| Common Name: | FLEXICLEAR BODY SEAM SEALER, PN 08401, 08405 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KUU7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) FLEXICLEAR(TM) BODY SEAM SEALER, PN 08401, 08405
03/02/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-5391-7
VERSION NUMBER: 50.01
ISSUE DATE: 03/02/15
SUPERCEDES DATE: 01/20/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) FLEXICLEAR(TM) BODY SEAM SEALER, PN 08401, 08405
PRODUCT IDENTIFICATION NUMBERS: 62-5508-5209-9
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AUTOMOTIVE, JOINT AND SEAM SEALER FOR INTERIOR AND EXTERIOR JOINTS AND
SEAMS.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE SOLID: CATEGORY 1.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN CORROSION/IRRITATION: CATEGORY 2.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
CARCINOGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
FLAMMABLE SOLID.
CAUSES EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS: SENSORY ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
SENSORY ORGANS
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
27% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
59% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
TOLUENE 108-88-3 15 - 40 TRADE SECRET *
STYRENE/ALPHA-METHYLSTYRENE 9011-11-4 10 - 30 TRADE SECRET *
COPOLYMER
HYDROCARBON POLYMER, TRADE SECRET* 10 - 30 TRADE SECRET *
HYDROGENATED
SYNTHETIC RUBBER POLYMER TRADE SECRET* 7 - 13 TRADE SECRET *
WHITE MINERAL OIL (PETROLEUM) 8042-47-5 7 - 13 TRADE SECRET *
SYNTHETIC AMORPHOUS SILICA, 112945-52-5 5 - 10 TRADE SECRET *
FUMED, CRYSTALLINE FREE
XYLENE 1330-20-7 1 - 5 TRADE SECRET *
ETHYLBENZENE 100-41-4 <2 TRADE SECRET *
BENZENE 71-43-2 <0.05 TRADE SECRET *
CUMENE 98-82-8 <0.05 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING
TOOLS. VACUUM OR SWEEP UP.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND CAUSE FLAMMABLE GASES OR VAPORS OR
DUST IN THE SPILL AREA TO BURN OR EXPLODE. PLACE IN A METAL CONTAINER
APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE.
SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT.
AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) WEAR
LOW STATIC OR PROPERLY GROUNDED SHOES. USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE THE RISK OF IGNITION,
DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS USING THIS
PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID
FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
IF THERE IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
LOSS OF STABILIZING MATERIALS. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS.
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
ETHYLBENZENE 100-41-4 ACGIH TWA: 20 PPM A3:
CONFIRMED
ANIMAL CARCIN.
ETHYLBENZENE 100-41-4 OSHA TWA:
435 MG/M3
(100 PPM)
ETHYLBENZENE 100-41-4 CMRG TWA: 25 PPM
STEL: 75 PPM
TOLUENE 108-88-3 CMRG STEL: 75 PPM SKIN NOTATION
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS. AS
HUMAN CARCIN
SILICA, AMORPHOUS 112945-52-5 OSHA TWA CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
XYLENE 1330-20-7 OSHA TWA:
435 MG/M3
(100 PPM)
XYLENE 1330-20-7 ACGIH TWA: 100 PPM A4:
STEL: 150 PPM NOT CLASS. AS
HUMAN CARCIN
XYLENE 1330-20-7 CMRG TWA: 50 PPM
STEL: 75 PPM
BENZENE 71-43-2 ACGIH TWA: 0.5 PPM A1:
STEL: 2.5 PPM CONFIRMED
HUMAN CARCIN.,
SKIN NOTATION
BENZENE 71-43-2 OSHA TWA: 1 PPM 29 CFR
TWA: 10 PPM 1910.1028
STEL: 5 PPM
CEIL: 25 PPM
WHITE MINERAL 8042-47-5 CMRG TWA: 5 MG/M3
OIL (PETROLEUM) STEL: 10 MG/M3
PARAFFIN OIL 8042-47-5 OSHA TWA (AS MIST):
5 MG/M3
MINERAL OILS, 8042-47-5 ACGIH TWA (INHALABLE A4:
HIGHLY-REFINED FRACTION): NOT CLASS. AS
OILS 5 MG/M3 HUMAN CARCIN
CUMENE 98-82-8 OSHA TWA: SKIN NOTATION
245 MG/M3
(50 PPM)
CUMENE 98-82-8 ACGIH TWA: 50 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
FLUOROELASTOMER POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: CLEAR BUTTERY PASTE WITH SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: 232 DEG. F [DETAILS: CONDITIONS: (TOLUENE)]
FLASH POINT: 24 DEG. F [TEST METHOD: CLOSED CUP] [DETAILS: METHOD D56]
EVAPORATION RATE: 4.50 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): FLAMMABLE SOLID: CATEGORY 1.
