| Common Name: | EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887 35887, 55887 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVB9, 59LX64 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887 35887, 55887
03/02/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 28-1029-9
VERSION NUMBER: 2.01
ISSUE DATE: 03/02/15
SUPERCEDES DATE: 02/21/14
PRODUCT IDENTIFIER:
3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887 35887, 55887
ID NUMBER(S):
LB-K100-0909-2, 41-0003-6760-1, 41-0003-7957-2, 41-0003-7997-8,
60-4550-5209-6, 60-4550-5482-9, 60-4550-7033-8, 60-9801-0922-1
RECOMMENDED USE: AUTOMOTIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH
OF THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
28-6974-1, 28-6979-0
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887, 35887, 55887 -
PART B (BASE)
02/24/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 28-6979-0
VERSION NUMBER: 5.02
ISSUE DATE: 02/24/16
SUPERCEDES DATE: 06/17/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887, 35887, 55887 -
PART B (BASE)
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, FLEXIBLE PARTS REPAIR
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN SENSITIZER: CATEGORY 1.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
BISPHENOL A-EPICHLOROHYDRIN 25068-38-6 20 - 50 TRADE SECRET*
POLYMER
TALC 14807-96-6 10 - 30 TRADE SECRET*
LIMESTONE 1317-65-3 10 - 30 TRADE SECRET*
1,2,3-PROPANETRIYL ESTER OF 74398-71-3 5 - 15 TRADE SECRET*
12-(OXIRANYLMETHOXY)-
9-OCTADECENOIC ACID
OXIDE GLASS CHEMICALS 65997-17-3 1 - 10 TRADE SECRET*
FILLER MIXTURE <3 TRADE SECRET*
STEARIC ACID 57-11-4 <1.5 TRADE SECRET*
QUARTZ SILICA 14808-60-7 <0.5 TRADE SECRET*
CARBON BLACK 1333-86-4 <0.09 TRADE SECRET*
EPICHLOROHYDRIN 106-89-8 <0.011 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CHLORIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
EPICHLOROHYDRIN 106-89-8 ACGIH TWA: 0.5 PPM A3:
CONFIRMED
ANIMAL
CARCIN.,
SKIN
NOTATION
EPICHLOROHYDRIN 106-89-8 OSHA TWA: SKIN
19 MG/M3 NOTATION
(5 PPM)
LIMESTONE 1317-65-3 OSHA TWA(AS TOTAL
DUST):
15 MG/M3
TWA(RESPIRABLE
FRACTION):
5 MG/M3
CARBON BLACK 1333-86-4 ACGIH TWA(INHALABLE A3:
FRACTION): CONFIRMED
3 MG/M3 ANIMAL
CARCIN.
CARBON BLACK 1333-86-4 CMRG TWA: 0.5 MG/M3
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4:
FRACTION): NOT CLASS.
2 MG/M3 AS HUMAN
CARCIN
TALC 14807-96-6 CMRG TWA(AS
RESPIRABLE
DUST):
0.5 MG/M3
TALC 14807-96-6 OSHA TWA
CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3;
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS
OF PARTICLES/
CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
QUARTZ SILICA 14808-60-7 ACGIH TWA(RESPIRABLE A2:
FRACTION): SUSPECTED
0.025 MG/M3 HUMAN
CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS OF
PARTICLES/
CU. FT.)
STEARATES 57-11-4 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS.
