| Common Name: | TOUCH 'N FOAM FIRE BREAK SEALANT |
| Manufacturer: | CONVENIENCE PRODUCTS |
| SDS Revision Date: | 3/17/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 2KVH8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACC. TO OSHA HCS (29 CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: 03/17/2016
REVISION: 03/17/2016
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: TOUCH 'N FOAM FIRE BREAK SEALANT
PRODUCT CODE: EHS 9701
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: SEALANT
RESTRICTIONS ON USE: SEE SECTIONS 8 AND 10 FOR FURTHER INFORMATION.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, FOAM PRODUCTS DIVISION
866 HORAN DRIVE
FENTON, MO 63026-2614
PHONE: 636-349-5855
TOLL-FREE: 1-800-325-6180
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.:
+1 (800)255-3924
+1 (813)248-0585
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING:
ISOCYANIC ACID, POLYMETHYLENEPOLYPHENYLENE ESTER, POLYMER WITH
1,2-ETHANEDIAMINE, METHYLOXIRANE AND 1,2-PROPANEDIOL
4,4'-METHYLENEDIPHENYL DIISOCYANATE
DIPHENYLMETHANEDIISOCYANATE, ISOMERES AND HOMOLOGUES
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P284: [IN CASE OF INADEQUATE VENTILATION] WEAR RESPIRATORY PROTECTION.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P405: STORE LOCKED UP.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG.
C/122 DEG. F.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
0% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN TOXICITY.
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
67815-87-6 ISOCYANIC ACID, POLYMETHYLENEPOLYPHENYLENE 40-60%
ESTER, POLYMER WITH 1,2-ETHANEDIAMINE,
METHYLOXIRANE AND 1,2-PROPANEDIOL
RESP. SENS. 1, H334
SKIN IRRIT. 2, H315; EYE IRRIT. 2A, H319;
SKIN SENS. 1, H317
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE </=10%
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2, H315;
EYE IRRIT. 2, H319; SKIN SENS. 1, H317;
STOT SE 3, H335
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERES AND </=10%
HOMOLOGUES
RESP. SENS. 1, H334; STOT RE 2, H373
ACUTE TOX. 4, H332; SKIN IRRIT. 2, H315;
EYE IRRIT. 2, H319; SKIN SENS. 1, H317;
STOT SE 3, H335
115-10-6 DIMETHYL ETHER 5-<10%
FLAM. GAS 1, H220
PRESS. GAS, H280
75-28-5 ISOBUTANE 2.5-5%
FLAM. GAS 1, H220
PRESS. GAS, H280
74-98-6 PROPANE 2.5-5%
FLAM. GAS 1, H220
PRESS. GAS, H280
ADDITIONAL INFORMATION:
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S) ARE
BEING WITHHELD AS A TRADE SECRET.
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
DO NOT PULL SOLIDIFIED PRODUCT AWAY FROM THE SKIN.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN, IF POSSIBLE.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. THEN CONSULT A
DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
BREATHING DIFFICULTY
COUGHING
DIZZINESS
ALLERGIC REACTIONS
NAUSEA
NAUSEA IN CASE OF INGESTION.
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
IRRITANT TO EYES.
VOMITING.
DIARRHEA.
DISORIENTATION
DANGER:
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF CONVULSION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MAY BE HARMFUL IF INHALED.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK ARE
POSSIBLE.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
IN CASES OF IRRITATION TO THE LUNGS, INITIAL TREATMENT WITH CORTICAL
STEROID INHALANTS.
MONITOR CIRCULATION. LATER OBSERVATION FOR PNEUMONIA AND PULMONARY EDEMA.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY OR ALCOHOL RESISTANT FOAM.
WATER IN FLOODING QUANTITIES.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY.
COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
ISOLATE AREA AND PREVENT ACCESS.
KEEP PEOPLE AT A DISTANCE AND STAY UPWIND.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
FLAMMABLE AEROSOL.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 120 DEG.
F / 49 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
EMERGENCY COOLING MUST BE AVAILABLE IN CASE OF NEARBY FIRE.
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
PROVIDE VENTILATION FOR RECEPTACLES.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
DO NOT STORE TOGETHER WITH ACIDS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
CEILING LIMIT VALUE: 0.2 MG/M3, 0.02 PPM
REL (USA):
LONG-TERM VALUE: 0.05 MG/M3, 0.005 PPM
CEILING LIMIT VALUE: 0.2* MG/M3, 0.02* PPM
*10-MIN
TLV (USA):
LONG-TERM VALUE: 0.051 MG/M3, 0.005 PPM
EL (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.01 PPM
SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.02 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 0.005 PPM
115-10-6 DIMETHYL ETHER:
WEEL (USA):
LONG-TERM VALUE: 1000 PPM
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
75-28-5 ISOBUTANE:
TLV (USA):
SHORT-TERM VALUE: 2370 MG/M3, 1000 PPM
EV (CANADA):
LONG-TERM VALUE: 800 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 1000 PPM
74-98-6 PROPANE:
PEL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
TLV (USA): REFER TO APPENDIX F INTLVS AND BEIS BOOK
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
EV (CANADA):
LONG-TERM VALUE: 1000 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 1000 PPM
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
CLEAN SKIN THOROUGHLY IMMEDIATELY AFTER HANDLING THE PRODUCT.
