| Common Name: | PANEL BONDING ADHESIVE PN 08115 |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVB4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) PANEL BONDING ADHESIVE PN 08115
09/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-1664-7
ISSUE DATE: 09/24/15
VERSION NUMBER: 12.10
SUPERCEDES DATE: 11/24/14
PRODUCT IDENTIFIER: 3M(TM) PANEL BONDING ADHESIVE PN 08115
ID NUMBER(S):
41-0003-6745-2, 41-0003-8009-1, 41-0003-8082-8, 41-9103-0505-5,
60-9800-3093-0, 60-9800-3246-4, 60-9800-4425-3, FS-9100-3423-0,
FS-9100-3424-8, FS-9100-3425-5, FS-9100-5376-8
RECOMMENDED USE: AUTOMOTIVE, ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
09-3599-9, 32-4327-6
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) PANEL BONDING (90 MINUTES) ADHESIVE PART A (ACCELERATOR) PN 08115,
38315, 58115
09/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 09-3599-9
ISSUE DATE: 09/24/15
VERSION NUMBER: 14.10
SUPERCEDES DATE: 09/11/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) PANEL BONDING (90 MINUTES) ADHESIVE PART A (ACCELERATOR) PN 08115,
38315, 58115
PRODUCT IDENTIFICATION NUMBERS: LB-K100-0010-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, USE WITH PART B, MSDS 32-4327-6
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SKIN SENSITIZER: CATEGORY 1B.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS. PERSONS PREVIOUSLY SENSITIZED TO
AMINES MAY DEVELOP A CROSS-SENSITIZATION REACTION TO CERTAIN OTHER AMINES.
36% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
37% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYMERIC DIAMIDE 68911-25-1 15 - 40 TRADE SECRET *
FUSED SILICA 60676-86-0 10 - 30 TRADE SECRET *
BUTADIENE ACRYLONITRILE 68683-29-4 9 - 30 TRADE SECRET *
COPOLYMER
BIS(3-AMINOPROPYL) ETHER OF 4246-51-9 7 - 13 TRADE SECRET *
DIETHYLENE GLYCOL
TRIS(2,4,6-DIMETHYLAMINO- 90-72-2 5 - 10 TRADE SECRET *
MONOMETHYL)PHENOL
AMINE EPOXY CURING AGENT 288-32-4 1 - 5 TRADE SECRET *
DIMETHYL SILOXANE, REACTION 67762-90-7 1 - 5 TRADE SECRET *
PRODUCT WITH SILICA
INORGANIC SALT - NJTSRN TRADE SECRET* 1 - 5 TRADE SECRET *
04499600-6317
BIS[(DIMETHYLAMINO)METHYL] 71074-89-0 0.1 - 1.5 TRADE SECRET *
PHENOL
N-AMINOETHYLPIPERAZINE 140-31-8 0.1 - 1.5 TRADE SECRET *
TOLUENE 108-88-3 <0.5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE
REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID
ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS
REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS. AS
HUMAN CARCIN
TOLUENE 108-88-3 CMRG STEL: 75 PPM SKIN NOTATION
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
SILICA, 60676-86-0 OSHA TWA CONCENTRATION:
AMORPHOUS 0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
DIMETHYL 67762-90-7 CMRG CEIL: 5 MG/M3
SILOXANE,
REACTION
PRODUCT WITH
SILICA
SILICA, 67762-90-7 OSHA TWA CONCENTRATION:
AMORPHOUS 0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
TRIS(2,4,6- 90-72-2 CMRG TWA: 5 PPM
DIMETHYLAMINO-
MONOMETHYL)
PHENOL
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: VISCOUS LIQUID
ODOR, COLOR, GRADE: TAN LIQUID, SLIGHT AMINE ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=110 DEG. C
FLASH POINT: 110 DEG. C [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: <=1 [REF STD: BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=200 MMHg [@ 20 DEG. C]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.2 G/ML
SPECIFIC GRAVITY: 1.2 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 - 225,000 CENTIPOISE [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0.01 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
4 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.4% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.4% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
4 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT: MAY BE HARMFUL IN CONTACT WITH SKIN.
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
FUSED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUSED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUSED SILICA INGESTION RAT LD50: >5,110 MG/KG
BUTADIENE DERMAL RABBIT LD50: >3,000 MG/KG
ACRYLONITRILE
COPOLYMER
BUTADIENE INGESTION RAT LD50: >15,300 MG/KG
ACRYLONITRILE
COPOLYMER
BIS(3-AMINOPROPYL) DERMAL RABBIT LD50: 2,500 MG/KG
ETHER OF
DIETHYLENE GLYCOL
BIS(3-AMINOPROPYL) INGESTION RAT LD50: 3,160 MG/KG
ETHER OF
DIETHYLENE GLYCOL
TRIS(2,4,6- DERMAL RAT LD50: 1,280 MG/KG
DIMETHYLAMINOMONO-
METHYL)PHENOL
TRIS(2,4,6- INGESTION RAT LD50: 1,000 MG/KG
DIMETHYLAMINOMONO-
METHYL)PHENOL
DIMETHYL DERMAL RABBIT LD50: >5,000 MG/KG
SILOXANE, REACTION
PRODUCT WITH
SILICA
DIMETHYL INHALATION- RAT LC50: >0.691 MG/L
SILOXANE, REACTION DUST/MIST
PRODUCT WITH (4 HOURS)
SILICA
DIMETHYL INGESTION RAT LD50: >5,110 MG/KG
SILOXANE, REACTION
PRODUCT WITH
SILICA
AMINE EPOXY DERMAL LD50:
CURING AGENT ESTIMATED TO BE
200 - 1,000 MG/KG
AMINE EPOXY INGESTION RAT LD50: 970 MG/KG
CURING AGENT
INORGANIC SALT - DERMAL RAT LD50:
NJTSRN ESTIMATED TO BE
04499600-6317 >5,000 MG/KG
INORGANIC SALT - INGESTION RAT LD50: 9,285 MG/KG
NJTSRN
04499600-6317
BIS[(DIMETHYLA- INGESTION LD50:
MINO)METHYL]PHENOL ESTIMATED TO BE
300 - 2,000 MG/KG
N-AMINOETHYL- DERMAL RABBIT LD50: 865 MG/KG
PIPERAZINE
N-AMINOETHYL- INGESTION RAT LD50: 1,470 MG/KG
PIPERAZINE
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR (4
HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT RABBIT CORROSIVE
POLYMERIC DIAMIDE RABBIT IRRITANT
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
BIS(3-AMINOPROPYL) ETHER OF RABBIT CORROSIVE
DIETHYLENE GLYCOL
TRIS(2,4,6-DIMETHYLAMINOMONO- RABBIT CORROSIVE
METHYL)PHENOL
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
BIS[(DIMETHYLAMINO)METHYL]PHENOL SIMILAR CORROSIVE
COMPOUNDS
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TOLUENE RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT SIMILAR CORROSIVE
HEALTH
HAZARDS
POLYMERIC DIAMIDE SIMILAR CORROSIVE
HEALTH
HAZARDS
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
BIS(3-AMINOPROPYL) ETHER OF SIMILAR CORROSIVE
DIETHYLENE GLYCOL HEALTH
HAZARDS
TRIS(2,4,6-DIMETHYLAMINOMONO- RABBIT CORROSIVE
METHYL)PHENOL
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
BIS[(DIMETHYLAMINO)METHYL]PHENOL SIMILAR CORROSIVE
COMPOUNDS
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TOLUENE RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
OVERALL PRODUCT GUINEA SENSITIZING
PIG
POLYMERIC DIAMIDE GUINEA SENSITIZING
PIG
FUSED SILICA HUMAN NOT SENSITIZING
AND
ANIMAL
BUTADIENE ACRYLONITRILE GUINEA SOME POSITIVE DATA EXIST, BUT
COPOLYMER PIG THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6-DIMETHYLAMINOMONO- GUINEA SOME POSITIVE DATA EXIST, BUT
METHYL)PHENOL PIG THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, REACTION HUMAN NOT SENSITIZING
PRODUCT WITH SILICA AND
ANIMAL
N-AMINOETHYLPIPERAZINE GUINEA SENSITIZING
PIG
TOLUENE GUINEA NOT SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
FUSED SILICA IN VITRO NOT MUTAGENIC
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL) IN VITRO NOT MUTAGENIC
PHENOL
DIMETHYL SILOXANE, REACTION PRODUCT IN VITRO NOT MUTAGENIC
WITH SILICA
N-AMINOETHYLPIPERAZINE IN VIVO NOT MUTAGENIC
N-AMINOETHYLPIPERAZINE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
FUSED SILICA NOT MOUSE SOME POSITIVE DATA EXIST, BUT
SPECIFIED THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, NOT MOUSE SOME POSITIVE DATA EXIST, BUT
REACTION PRODUCT SPECIFIED THE DATA ARE NOT SUFFICIENT FOR
WITH SILICA CLASSIFICATION
TOLUENE DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
FUSED SILICA INGESTION NOT TOXIC TO FEMALE REPRODUCTION
FUSED SILICA INHALATION NOT TOXIC TO MALE REPRODUCTION
FUSED SILICA INGESTION NOT TOXIC TO DEVELOPMENT
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO FEMALE REPRODUCTION
REACTION PRODUCT WITH
SILICA
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO MALE REPRODUCTION
REACTION PRODUCT WITH
SILICA
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO DEVELOPMENT
REACTION PRODUCT WITH
SILICA
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO FEMALE REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO MALE REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO DEVELOPMENT
TOLUENE INHALATION SOME POSITIVE FEMALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
TOLUENE INHALATION SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
FUSED SILICA RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
FUSED SILICA RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
FUSED SILICA RAT NOAEL: 1,350 MG/KG/DAY DURING
ORGANOGENESIS
DIMETHYL SILOXANE, RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: DURING
REACTION PRODUCT 1,350 MG/KG/DAY ORGANOGENESIS
WITH SILICA
N-AMINOETHYL- RAT NOAEL: 598 MG/KG/DAY PREMATING &
PIPERAZINE DURING GESTATION
N-AMINOETHYL- RAT NOAEL: 409 MG/KG/DAY 32 DAYS
PIPERAZINE
N-AMINOETHYL- RAT NOAEL: 899 MG/KG/DAY PREMATING &
PIPERAZINE DURING GESTATION
TOLUENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: 520 MG/KG/DAY DURING GESTATION
TOLUENE HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
BIS(3-AMINOPROPYL) INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
ETHER OF IRRITATION BUT THE DATA ARE NOT
DIETHYLENE GLYCOL SUFFICIENT FOR
CLASSIFICATION
TRIS(2,4,6- INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
DIMETHYLAMINOMONO- IRRITATION BUT THE DATA ARE NOT
METHYL)PHENOL SUFFICIENT FOR
CLASSIFICATION
N-AMINOETHYL- INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
PIPERAZINE IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DIZZINESS
DEPRESSION
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DIZZINESS
DEPRESSION
NAME SPECIES TEST RESULT EXPOSURE DURATION
BIS(3-AMINOPROPYL) ETHER NOAEL:
OF DIETHYLENE GLYCOL NOT AVAILABLE
TRIS(2,4,6- NOAEL:
DIMETHYLAMINOMONOMETHYL) NOT AVAILABLE
PHENOL
N-AMINOETHYLPIPERAZINE NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
FUSED SILICA INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
SILICOSIS
TRIS(2,4,6- DERMAL SKIN SOME POSITIVE DATA
DIMETHYLAMINOMO- LIVER EXIST, BUT THE
NOMETHYL)PHENOL NERVOUS SYSTEM DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6- DERMAL AUDITORY SYSTEM ALL DATA ARE NEGATIVE
DIMETHYLAMINO- HEMATOPOIETIC
MONOMETHYL)PHENOL SYSTEM
EYES
DIMETHYL INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
SILOXANE, SILICOSIS
REACTION PRODUCT
WITH SILICA
N-AMINOETHYL- INGESTION HEART ALL DATA ARE NEGATIVE
PIPERAZINE ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM THROUGH PROLONGED OR
EYES REPEATED EXPOSURE
OLFACTORY SYSTEM
TOLUENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEART SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA
KIDNEY ARE NOT SUFFICIENT
AND/OR BLADDER FOR CLASSIFICATION
TOLUENE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION BONE, TEETH, SOME POSITIVE DATA
NAILS, AND/OR HAIR EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
VASCULAR SYSTEM NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEART SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION LIVER SOME POSITIVE DATA
KIDNEY AND/OR EXIST, BUT THE DATA ARE
BLADDER NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
FUSED SILICA HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
TRIS(2,4,6- RAT NOAEL: 28 DAYS
DIMETHYLAMINO- 125 MG/KG/DAY
MONOMETHYL)PHENOL
TRIS(2,4,6- RAT NOAEL: 28 DAYS
DIMETHYLAMINO- 125 MG/KG/DAY
MONOMETHYL)PHENOL
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL EXPOSURE
REACTION PRODUCT NOT AVAILABLE
WITH SILICOSIS
SILICA
N-AMINOETHYL- RAT NOAEL: 28 DAYS
PIPERAZINE 598 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
INORGANIC SALT - NJTSRN 04499600-6317 TRADE SECRET 1 - 5
(NITRATE COMPOUNDS (WATER DISSOCIABLE;
REPORTABLE ONLY WHEN IN AQUEOUS SOLUTION))
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
BENZENE 71-43-2 MALE REPRODUCTIVE TOXIN
BENZENE 71-43-2 CARCINOGEN
BENZENE 71-43-2 DEVELOPMENTAL TOXIN
TOLUENE 108-88-3 FEMALE REPRODUCTIVE TOXIN
TOLUENE 108-88-3 DEVELOPMENTAL TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 09-3599-9
ISSUE DATE: 09/24/15
VERSION NUMBER: 14.10
SUPERCEDES DATE: 09/11/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) PANEL BONDING ADHESIVE PART B PNS 08115, 38315, 58115
09/23/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 32-4327-6
ISSUE DATE: 09/23/15
VERSION NUMBER: 1.01
SUPERCEDES DATE: 11/24/14
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) PANEL BONDING ADHESIVE PART B PNS 08115, 38315, 58115
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, STRUCTURAL PANEL BONDING ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE
DIFFERENT FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED
BY OTHER AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
CARCINOGENICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
34% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
4,4'-ISOPROPYLIDENEDIPHENOL- 25068-38-6 30 - 60 TRADE SECRET *
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS 65997-17-3 10 - 30 TRADE SECRET *
FUSED SILICA 60676-86-0 7 - 13 TRADE SECRET *
1,4-BIS[(2,3-EPOXYPROPOXY) 14228-73-0 7 - 13 TRADE SECRET *
METHYL]CYCLOHEXANE
ACRYLATE POLYMER TRADE SECRET* 5 - 10 TRADE SECRET *
SILICA 7631-86-9 1 - 5 TRADE SECRET *
3-(TRIMETHOXYSILYL)PROPYL 2530-83-8 0.5 - 1.5 TRADE SECRET *
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION 67762-90-7 0.5 - 1.5 TRADE SECRET *
PRODUCT WITH SILICA
CARBON BLACK 11333-86-4 <0.5 TRADE SECRET *
EPICHLOROHYDRIN 106-89-8 <0.02 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES. STORE AWAY FROM
OXIDIZING AGENTS. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
EPICHLOROHYDRIN 106-89-8 ACGIH TWA: 0.5 PPM A3:
CONFIRMED
ANIMAL
CARCIN.,
SKIN
NOTATION
EPICHLOROHYDRIN 106-89-8 OSHA TWA: SKIN
19 MG/M3 NOTATION
(5 PPM)
CARBON BLACK 1333-86-4 ACGIH TWA (INHALABLE A3:
FRACTION): CONFIRMED
3 MG/M3 ANIMAL
CARCIN.
CARBON BLACK 1333-86-4 CMRG TWA: 0.5 MG/M3
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
3-(TRIMETHOXY- 2530-83-8 CMRG TWA: 5 PPM
SILYL)PROPYL
GLYCIDYL
ETHER
SILICA, 60676-86-0 OSHA TWA
AMORPHOUS CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
OXIDE GLASS 65997-17-3 MANUFACTURER TWA (AS DUST):
CHEMICALS DETERMINED 10 MG/M3
DIMETHYL 67762-90-7 CMRG CEIL: 5 MG/M3
SILOXANE,
REACTION
PRODUCT WITH
SILICA
SILICA, 67762-90-7 OSHA TWA
AMORPHOUS CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS
OF PARTICLES/
CU. FT.
SILICA 7631-86-9 CMRG TWA (AS
RESPIRABLE
DUST):
3 MG/M3
SILICA, 7631-86-9 OSHA TWA
AMORPHOUS CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS
OF PARTICLES/
CU. FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: BLACK, VISCOUS LIQUID.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >= 95 DEG. F
FLASH POINT: >= 220 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: <=1 UNITS NOT AVAIL. OR NOT APPL. [REF STD: BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <= 27 PSIA
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 10.014 LB/GAL
SPECIFIC GRAVITY: 1.2 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
100,000 CENTIPOISE - 225,000 CENTIPOISE [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0.00162 LB HAPS/GAL
VOLATILE ORGANIC COMPOUNDS:
15 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
1.6% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 1.6% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
15 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
AMINES
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES NOT SPECIFIED
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
GENERIC: 65997-17-3 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
GLASS FILAMENTS CARCINOGEN PROGRAM CARCINOGENS
CARBON BLACK 1333-86-4 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN RESEARCH ON CANCER
CARC.
EPICHLOROHYDRIN 106-89-8 GRP. 2A: INTERNATIONAL AGENCY FOR
PROBABLE HUMAN RESEARCH ON CANCER
CARC.
EPICHLOROHYDRIN 106-89-8 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE: >12.5 MG/L
(4 HR)
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
4,4'-ISOPROPYL- DERMAL RAT LD50: >1,600 MG/KG
IDENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPROPYLI- INGESTION RAT LD50: >1,000 MG/KG
DENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
OXIDE GLASS DERMAL LD50:
CHEMICALS ESTIMATED TO BE
>5,000 MG/KG
OXIDE GLASS INGESTION LD50:
CHEMICALS ESTIMATED TO BE
2,000 - 5,000 MG/KG
1,4-BIS[(2,3- DERMAL RABBIT LD50: 2,500 MG/KG
EPOXYPROPOXY)
METHYL]
CYCLOHEXANE
FUSED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
1,4-BIS[(2,3- INGESTION RAT LD50: 2,450 MG/KG
EPOXYPROPOXY)
METHYL]
CYCLOHEXANE
FUSED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUSED SILICA INGESTION RAT LD50: >5,110 MG/KG
ACRYLATE POLYMER DERMAL RABBIT LD50: >5,000 MG/KG
ACRYLATE POLYMER INGESTION RAT LD50: >5,000 MG/KG
SILICA DERMAL RABBIT LD50: >5,000 MG/KG
SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
SILICA INGESTION RAT LD50: >5,110 MG/KG
3-(TRIMETHOXY- DERMAL RABBIT LD50: 4,000 MG/KG
SILYL)PROPYL
GLYCIDYL ETHER
3-(TRIMETHOXY- INHALATION- RAT LC50: >5.3 MG/L
SILYL)PROPYL DUST/MIST
GLYCIDYL ETHER (4 HOURS)
3-(TRIMETHOXY- INGESTION RAT LD50: 7,010 MG/KG
SILYL)PROPYL
GLYCIDYL ETHER
DIMETHYL DERMAL RABBIT LD50: >5,000 MG/KG
SILOXANE,
REACTION PRODUCT
WITH SILICA
DIMETHYL INHALATION- RAT LC50: >0.691 MG/L
SILOXANE, DUST/MIST
REACTION PRODUCT (4 HOURS)
WITH SILICA
DIMETHYL INGESTION RAT LD50: >5,110 MG/KG
SILOXANE,
REACTION PRODUCT
WITH SILICA
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
EPICHLOROHYDRIN DERMAL RABBIT LD50: 755 MG/KG
EPICHLOROHYDRIN INHALATION- RAT LC50: 1.7 MG/L
VAPOR (4
HOURS)
EPICHLOROHYDRIN INGESTION RAT LD50: 260 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MILD IRRITANT
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
1,4-BIS[(2,3-EPOXYPROPOXY) PROFESSIONAL MILD IRRITANT
METHYL]CYCLOHEXANE JUDGEMENT
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLATE POLYMER PROFESSIONAL MINIMAL IRRITATION
JUDGEMENT
SILICA RABBIT NO SIGNIFICANT IRRITATION
3-(TRIMETHOXYSILYL)PROPYL RABBIT MILD IRRITANT
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
EPICHLOROHYDRIN HUMAN CORROSIVE
AND
ANIMAL
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MODERATE IRRITANT
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
1,4-BIS[(2,3-EPOXYPROPOXY) PROFESSIONAL MILD IRRITANT
METHYL]CYCLOHEXANE JUDGEMENT
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLATE POLYMER PROFESSIONAL MILD IRRITANT
JUDGEMENT
SILICA RABBIT NO SIGNIFICANT IRRITATION
3-(TRIMETHOXYSILYL)PROPYL RABBIT CORROSIVE
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
EPICHLOROHYDRIN RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN SENSITIZING
EPICHLOROHYDRIN POLYMER AND
ANIMAL
1,4-BIS[(2,3-EPOXYPROPOXY) SIMILAR SENSITIZING
METHYL]CYCLOHEXANE COMPOUNDS
FUSED SILICA HUMAN NOT SENSITIZING
AND
ANIMAL
SILICA HUMAN NOT SENSITIZING
AND
ANIMAL
3-(TRIMETHOXYSILYL)PROPYL GUINEA SOME POSITIVE DATA EXIST,
GLYCIDYL ETHER PIG BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, REACTION HUMAN NOT SENSITIZING
PRODUCT WITH SILICA AND
ANIMAL
EPICHLOROHYDRIN HUMAN SENSITIZING
AND
ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN SOME POSITIVE DATA EXIST,
EPICHLOROHYDRIN POLYMER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- IN VIVO NOT MUTAGENIC
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- IN VITRO SOME POSITIVE DATA EXIST, BUT
EPICHLOROHYDRIN POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIDE GLASS CHEMICALS IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
FUSED SILICA IN VITRO NOT MUTAGENIC
SILICA IN VITRO NOT MUTAGENIC
3-(TRIMETHOXYSILYL)PROPYL IN VIVO NOT MUTAGENIC
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL IN VITRO SOME POSITIVE DATA EXIST, BUT
GLYCIDYL ETHER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN IN VIVO MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL MOUSE SOME POSITIVE DATA
EPICHLOROHYDRIN POLYMER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
OXIDE GLASS CHEMICALS INHALATION MULTIPLE SOME POSITIVE DATA
ANIMAL EXIST, BUT THE DATA ARE
SPECIES NOT SUFFICIENT FOR
CLASSIFICATION
FUSED SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL DERMAL MOUSE NOT CARCINOGENIC
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION NOT MOUSE SOME POSITIVE DATA
PRODUCT WITH SILICA SPECIFIED EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
EPICHLOROHYDRIN DERMAL MOUSE NOT CARCINOGENIC
EPICHLOROHYDRIN INGESTION RAT CARCINOGENIC
EPICHLOROHYDRIN INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO FEMALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO MALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
FUSED SILICA INGESTION NOT TOXIC TO FEMALE REPRODUCTION
FUSED SILICA INHALATION NOT TOXIC TO MALE REPRODUCTION
FUSED SILICA INGESTION NOT TOXIC TO DEVELOPMENT
SILICA INGESTION NOT TOXIC TO FEMALE REPRODUCTION
SILICA INGESTION NOT TOXIC TO MALE REPRODUCTION
SILICA INGESTION NOT TOXIC TO DEVELOPMENT
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT TOXIC TO FEMALE REPRODUCTION
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT TOXIC TO MALE REPRODUCTION
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL INGESTION SOME POSITIVE DEVELOPMENTAL DATA
GLYCIDYL ETHER EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO FEMALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO MALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO DEVELOPMENT
PRODUCT WITH SILICA
EPICHLOROHYDRIN INHALATION NOT TOXIC TO FEMALE REPRODUCTION
EPICHLOROHYDRIN INHALATION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
EPICHLOROHYDRIN INGESTION TOXIC TO MALE REPRODUCTION
EPICHLOROHYDRIN INHALATION TOXIC TO MALE REPRODUCTION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT NOAEL: DURING
EPICHLOROHYDRIN POLYMER 300 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
FUSED SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
FUSED SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
FUSED SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: DURING
GLYCIDYL ETHER 3,000 MG/KG/DAY ORGANOGENESIS
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 509 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL 1 GENERATION
PRODUCT WITH SILICA 497 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: DURING
PRODUCT WITH SILICA 1,350 MG/KG/DAY ORGANOGENESIS
EPICHLOROHYDRIN RAT NOAEL: 10 WEEKS
0.2 MG/L
EPICHLOROHYDRIN MULTIPLE NOAEL: DURING
ANIMAL 0.09 MG/L ORGANOGENESIS
SPECIES
EPICHLOROHYDRIN MULTIPLE NOAEL: DURING
ANIMAL 160 MG/KG/DAY GESTATION
SPECIES
EPICHLOROHYDRIN RAT LOAEL: 23 DAYS
6.25 MG/KG/DAY
EPICHLOROHYDRIN RAT NOAEL: 10 WEEKS
0.02 MG/L
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
1,4-BIS[(2,3- INHALATION RESPIRATORY SOME POSITIVE DATA
EPOXYPROPOXY) IRRITATION EXIST, BUT THE DATA
METHYL]CYCLO- ARE NOT SUFFICIENT FOR
HEXANE CLASSIFICATION
EPICHLOROHYDRIN INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
EPICHLOROHYDRIN INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
1,4-BIS[(2,3- NOAEL:
EPOXYPROPOXY) NOT AVAILABLE
METHYL]CYCLO-
HEXANE
EPICHLOROHYDRIN HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
EPICHLOROHYDRIN HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
4,4'- DERMAL LIVER SOME POSITIVE DATA
ISOPROPYLIDENEDI- EXIST, BUT THE
PHENOL-EPICHLOROHYDRIN DATA ARE NOT
POLYMER SUFFICIENT FOR
CLASSIFICATION
4,4'- DERMAL NERVOUS SYSTEM ALL DATA ARE
ISOPROPYLIDENEDIPHENOL- NEGATIVE
EPICHLOROHYDRIN POLYMER
4,4'- INGESTION AUDITORY SYSTEM ALL DATA ARE
ISOPROPYLIDENEDIPHENOL- HEART NEGATIVE
EPICHLOROHYDRIN POLYMER ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
EYES
KIDNEY AND/OR
BLADDER
OXIDE GLASS CHEMICALS INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
FUSED SILICA INHALATION RESPIRATORY ALL DATA ARE
SYSTEM NEGATIVE
SILICOSIS
SILICA INHALATION RESPIRATORY ALL DATA ARE
SYSTEM NEGATIVE
SILICOSIS
3-(TRIMETHOXYSILYL) INGESTION HEART ALL DATA ARE
PROPYL GLYCIDYL ETHER ENDOCRINE NEGATIVE
SYSTEM
BONE, TEETH,
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
DIMETHYL SILOXANE, INHALATION RESPIRATORY ALL DATA ARE
REACTION PRODUCT WITH SYSTEM NEGATIVE
SILICA SILICOSIS
CARBON BLACK INHALATION PNEUMOCONIOSIS SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN INHALATION LIVER CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
EPICHLOROHYDRIN INHALATION KIDNEY AND/OR MAY CAUSE DAMAGE TO
BLADDER ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
EPICHLOROHYDRIN INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION HEART SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION BLOOD ALL DATA ARE
NEGATIVE
EPICHLOROHYDRIN INGESTION HEART SOME POSITIVE DATA
BLOOD EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
4,4'- RAT NOAEL: 2 YEARS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
4,4'- RAT NOAEL: 13 WEEKS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
4,4'- RAT NOAEL: 28 DAYS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
FUSED SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 28 DAYS
GLYCIDYL ETHER 1,000 MG/KG/DAY
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL
REACTION PRODUCT WITH NOT AVAILABLE EXPOSURE
SILICA
CARBON BLACK HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
EPICHLOROHYDRIN RAT NOAEL: 19 DAYS
0.21 MG/L
EPICHLOROHYDRIN RAT NOAEL: 0.04 MG/L 136 WEEKS
EPICHLOROHYDRIN RAT NOAEL: 4 WEEKS
0.377 MG/L
EPICHLOROHYDRIN RAT LOAEL: 4 WEEKS
0.211 MG/L
EPICHLOROHYDRIN RAT NOAEL: 0.02 MG/L 98 DAYS
EPICHLOROHYDRIN RAT NOAEL: 0.002 MG/L 98 DAYS
EPICHLOROHYDRIN MULTIPLE NOAEL: 0.02 MG/L 13 WEEKS
ANIMAL
SPECIES
EPICHLOROHYDRIN RAT NOAEL: 90 DAYS
0.189 MG/L
EPICHLOROHYDRIN RAT NOAEL: 12 WEEKS
80 MG/KG/DAY
EPICHLOROHYDRIN RAT NOAEL: 90 DAYS
25 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
EPICHLOROHYDRIN 106-89-8 MALE REPRODUCTIVE TOXIN
EPICHLOROHYDRIN 106-89-8 CARCINOGEN
CARBON BLACK 1333-86-4 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 32-4327-6
ISSUE DATE: 09/23/15
VERSION NUMBER: 1.01
SUPERCEDES DATE: 11/24/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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