AS HUMAN
CARCIN
OXIDE GLASS 65997-17-3 MANUFACTURER TWA(AS DUST):
CHEMICALS DETERMINED 10 MG/M3
FILLER MIXTURE CMRG CEIL: 5 MG/M3
SILICA, MIXTURE OSHA TWA
AMORPHOUS CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/
CU. FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. PROVIDE APPROPRIATE LOCAL EXHAUST
VENTILATION FOR CUTTING, GRINDING, SANDING OR MACHINING.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: BLACK, WITH LITTLE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.0 - 1.5 G/ML
SPECIFIC GRAVITY: 1.0 - 1.5 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 40 - 110 SEC [DETAILS: PRESSFLOW VISCOSITY]
HAZARDOUS AIR POLLUTANTS:
0.00024 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
PHOSGENE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
CARBON BLACK 1333-86-4 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
EPICHLOROHYDRIN 106-89-8 GRP. 2A: INTERNATIONAL AGENCY
PROBABLE HUMAN CARC. FOR RESEARCH ON CANCER
EPICHLOROHYDRIN 106-89-8 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON CANCER
HUMANS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
BISPHENOL DERMAL RAT LD50: >1,600 MG/KG
A-EPICHLOROHYDRIN
POLYMER
BISPHENOL INGESTION RAT LD50: >1,000 MG/KG
A-EPICHLOROHYDRIN
POLYMER
TALC DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
TALC INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
1,2,3-PROPANETRIYL DERMAL RABBIT LD50: >2,000 MG/KG
ESTER OF 12-
(OXIRANYLMETHOXY)-
9-OCTADECENOIC
ACID
1,2,3-PROPANETRIYL INGESTION RAT LD50: >5,000 MG/KG
ESTER OF 12-
(OXIRANYLMETHOXY)-
9-OCTADECENOIC
ACID
OXIDE GLASS DERMAL LD50:
CHEMICALS ESTIMATED TO BE
>5,000 MG/KG
OXIDE GLASS INGESTION LD50:
CHEMICALS ESTIMATED TO BE
2,000 - 5,000 MG/KG
FILLER DERMAL RABBIT LD50: >5,000 MG/KG
FILLER INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FILLER INGESTION RAT LD50: >5,110 MG/KG
STEARIC ACID DERMAL RABBIT LD50: >2,000 MG/KG
STEARIC ACID INGESTION RAT LD50: >5,000 MG/KG
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
EPICHLOROHYDRIN DERMAL RABBIT LD50: 755 MG/KG
EPICHLOROHYDRIN INHALATION- RAT LC50: 1.7 MG/L
VAPOR
(4 HOURS)
EPICHLOROHYDRIN INGESTION RAT LD50: 260 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
BISPHENOL A-EPICHLOROHYDRIN RABBIT MILD IRRITANT
POLYMER
TALC RABBIT NO SIGNIFICANT IRRITATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
FILLER RABBIT NO SIGNIFICANT IRRITATION
STEARIC ACID RABBIT MILD IRRITANT
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
EPICHLOROHYDRIN HUMAN AND CORROSIVE
ANIMAL
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
BISPHENOL A-EPICHLOROHYDRIN RABBIT MODERATE IRRITANT
POLYMER
TALC RABBIT NO SIGNIFICANT IRRITATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
FILLER RABBIT NO SIGNIFICANT IRRITATION
STEARIC ACID PROFESSIONAL MODERATE IRRITANT
JUDGEMENT
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
EPICHLOROHYDRIN RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
BISPHENOL A-EPICHLOROHYDRIN HUMAN AND SENSITIZING
POLYMER ANIMAL
FILLER HUMAN AND NOT SENSITIZING
ANIMAL
EPICHLOROHYDRIN HUMAN AND SENSITIZING
ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
BISPHENOL A-EPICHLOROHYDRIN HUMAN SOME POSITIVE DATA EXIST, BUT
POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
BISPHENOL A-EPICHLOROHYDRIN IN VIVO NOT MUTAGENIC
POLYMER
BISPHENOL A-EPICHLOROHYDRIN IN VITRO SOME POSITIVE DATA EXIST, BUT
POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
OXIDE GLASS CHEMICALS IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
FILLER IN VITRO NOT MUTAGENIC
STEARIC ACID IN VITRO NOT MUTAGENIC
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN IN VIVO MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
BISPHENOL DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
A-EPICHLOROHYDRIN THE DATA ARE NOT SUFFICIENT
POLYMER FOR CLASSIFICATION
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIDE GLASS INHALATION MULTIPLE SOME POSITIVE DATA EXIST, BUT
CHEMICALS ANIMAL THE DATA ARE NOT SUFFICIENT
SPECIES FOR CLASSIFICATION
FILLER NOT MOUSE SOME POSITIVE DATA EXIST, BUT
SPECIFIED THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
STEARIC ACID INGESTION RAT NOT CARCINOGENIC
QUARTZ SILICA INHALATION HUMAN AND CARCINOGENIC
ANIMAL
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
EPICHLOROHYDRIN DERMAL MOUSE NOT CARCINOGENIC
EPICHLOROHYDRIN INGESTION RAT CARCINOGENIC
EPICHLOROHYDRIN INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
BISPHENOL A-EPICHLOROHYDRIN INGESTION NOT TOXIC TO FEMALE
POLYMER REPRODUCTION
BISPHENOL A-EPICHLOROHYDRIN INGESTION NOT TOXIC TO MALE
POLYMER REPRODUCTION
BISPHENOL A-EPICHLOROHYDRIN DERMAL NOT TOXIC TO DEVELOPMENT
POLYMER
BISPHENOL A-EPICHLOROHYDRIN INGESTION NOT TOXIC TO DEVELOPMENT
POLYMER
TALC INGESTION NOT TOXIC TO DEVELOPMENT
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
FILLER INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
FILLER INGESTION NOT TOXIC TO MALE
REPRODUCTION
FILLER INGESTION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN INHALATION NOT TOXIC TO FEMALE
REPRODUCTION
EPICHLOROHYDRIN INHALATION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN INGESTION SOME POSITIVE DEVELOPMENTAL
DATA EXIT, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INGESTION TOXIC TO MALE REPRODUCTION
EPICHLOROHYDRIN INHALATION TOXIC TO MALE REPRODUCTION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
BISPHENOL A-EPICHLOROHYDRIN RAT NOAEL: 2 GENERATION
POLYMER 750 MG/KG/DAY
BISPHENOL A-EPICHLOROHYDRIN RAT NOAEL: 2 GENERATION
POLYMER 750 MG/KG/DAY
BISPHENOL A-EPICHLOROHYDRIN RABBIT NOAEL: DURING
POLYMER 300 MG/KG/DAY ORGANOGENESIS
BISPHENOL A-EPICHLOROHYDRIN RAT NOAEL: 2 GENERATION
POLYMER 750 MG/KG/DAY
TALC RAT NOAEL: DURING
1,600 MG/KG ORGANOGENESIS
LIMESTONE RAT NOAEL: PREMATING &
625 MG/KG/DAY DURING
GESTATION
FILLER RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
FILLER RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
FILLER RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
EPICHLOROHYDRIN RAT NOAEL: 10 WEEKS
0.2 MG/L
EPICHLOROHYDRIN MULTIPLE NOAEL: DURING
ANIMAL 0.09 MG/L ORGANOGENESIS
SPECIES
EPICHLOROHYDRIN MULTIPLE NOAEL: DURING
ANIMAL 160 MG/KG/DAY GESTATION
SPECIES
EPICHLOROHYDRIN RAT LOAEL: 23 DAYS
6.25 MG/KG/DAY
EPICHLOROHYDRIN RAT NOAEL: 10 WEEKS
0.02 MG/L
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
STEARIC ACID INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
EPICHLOROHYDRIN INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
EPICHLOROHYDRIN INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 90 MINUTES
0.812 MG/L
STEARIC ACID NOAEL:
NOT AVAILABLE
EPICHLOROHYDRIN HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
EPICHLOROHYDRIN HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
BISPHENOL A- DERMAL LIVER SOME POSITIVE DATA EXIST,
EPICHLOROHYDRIN BUT THE DATA ARE NOT
POLYMER SUFFICIENT FOR
CLASSIFICATION
BISPHENOL A- DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
EPICHLOROHYDRIN
POLYMER
BISPHENOL A- INGESTION AUDITORY SYSTEM ALL DATA ARE NEGATIVE
EPICHLOROHYDRIN HART
POLYMER ENDOCRINE
SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
EYES
KINDEY AND/OR
BLADDER
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA EXIST,
FIBROSIS BUT THE DATA ARE NOT
RESPIRATORY SUFFICIENT FOR
SYSTEM CLASSIFICATION
LIMESTONE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
OXIDE GLASS INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
CHEMICALS SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
FILLER INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
SYSTEM
SILICOSIS
STEARIC ACID INGESTION BLOOD SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
CARBON BLACK INHALATION PNEUMOCONIOSIS SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION LIVER CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
EPICHLOROHYDRIN INHALATION KIDNEY AND/OR MAY CAUSE DAMAGE TO ORGANS
BLADDER THOUGH PROLONGED OR
REPEATED EXPOSURE
EPICHLOROHYDRIN INHALATION ENDOCRINE SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION HEART SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION NERVOUS SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INHALATION BLOOD ALL DATA ARE NEGATIVE
EPICHLOROHYDRIN INGESTION HEART SOME POSITIVE DATA EXIST,
BLOOD BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
EPICHLOROHYDRIN INGESTION LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
BISPHENOL RAT NOAEL: 2 YEARS
A-EPICHLOROHYDRIN 1,000 MG/KG/DAY
POLYMER
BISPHENOL RAT NOAEL: 13 WEEKS
A-EPICHLOROHYDRIN 1,000 MG/KG/DAY
POLYMER
BISPHENOL RAT NOAEL: 28 DAYS
A-EPICHLOROHYDRIN 1,000 MG/KG/DAY
POLYMER
TALC HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
LIMESTONE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
OXIDE GLASS HUMAN NOAEL: OCCUPATIONAL
CHEMICALS NOT AVAILABLE EXPOSURE
FILLER HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
STEARIC ACID RAT NOAEL: 6 WEEKS
NOT AVAILABLE
QUARTZ SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
CARBON BLACK HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
EPICHLOROHYDRIN RAT NOAEL: 0.21 MG/L 19 DAYS
EPICHLOROHYDRIN RAT NOAEL: 0.04 MG/L 136 WEEKS
EPICHLOROHYDRIN RAT NOAEL: 4 WEEKS
0.377 MG/L
EPICHLOROHYDRIN RAT LOAEL: 4 WEEKS
0.211 MG/L
EPICHLOROHYDRIN RAT NOAEL: 0.02 MG/L 98 DAYS
EPICHLOROHYDRIN RAT NOAEL: 0.002 MG/L 98 DAYS
EPICHLOROHYDRIN MULTIPLE NOAEL: 0.02 MG/L 13 WEEKS
ANIMAL
SPECIES
EPICHLOROHYDRIN RAT NOAEL: 0.189 MG/L 90 DAYS
EPICHLOROHYDRIN RAT NOAEL: 12 WEEKS
80 MG/KG/DAY
EPICHLOROHYDRIN RAT NOAEL: 90 DAYS
25 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES.
COMBUSTION PRODUCTS WILL INCLUDE HALOGEN ACID (HCl/HF/HBr). FACILITY
MUST BE CAPABLE OF HANDLING HALOGENATED MATERIALS.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE NONE CARCINOGEN
(AIRBORNE PARTICLES OF
RESPIRABLE SIZE)
EPICHLOROHYDRIN 106-89-8 MALE REPRODUCTIVE TOXIN
EPICHLOROHYDRIN 106-89-8 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 28-6979-0
VERSION NUMBER: 5.02
ISSUE DATE: 02/24/16
SUPERCEDES DATE: 06/17/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887, 35887, 55887 -
ACCELERATOR (PART A)
03/18/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 28-6974-1
VERSION NUMBER: 3.02
ISSUE DATE: 03/18/16
SUPERCEDES DATE: 02/24/16
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) EZ SAND MULTI-PURPOSE REPAIR MATERIAL PNS 05887, 35887, 55887 -
ACCELERATOR (PART A)
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AUTOMOTIVE, PART A SIDE OF 2-PART EPOXY ADHESIVE FOR FLEXIBLE PARTS REPAIR
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
HEALTH HAZARD
PICTOGRAMS:
CORROSION
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
65% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
65% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
MERCAPTAN-TERMINATED EPOXY TRADE SECRET* 40 - 70 TRADE SECRET*
CURING AGENT
TALC 14807-96-6 10 - 30 TRADE SECRET*
LIMESTONE 1317-65-3 10 - 30 TRADE SECRET*
OXIDE GLASS CHEMICALS 65997-17-3 1 - 10 TRADE SECRET*
TRIS(2,4,6-DIMETHYLAMINOMONO- 90-72-2 1 - 5 TRADE SECRET*
METHYL)PHENOL
TITANIUM DIOXIDE 13463-67-7 <1.0 TRADE SECRET*
QUARTZ SILICA 14808-60-7 <0.5 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL
AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. CLEAN UP RESIDUE. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS.
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
LIMESTONE 1317-65-3 OSHA TWA(AS TOTAL
DUST):15 MG/M3
TWA(RESPIRABLE
FRACTION):
5 MG/M3
TITANIUM 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
DIOXIDE NOT CLASS.
AS HUMAN
CARCIN
TITANIUM 13463-67-7 CMRG TWA(AS
DIOXIDE RESPIRABLE
DUST): 5 MG/M3
TITANIUM 13463-67-7 OSHA TWA(AS TOTAL
DIOXIDE DUST): 15 MG/M3
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4:
FRACTION): NOT CLASS.
2 MG/M3 AS HUMAN
CARCIN
TALC 14807-96-6 CMRG TWA(AS
RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA
CONCENTRATION(AS
TOTAL DUST):
0.3 MG/M3
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS OF
PARTICLES/CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
QUARTZ 14808-60-7 ACGIH TWA(RESPIRABLE A2:
SILICA FRACTION): SUSPECTED
0.025 MG/M3 HUMAN
CARCIN.
QUARTZ 14808-60-7 OSHA TWA
SILICA CONCENTRATION(AS
TOTAL DUST):
0.3 MG/M3
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS OF
PARTICLES/CU. FT.)
OXIDE GLASS 65997-17-3 MANUFACTURER TWA(AS DUST):
CHEMICALS DETERMINED 10 MG/M3
TRIS(2,4,6- 90-72-2 CMRG TWA: 5 PPM
DIMETHYL-
AMINOMONO-
METHYL)PHENOL
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. PROVIDE APPROPRIATE LOCAL EXHAUST
VENTILATION FOR CUTTING, GRINDING, SANDING OR MACHINING.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: OFF-WHITE, STRONG MERCAPTAN ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: 474 DEG. F
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 8.8 - 9.4 LB/GAL
SPECIFIC GRAVITY: 1.078 - 1.09 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100 - 150 SEC [DETAILS: PRESSFLOW VISCOSITY]
HAZARDOUS AIR POLLUTANTS:
0.00024 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON CANCER
HUMANS
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON CANCER
CARC.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
TALC DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
TALC INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
OXIDE GLASS DERMAL LD50:
CHEMICALS ESTIMATED TO BE
>5,000 MG/KG
OXIDE GLASS INGESTION LD50:
CHEMICALS ESTIMATED TO BE
2,000 - 5,000 MG/KG
TRIS(2,4,6- DERMAL RAT LD50: 1,280 MG/KG
DIMETHYLAMINOMONO-
METHYL)PHENOL
TRIS(2,4,6- INGESTION RAT LD50: 1,000 MG/KG
DIMETHYLAMINOMONO-
METHYL)PHENOL
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
TRIS RABBIT CORROSIVE
(2,4,6-DIMETHYLAMINOMONOMETHYL)
PHENOL
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
TRIS RABBIT CORROSIVE
(2,4,6-DIMETHYLAMINOMONOMETHYL)
PHENOL
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
TRIS GUINEA PIG SOME POSITIVE DATA EXIST,
(2,4,6-DIMETHYLAMINOMONOMETHYL) BUT THE DATA ARE NOT
PHENOL SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE HUMAN AND NOT SENSITIZING
ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
OXIDE GLASS CHEMICALS IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TRIS IN VITRO NOT MUTAGENIC
(2,4,6-DIMETHYLAMINOMONO-
METHYL)PHENOL
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIDE GLASS INHALATION MULTIPLE SOME POSITIVE DATA EXIST, BUT
CHEMICALS ANIMAL THE DATA ARE NOT SUFFICIENT
SPECIES FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
QUARTZ SILICA INHALATION HUMAN CARCINOGENIC
AND ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TALC INGESTION NOT TOXIC TO DEVELOPMENT
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC RAT NOAEL: 1,600 MG/KG DURING ORGANOGENESIS
LIMESTONE RAT NOAEL: PREMATING &
625 MG/KG/DAY DURING GESTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE
NEGATIVE
TRIS(2,4,6- INHALATION RESPIRATORY SOME POSITIVE DATA
DIMETHYLAMINO- IRRITATION EXIST, BUT THE DATA
MONOMETHYL)PHENOL ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
LIMESTONE RAT NOAEL: 90 MINUTES
0.812 MG/L
TRIS(2,4,6- NOAEL:
DIMETHYLAMINOMONOMETHYL) NOT AVAILABLE
PHENOL
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA EXIST,
RESPIRATORY SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
LIMESTONE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
OXIDE GLASS INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
CHEMICALS BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TRIS(2,4,6- DERMAL SKIN SOME POSITIVE DATA EXIST,
DIMETHYL- LIVER BUT THE DATA ARE NOT
AMINOMONO- NERVOUS SYSTEM SUFFICIENT FOR
METHYL)PHENOL CLASSIFICATION
TRIS(2,4,6- DERMAL AUDITORY SYSTEM ALL DATA ARE NEGATIVE
DIMETHYL- HEMATOPOIETIC
AMINOMONO- SYSTEM
METHYL)PHENOL EYES
TITANIUM INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
DIOXIDE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM INHALATION PULMONARY FIBROSIS ALL DATA ARE NEGATIVE
DIOXIDE
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
LIMESTONE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
OXIDE GLASS HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
CHEMICALS EXPOSURE
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYLAMINOMONO-
METHYL)PHENOL
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYLAMINOMONO-
METHYL)PHENOL
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
QUARTZ SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE (AIRBORNE NONE CARCINOGEN
PARTICLES OF RESPIRABLE SIZE)
LEAD 7439-92-1 FEMALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 MALE REPRODUCTIVE TOXIN
LEAD 7439-92-1 CARCINOGEN
LEAD 7439-92-1 DEVELOPMENTAL TOXIN
TITANIUM DIOXIDE 13463-67-7 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 28-6974-1
VERSION NUMBER: 3.02
ISSUE DATE: 03/18/16
SUPERCEDES DATE: 02/24/16
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
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