ENGINEERING CONTROLS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
BREATHING EQUIPMENT:
COMBINED ORGANIC VAPOR AND PARTICULATE RESPIRATOR IS RECOMMENDED FOR USE
DURING ALL PROCESSING ACTIVITIES.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
AVOID RELEASE TO THE ENVIRONMENT.
RISK MANAGEMENT MEASURES SEE SECTION 7 FOR ADDITIONAL INFORMATION.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: AEROSOL
COLOR: RED
ODOR: WEAK, CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -25 DEG. C (-13 DEG. F) (PROPELLANT)
FLASH POINT: -104 DEG. C (-155 DEG. F) (PROPELLANT)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: 235 DEG. C (455 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C (68 DEG. F): 1.05 G/CM3 (8.762 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
VOC (CALIFORNIA): 163 G/L (EPA METHOD 24)
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
POSSIBILITY OF HAZARDOUS REACTIONS:
FLAMMABLE AEROSOL.
DEVELOPS READILY FLAMMABLE GASES / FUMES.
REACTS WITH OXIDIZING AGENTS.
REACTS WITH STRONG ACIDS AND ALKALI.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMIZED.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
CONDITIONS TO AVOID:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDIZING AGENTS.
INCOMPATIBLE MATERIALS: OXIDIZERS, STRONG BASES, STRONG ACIDS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
NITROGEN OXIDES (NOX)
HYDROGEN CYANIDE (PRUSSIC ACID)
PHOSPHORUS OXIDES (E.G. P2O5)
CHLORINE
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL LD50: 2200 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZATION POSSIBLE THROUGH INHALATION.
SENSITIZATION POSSIBLE THROUGH SKIN CONTACT.
SUBACUTE TO CHRONIC TOXICITY:
INHALATION OF CONCENTRATED VAPORS AS WELL AS ORAL INTAKE WILL LEAD TO
ANAESTHESIA-LIKE CONDITIONS AND HEADACHE, DIZZINESS, ETC.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
MAY BE HARMFUL IF INHALED.
REPEATED DOSE TOXICITY:
MAY CAUSE AN ALLERGIC SKIN REACTION.
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
AVOID TRANSFER INTO THE ENVIRONMENT.
THIS STATEMENT WAS DEDUCED FROM PRODUCTS WITH A SIMILAR STRUCTURE OR
COMPOSITION. DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE
OR SEWAGE SYSTEM, EVEN IN SMALL QUANTITIES.
DANGER TO DRINKING WATER IF EVEN EXTREMELY SMALL QUANTITIES LEAK INTO
THE GROUND.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM. CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE
AFTER SOLIDIFICATION FOLLOWING CONSULTATION WITH THE WASTE DISPOSAL
FACILITY OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO THE
NECESSARY TECHNICAL REGULATIONS. THE USER OF THIS MATERIAL HAS THE
RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN
COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS
REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS
WASTES. RESIDUAL MATERIALS SHOULD BE TREATED AS HAZARDOUS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1950
UN PROPER SHIPPING NAME:
DOT: AEROSOLS
ADR: 1950 AEROSOLS
IMDG: AEROSOLS
IATA: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
CLASS: 2 GASES
LABEL: 2.1
ADR: CLASS 2.1, FLAMMABLE GASES
CLASS: 2 5F GASES
LABEL: 2.1
IMDG: CLASS 2.1 - FLAMMABLE GASES
CLASS: 2 GASES
LABEL: 2.1
IATA: CLASS 2.1, FLAMMABLE GASES
CLASS: 2.1
LABEL: 2.1
PACKING GROUP:
THIS UN-NUMBER IS NOT ASSIGNED A PACKING GROUP. AEROSOLS ARE NOT ASSIGNED A
PACKING GROUP.
DOT, ADR, IMDG, IATA: NOT REGULATED.
ENVIRONMENTAL HAZARDS: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
DANGER CODE (KEMLER):
EMS NUMBER: F-D, S-U
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE D, CBD
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERES CBD AND HOMOLOGUES
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 3
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERES AND HOMOLOGUES 3
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADA:
CANADIAN SUBSTANCE LISTINGS:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DATE OF PREPARATION / LAST REVISION: 03/17/2016 / -
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS
BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
FLAM. GAS 1: FLAMMABLE GASES, HAZARD CATEGORY 1
FLAM. AEROSOL 1: FLAMMABLE AEROSOLS, HAZARD CATEGORY 1
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2A
RESP. SENS. 1: SENSITIZATION - RESPIRAT., HAZARD CATEGORY 1
SKIN SENS. 1: SENSITIZATION - SKIN, HAZARD CATEGORY 1
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES (OFMPUB.EPA.GOV/SOR
INTERNET/REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED. ISBN:
ISBN: 978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY:
THE BASIC SCIENCE OF POISONS, 8TH ED., KLAASEN, CURTIS D., ED., ISBN:
978-0-07-176923-5.
SAFETY DATA SHEETS, INDIVIDUAL MANUFACTURERS
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