISOCYANATE
P,P'-METHYLENEBIS DERMAL RABBIT LD50: >5,000 MG/KG
(PHENYL ISOCYANATE)
P,P'-METHYLENEBIS INHALATION- RAT LC50: 0.368 MG/L
(PHENYL ISOCYANATE) DUST/MIST
(4 HOURS)
P,P'-METHYLENEBIS INGESTION RAT LD50: 31,600 MG/KG
(PHENYL ISOCYANATE)
1,1'-METHYLENEBIS DERMAL RABBIT LD50: >5,000 MG/KG
(ISOCYANATOBENZENE)
1,1'-METHYLENEBIS INHALATION- RAT LC50: 0.368 MG/L
(ISOCYANATOBENZENE) DUST/MIST
(4 HOURS)
1,1'-METHYLENEBIS INGESTION RAT LD50: 31,600 MG/KG
(ISOCYANATOBENZENE)
DIMETHYL SILOXANE, DERMAL RABBIT LD50: >5,000 MG/KG
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, INHALATION- RAT LC50: >0.691 MG/L
REACTION PRODUCT DUST/MIST
WITH SILICA (4 HOURS)
DIMETHYL SILOXANE, INGESTION RAT LD50: >5,110 MG/KG
REACTION PRODUCT
WITH SILICA
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL IRRITANT
CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL IRRITANT
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL IRRITANT
CLASSIFICATION
DIMETHYL SILOXANE, REACTION PRODUCT RABBIT NO SIGNIFICANT
WITH SILICA IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL SEVERE IRRITANT
CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
DIMETHYL SILOXANE, REACTION PRODUCT RABBIT NO SIGNIFICANT
WITH SILICA IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL SENSITIZING
CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SENSITIZING
CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) OFFICIAL SENSITIZING
CLASSIFICATION
DIMETHYL SILOXANE, REACTION PRODUCT HUMAN NOT CLASSIFIED
WITH SILICA AND ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE HUMAN SENSITIZING
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) HUMAN SENSITIZING
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
POLYMETHYLENE POLYPHENYLENE IN VITRO SOME POSITIVE DATA EXIST, BUT
ISOCYANATE THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL IN VITRO SOME POSITIVE DATA EXIST, BUT
ISOCYANATE) THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1,1'-METHYLENEBIS(ISOCYANATO- IN VITRO SOME POSITIVE DATA EXIST, BUT
BENZENE) THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE INHALATION RAT SOME POSITIVE DATA EXIST,
ISOCYANATE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
P,P'-METHYLENEBIS(PHENYL INHALATION RAT SOME POSITIVE DATA EXIST,
ISOCYANATE) BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
1,1'-METHYLENEBIS INHALATION RAT SOME POSITIVE DATA EXIST,
(ISOCYANATOBENZENE) BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, REACTION NOT MOUSE SOME POSITIVE DATA EXIST,
PRODUCT WITH SILICA SPECIFIED BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
POLYMETHYLENE POLYPHENYLENE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
ISOCYANATE
P,P'-METHYLENEBIS(PHENYL INHALATION NOT CLASSIFIED FOR DEVELOPMENT
ISOCYANATE)
1,1'-METHYLENEBIS INHALATION NOT CLASSIFIED FOR DEVELOPMENT
(ISOCYANATOBENZENE)
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR FEMALE
PRODUCT WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR MALE
PRODUCT WITH SILICA REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR DEVELOPMENT
PRODUCT WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE
DURATION
POLYMETHYLENE POLYPHENYLENE RAT NOAEL: DURING
ISOCYANATE 0.004 MG/L ORGANOGENESIS
P,P'-METHYLENEBIS RAT NOAEL: DURING
(PHENYL ISOCYANATE) 0.004 MG/L ORGANOGENESIS
1,1'-METHYLENEBIS RAT NOAEL: DURING
(ISOCYANATOBENZENE) 0.004 MG/L ORGANOGENESIS
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 509 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 497 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: DURING
PRODUCT WITH SILICA 1,350 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
POLYMETHYLENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
POLYPHENYLENE IRRITATION IRRITATION
ISOCYANATE
P,P'-METHYLENEBIS INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(PHENYL ISOCYANATE) IRRITATION IRRITATION
1,1'-METHYLENEBIS INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
(ISOCYANATOBENZENE) IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
POLYMETHYLENE OFFICIAL NOAEL:
POLYPHENYLENE CLASSIFICATION NOT AVAILABLE
ISOCYANATE
P,P'-METHYLENEBIS OFFICIAL NOAEL:
(PHENYL ISOCYANATE) CLASSIFICATION NOT AVAILABLE
1,1'-METHYLENEBIS OFFICIAL NOAEL:
(ISOCYANATOBENZENE) CLASSIFICATION NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
POLYMETHYLENE INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
POLYPHENYLENE SYSTEM THROUGH PROLONGED OR
ISOCYANATE REPEATED EXPOSURE
P,P'-METHYLENEBIS INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(PHENYL ISOCYANATE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
1,1'-METHYLENEBIS INHALATION RESPIRATORY CAUSES DAMAGE TO ORGANS
(ISOCYANATOBENZENE) SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
DIMETHYL SILOXANE, INHALATION RESPIRATORY NOT CLASSIFIED
REACTION PRODUCT SYSTEM
WITH SILICA SILICOSIS
NAME SPECIES TEST RESULT EXPOSURE DURATION
POLYMETHYLENE RAT LOAEL: 13 WEEKS
POLYPHENYLENE 0.004 MG/L
ISOCYANATE
P,P'-METHYLENEBIS RAT LOAEL: 13 WEEKS
(PHENYL ISOCYANATE) 0.004 MG/L
1,1'-METHYLENEBIS RAT LOAEL: 13 WEEKS
(ISOCYANATOBENZENE) 0.004 MG/L
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL
REACTION PRODUCT NOT AVAILABLE EXPOSURE
WITH SILICA
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 TRADE SECRET 30 - 60
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 30 - 60
(DIISOCYANATES (CERTAIN CHEMICALS ONLY))
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 TRADE SECRET 15 - 40
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 15 - 40
(BENZENE, 1,1'-METHYLENEBIS[4-ISOCYANATO-)
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 15 - 40
(DIISOCYANATES (CERTAIN CHEMICALS ONLY))
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 07-3996-1
VERSION NUMBER: 12.00
ISSUE DATE: 10/22/18
SUPERCEDES DATE: 05/23/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
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FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
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KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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