FLAMMABLE LIMITS(LEL): 1.27 % VOLUME
FLAMMABLE LIMITS(UEL): 7.00 % VOLUME
VAPOR PRESSURE: 25.19 MMHg [DETAILS: CONDITIONS: @ 68F]
VAPOR DENSITY: 3.14 [REF STD: AIR=1]
DENSITY: 0.98 G/ML
SPECIFIC GRAVITY: 0.980 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY APPROXIMATELY: 450,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: 0.83 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
39.5 % WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
393 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
PERCENT VOLATILE: 40.1 % WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
393 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
SPARKS AND/OR FLAMES
HEAT
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
OLFACTORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE DECREASED ABILITY TO DETECT ODORS AND/OR
COMPLETE LOSS OF SMELL.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
BENZENE 71-43-2 GRP. 1: INTERNATIONAL AGENCY FOR
CARCINOGENIC TO HUMANS RESEARCH ON CANCER
BENZENE 71-43-2 KNOWN HUMAN CARCINOGEN NATIONAL TOXICOLOGY
PROGRAM CARCINOGENS
BENZENE 71-43-2 CANCER HAZARD OSHA CARCINOGENS
CUMENE 98-82-8 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN CARC. RESEARCH ON CANCER
ETHYLBENZENE 100-41-4 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN CARC. RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
STYRENE/ALPHA-METHYLSTYRENE INGESTION LD50:
COPOLYMER ESTIMATED TO BE
2,000 - 5,000 MG/KG
HYDROCARBON POLYMER, DERMAL RAT LD50: >2,000 MG/KG
HYDROGENATED
HYDROCARBON POLYMER, INGESTION RAT LD50: >5,000 MG/KG
HYDROGENATED
WHITE MINERAL OIL DERMAL RABBIT LD50: >2,000 MG/KG
(PETROLEUM)
WHITE MINERAL OIL INGESTION RAT LD50: >5,000 MG/KG
(PETROLEUM)
SYNTHETIC RUBBER POLYMER INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
SYNTHETIC AMORPHOUS SILICA, DERMAL RABBIT LD50: >5,000 MG/KG
FUMED, CRYSTALLINE FREE
SYNTHETIC AMORPHOUS SILICA, INHALATION- RAT LC50: >0.691 MG/L
FUMED, CRYSTALLINE FREE DUST/MIST
(4 HOURS)
SYNTHETIC AMORPHOUS SILICA, INGESTION RAT LD50: >5,110 MG/KG
FUMED, CRYSTALLINE FREE
XYLENE DERMAL RABBIT LD50: >4,200 MG/KG
XYLENE INHALATION- RAT LC50: 29 MG/L
VAPOR
(4 HOURS)
XYLENE INGESTION RAT LD50: 3,523 MG/KG
ETHYLBENZENE DERMAL RABBIT LD50: 15,433 MG/KG
ETHYLBENZENE INHALATION- RAT LC50: 17.4 MG/L
VAPOR
(4 HOURS)
ETHYLBENZENE INGESTION RAT LD50: 4,769 MG/KG
CUMENE DERMAL RABBIT LD50: >3,160 MG/KG
CUMENE INHALATION- RAT LC50: 39.4 MG/L
VAPOR
(4 HOURS)
CUMENE INGESTION RAT LD50: 1,400 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TOLUENE RABBIT IRRITANT
WHITE MINERAL OIL (PETROLEUM) RABBIT NO SIGNIFICANT IRRITATION
SYNTHETIC AMORPHOUS SILICA, RABBIT NO SIGNIFICANT IRRITATION
FUMED, CRYSTALLINE FREE
XYLENE RABBIT MILD IRRITANT
ETHYLBENZENE RABBIT MILD IRRITANT
CUMENE RABBIT MINIMAL IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TOLUENE RABBIT MODERATE IRRITANT
WHITE MINERAL OIL (PETROLEUM) RABBIT MILD IRRITANT
SYNTHETIC AMORPHOUS SILICA, RABBIT NO SIGNIFICANT IRRITATION
FUMED, CRYSTALLINE FREE
XYLENE RABBIT MILD IRRITANT
ETHYLBENZENE RABBIT MODERATE IRRITANT
CUMENE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
TOLUENE GUINEA PIG NOT SENSITIZING
WHITE MINERAL OIL (PETROLEUM) GUINEA PIG NOT SENSITIZING
SYNTHETIC AMORPHOUS SILICA, FUMED, HUMAN AND ANIMAL NOT SENSITIZING
CRYSTALLINE FREE
ETHYLBENZENE HUMAN NOT SENSITIZING
CUMENE GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
WHITE MINERAL OIL (PETROLEUM) IN VITRO NOT MUTAGENIC
SYNTHETIC AMORPHOUS SILICA, FUMED, IN VITRO NOT MUTAGENIC
CRYSTALLINE FREE
XYLENE IN VITRO NOT MUTAGENIC
XYLENE IN VIVO NOT MUTAGENIC
ETHYLBENZENE IN VIVO NOT MUTAGENIC
ETHYLBENZENE IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE IN VITRO NOT MUTAGENIC
CUMENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
WHITE MINERAL OIL DERMAL MOUSE NOT CARCINOGENIC
(PETROLEUM)
WHITE MINERAL OIL INHALATION MULTIPLE NOT CARCINOGENIC
(PETROLEUM) ANIMAL
SPECIES
SYNTHETIC AMORPHOUS NOT MOUSE SOME POSITIVE DATA
SILICA, FUMED, SPECIFIED EXIST, BUT THE DATA
CRYSTALLINE FREE ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE DERMAL RAT NOT CARCINOGENIC
XYLENE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
XYLENE INHALATION HUMAN SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION MULTIPLE CARCINOGENIC
ANIMAL
SPECIES
CUMENE INHALATION MULTIPLE CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TOLUENE INHALATION SOME POSITIVE FEMALE
REPRODUCTIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION SOME POSITIVE MALE
REPRODUCTIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
WHITE MINERAL OIL (PETROLEUM) INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
WHITE MINERAL OIL (PETROLEUM) INGESTION NOT TOXIC TO MALE
REPRODUCTION
WHITE MINERAL OIL (PETROLEUM) INGESTION NOT TOXIC TO DEVELOPMENT
SYNTHETIC AMORPHOUS SILICA, INGESTION NOT TOXIC TO FEMALE
FUMED, CRYSTALLINE FREE REPRODUCTION
SYNTHETIC AMORPHOUS SILICA, INGESTION NOT TOXIC TO MALE
FUMED, CRYSTALLINE FREE REPRODUCTION
SYNTHETIC AMORPHOUS SILICA, INGESTION NOT TOXIC TO DEVELOPMENT
FUMED, CRYSTALLINE FREE
XYLENE INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
XYLENE INGESTION NOT TOXIC TO MALE
REPRODUCTION
XYLENE INHALATION SOME POSITIVE FEMALE
REPRODUCTIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INGESTION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
XYLENE INHALATION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
ETHYLBENZENE INHALATION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
CUMENE INHALATION NOT TOXIC TO FEMALE
REPRODUCTION
CUMENE INGESTION NOT TOXIC TO MALE
REPRODUCTION
CUMENE INHALATION NOT TOXIC TO MALE
REPRODUCTION
CUMENE INHALATION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
TOLUENE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING GESTATION
520 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING AND/OR ABUSE
NOT AVAILABLE
WHITE MINERAL OIL RAT NOAEL: 13 WEEKS
(PETROLEUM) 4,350 MG/KG/DAY
WHITE MINERAL OIL RAT NOAEL: 13 WEEKS
(PETROLEUM) 4,350 MG/KG/DAY
WHITE MINERAL OIL RAT NOAEL: DURING GESTATION
(PETROLEUM) 4,350 MG/KG/DAY
SYNTHETIC AMORPHOUS RAT NOAEL: 1 GENERATION
SILICA, FUMED, 509 MG/KG/DAY
CRYSTALLINE FREE
SYNTHETIC AMORPHOUS RAT NOAEL: 1 GENERATION
SILICA, FUMED, 497 MG/KG/DAY
CRYSTALLINE FREE
SYNTHETIC AMORPHOUS RAT NOAEL: DURING ORGANOGENESIS
SILICA, FUMED, 1,350 MG/KG/DAY
CRYSTALLINE FREE
XYLENE MOUSE NOAEL: 103 WEEKS
1,000 MG/KG/DAY
XYLENE MOUSE NOAEL: 103 WEEKS
1,000 MG/KG/DAY
XYLENE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
XYLENE MOUSE NOAEL: DURING ORGANOGENESIS
NOT AVAILABLE
XYLENE MULTIPLE NOAEL: DURING GESTATION
ANIMAL NOT AVAILABLE
SPECIES
ETHYLBENZENE RAT NOAEL: 4.3 MG/L PREMATING & DURING
GESTATION
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RAT NOAEL: 6 MONTHS
769 MG/KG/DAY
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RABBIT NOAEL: 11.3 MG/L DURING ORGANOGENESIS
LACTATION:
NAME ROUTE SPECIES VALUE
XYLENE INGESTION MOUSE DOES NOT CAUSE EFFECTS ON OR
VIA LACTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
TOLUENE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
XYLENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
ORGANS
XYLENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
XYLENE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INHALATION EYES SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
XYLENE INGESTION EYES SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ETHYLBENZENE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CUMENE INHALATION RESPIRATORY IRRITATION MAY CAUSE
RESPIRATORY
IRRITATION
CUMENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
TOLUENE HUMAN NOAEL: NOT AVAILABLE
TOLUENE HUMAN NOAEL: NOT AVAILABLE
TOLUENE MOUSE NOAEL: 0.004 MG/L 3 HOURS
TOLUENE HUMAN NOAEL: NOT AVAILABLE POISONING AND/OR
ABUSE
XYLENE RAT LOAEL: 6.3 MG/L 8 HOURS
XYLENE HUMAN NOAEL: NOT AVAILABLE
XYLENE HUMAN NOAEL: NOT AVAILABLE
XYLENE RAT NOAEL: 3.5 MG/L NOT AVAILABLE
XYLENE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
XYLENE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
XYLENE RAT NOAEL: 250 MG/KG NOT APPLICABLE
ETHYLBENZENE HUMAN NOAEL: NOT AVAILABLE
ETHYLBENZENE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
CUMENE MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
CUMENE HUMAN LOAEL: 0.2 MG/L OCCUPATIONAL
EXPOSURE
CUMENE MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM THROUGH PROLONGED OR
EYES REPEATED EXPOSURE
OLFACTORY SYSTEM
TOLUENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION HEART SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA
KIDNEY AND/OR BLADDER ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION BONE, TEETH, NAILS, SOME POSITIVE DATA
AND/OR HAIR EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
VASCULAR SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION HEART SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION LIVER SOME POSITIVE DATA
KIDNEY AND/OR BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
WHITE MINERAL INGESTION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
OIL (PETROLEUM) EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
WHITE MINERAL INGESTION LIVER SOME POSITIVE DATA
OIL (PETROLEUM) IMMUNE SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
SYNTHETIC INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
AMORPHOUS SILICOSIS
SILICA, FUMED,
CRYSTALLINE
FREE
XYLENE INHALATION NERVOUS SYSTEM CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
XYLENE INHALATION AUDITORY SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH PROLONGED
OR REPEATED EXPOSURE
XYLENE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INHALATION HEART ALL DATA ARE NEGATIVE
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
MUSCLES
KIDNEY AND/OR BLADDER
RESPIRATORY SYSTEM
XYLENE INGESTION AUDITORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
XYLENE INGESTION HEART ALL DATA ARE NEGATIVE
SKIN
ENDOCRINE SYSTEM
BONE, TEETH, NAILS,
AND/OR HAIR
HEMATOPOIETIC SYSTEM
IMMUNE SYSTEM
NERVOUS SYSTEM
RESPIRATORY SYSTEM
ETHYLBENZENE INHALATION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION HEMATOPOIETIC SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION AUDITORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHYLBENZENE INHALATION BONE, TEETH, NAILS, ALL DATA ARE NEGATIVE
