| Common Name: | SMC/FIBERGLASS REPAIR ADHESIVE-90, 08274 |
| Manufacturer: | 3M |
| SDS Revision Date: | 10/11/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVD7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-90, 08274
10/11/21
3M
SAFETY DATA SHEET
COPYRIGHT, 2021, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 30-6204-9
VERSION NUMBER: 2.07
ISSUE DATE: 10/11/21
SUPERCEDES DATE: 07/23/21
PRODUCT IDENTIFIER: 3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-90, 08274
ID NUMBER(S):
41-0003-8007-5, 60-4550-5119-7
7000119863
RECOMMENDED USE: AUTOMOTIVE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET. THE DOCUMENT NUMBERS FOR COMPONENTS OF
THIS PRODUCT ARE: 30-8517-2, 33-9460-8
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M.
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-90 PART B, PNS 08274, 08283
10/11/21
3M
SAFETY DATA SHEET
COPYRIGHT, 2021, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 33-9460-8
VERSION NUMBER: 3.00
ISSUE DATE: 10/11/21
SUPERCEDES DATE: 01/18/21
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SMC/FIBERGLASS REPAIR ADHESIVE-90 PART B, PNS 08274, 08283
PRODUCT IDENTIFICATION NUMBERS:
60-4100-0975-1
7100016227
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
CARCINOGENICITY: CATEGORY 2.
GERM CELL MUTAGENICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
SUSPECTED OF CAUSING GENETIC DEFECTS.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
12% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
92% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
4,4'-ISOPROPYLIDENEDIPHENOL- 25068-38-6 30 - 60 TRADE SECRET *
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS 65997-17-3 10 - 30 TRADE SECRET *
1,4-BIS[(2,3-EPOXYPROPOXY) 14228-73-0 7 - 13 TRADE SECRET *
METHYL]CYCLOHEXANE
FUSED SILICA 60676-86-0 7 - 13 TRADE SECRET *
ACRYLATE POLYMER TRADE SECRET* 1 - 11 TRADE SECRET *
SILICA 7631-86-9 1 - 5 TRADE SECRET *
3-(TRIMETHOXYSILYL)PROPYL 2530-83-8 0.5 - 1.5 TRADE SECRET *
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION 67762-90-7 0.5 - 1.5 TRADE SECRET *
PRODUCT WITH SILICA
CARBON BLACK 1333-86-4 <0.5 TRADE SECRET *
TOLUENE 108-88-3 <0.3 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC SKIN REACTION (REDNESS, SWELLING, BLISTERING, AND ITCHING).
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WHEN FIRE FIGHTING CONDITIONS ARE SEVERE AND TOTAL THERMAL DECOMPOSITION
OF THE PRODUCT IS POSSIBLE, WEAR FULL PROTECTIVE CLOTHING, INCLUDING
HELMET, SELF-CONTAINED, POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING
APPARATUS, BUNKER COAT AND PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE
MASK, AND PROTECTIVE COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES. STORE AWAY FROM
OXIDIZING AGENTS. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS.
AS HUMAN
CARCIN,
OTOTOXICANT
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
CARBON BLACK 1333-86-4 ACGIH TWA (INHALABLE A3:
FRACTION): CONFIRMED
3 MG/M3 ANIMAL
CARCIN.
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
DUST, INERT 60676-86-0 OSHA TWA (AS TOTAL
OR NUISANCE DUST):
15 MG/M3
TWA (AS TOTAL
DUST):
50 MILLIONS
OF PARTICLES/
CU. FT.
(15 MG/M3)
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
TWA
(RESPIRABLE
FRACTION):
15 MILLIONS
OF PARTICLES/
CU. FT.
(5 MG/M3)
SILICA, AMORPHOUS 60676-86-0 OSHA TWA:
20 MILLIONS
OF PARTICLES/
CU. FT.
TWA
CONCENTRATION:
0.8 MG/M3
CERAMIC FIBERS 65997-17-3 ACGIH TWA A2:
(AS FIBER): SUSPECTED
0.2 FIBER/CC HUMAN
CARCIN.
OXIDE GLASS 65997-17-3 MANUFACTURER TWA (AS
CHEMICALS DETERMINED NON-FIBROUS,
RESPIRABLE)
(8 HOURS):
3 MG/M3
TWA (AS
NON-FIBROUS,
INHALABLE
FRACTION)
(8 HOURS):
10 MG/M3
SPECIAL PURPOSE 65997-17-3 ACGIH TWA (AS A3:
GLASS FIBERS FIBER): CONFIRMED
1 FIBER/CC ANIMAL
CARCIN.
SILICA, 67762-90-7 OSHA TWA:
AMORPHOUS 20 MILLIONS
OF PARTICLES/
CU. FT.
TWA
CONCENTRATION:
0.8 MG/M3
DUST, INERT 7631-86-9 OSHA TWA (AS
OR NUISANCE TOTAL DUST):
15 MG/M3
TWA (AS
TOTAL DUST):
50 MILLIONS
OF PARTICLES/
CU. FT.
(15 MG/M3)
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
TWA
(RESPIRABLE
FRACTION):
15 MILLIONS
OF PARTICLES/
CU. FT.
(5 MG/M3)
SILICA, 7631-86-9 OSHA TWA:
AMORPHOUS 20 MILLIONS
OF PARTICLES/
CU. FT.
TWA
CONCENTRATION:
0.8 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: COLOR
LIQUID: BLACK
ODOR: ACRYLIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >=95 DEG. F
FLASH POINT >=220 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: <=1 UNITS NOT AVAIL. OR NOT APPL. [REF STD:BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=27 PSIA
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 8.01 LB/GAL
DENSITY: 0.96 G/ML
SPECIFIC GRAVITY: 0.96 [REF STD:WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
100,000 CENTIPOISE - 225,000 CENTIPOISE [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0.00162 LB HAPS/GAL
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
15 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
1.6% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 1.6% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
15 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
AMINES
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES NOT SPECIFIED
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
HYDROGEN CHLORIDE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
GENOTOXICITY:
GENOTOXICITY AND MUTAGENICITY:
MAY INTERACT WITH GENETIC MATERIAL AND POSSIBLY ALTER GENE EXPRESSION.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
CARBON BLACK 1333-86-4 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE:
(4 HR) 5 - 12.5 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL RAT LD50: >1,600 MG/KG
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION RAT LD50: >1,000 MG/KG
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS DERMAL LD50 ESTIMATED
TO BE: >5,000 MG/KG
OXIDE GLASS CHEMICALS INGESTION LD50 ESTIMATED
TO BE:
2,000 - 5,000 MG/KG
FUSED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
1,4-BIS[(2,3-EPOXYPROPOXY) INGESTION RAT LD50: 1,000 MG/KG
METHYL]CYCLOHEXANE
FUSED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUSED SILICA INGESTION RAT LD50: >5,110 MG/KG
ACRYLATE POLYMER DERMAL RABBIT LD50: >5,000 MG/KG
ACRYLATE POLYMER INGESTION RAT LD50: >5,000 MG/KG
SILICA DERMAL RABBIT LD50: >5,000 MG/KG
SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
SILICA INGESTION RAT LD50: >5,110 MG/KG
3-(TRIMETHOXYSILYL)PROPYL DERMAL RABBIT LD50: 4,000 MG/KG
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL INHALATION- RAT LC50: >5.3 MG/L
GLYCIDYL ETHER DUST/MIST
(4 HOURS)
3-(TRIMETHOXYSILYL)PROPYL INGESTION RAT LD50: 7,010 MG/KG
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION DERMAL RABBIT LD50: >5,000 MG/KG
PRODUCT WITH SILICA
DIMETHYL SILOXANE, REACTION INHALATION- RAT LC50: >0.691 MG/L
PRODUCT WITH SILICA DUST/MIST
(4 HOURS)
DIMETHYL SILOXANE, REACTION INGESTION RAT LD50: >5,110 MG/KG
PRODUCT WITH SILICA
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MILD IRRITANT
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
1,4-BIS[(2,3-EPOXYPROPOXY) IN VITRO IRRITANT
METHYL]CYCLOHEXANE DATA
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLATE POLYMER PROFESSIONAL MINIMAL IRRITATION
JUDGMENT
SILICA RABBIT NO SIGNIFICANT IRRITATION
3-(TRIMETHOXYSILYL)PROPYL RABBIT MILD IRRITANT
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
TOLUENE RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MODERATE IRRITANT
EPICHLOROHYDRIN POLYMER
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
1,4-BIS[(2,3-EPOXYPROPOXY) IN VITRO NO SIGNIFICANT IRRITATION
METHYL]CYCLOHEXANE DATA
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLATE POLYMER PROFESSIONAL MILD IRRITANT
JUDGMENT
SILICA RABBIT NO SIGNIFICANT IRRITATION
3-(TRIMETHOXYSILYL)PROPYL RABBIT CORROSIVE
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
CARBON BLACK RABBIT NO SIGNIFICANT IRRITATION
TOLUENE RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN AND SENSITIZING
EPICHLOROHYDRIN POLYMER ANIMAL
1,4-BIS[(2,3-EPOXYPROPOXY) SIMILAR SENSITIZING
METHYL]CYCLOHEXANE COMPOUNDS
FUSED SILICA HUMAN AND NOT CLASSIFIED
ANIMAL
SILICA HUMAN AND NOT CLASSIFIED
ANIMAL
3-(TRIMETHOXYSILYL)PROPYL GUINEA PIG NOT CLASSIFIED
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION HUMAN AND NOT CLASSIFIED
PRODUCT WITH SILICA ANIMAL
TOLUENE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN NOT CLASSIFIED
EPICHLOROHYDRIN POLYMER
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- IN VIVO NOT MUTAGENIC
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- IN VITRO SOME POSITIVE DATA EXIST,
EPICHLOROHYDRIN POLYMER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
OXIDE GLASS CHEMICALS IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
1,4-BIS[(2,3-EPOXYPROPOXY) IN VITRO MUTAGENIC; STRUCTURALLY
METHYL]CYCLOHEXANE RELATED TO GERM CELL
MUTAGENS
FUSED SILICA IN VITRO NOT MUTAGENIC
SILICA IN VITRO NOT MUTAGENIC
3-(TRIMETHOXYSILYL)PROPYL IN VIVO NOT MUTAGENIC
GLYCIDYL ETHER
3-(TRIMETHOXYSILYL)PROPYL IN VITRO SOME POSITIVE DATA EXIST,
GLYCIDYL ETHER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
DIMETHYL SILOXANE, REACTION IN VITRO NOT MUTAGENIC
PRODUCT WITH SILICA
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL MOUSE SOME POSITIVE DATA
EPICHLOROHYDRIN POLYMER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIDE GLASS CHEMICALS INHALATION MULTIPLE SOME POSITIVE DATA
ANIMAL EXIST, BUT THE DATA
SPECIES ARE NOT SUFFICIENT
FOR CLASSIFICATION
FUSED SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
3-(TRIMETHOXYSILYL)PROPYL DERMAL MOUSE NOT CARCINOGENIC
GLYCIDYL ETHER
DIMETHYL SILOXANE, REACTION NOT MOUSE SOME POSITIVE DATA
PRODUCT WITH SILICA SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR
EPICHLOROHYDRIN POLYMER FEMALE REPRODUCTION
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR
EPICHLOROHYDRIN POLYMER MALE REPRODUCTION
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL NOT CLASSIFIED FOR
EPICHLOROHYDRIN POLYMER DEVELOPMENT
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR
EPICHLOROHYDRIN POLYMER DEVELOPMENT
FUSED SILICA INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
FUSED SILICA INHALATION NOT CLASSIFIED FOR
MALE REPRODUCTION
FUSED SILICA INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
SILICA INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
SILICA INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
SILICA INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT CLASSIFIED FOR
GLYCIDYL ETHER FEMALE REPRODUCTION
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT CLASSIFIED FOR
GLYCIDYL ETHER MALE REPRODUCTION
3-(TRIMETHOXYSILYL)PROPYL INGESTION NOT CLASSIFIED FOR
GLYCIDYL ETHER DEVELOPMENT
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR
PRODUCT WITH SILICA FEMALE REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR
PRODUCT WITH SILICA MALE REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR
PRODUCT WITH SILICA DEVELOPMENT
TOLUENE INHALATION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED FOR
MALE REPRODUCTION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE
DURATION
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT NOAEL: DURING
EPICHLOROHYDRIN POLYMER 300 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
FUSED SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
FUSED SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
FUSED SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 1 GENERATION
GLYCIDYL ETHER 1,000 MG/KG/DAY
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: DURING
GLYCIDYL ETHER 3,000 MG/KG/DAY ORGANOGENESIS
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 509 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: 1 GENERATION
PRODUCT WITH SILICA 497 MG/KG/DAY
DIMETHYL SILOXANE, REACTION RAT NOAEL: DURING
PRODUCT WITH SILICA 1,350 MG/KG/DAY ORGANOGENESIS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING
520 MG/KG/DAY GESTATION
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
1,4-BIS INHALATION RESPIRATORY SOME POSITIVE DATA
[(2,3-EPOXYPROPOXY) IRRITATION EXIST, BUT THE DATA
METHYL]CYCLOHEXANE ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION CENTRAL MAY CAUSE
NERVOUS SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL MAY CAUSE
NERVOUS SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
1,4-BIS[(2,3-EPOXYPROPOXY) SIMILAR NOAEL:
METHYL]CYCLOHEXANE HEALTH NOT AVAILABLE
HAZARDS
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
4,4'- DERMAL LIVER NOT CLASSIFIED
ISOPROPYLIDENEDIPHENOL-
EPICHLOROHYDRIN POLYMER
4,4'- DERMAL NERVOUS SYSTEM NOT CLASSIFIED
ISOPROPYLIDENEDIPHENOL-
EPICHLOROHYDRIN POLYMER
4,4'- INGESTION AUDITORY SYSTEM NOT CLASSIFIED
ISOPROPYLIDENEDIPHENOL- HEART
EPICHLOROHYDRIN POLYMER ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
EYES
KIDNEY AND/OR
BLADDER
OXIDE GLASS CHEMICALS INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
FUSED SILICA INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
SILICOSIS
SILICA INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
SILICOSIS
3-(TRIMETHOXYSILYL) INGESTION HEART NOT CLASSIFIED
PROPYL GLYCIDYL ETHER ENDOCRINE SYSTEM
BONE, TEETH,
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
DIMETHYL SILOXANE, INHALATION RESPIRATORY NOT CLASSIFIED
REACTION PRODUCT SYSTEM
WITH SILICA SILICOSIS
CARBON BLACK INHALATION PNEUMOCONIOSIS NOT CLASSIFIED
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE
EYES TO ORGANS
OLFACTORY SYSTEM THROUGH
PROLONGED OR
REPEATED
EXPOSURE
TOLUENE INHALATION NERVOUS SYSTEM MAY CAUSE
DAMAGE TO
ORGANS THOUGH
PROLONGED OR
REPEATED
EXPOSURE
TOLUENE INHALATION RESPIRATORY SOME POSITIVE
SYSTEM DATA EXIST, BUT
THE DATA ARE
NOT SUFFICIENT
FOR
CLASSIFICATION
TOLUENE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR
HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
VASCULAR SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE
DATA EXIST, BUT
THE DATA ARE
NOT SUFFICIENT
FOR
CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
NAME SPECIES TEST RESULT EXPOSURE
DURATION
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 YEARS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL RAT NOAEL: 13 WEEKS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 28 DAYS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
OXIDE GLASS CHEMICALS HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
FUSED SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
3-(TRIMETHOXYSILYL)PROPYL RAT NOAEL: 28 DAYS
GLYCIDYL ETHER 1,000 MG/KG/DAY
DIMETHYL SILOXANE, REACTION HUMAN NOAEL: OCCUPATIONAL
PRODUCT WITH SILICA NOT AVAILABLE EXPOSURE
CARBON BLACK HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE MULTIPLE NOAEL: 11.3 MG/L 15 WEEKS
ANIMAL
SPECIES
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. COMBUSTION PRODUCTS WILL INCLUDE HALOGEN ACID
(HCL/HF/HBR). FACILITY MUST BE CAPABLE OF HANDLING HALOGENATED MATERIALS.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
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| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
CARCINOGENICITY
GERM CELL MUTAGENICITY
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 33-9460-8
VERSION NUMBER: 3.00
ISSUE DATE: 10/11/21
SUPERCEDES DATE: 01/18/21
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3M(TM) SMC/FIBERGLASS REPAIR (90 MINUTES) ADHESIVE PN 08274 - ACCELERATOR
09/08/21
3M
SAFETY DATA SHEET
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VERSION NUMBER: 1.14
ISSUE DATE: 09/08/21
SUPERCEDES DATE: 01/18/21
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) SMC/FIBERGLASS REPAIR (90 MINUTES) ADHESIVE PN 08274 - ACCELERATOR
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AUTOMOTIVE, ADHESIVE ACCELERATOR USED WITH 08274 ADHESIVE BASE. 08274 IS A
TWO PART ADHESIVE DESIGNED TO BOND SMC/FIBERGLASS AND ALUMINUM BODY PANELS.
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1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SKIN SENSITIZER: CATEGORY 1B.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS: BLOOD OR BLOOD-FORMING ORGANS
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
OVEREXPOSURE TO THIS PRODUCT MAY RESULT IN METHEMOGLOBINEMIA.
METHEMOGLOBINEMIA MAY BE CLINICALLY SUSPECTED BY THE PRESENCE OF CLINICAL
"CYANOSIS" IN THE PRESENCE OF A NORMAL PaO2 (AS OBTAINED BY ARTERIAL BLOOD
GASES). ROUTINE PULSE OXIMETRY MAY BE INACCURATE FOR MONITORING OXYGEN
SATURATION IN THE PRESENCE OF METHEMOGLOBINEMIA, AND SHOULD NOT BE USED TO
MAKE THE DIAGNOSIS OF THIS DISORDER. IF THE PATIENT IS SYMPTOMATIC OR IF
THE METHEMOGLOBIN LEVEL IS >20%, SPECIFIC THERAPY WITH METHYLENE BLUE
SHOULD BE CONSIDERED AS PART OF THE MEDICAL MANAGEMENT.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A CROSS-SENSITIZATION
REACTION TO CERTAIN OTHER AMINES.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYMERIC DIAMIDE 68911-25-1 30 - 60 TRADE SECRET *
BUTADIENE ACRYLONITRILE COPOLYMER 68683-29-4 10 - 30 TRADE SECRET *
FUSED SILICA 60676-86-0 10 - 30 TRADE SECRET *
BIS(3-AMINOPROPYL) ETHER OF 4246-51-9 <10 TRADE SECRET *
DIETHYLENE GLYCOL
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL) 90-72-2 5 - 10 TRADE SECRET *
PHENOL
AMINE EPOXY CURING AGENT 288-32-4 1 - 5 TRADE SECRET *
DIMETHYL SILOXANE, REACTION 67762-90-7 1 - 5 TRADE SECRET *
PRODUCT WITH SILICA
NITRIC ACID, AMMONIUM CALCIUM SALT 15245-12-2 1 - 5 TRADE SECRET *
BIS[(DIMETHYLAMINO)METHYL]PHENOL 71074-89-0 0.1 - 1.5 TRADE SECRET *
N-AMINOETHYLPIPERAZINE 140-31-8 0.1 - 1.5 TRADE SECRET *
TOLUENE 108-88-3 <0.5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SKIN BURNS (LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE PAIN, BLISTERING,
AND TISSUE DESTRUCTION). ALLERGIC SKIN REACTION (REDNESS, SWELLING,
BLISTERING, AND ITCHING). SERIOUS DAMAGE TO THE EYES (CORNEAL CLOUDINESS,
SEVERE PAIN, TEARING, ULCERATIONS, AND SIGNIFICANTLY IMPAIRED OR LOSS OF
VISION). CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHE, DIZZINESS,
DROWSINESS, INCOORDINATION, NAUSEA, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS). TARGET ORGAN EFFECTS. SEE SECTION 11 FOR ADDITIONAL
DETAILS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
OVEREXPOSURE TO THIS PRODUCT MAY RESULT IN METHEMOGLOBINEMIA.
METHEMOGLOBINEMIA MAY BE CLINICALLY SUSPECTED BY THE PRESENCE OF CLINICAL
"CYANOSIS" IN THE PRESENCE OF A NORMAL PaO2 (AS OBTAINED BY ARTERIAL BLOOD
GASES). ROUTINE PULSE OXIMETRY MAY BE INACCURATE FOR MONITORING OXYGEN
SATURATION IN THE PRESENCE OF METHEMOGLOBINEMIA, AND SHOULD NOT BE USED TO
MAKE THE DIAGNOSIS OF THIS DISORDER. IF THE PATIENT IS SYMPTOMATIC OR IF
THE METHEMOGLOBIN LEVEL IS >20%, SPECIFIC THERAPY WITH METHYLENE BLUE
SHOULD BE CONSIDERED AS PART OF THE MEDICAL MANAGEMENT.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY
FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS.
AS HUMAN
CARCIN,
OTOTOXICANT
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
DUST, INERT 60676-86-0 OSHA TWA (AS TOTAL
OR NUISANCE DUST): 15 MG/M3
TWA (AS TOTAL
DUST):
50 MILLIONS OF
PARTICLES/CU.
FT. (15 MG/M3)
TWA (RESPIRABLE
FRACTION):
5 MG/M3
TWA (RESPIRABLE
FRACTION):
15 MILLIONS OF
PARTICLES/CU.
FT. (5 MG/M3)
SILICA, AMORPHOUS 60676-86-0 OSHA TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
TWA
CONCENTRATION:
0.8 MG/M3
SILICA, AMORPHOUS 67762-90-7 OSHA TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
TWA
CONCENTRATION:
0.8 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: LIQUID
COLOR: TAN
SPECIFIC PHYSICAL FORM: VISCOUS LIQUID
ODOR: SLIGHT AMINE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=110 DEG. C
FLASH POINT: 110 DEG. C [TEST METHOD:CLOSED CUP]
EVAPORATION RATE: <=1 [REF STD:BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=200 MMHg [@ 20 DEG. C]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.2 G/ML
DENSITY: 10.01 LB/GAL
SPECIFIC GRAVITY: 1.2 [REF STD:WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 CENTIPOISE - 225,000 CENTIPOISE [TEST METHOD:BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: 0.01 LB HAPS/LB SOLIDS [TEST METHOD:CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
4 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0.4% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 0.4% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
4 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT: MAY BE HARMFUL IN CONTACT WITH SKIN.
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
METHEMOGLOBINEMIA:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, DIFFICULTY
BREATHING, AND GENERALIZED WEAKNESS.
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A CROSS-SENSITIZATION
REACTION TO CERTAIN OTHER AMINES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
POLYMERIC DIAMIDE DERMAL RAT LD50: >2,000 MG/KG
POLYMERIC DIAMIDE INGESTION RAT LD50: >2,000 MG/KG
FUSED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUSED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUSED SILICA INGESTION RAT LD50: >5,110 MG/KG
BUTADIENE ACRYLONITRILE DERMAL RABBIT LD50: >3,000 MG/KG
COPOLYMER
BUTADIENE ACRYLONITRILE INGESTION RAT LD50: >15,300 MG/KG
COPOLYMER
TRIS(2,4,6- DERMAL RAT LD50: 1,280 MG/KG
DIMETHYLAMINOMONOMETHYL)
PHENOL
TRIS(2,4,6- INGESTION RAT LD50: 1,000 MG/KG
DIMETHYLAMINOMONOMETHYL)
PHENOL
BIS(3-AMINOPROPYL) ETHER DERMAL RABBIT LD50: 2,500 MG/KG
OF DIETHYLENE GLYCOL
BIS(3-AMINOPROPYL) ETHER INGESTION RAT LD50: 3,160 MG/KG
OF DIETHYLENE GLYCOL
DIMETHYL SILOXANE, DERMAL RABBIT LD50: >5,000 MG/KG
REACTION PRODUCT
WITH SILICA
DIMETHYL SILOXANE, INHALATION- RAT LC50: >0.691 MG/L
REACTION PRODUCT DUST/MIST
WITH SILICA (4 HOURS)
DIMETHYL SILOXANE, INGESTION RAT LD50: >5,110 MG/KG
REACTION PRODUCT
WITH SILICA
AMINE EPOXY CURING AGENT INGESTION RAT LD50: 970 MG/KG
AMINE EPOXY CURING AGENT DERMAL SIMILAR LD50: 400 MG/KG
COMPOUNDS
NITRIC ACID, AMMONIUM INGESTION RAT LD50:
CALCIUM SALT >300, <2000 MG/KG
NITRIC ACID, AMMONIUM DERMAL SIMILAR LD50: >2,000 MG/KG
CALCIUM SALT COMPOUNDS
BIS[(DIMETHYLAMINO) INGESTION LD50 ESTIMATED
METHYL]PHENOL TO BE:
300 - 2,000 MG/KG
N-AMINOETHYLPIPERAZINE DERMAL RABBIT LD50: 865 MG/KG
N-AMINOETHYLPIPERAZINE INGESTION RAT LD50: 1,470 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT RABBIT CORROSIVE
POLYMERIC DIAMIDE RAT IRRITANT
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
BUTADIENE ACRYLONITRILE COPOLYMER RABBIT IRRITANT
TRIS(2,4,6- RABBIT CORROSIVE
DIMETHYLAMINOMONOMETHYL)PHENOL
BIS(3-AMINOPROPYL) ETHER OF RABBIT CORROSIVE
DIETHYLENE GLYCOL
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
AMINE EPOXY CURING AGENT RABBIT CORROSIVE
NITRIC ACID, AMMONIUM CALCIUM SALT SIMILAR NO SIGNIFICANT IRRITATION
COMPOUNDS
BIS[(DIMETHYLAMINO)METHYL]PHENOL SIMILAR CORROSIVE
COMPOUNDS
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TOLUENE RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT SIMILAR CORROSIVE
HEALTH
HAZARDS
POLYMERIC DIAMIDE IN VITRO SEVERE IRRITANT
DATA
FUSED SILICA RABBIT NO SIGNIFICANT IRRITATION
BUTADIENE ACRYLONITRILE COPOLYMER RABBIT MILD IRRITANT
TRIS(2,4,6- RABBIT CORROSIVE
DIMETHYLAMINOMONOMETHYL)PHENOL
BIS(3-AMINOPROPYL) ETHER OF SIMILAR CORROSIVE
DIETHYLENE GLYCOL HEALTH
HAZARDS
DIMETHYL SILOXANE, REACTION RABBIT NO SIGNIFICANT IRRITATION
PRODUCT WITH SILICA
AMINE EPOXY CURING AGENT RABBIT CORROSIVE
NITRIC ACID, AMMONIUM CALCIUM SALT RABBIT CORROSIVE
BIS[(DIMETHYLAMINO)METHYL]PHENOL SIMILAR CORROSIVE
COMPOUNDS
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TOLUENE RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
OVERALL PRODUCT GUINEA PIG SENSITIZING
POLYMERIC DIAMIDE GUINEA PIG SENSITIZING
FUSED SILICA HUMAN AND NOT CLASSIFIED
ANIMAL
BUTADIENE ACRYLONITRILE COPOLYMER GUINEA PIG SENSITIZING
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL GUINEA PIG NOT CLASSIFIED
DIMETHYL SILOXANE, REACTION PRODUCT HUMAN AND NOT CLASSIFIED
WITH SILICA ANIMAL
NITRIC ACID, AMMONIUM CALCIUM SALT MOUSE NOT CLASSIFIED
N-AMINOETHYLPIPERAZINE GUINEA PIG SENSITIZING
TOLUENE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
POLYMERIC DIAMIDE IN VITRO NOT MUTAGENIC
FUSED SILICA IN VITRO NOT MUTAGENIC
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL) IN VITRO NOT MUTAGENIC
PHENOL
DIMETHYL SILOXANE, REACTION PRODUCT IN VITRO NOT MUTAGENIC
WITH SILICA
AMINE EPOXY CURING AGENT IN VITRO NOT MUTAGENIC
AMINE EPOXY CURING AGENT IN VIVO NOT MUTAGENIC
NITRIC ACID, AMMONIUM CALCIUM SALT IN VITRO NOT MUTAGENIC
N-AMINOETHYLPIPERAZINE IN VIVO NOT MUTAGENIC
N-AMINOETHYLPIPERAZINE IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
FUSED SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL SILOXANE, REACTION NOT MOUSE SOME POSITIVE DATA
PRODUCT WITH SILICA SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
POLYMERIC DIAMIDE INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
POLYMERIC DIAMIDE INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
POLYMERIC DIAMIDE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
FUSED SILICA INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
FUSED SILICA INHALATION NOT CLASSIFIED FOR
MALE REPRODUCTION
FUSED SILICA INGESTION NOT CLASSIFIED FOR DEVELOPMENT
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR
PRODUCT WITH SILICA FEMALE REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR
PRODUCT WITH SILICA MALE REPRODUCTION
DIMETHYL SILOXANE, REACTION INGESTION NOT CLASSIFIED FOR DEVELOPMENT
PRODUCT WITH SILICA
AMINE EPOXY CURING AGENT INGESTION TOXIC TO DEVELOPMENT
N-AMINOETHYLPIPERAZINE INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED FOR
MALE REPRODUCTION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
POLYMERIC DIAMIDE RAT NOAEL: PREMATING
1,000 MG/KG/DAY INTO LACTATION
POLYMERIC DIAMIDE RAT NOAEL: 29 DAYS
1,000 MG/KG/DAY
POLYMERIC DIAMIDE RAT NOAEL: PREMATING
1,000 MG/KG/DAY INTO LACTATION
FUSED SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
FUSED SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
FUSED SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
DIMETHYL SILOXANE, RAT NOAEL: 1 GENERATION
REACTION PRODUCT 509 MG/KG/DAY
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: 1 GENERATION
REACTION PRODUCT 497 MG/KG/DAY
WITH SILICA
DIMETHYL SILOXANE, RAT NOAEL: DURING
REACTION PRODUCT 1,350 MG/KG/DAY ORGANOGENESIS
WITH SILICA
AMINE EPOXY CURING AGENT RAT NOAEL: DURING
60 MG/KG/DAY ORGANOGENESIS
N-AMINOETHYLPIPERAZINE RAT NOAEL: PREMATING &
598 MG/KG/DAY DURING GESTATION
N-AMINOETHYLPIPERAZINE RAT NOAEL: 32 DAYS
409 MG/KG/DAY
N-AMINOETHYLPIPERAZINE RABBIT NOAEL: DURING
75 MG/KG/DAY GESTATION
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING
520 MG/KG/DAY GESTATION
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
POLYMERIC DIAMIDE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
POLYMERIC DIAMIDE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS OR
DEPRESSION DIZZINESS
BUTADIENE INHALATION RESPIRATORY SOME POSITIVE DATA
ACRYLONITRILE IRRITATION EXIST, BUT THE DATA
COPOLYMER ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6- INHALATION RESPIRATORY SOME POSITIVE DATA
DIMETHYLAMINOMONO- IRRITATION EXIST, BUT THE DATA
METHYL)PHENOL ARE NOT SUFFICIENT
FOR CLASSIFICATION
BIS(3-AMINOPROPYL) INHALATION RESPIRATORY SOME POSITIVE DATA
ETHER OF DIETHYLENE IRRITATION EXIST, BUT THE DATA
GLYCOL ARE NOT SUFFICIENT
FOR CLASSIFICATION
AMINE EPOXY CURING INHALATION RESPIRATORY SOME POSITIVE DATA
AGENT IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NITRIC ACID, INHALATION RESPIRATORY SOME POSITIVE DATA
AMMONIUM CALCIUM IRRITATION EXIST, BUT THE DATA
SALT ARE NOT SUFFICIENT
FOR CLASSIFICATION
NITRIC ACID, INGESTION METHEMOGLOBINEMIA CAUSES DAMAGE
AMMONIUM CALCIUM TO ORGANS
SALT
N-AMINOETHYL- INHALATION RESPIRATORY SOME POSITIVE DATA
PIPERAZINE IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS
DEPRESSION OR DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DROWSINESS
DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
POLYMERIC DIAMIDE SIMILAR IRRITATION
HEALTH POSITIVE
HAZARDS
POLYMERIC DIAMIDE RAT NOAEL:
NOT AVAILABLE
BUTADIENE ACRYLONITRILE SIMILAR NOAEL:
COPOLYMER HEALTH NOT AVAILABLE
HAZARDS
TRIS(2,4,6- NOAEL:
DIMETHYLAMINOMONOMETHYL) NOT AVAILABLE
PHENOL
BIS(3-AMINOPROPYL) ETHER NOAEL:
OF DIETHYLENE GLYCOL NOT AVAILABLE
AMINE EPOXY CURING AGENT SIMILAR NOAEL:
HEALTH NOT AVAILABLE
HAZARDS
NITRIC ACID, AMMONIUM SIMILAR NOAEL:
CALCIUM SALT HEALTH NOT AVAILABLE
HAZARDS
NITRIC ACID, AMMONIUM SIMILAR NOAEL:
CALCIUM SALT COMPOUNDS NOT AVAILABLE
N-AMINOETHYLPIPERAZINE NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
POLYMERIC DIAMIDE INGESTION HEART NOT CLASSIFIED
SKIN
ENDOCRINE SYSTEM
GASTROINTESTINAL
TRACT
BONE, TEETH,
NAILS,
AND/OR HAIR
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
EYES
KIDNEY AND/OR
BLADDER
RESPIRATORY
SYSTEM
VASCULAR SYSTEM
FUSED SILICA INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
SILICOSIS
TRIS(2,4,6- DERMAL SKIN NOT CLASSIFIED
DIMETHYLAMINOMONO- LIVER
METHYL)PHENOL NERVOUS SYSTEM
AUDITORY SYSTEM
HEMATOPOIETIC
SYSTEM
EYES
DIMETHYL SILOXANE, INHALATION RESPIRATORY NOT CLASSIFIED
REACTION PRODUCT SYSTEM
WITH SILICA SILICOSIS
AMINE EPOXY CURING INGESTION KIDNEY AND/OR NOT CLASSIFIED
AGENT BLADDER
AMINE EPOXY CURING INGESTION HEART NOT CLASSIFIED
AGENT LIVER
BLOOD
NERVOUS SYSTEM
EYES
N-AMINOETHYLPIPERAZINE DERMAL SKIN NOT CLASSIFIED
N-AMINOETHYLPIPERAZINE DERMAL HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
N-AMINOETHYLPIPERAZINE INHALATION RESPIRATORY CAUSES DAMAGE
SYSTEM TO ORGANS
THROUGH
PROLONGED OR
REPEATED
EXPOSURE
N-AMINOETHYLPIPERAZINE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
EYES
KIDNEY AND/OR
BLADDER
N-AMINOETHYLPIPERAZINE INGESTION HEART NOT CLASSIFIED
ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
EYES ORGANS THROUGH
OLFACTORY SYSTEM PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION NERVOUS SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION RESPIRATORY SOME POSITIVE
SYSTEM DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR
HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
VASCULAR SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE
DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
NAME SPECIES TEST RESULT EXPOSURE DURATION
POLYMERIC DIAMIDE RAT NOAEL: 29 DAYS
1,000 MG/KG/DAY
FUSED SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TRIS(2,4,6- RAT NOAEL: 28 DAYS
DIMETHYLAMINOMONOMETHYL) 125 MG/KG/DAY
PHENOL
DIMETHYL SILOXANE, HUMAN NOAEL: OCCUPATIONAL
REACTION PRODUCT WITH NOT AVAILABLE EXPOSURE
SILICA
AMINE EPOXY CURING AGENT RAT NOAEL: 90 DAYS
60 MG/KG/DAY
AMINE EPOXY CURING AGENT RAT NOAEL: 90 DAYS
180 MG/KG/DAY
N-AMINOETHYLPIPERAZINE RAT NOAEL: 29 DAYS
100 MG/KG/DAY
N-AMINOETHYLPIPERAZINE RAT NOAEL: 29 DAYS
1,000 MG/KG/DAY
N-AMINOETHYLPIPERAZINE RAT NOAEL: 13 WEEKS
0.2 MG/M3
N-AMINOETHYLPIPERAZINE RAT NOAEL: 13 WEEKS
53.8 MG/M3
N-AMINOETHYLPIPERAZINE RAT NOAEL: 28 DAYS
598 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE MULTIPLE NOAEL: 11.3 MG/L 15 WEEKS
ANIMAL
SPECIES
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 30-8517-2
VERSION NUMBER: 1.14
ISSUE DATE: 09/08/21
SUPERCEDES DATE: 01/18/21
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