| Common Name: | COMPOSITE & METAL BONDING ADHESVIE - 35 PN 08273, 58273 |
| Manufacturer: | 3M |
| SDS Revision Date: | 8/31/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVD6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) COMPOSITE & METAL BONDING ADHESVIE - 35 PN 08273, 58273
08/31/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 27-0452-6
VERSION NUMBER: 5.00
ISSUE DATE: 08/31/15
SUPERCEDES DATE: 05/30/14
PRODUCT IDENTIFIER:
3M(TM) COMPOSITE & METAL BONDING ADHESVIE - 35 PN 08273, 58273
ID NUMBER(S):
LB-K100-0712-4, LB-K100-0907-6, 41-0003-6755-1, 41-0003-8005-9,
41-9103-0380-3, 60-4550-5028-0, 60-4550-7095-7
RECOMMENDED USE:
AUTOMOTIVE, URETHANE REPAIR ADHESIVE USED TO BOND SMC AND FRP (TRADITIONAL
FIBERGLASS) BODY PANELS TO EACH OTHER AND TO PRIMED METAL FRAMES.
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
PART A CONTAINS A CHEMICAL SUBSTANCE NOT ON THE US TSCA INVENTORY. THIS
EXPERIMENTAL PRODUCT SHOULD BE EVALUATED BY A TECHNICALLY QUALIFIED
INDIVIDUAL FOR R & D USES ONLY.
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
27-0145-6, 27-4706-1
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-35 PART B, PN 08273, 58273
05/23/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 27-0145-6
VERSION NUMBER: 3.00
ISSUE DATE: 05/23/14
SUPERCEDES DATE: 12/10/12
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-35 PART B, PN 08273, 58273
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0711-6, LB-K100-0910-5, LB-K100-1317-9
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, BODY REPAIR
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYETHER POLYOL TRADE SECRET* 30 - 60 TRADE SECRET *
(NJTSRN 04499600-6782)
POLYOL (NJTSRN 04499600-6783) TRADE SECRET* 15 - 40 TRADE SECRET *
TALC 14807-96-6 15 - 40 TRADE SECRET *
URETHANE PREPOLYMER TRADE SECRET* 3 - 7 TRADE SECRET *
(NJTSRN 04499600-6781)
THICKENING AGENT TRADE SECRET* 1 - 5 TRADE SECRET *
PIPERAZINE 110-85-0 <1 TRADE SECRET *
QUARTZ SILICA 14808-60-7 <0.1 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 <0.1 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT USE IN A CONFINED AREA WITH
MINIMAL AIR EXCHANGE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN
READ AND UNDERSTOOD. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT
GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING
BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC
ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.)
AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES. STORE AWAY FROM
OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
PIPERAZINE 110-85-0 ACGIH TWA (AS PIPERAZINE, SENSITIZER
INHALABLE FRACTION
& VAPOR):
0.03 PPM
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3
TITANIUM DIOXIDE 13463-67-7 CMRG TWA (AS RESPIRABLE
DUST): 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 OSHA TWA (AS TOTAL
DUST): 15 MG/M3
TALC 14807-96-6 ACGIH TWA (RESPIRABLE
FRACTION): 2 MG/M3
TALC 14807-96-6 CMRG TWA (AS RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
QUARTZ SILICA 14808-60-7 ACGIH TWA (RESPIRABLE
FRACTION): 0.025 MG/M3
QUARTZ SILICA 14808-60-7 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: VISCOUS
ODOR, COLOR, GRADE: SLIGHT AMMONIA LIKE ODOR, DARK GREEN.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >340 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: <=1 [DETAILS: GELS WITH EXPOSURE TO HUMIDITY.]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: <=0.000004 MMHg [@ 68 DEG. F]
VAPOR DENSITY: >=1 [REF STD: AIR=1]
DENSITY: 1.2 G/ML
SPECIFIC GRAVITY: 1.0 - 1.2 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.093% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
1 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HIGH SHEAR AND HIGH TEMPERATURE CONDITIONS
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
ALCOHOLS
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES NOT SPECIFIED
HYDROGEN CYANIDE NOT SPECIFIED
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
VAPORS RELEASED DURING CURING MAY CAUSE IRRITATION OF THE RESPIRATORY
SYSTEM. SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE,
HEADACHE, HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION. ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
VAPORS RELEASED DURING CURING MAY CAUSE EYE IRRITATION. SIGNS/SYMPTOMS MAY
INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR HAZY VISION.
INGESTION: NO HEALTH EFFECTS ARE EXPECTED.
TARGET ORGAN EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT C.A.S. NO. CLASS DESCRIPTION REGULATION
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO HUMANS FOR RESEARCH ON CANCER
SILICA, CRYS 14808-60-7 KNOWN HUMAN CARCINOGEN NATIONAL TOXICOLOGY
AIRRESP PROGRAM CARCINOGENS
TITANIUM 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
DIOXIDE POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
POLYETHER POLYOL DERMAL RAT LD50: >2,000 MG/KG
(NJTSRN 04499600-6782)
POLYETHER POLYOL INGESTION RAT LD50: >2,500 MG/KG
(NJTSRN 04499600-6782)
TALC DERMAL LD50: NOT AVAILABLE
TALC INGESTION LD50: NOT AVAILABLE
POLYOL DERMAL RABBIT LD50: >5,000 MG/KG
(NJTSRN 04499600-6783)
POLYOL INGESTION RAT LD50: >10,000 MG/KG
(NJTSRN 04499600-6783)
URETHANE PREPOLYMER INGESTION LD50:
(NJTSRN 04499600-6781) ESTIMATED TO BE
2,000 - 5,000 MG/KG
PIPERAZINE DERMAL ESTIMATED TO BE
>5,000 MG/KG
PIPERAZINE INHALATION- ESTIMATED TO BE
DUST/MIST >12.5 MG/L
PIPERAZINE INHALATION- ESTIMATED TO BE
VAPOR >50 MG/L
PIPERAZINE INGESTION ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
QUARTZ SILICA NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN AND CARCINOGENIC
ANIMAL
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TALC INGESTION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC RAT NOAEL: 1,600 MG/KG DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE SPECIES TEST RESULT EXPOSURE
DURATION
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
RESPIRATORY SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS ALL DATA ARE NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
QUARTZ SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TITANIUM DIOXIDE RAT LOAEL: 0.010 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
NOT REGULATED PER U.S. DOT, IATA OR IMO.
THESE TRANSPORTATION CLASSIFICATIONS ARE PROVIDED AS A CUSTOMER SERVICE. AS
THE SHIPPER YOU REMAIN RESPONSIBLE FOR COMPLYING WITH ALL APPLICABLE LAWS
AND REGULATIONS, INCLUDING PROPER TRANSPORTATION CLASSIFICATION AND
PACKAGING. 3M TRANSPORTATION CLASSIFICATIONS ARE BASED ON PRODUCT
FORMULATION, PACKAGING, 3M POLICIES AND 3M UNDERSTANDING OF APPLICABLE
CURRENT REGULATIONS. 3M DOES NOT GUARANTEE THE ACCURACY OF THIS
CLASSIFICATION INFORMATION. THIS INFORMATION APPLIES ONLY TO TRANSPORTATION
CLASSIFICATION AND NOT THE PACKAGING, LABELING, OR MARKING REQUIREMENTS.
THE ORIGINAL 3M PACKAGE IS CERTIFIED FOR U.S. GROUND SHIPMENT ONLY. IF YOU
ARE SHIPPING BY AIR OR OCEAN, THE PACKAGE MAY NOT MEET APPLICABLE
REGULATORY REQUIREMENTS.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 27-0145-6
VERSION NUMBER: 3.00
ISSUE DATE: 05/23/14
SUPERCEDES DATE: 12/10/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-35 PART A, PN 08273, 58273
04/21/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 27-4706-1
VERSION NUMBER: 3.01
ISSUE DATE: 04/21/15
SUPERCEDES DATE: 05/23/14
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-35 PART A, PN 08273, 58273
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0739-0, LB-K100-0908-6, LB-K100-1317-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, REPAIR ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
ACUTE TOXICITY (INHALATION): CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
35% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
METHYLENE PHENYLENE ISOCYANATE 101-68-8 25 - 60 TRADE SECRET *
URETHANE PREPOLYMER TRADE SECRET* 15 - 40 TRADE SECRET *
(NJTSRN 04499600-6779)
DIISOCYANATE POLYMER TRADE SECRET* 5 - 20 TRADE SECRET *
ALUMINUM SILICATE TRADE SECRET* 7 - 13 TRADE SECRET *
(NJTSRN 04499600-6789)
TALC 14807-96-6 7 - 13 TRADE SECRET *
ALUMINUM OXIDE (NON-FIBROUS) TRADE SECRET* 1 - 7
SODIUM OXIDE TRADE SECRET* 1 - 5
THICKENING AGENT TRADE SECRET* 1 - 5 TRADE SECRET *
(NJTSRN 04499600-6784)
CALCIUM OXIDE TRADE SECRET* 1 - 5
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8%
CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR
10 MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN
30 MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO
AVOID PRESSURE BUILD-UP. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT USE IN A CONFINED AREA WITH
MINIMAL AIR EXCHANGE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO
NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
LOSS OF STABILIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED, DO NOT
RESEAL CONTAINER. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY
FROM STRONG BASES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
FREE 101-68-8 MANUFACTURER TWA: 0.005 PPM
ISOCYANATES DETERMINED STEL: 0.02 PPM
METHYLENE 101-68-8 ACGIH TWA: 0.005 PPM
PHENYLENE
ISOCYANATE
METHYLENE 101-68-8 OSHA CEIL:
PHENYLENE 0.2 MG/M3
ISOCYANATE (0.02 PPM)
TALC 14807-96-6 ACGIH TWA (RESPIRABLE A4:
FRACTION): NOT CLASS. AS
2 MG/M3 HUMAN CARCIN
TALC 14807-96-6 CMRG TWA (AS RESPIRABLE
DUST): 0.5 MG/M3
TALC 14807-96-6 OSHA TWA CONCENTRATION
(AS TOTAL DUST):
0.3 MG/M3
TWA CONCENTRATION
(RESPIRABLE):
0.1 MG/M3 (2.4
MILLIONS OF
PARTICLES/CU. FT.)
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
ALUMINUM OXIDE TRADE ACGIH TWA (RESPIRABLE A4:
(NON-FIBROUS) SECRET FRACTION): NOT CLASS. AS
1 MG/M3 HUMAN CARCIN
ALUMINUM OXIDE TRADE CMRG TWA: 1 FIBER/CC
(NON-FIBROUS) SECRET
ALUMINUM OXIDE TRADE OSHA TWA (AS TOTAL
(NON-FIBROUS) SECRET DUST): 15 MG/M3
TWA (RESPIRABLE
FRACTION): 5 MG/M3
ALUMINUM TRADE CMRG TWA (AS RESPIRABLE
SILICATE SECRET DUST): 3 MG/M3
(NJTSRN
04499600-6789)
ALUMINUM TRADE OSHA TWA CONCENTRATION:
SILICATE SECRET 0.8 MG/M3
(NJTSRN
04499600-6789) TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
CALCIUM OXIDE TRADE ACGIH TWA: 2 MG/M3
SECRET
CALCIUM OXIDE TRADE OSHA TWA: 5 MG/M3
SECRET
THICKENING TRADE OSHA TWA CONCENTRATION:
AGENT SECRET 0.8 MG/M3
(NJTSRN
04499600-6784) TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE VENTILATED ENCLOSURE FOR HEAT CURING. CURING ENCLOSURES MUST BE
EXHAUSTED TO OUTDOORS OR TO A SUITABLE EMISSION CONTROL DEVICE. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - NITRILE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: WHITE, SLIGHT ISOCYANATE ODOR
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >383 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: <1 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: .010 MMHg [DETAILS: @77.00 F FOR PRODUCT]
VAPOR DENSITY: <1 [REF STD: AIR=1]
DENSITY: 10.72 LB/GAL
SPECIFIC GRAVITY: 1.288 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.779 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION MAY OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
10 - 20 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
METHYLENE PHENYLENE INHALATION- LC50:
ISOCYANATE VAPOR ESTIMATED TO BE
10 - 20 MG/L
METHYLENE PHENYLENE DERMAL RABBIT LD50: >5,000 MG/KG
ISOCYANATE
METHYLENE PHENYLENE INHALATION- RAT LC50: 0.369 MG/L
ISOCYANATE DUST/MIST
(4 HOURS)
METHYLENE PHENYLENE INGESTION RAT LD50: 31,600 MG/KG
ISOCYANATE
URETHANE PREPOLYMER INGESTION LD50:
(NJTSRN 04499600-6779) ESTIMATED TO BE
2,000 - 5,000 MG/KG
DIISOCYANATE POLYMER INHALATION- LC50:
VAPOR ESTIMATED TO BE
10 - 20 MG/L
DIISOCYANATE POLYMER DERMAL RABBIT LD50: >5,000 MG/KG
DIISOCYANATE POLYMER INHALATION- RAT LC50: 0.369 MG/L
DUST/MIST
(4 HOURS)
DIISOCYANATE POLYMER INGESTION RAT LD50: 31,600 MG/KG
TALC DERMAL LD50: NOT AVAILABLE
TALC INGESTION LD50: NOT AVAILABLE
ALUMINUM SILICATE DERMAL RABBIT LD50: >5,000 MG/KG
(NJTSRN 04499600-6789)
ALUMINUM SILICATE INHALATION- RAT LC50: >0.691 MG/L
(NJTSRN 04499600-6789) DUST/MIST
(4 HOURS)
ALUMINUM SILICATE INGESTION RAT LD50: >5,110 MG/KG
(NJTSRN 04499600-6789)
ALUMINUM OXIDE DERMAL LD50:
(NON-FIBROUS) ESTIMATED TO BE
>5,000 MG/KG
ALUMINUM OXIDE INHALATION- RAT LC50: >2.3 MG/L
(NON-FIBROUS) DUST/MIST
(4 HOURS)
ALUMINUM OXIDE INGESTION RAT LD50: >5,000 MG/KG
(NON-FIBROUS)
SODIUM OXIDE INGESTION LD50:
ESTIMATED TO BE
50 - 300 MG/KG
CALCIUM OXIDE INGESTION RAT LD50: >2,500 MG/KG
THICKENING AGENT DERMAL RABBIT LD50: >5,000 MG/KG
(NJTSRN 04499600-6784)
THICKENING AGENT INHALATION- RAT LC50: >0.691 MG/L
(NJTSRN 04499600-6784) DUST/MIST
(4 HOURS)
THICKENING AGENT INGESTION RAT LD50: >5,110 MG/KG
(NJTSRN 04499600-6784)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYLENE PHENYLENE OFFICIAL IRRITANT
ISOCYANATE CLASSIFICATION
DIISOCYANATE POLYMER OFFICIAL IRRITANT
CLASSIFICATION
TALC RABBIT NO SIGNIFICANT IRRITATION
ALUMINUM SILICATE RABBIT NO SIGNIFICANT IRRITATION
(NJTSRN 04499600-6789)
ALUMINUM OXIDE (NON-FIBROUS) RABBIT NO SIGNIFICANT IRRITATION
CALCIUM OXIDE HUMAN CORROSIVE
THICKENING AGENT RABBIT NO SIGNIFICANT IRRITATION
(NJTSRN 04499600-6784)
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYLENE PHENYLENE OFFICIAL SEVERE IRRITANT
ISOCYANATE CLASSIFICATION
DIISOCYANATE POLYMER OFFICIAL SEVERE IRRITANT
CLASSIFICATION
TALC RABBIT NO SIGNIFICANT IRRITATION
ALUMINUM SILICATE RABBIT NO SIGNIFICANT IRRITATION
(NJTSRN 04499600-6789)
ALUMINUM OXIDE (NON-FIBROUS) RABBIT NO SIGNIFICANT IRRITATION
CALCIUM OXIDE RABBIT CORROSIVE
THICKENING AGENT RABBIT NO SIGNIFICANT IRRITATION
(NJTSRN 04499600-6784)
SKIN SENSITIZATION:
NAME SPECIES VALUE
METHYLENE PHENYLENE OFFICIAL SENSITIZING
ISOCYANATE CLASSIFICATION
DIISOCYANATE POLYMER OFFICIAL SENSITIZING
CLASSIFICATION
ALUMINUM SILICATE HUMAN AND ANIMAL NOT SENSITIZING
(NJTSRN 04499600-6789)
THICKENING AGENT HUMAN AND ANIMAL NOT SENSITIZING
(NJTSRN 04499600-6784)
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
METHYLENE PHENYLENE ISOCYANATE HUMAN SENSITIZING
DIISOCYANATE POLYMER HUMAN SENSITIZING
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
METHYLENE PHENYLENE IN VITRO SOME POSITIVE DATA EXIST, BUT
ISOCYANATE THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIISOCYANATE POLYMER IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
ALUMINUM SILICATE IN VITRO NOT MUTAGENIC
(NJTSRN 04499600-6789)
ALUMINUM OXIDE (NON-FIBROUS) IN VITRO NOT MUTAGENIC
CALCIUM OXIDE IN VITRO NOT MUTAGENIC
THICKENING AGENT IN VITRO NOT MUTAGENIC
(NJTSRN 04499600-6784)
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
METHYLENE PHENYLENE INHALATION RAT SOME POSITIVE DATA
ISOCYANATE EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIISOCYANATE POLYMER INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ALUMINUM SILICATE NOT SPECIFIED MOUSE SOME POSITIVE DATA
(NJTSRN 04499600-6789) EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ALUMINUM OXIDE INHALATION RAT NOT CARCINOGENIC
(NON-FIBROUS)
THICKENING AGENT NOT SPECIFIED MOUSE SOME POSITIVE DATA
(NJTSRN 04499600-6784) EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
METHYLENE PHENYLENE ISOCYANATE INHALATION SOME POSITIVE DEVELOPMENTAL
DATA EXITS, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
DIISOCYANATE POLYMER INHALATION SOME POSITIVE DEVELOPMENTAL
DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
TALC INGESTION NOT TOXIC TO DEVELOPMENT
ALUMINUM SILICATE INGESTION NOT TOXIC TO FEMALE
(NJTSRN 04499600-6789) REPRODUCTION
ALUMINUM SILICATE INGESTION NOT TOXIC TO MALE
(NJTSRN 04499600-6789) REPRODUCTION
ALUMINUM SILICATE INGESTION NOT TOXIC TO DEVELOPMENT
(NJTSRN 04499600-6789)
THICKENING AGENT INGESTION NOT TOXIC TO FEMALE
(NJTSRN 04499600-6784) REPRODUCTION
THICKENING AGENT INGESTION NOT TOXIC TO MALE
(NJTSRN 04499600-6784) REPRODUCTION
THICKENING AGENT INGESTION NOT TOXIC TO DEVELOPMENT
(NJTSRN 04499600-6784)
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYLENE PHENYLENE RAT NOAEL: 0.004 MG/L DURING
ISOCYANATE ORGANOGENESIS
DIISOCYANATE POLYMER RAT NOAEL: 0.004 MG/L DURING
ORGANOGENESIS
TALC RAT NOAEL: 1,600 MG/KG DURING
ORGANOGENESIS
ALUMINUM SILICATE RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
(NJTSRN 04499600-6789)
ALUMINUM SILICATE RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
(NJTSRN 04499600-6789)
ALUMINUM SILICATE RAT NOAEL: DURING
(NJTSRN 04499600-6789) 1,350 MG/KG/DAY ORGANOGENESIS
THICKENING AGENT RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
(NJTSRN 04499600-6784)
THICKENING AGENT RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
(NJTSRN 04499600-6784)
THICKENING AGENT RAT NOAEL: DURING
(NJTSRN 04499600-6784) 1,350 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYLENE PHENYLENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
ISOCYANATE IRRITATION IRRITATION
DIISOCYANATE POLYMER INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
CALCIUM OXIDE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYLENE PHENYLENE OFFICIAL NOAEL:
ISOCYANATE CLASSIFICATION NOT AVAILABLE
DIISOCYANATE POLYMER OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
CALCIUM OXIDE NOT AVAILABLE NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYLENE PHENYLENE INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO
ISOCYANATE ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
DIISOCYANATE POLYMER INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
RESPIRATORY SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ALUMINUM SILICATE INHALATION RESPIRATORY SYSTEM ALL DATA ARE
(NJTSRN 04499600-6789) SILICOSIS NEGATIVE
ALUMINUM OXIDE INHALATION PNEUMOCONIOSIS SOME POSITIVE DATA
(NON-FIBROUS) PULMONARY FIBROSIS EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
THICKENING AGENT INHALATION RESPIRATORY SYSTEM ALL DATA ARE
(NJTSRN 04499600-6784) SILICOSIS NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYLENE PHENYLENE RAT LOAEL: 0.004 MG/L 13 WEEKS
ISOCYANATE
DIISOCYANATE POLYMER RAT LOAEL: 0.004 MG/L 13 WEEKS
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
ALUMINUM SILICATE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
(NJTSRN 04499600-6789) EXPOSURE
ALUMINUM OXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
(NON-FIBROUS) EXPOSURE
THICKENING AGENT HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
(NJTSRN 04499600-6784) EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. AS A DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE
PERMITTED WASTE DISPOSAL FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
METHYLENE PHENYLENE ISOCYANATE 101-68-8 25 - 60
METHYLENE PHENYLENE ISOCYANATE (BENZENE, 1,1'- 101-68-8 25 - 60
METHYLENEBIS[4-ISOCYANATO-)
METHYLENE PHENYLENE ISOCYANATE 101-68-8 25 - 60
(DIISOCYANATES (CERTAIN CHEMICALS ONLY))
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS REACTS WITH WATER
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 27-4706-1
VERSION NUMBER: 3.01
ISSUE DATE: 04/21/15
SUPERCEDES DATE: 05/23/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
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KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM