| Common Name: | LOCTITE AA 324 UV GLASS BONDER KNOWN AS SPEEDBONDER 324 STRUCTURAL, 32430 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 9/6/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2LTC7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 09/06/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE AA 324 UV GLASS BONDER KNOWN AS SPEEDBONDER(TM) 324 STRUCTURAL
IDH NUMBER: 88478
PRODUCT TYPE: ACRYLIC ADHESIVE
ITEM NUMBER: 32430
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
COMBUSTIBLE LIQUID.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. AVOID
BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CONTROL CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
POLYURETHANE METHACRYLATE RESIN UNKNOWN 30 - 60
2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 30
HIGH BOILING METHACRYLATE PROPRIETARY 10 - 30
HYDROXYALKYL METHACRYLATE 27813-02-1 1 - 5
TERT-BUTYL PERBENZOATE 614-45-9 1 - 5
ACRYLIC ACID 79-10-7 1 - 5
SACCHARIN 81-07-2 1 - 5
ADHESION PROMOTER PROPRIETARY 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH
CLOTHING BEFORE REUSE. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE EXPECTED.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING ORGANIC VAPOURS.
ISOCYANATES. HYDROGEN CYANIDE. AMINES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G.
SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). STORE IN A
PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT TASTE OR SWALLOW. USE ONLY
WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARK AND FLAME.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100.4 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
POLYURETHANE NONE NONE NONE NONE
METHACRYLATE RESIN
2-HYDROXYETHYL NONE NONE NONE 3 PPM
METHACRYLATE CEILING
HIGH BOILING NONE NONE NONE NONE
METHACRYLATE
HYDROXYALKYL NONE NONE NONE 1 PPM TWA
METHACRYLATE 3 PPM STEL
TERT-BUTYL PERBENZOATE NONE NONE NONE NONE
ACRYLIC ACID 2 PPM TWA NONE NONE 1 PPM TWA
(SKIN) 3 PPM STEL
(SKIN)
SACCHARIN NONE NONE NONE NONE
ADHESION PROMOTER 20 PPM TWA NONE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT. NEOPRENE, BUTYL-RUBBER, OR NITRILE-RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: YELLOW
ODOR: SHARP, IRRITATING
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <10 MMHg (27 DEG. C (80.6 DEG. F))
BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F) (1,013 HPA)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.1 AT 26.6 DEG. C (79.88 DEG. F)
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 90 DEG. C (194 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 2% (ACRYLIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 8% (ACRYLIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 2.26%; 21.54 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING ORGANIC VAPOURS.
ISOCYANATES. HYDROGEN CYANIDE. AMINES.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. REDUCING AGENTS. ACIDS. BASES. ALKALIS. AMINES.
FREE RADICAL INITIATORS. PEROXIDES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
EXPOSURE TO SUNLIGHT. KEEP AWAY FROM HEAT, SPARK AND FLAME. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
POLYURETHANE NONE IRRITANT, ALLERGEN
METHACRYLATE RESIN
2-HYDROXYETHYL ORAL LD50 (RAT): IRRITANT, ALLERGEN
METHACRYLATE 11.2 G/KG
ORAL LD50 (RAT):
5,050 MG/KG
HIGH BOILING NONE IRRITANT, ALLERGEN
METHACRYLATE
HYDROXYALKYL NONE IRRITANT, ALLERGEN
METHACRYLATE
TERT-BUTYL PERBENZOATE NONE CENTRAL NERVOUS SYSTEM,
IRRITANT, MUTAGEN
ACRYLIC ACID ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
33.5 MG/KG IRRITANT, KIDNEY, LIVER
ORAL LD50 (RAT):
2.5 G/KG
ORAL LD50 (RAT):
193 MG/KG
ORAL LD50 (RAT):
1,250 MG/KG
INHALATION LC50
(RAT, 4 H):
1,200 MG/L
SACCHARIN NONE NO TARGET ORGANS
ADHESION PROMOTER ORAL LD50 (RABBIT): CORROSIVE, IRRITANT,
1,200 MG/KG ALLERGEN
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
POLYURETHANE NO NO NO
METHACRYLATE RESIN
2-HYDROXYETHYL NO NO NO
METHACRYLATE
HIGH BOILING NO NO NO
METHACRYLATE
HYDROXYALKYL NO NO NO
METHACRYLATE
TERT-BUTYL PERBENZOATE NO NO NO
ACRYLIC ACID NO NO NO
SACCHARIN NO NO NO
ADHESION PROMOTER NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). ACRYLIC ACID
(CAS# 79-10-7). SACCHARIN (CAS# 81-07-2).
CERCLA REPORTABLE QUANTITY:
TERT-BUTYL PERBENZOATE (CAS# 614-45-9): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 09/06/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.