AND/OR HAIR
MUSCLES
ETHYLBENZENE INHALATION HEART ALL DATA ARE NEGATIVE
IMMUNE SYSTEM
RESPIRATORY SYSTEM
ETHYLBENZENE INGESTION LIVER SOME POSITIVE DATA
KIDNEY AND/OR BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE INHALATION AUDITORY SYSTEM SOME POSITIVE DATA
ENDOCRINE SYSTEM EXIST, BUT THE DATA
HEMATOPOIETIC SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
NERVOUS SYSTEM
EYES
CUMENE INHALATION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
CUMENE INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE INGESTION HEART ALL DATA ARE NEGATIVE
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
LIVER
RESPIRATORY SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
TOLUENE HUMAN NOAEL: NOT AVAILABLE POISONING AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: NOT AVAILABLE 20 DAYS
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TOLUENE RAT NOAEL: 625 MG/KG/DAY 13 WEEKS
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 600 MG/KG/DAY 14 DAYS
TOLUENE MOUSE NOAEL: 105 MG/KG/DAY 28 DAYS
TOLUENE MOUSE NOAEL: 105 MG/KG/DAY 4 WEEKS
WHITE MINERAL RAT NOAEL: 90 DAYS
OIL 1,381 MG/KG/DAY
(PETROLEUM)
WHITE MINERAL RAT NOAEL: 90 DAYS
OIL 1,336 MG/KG/DAY
(PETROLEUM)
SYNTHETIC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
AMORPHOUS
SILICA, FUMED,
CRYSTALLINE
FREE
XYLENE RAT LOAEL: 0.4 MG/L 4 WEEKS
XYLENE RAT LOAEL: 7.8 MG/L 5 DAYS
XYLENE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
XYLENE MULTIPLE NOAEL: 3.5 MG/L 13 WEEKS
ANIMAL
SPECIES
XYLENE RAT NOAEL: 900 MG/KG/DAY 2 WEEKS
XYLENE RAT NOAEL: 90 DAYS
1,500 MG/KG/DAY
XYLENE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
XYLENE MOUSE NOAEL: 103 WEEKS
1,000 MG/KG/DAY
ETHYLBENZENE RAT NOAEL: 1.1 MG/L 2 YEARS
ETHYLBENZENE MOUSE NOAEL: 1.1 MG/L 103 WEEKS
ETHYLBENZENE RAT NOAEL: 3.4 MG/L 28 DAYS
ETHYLBENZENE RAT NOAEL: 2.4 MG/L 5 DAYS
ETHYLBENZENE MOUSE NOAEL: 3.3 MG/L 103 WEEKS
ETHYLBENZENE MULTIPLE NOAEL: 4.2 MG/L 90 DAYS
ANIMAL
SPECIES
ETHYLBENZENE MULTIPLE NOAEL: 3.3 MG/L 2 YEARS
ANIMAL
SPECIES
ETHYLBENZENE RAT NOAEL: 680 MG/KG/DAY 6 MONTHS
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RAT NOAEL: 4.9 MG/L 13 WEEKS
CUMENE RAT NOAEL: 59 MG/L 13 WEEKS
CUMENE RAT NOAEL: 769 MG/KG/DAY 6 MONTHS
CUMENE RAT NOAEL: 769 MG/KG/DAY 6 MONTHS
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
WHITE MINERAL OIL (PETROLEUM) ASPIRATION HAZARD
XYLENE ASPIRATION HAZARD
ETHYLBENZENE ASPIRATION HAZARD
CUMENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE), D018 (BENZENE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
TOLUENE 108-88-3 15 - 40
XYLENE (BENZENE, 1,2-DIMETHYL-) 1330-20-7 1 - 5
XYLENE (BENZENE, DIMETHYL-) 1330-20-7 1 - 5
XYLENE 1330-20-7 1 - 5
XYLENE (BENZENE, 1,3-DIMETHYL-) 1330-20-7 1 - 5
XYLENE (BENZENE, 1,4-DIMETHYL-) 1330-20-7 1 - 5
ETHYLBENZENE 100-41-4 <2
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
ETHYLBENZENE 100-41-4 CARCINOGEN
TOLUENE 108-88-3 FEMALE REPRODUCTIVE TOXIN
TOLUENE 108-88-3 DEVELOPMENTAL TOXIN
BENZENE 71-43-2 MALE REPRODUCTIVE TOXIN
BENZENE 71-43-2 CARCINOGEN
BENZENE 71-43-2 DEVELOPMENTAL TOXIN
CUMENE 98-82-8 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-5391-7
VERSION NUMBER: 50.01
ISSUE DATE: 03/02/15
SUPERCEDES DATE: 01/20/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM