| Common Name: | RIGID PARTS PLASTIC REPAIR ADHESIVE, PN 05883, 05885, 55885 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/20/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVB8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) RIGID PARTS PLASTIC REPAIR ADHESIVE, PN 05883, 05885, 55885
03/20/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 06-7087-7
VERSION NUMBER: 13.00
ISSUE DATE: 03/20/15
SUPERCEDES DATE: 03/26/13
PRODUCT IDENTIFIER:
3M(TM) RIGID PARTS PLASTIC REPAIR ADHESIVE, PN 05883, 05885, 55885
ID NUMBER(S):
41-0003-6670-2, 41-0003-8016-6, 41-3701-2159-6, 60-4550-7093-2,
60-9800-3084-9, 60-9800-3088-0, 60-9800-3511-1
RECOMMENDED USE: AUTOMOTIVE, TWO-PART EPOXY TYPE ADHESIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
06-3177-0, 06-3176-2
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) RIGID PARTS REPAIR ADHESIVE PART A (ACCELERATOR) PN 05883, 05885,
08275, 08266, 55885
03/19/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 06-3176-2
VERSION NUMBER: 19.00
ISSUE DATE: 03/19/15
SUPERCEDES DATE: 01/13/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) RIGID PARTS REPAIR ADHESIVE PART A (ACCELERATOR) PN 05883, 05885,
08275, 08266, 55885
PRODUCT IDENTIFICATION NUMBERS: 41-0003-6667-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, USE WITH PART B, MSDS 06-3177-0
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
REPRODUCTIVE TOXICITY: CATEGORY 2.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
HEALTH HAZARD
PICTOGRAMS:
CORROSION
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
MERCAPTAN-TERMINATED EPOXY TRADE SECRET* 40 - 70 TRADE SECRET *
CURING AGENT
TALC 14807-96-6 10 - 30 TRADE SECRET *
LIMESTONE 1317-65-3 10 - 30 TRADE SECRET *
BUTYL BENZYL PHTHALATE 85-68-7 3 - 7 TRADE SECRET *
TRIS(2,4,6-DIMETHYLAMINO- 190-72-2 3 - 7 TRADE SECRET *
MONOMETHYL) PHENOL
DIMETHYL SILOXANE, REACTION 67762-90-7 1 - 5 TRADE SECRET *
PRODUCT WITH SILICA
QUARTZ SILICA 14808-60-7 <0.25 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
LIMESTONE 1317-65-3 OSHA TWA (AS TOTAL DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION): 5 MG/M3
TALC 14807-96-6 ACGIH TWA (RESPIRABLE A4:
FRACTION): 2 MG/M3 NOT CLASS. AS
HUMAN CARCIN
TALC 14807-96-6 CMRG TWA (AS RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
QUARTZ SILICA 14808-60-7 ACGIH TWA (RESPIRABLE A2:
FRACTION): SUSPECTED
0.025 MG/M3 HUMAN CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
DIMETHYL 67762-90-7 CMRG CEIL: 5 MG/M3
SILOXANE,
REACTION PRODUCT
WITH SILICA
SILICA, AMORPHOUS 67762-90-7 OSHA TWA CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
TRIS(2,4,6- 90-72-2 CMRG TWA: 5 PPM
DIMETHYL-
AMINOMONOMETHYL)
PHENOL
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
NEOPRENE
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID PASTE
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: STRONG MERCAPTAN ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
SPECIFIC GRAVITY: 1.0 [REF STD: WATER=1]
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS:
0.0000861 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS 14808-60-7 KNOWN HUMAN CARCINOGEN NATIONAL TOXICOLOGY
AIRRESP PROGRAM CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO HUMANS FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
MERCAPTAN-TERMINATED EPOXY DERMAL RABBIT LD50: >10,200 MG/KG
CURING AGENT
MERCAPTAN-TERMINATED EPOXY INGESTION RAT LD50: 2,600 MG/KG
CURING AGENT
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3.0 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
TALC DERMAL LD50: NOT AVAILABLE
TALC INGESTION LD50: NOT AVAILABLE
BUTYL BENZYL PHTHALATE DERMAL RABBIT LD50: >10,000 MG/KG
BUTYL BENZYL PHTHALATE INHALATION- RAT LC50: >6.7 MG/L
DUST/MIST
(4 HOURS)
BUTYL BENZYL PHTHALATE INGESTION RAT LD50: 2,330 MG/KG
TRIS(2,4,6- DERMAL RAT LD50: 1,280 MG/KG
DIMETHYLAMINOMONOMETHYL)
PHENOL
TRIS(2,4,6- INGESTION RAT LD50: 1,000 MG/KG
DIMETHYLAMINOMONOMETHYL)
PHENOL
DIMETHYL SILOXANE, REACTION DERMAL RABBIT LD50: >5,000 MG/KG
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INHALATION- RAT LC50: >0.691 MG/L
PRODUCT WITH SILICA DUST/MIST
(4 HOURS)
DIMETHYL SILOXANE, REACTION INGESTION RAT LD50: >5,110 MG/KG
PRODUCT WITH SILICA
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
BUTYL BENZYL PHTHALATE RABBIT NO SIGNIFICANT IRRITATION
TRIS(2,4,6- RABBIT CORROSIVE
DIMETHYLAMINOMONOMETHYL)
PHENOL
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
BUTYL BENZYL PHTHALATE RABBIT MILD IRRITANT
TRIS(2,4,6- RABBIT CORROSIVE
DIMETHYLAMINOMONOMETHYL)
PHENOL
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
SKIN SENSITIZATION:
NAME SPECIES VALUE
BUTYL BENZYL PHTHALATE HUMAN AND ANIMAL NOT SENSITIZING
TRIS(2,4,6- GUINEA PIG SOME POSITIVE DATA
DIMETHYLAMINOMONOMETHYL) EXIST, BUT THE DATA
PHENOL ARE NOT SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, REACTION HUMAN AND ANIMAL NOT SENSITIZING
PRODUCT WITH SILICA
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
BUTYL BENZYL PHTHALATE IN VITRO NOT MUTAGENIC
BUTYL BENZYL PHTHALATE IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
TRIS(2,4,6- IN VITRO NOT MUTAGENIC
DIMETHYLAMINOMONOMETHYL)
PHENOL
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL PHTHALATE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, NOT SPECIFIED MOUSE SOME POSITIVE DATA
REACTION PRODUCT WITH EXIST, BUT THE DATA
SILICA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN AND CARCINOGENIC
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
TALC INGESTION NOT TOXIC TO DEVELOPMENT
BUTYL BENZYL PHTHALATE INGESTION TOXIC TO FEMALE REPRODUCTION
BUTYL BENZYL PHTHALATE INGESTION TOXIC TO MALE REPRODUCTION
BUTYL BENZYL PHTHALATE INGESTION TOXIC TO DEVELOPMENT
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO FEMALE REPRODUCTION
REACTION PRODUCT WITH
SILICA
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO MALE REPRODUCTION
REACTION PRODUCT WITH
SILICA
DIMETHYL SILOXANE, INGESTION NOT TOXIC TO DEVELOPMENT
REACTION PRODUCT WITH
SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: PREMATING & DURING
625 MG/KG/DAY GESTATION
TALC RAT NOAEL: DURING ORGANOGENESIS
1,600 MG/KG
BUTYL BENZYL PHTHALATE RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
BUTYL BENZYL PHTHALATE RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
BUTYL BENZYL PHTHALATE RAT NOAEL: 2 GENERATION
50 MG/KG/DAY
DIMETHYL SILOXANE, RAT NOAEL: 1 GENERATION
REACTION PRODUCT WITH 509 MG/KG/DAY
SILICA
DIMETHYL SILOXANE, RAT NOAEL: 1 GENERATION
REACTION PRODUCT WITH 497 MG/KG/DAY
SILICA
DIMETHYL SILOXANE, RAT NOAEL: DURING ORGANOGENESIS
REACTION PRODUCT WITH 1,350 MG/KG/DAY
SILICA
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
TRIS(2,4,6- INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
DIMETHYL- EXIST, BUT THE DATA
AMINOMONOMETHYL) ARE NOT SUFFICIENT
PHENOL FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 0.812 MG/L 90 MINUTES
TRIS(2,4,6- NOAEL:
DIMETHYLAMINOMONOMETHYL) NOT AVAILABLE
PHENOL
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
RESPIRATORY SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL INHALATION LIVER SOME POSITIVE DATA
PHTHALATE KIDNEY AND/OR BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
PHTHALATE EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
PHTHALATE EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL INGESTION BLOOD SOME POSITIVE DATA
PHTHALATE EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
BUTYL BENZYL INGESTION LIVER SOME POSITIVE DATA
PHTHALATE EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6- DERMAL SKIN SOME POSITIVE DATA
DIMETHYL- LIVER EXIST, BUT THE DATA
AMINOMONOMETHYL) NERVOUS SYSTEM ARE NOT SUFFICIENT
PHENOL FOR CLASSIFICATION
TRIS(2,4,6- DERMAL AUDITORY SYSTEM ALL DATA ARE
DIMETHYL- HEMATOPOIETIC SYSTEM NEGATIVE
AMINOMONOMETHYL) EYES
PHENOL
DIMETHYL INHALATION RESPIRATORY SYSTEM ALL DATA ARE
SILOXANE, SILICOSIS NEGATIVE
REACTION PRODUCT
WITH SILICA
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
BUTYL BENZYL RAT NOAEL: 0.789 MG/L 90 DAYS
PHTHALATE
BUTYL BENZYL RAT NOAEL: 240 MG/KG/DAY 2 YEARS
PHTHALATE
BUTYL BENZYL RAT NOAEL: 960 MG/KG/DAY 90 DAYS
PHTHALATE
BUTYL BENZYL RAT NOAEL: 500 MG/KG/DAY 2 YEARS
PHTHALATE
BUTYL BENZYL RAT NOAEL: 381 MG/KG/DAY 90 DAYS
PHTHALATE
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYL-
AMINOMONOMETHYL)
PHENOL
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYL-
AMINOMONOMETHYL)
PHENOL
DIMETHYL SILOXANE, HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
REACTION PRODUCT
WITH SILICA
QUARTZ SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. IF NO OTHER DISPOSAL OPTIONS ARE AVAILABLE,
WASTE PRODUCT THAT HAS BEEN COMPLETELY CURED OR POLYMERIZED MAY BE PLACED
IN A LANDFILL PROPERLY DESIGNED FOR INDUSTRIAL WASTE. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE (AIRBORNE NONE CARCINOGEN
PARTICLES OF RESPIRABLE SIZE)
BUTYL BENZYL PHTHALATE 85-68-7 DEVELOPMENTAL TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 06-3176-2
VERSION NUMBER: 19.00
ISSUE DATE: 03/19/15
SUPERCEDES DATE: 01/13/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) RIGID PARTS REPAIR ADHESIVE, PN 05883, 05885, 08275,08266, 55885
PART B
01/15/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 06-3177-0
VERSION NUMBER: 17.03
ISSUE DATE: 01/15/15
SUPERCEDES DATE: 12/10/12
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) RIGID PARTS REPAIR ADHESIVE, PN 05883, 05885, 08275,08266, 55885
PART B
PRODUCT IDENTIFICATION NUMBERS: 41-0003-6668-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, USE WITH PART A, MSDS 06-3176-2
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN SENSITIZER: CATEGORY 1.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
4,4'-ISOPROPYLIDENEDIPHENOL- 25068-38-6 40 - 70 TRADE SECRET *
EPICHLOROHYDRIN POLYMER
TALC 14807-96-6 10 - 30 TRADE SECRET *
LIMESTONE 1317-65-3 10 - 30 TRADE SECRET *
1,2,3-PROPANETRIYL ESTER OF 74398-71-3 3 - 7 TRADE SECRET *
12-(OXIRANYLMETHOXY)-9-
OCTADECENOIC ACID
DIMETHYL SILOXANE, REACTION 67762-90-7 1 - 5 TRADE SECRET *
PRODUCT WITH SILICA
QUARTZ SILICA 14808-60-7 <=0.25 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
NON-COMBUSTIBLE. USE A FIRE FIGHTING AGENT SUITABLE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
LIMESTONE 1317-65-3 OSHA TWA (AS TOTAL DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION): 5 MG/M3
TALC 14807-96-6 ACGIH TWA (RESPIRABLE A4:
FRACTION): NOT CLASS. AS
2 MG/M3 HUMAN CARCIN
TALC 14807-96-6 CMRG TWA (AS RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
QUARTZ SILICA 14808-60-7 ACGIH TWA (RESPIRABLE A2:
FRACTION): SUSPECTED
0.025 MG/M3 HUMAN CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
DIMETHYL 67762-90-7 CMRG CEIL: 5 MG/M3
SILOXANE,
REACTION PRODUCT
WITH SILICA
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BLUE, WITH LITTLE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.0 G/ML
SPECIFIC GRAVITY: 1.0 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS:
0.0000750 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
DUST FROM CUTTING, GRINDING, SANDING OR MACHINING MAY CAUSE IRRITATION OF
THE RESPIRATORY SYSTEM. SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL
DISCHARGE, HEADACHE, HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED
OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
CARCINOGENICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS AIRRESP 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON
HUMANS CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL RAT LD50: >1,600 MG/KG
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION RAT LD50: >1,000 MG/KG
EPICHLOROHYDRIN POLYMER
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3.0 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
TALC DERMAL LD50: NOT AVAILABLE
TALC INGESTION LD50: NOT AVAILABLE
1,2,3-PROPANETRIYL ESTER OF DERMAL RABBIT LD50: >2,000 MG/KG
12-(OXIRANYLMETHOXY)-9-
OCTADECENOIC ACID
1,2,3-PROPANETRIYL ESTER OF INGESTION RAT LD50: >5,000 MG/KG
12-(OXIRANYLMETHOXY)-9-
OCTADECENOIC ACID
DIMETHYL SILOXANE, REACTION DERMAL RABBIT LD50: >5,000 MG/KG
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INHALATION- RAT LC50: >0.691 MG/L
PRODUCT WITH SILICA DUST/MIST
(4 HOURS)
DIMETHYL SILOXANE, REACTION INGESTION RAT LD50: >5,110 MG/KG
PRODUCT WITH SILICA
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MILD IRRITANT
EPICHLOROHYDRIN POLYMER
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MODERATE IRRITANT
EPICHLOROHYDRIN POLYMER
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
SKIN SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN AND ANIMAL SENSITIZING
EPICHLOROHYDRIN POLYMER
DIMETHYL SILOXANE, REACTION HUMAN AND ANIMAL NOT SENSITIZING
PRODUCT WITH SILICA
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN SOME POSITIVE DATA EXIST,
EPICHLOROHYDRIN POLYMER BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- IN VIVO NOT MUTAGENIC
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- IN VITRO SOME POSITIVE DATA EXIST, BUT
EPICHLOROHYDRIN POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL MOUSE SOME POSITIVE DATA
EPICHLOROHYDRIN POLYMER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, NOT MOUSE SOME POSITIVE DATA
REACTION PRODUCT WITH SILICA SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO FEMALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO MALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
TALC INGESTION NOT TOXIC TO DEVELOPMENT
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO FEMALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO MALE REPRODUCTION
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INGESTION NOT TOXIC TO DEVELOPMENT
PRODUCT WITH SILICA
NAME SPECIES TEST RESULT EXPOSURE DURATION
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT NOAEL: DURING
EPICHLOROHYDRIN POLYMER 300 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
LIMESTONE RAT NOAEL: PREMATING &
625 MG/KG/DAY DURING GESTATION
TALC RAT NOAEL: DURING
1,600 MG/KG ORGANOGENESIS
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 509 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 497 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: DURING
PRODUCT WITH SILICA 1,350 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 0.812 MG/L 90 MINUTES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
4,4'- DERMAL LIVER SOME POSITIVE DATA
ISOPROPYLIDENEDIPHENOL- EXIST, BUT THE DATA
EPICHLOROHYDRIN POLYMER ARE NOT SUFFICIENT
FOR CLASSIFICATION
4,4'- DERMAL NERVOUS SYSTEM ALL DATA ARE
ISOPROPYLIDENEDIPHENOL- NEGATIVE
EPICHLOROHYDRIN POLYMER
4,4'- INGESTION AUDITORY SYSTEM ALL DATA ARE
ISOPROPYLIDENEDIPHENOL- HEART NEGATIVE
EPICHLOROHYDRIN POLYMER ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
EYES
KIDNEY AND/OR
BLADDER
LIMESTONE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA
FIBROSIS EXIST, BUT THE DATA
RESPIRATORY ARE NOT SUFFICIENT
SYSTEM FOR CLASSIFICATION
DIMETHYL SILOXANE, INHALATION RESPIRATORY ALL DATA ARE
REACTION PRODUCT WITH SYSTEM NEGATIVE
SILICA SILICOSIS
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
4,4'- RAT NOAEL: 2 YEARS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
4,4'- RAT NOAEL: 13 WEEKS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
4,4'- RAT NOAEL: 28 DAYS
ISOPROPYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN POLYMER
LIMESTONE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TALC HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL
REACTION PRODUCT WITH NOT AVAILABLE EXPOSURE
SILICA
QUARTZ SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. IF NO OTHER DISPOSAL OPTIONS ARE AVAILABLE,
WASTE PRODUCT THAT HAS BEEN COMPLETELY CURED OR POLYMERIZED MAY BE PLACED
IN A LANDFILL PROPERLY DESIGNED FOR INDUSTRIAL WASTE. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE (AIRBORNE NONE CARCINOGEN
PARTICLES OF RESPIRABLE SIZE)
EPICHLOROHYDRIN 106-89-8 MALE REPRODUCTIVE TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 06-3177-0
VERSION NUMBER: 17.03
ISSUE DATE: 01/15/15
SUPERCEDES DATE: 12/10/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
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KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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