| Common Name: | LOCTITE AA 326 TWO STEP ACRYLIC RAPID CURING KNOWN AS SPEEDBONDER 326 STR, 32629 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/6/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2LTC9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 008.1
ISSUE DATE: 08/06/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE AA 326 TWO STEP ACRYLIC RAPID CURING KNOWN AS SPEEDBONDER(TM) 326
STRUCTURAL
PRODUCT TYPE: ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 135402
ITEM NUMBER: 32629
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
CARCINOGENICITY 2
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING VAPORS, MIST,
OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TOLUENE DIISOCYANATE, 50 - 60
POLY(ALKYL ETHER DERIVATIVE),
HYDROXYPROPYL METHACRYLATE,
PROPANE DERIVATIVE RESIN
2-HYDROXYETHYL METHACRYLATE 868-77-9 20 - 30
HIGH BOILING METHACRYLATE PROPRIETARY 10 - 20
HYDROXYALKYL METHACRYLATE 27813-02-1 1 - 5
ACRYLIC ACID 79-10-7 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 0.1 - 1
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 0.1 - 1
METHACRYLIC ACID 79-41-4 0.1 - 1
ETHYLENE GLYCOL 107-21-1 0.1 - 1
CUMENE 98-82-8 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH
CLOTHING BEFORE REUSE. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. KEEP INDIVIDUAL CALM. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY CAUSE RAPID EVOLUTION OF HEAT AND INCREASE
IN PRESSURE THAT COULD RESULT IN VIOLENT RUPTURE OF SEALED STORAGE VESSELS
OR CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G.
SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). STORE IN A
PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER TO SECTION 8
"EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
DO NOT TASTE OR SWALLOW. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 32 DEG. C (89.6
DEG. F) KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND
OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
TOLUENE DIISOCYANATE, NONE NONE NONE NONE
POLY(ALKYL ETHER
DERIVATIVE),
HYDROXYPROPYL
METHACRYLATE,
PROPANE DERIVATIVE
RESIN
2-HYDROXYETHYL NONE NONE NONE 3 PPM CEILING
METHACRYLATE
HIGH BOILING NONE NONE NONE NONE
METHACRYLATE NONE NONE NONE NONE
HYDROXYALKYL NONE NONE NONE 1 PPM TWA
METHACRYLATE 3 PPM STEL
ACRYLIC ACID 2 PPM TWA NONE NONE 1 PPM TWA
(SKIN) 3 PPM STEL
(SKIN)
CUMENE HYDROPEROXIDE NONE NONE 1 PPM NONE
(6 MG/M3)
TWA (SKIN)
1-ACETYL-2- NONE NONE NONE NONE
PHENYLHYDRAZINE
METHACRYLIC ACID 20 PPM TWA NONE NONE NONE
ETHYLENE GLYCOL 25 PPM TWA NONE NONE NONE
VAPOR
FRACTION
50 PPM
STEL VAPOR
FRACTION
10 MG/M3
STEL
AEROSOL,
INHALABLE.
CUMENE 50 PPM TWA 50 PPM NONE NONE
(245 MG/M3)
PEL
(SKIN)
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION BELOW OCCUPATIONAL EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT. NEOPRENE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: AMBER
ODOR: SHARP, IRRITATING
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <10 MM Hg (27 DEG. C (80.6 DEG. F))
BOILING POINT/RANGE: >149 DEG. C (>300.2 F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.1 AT 26.6 DEG. C (79.88 DEG. F)
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93.3 DEG. C (>199.94 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 2% (ACRYLIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 8% (ACRYLIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 3.11%; 35.5 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. REDUCING AGENTS. ACIDS. BASES. COPPER. ALKALIS.
ALDEHYDES. AMINES. FREE RADICAL INITIATORS. PEROXIDES. HEAVY METALS. OTHER
POLYMERIZATION INITIATORS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. STORE AWAY FROM
INCOMPATIBLE MATERIALS. EXPOSURE TO SUNLIGHT. AVOID MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE IRRITATION TO NOSE AND THROAT. MAY BE HARMFUL IF INHALED.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF
SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
TOLUENE DIISOCYANATE, NONE IRRITANT, ALLERGEN
POLY(ALKYL ETHER
DERIVATIVE),
HYDROXYPROPYL
METHACRYLATE,
PROPANE DERIVATIVE
RESIN
2-HYDROXYETHYL ORAL LD50 IRRITANT, ALLERGEN
METHACRYLATE (MOUSE):
3,275 MG/KG
ORAL LD50 (RAT):
11.2 G/KG
ORAL LD50 (RAT):
5,050 MG/KG
HIGH BOILING NONE IRRITANT, ALLERGEN
METHACRYLATE
HYDROXYALKYL NONE IRRITANT, ALLERGEN
METHACRYLATE
ACRYLIC ACID ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
33.5 MG/KG IRRITANT, KIDNEY, LIVER
ORAL LD50 (MOUSE):
2,400 MG/KG
ORAL LD50 (RAT):
2.5 G/KG
ORAL LD50 (RAT):
193 MG/KG
ORAL LD50 (RAT):
1,250 MG/KG
CUMENE HYDROPEROXIDE NONE ALLERGEN, CENTRAL NERVOUS
SYSTEM, CORROSIVE, IRRITANT,
MUTAGEN
1-ACETYL-2- ORAL LD50 (MOUSE): ALLERGEN, BLOOD, KIDNEY,
PHENYLHYDRAZINE 270 MG/KG MUTAGEN, SOME EVIDENCE OF
CARCINOGENICITY
METHACRYLIC ACID ORAL LD50 (MOUSE): CORROSIVE, IRRITANT, ALLERGEN
1,332 MG/KG
ORAL LD50 (MOUSE):
1,600 MG/KG
ORAL LD50 (MOUSE):
1,250 MG/KG
ORAL LD50
(RABBIT):
1,200 MG/KG
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50
(RABBIT):
500 MG/KG
ETHYLENE GLYCOL ORAL LD50 (RAT): BLOOD, BONE MARROW,
5.89 G/KG CENTRAL NERVOUS
ORAL LD50 SYSTEM, DEVELOPMENTAL,
(MOUSE): EYES, IRRITANT,
14.6 G/KG KIDNEY, LIVER, METABOLIC
DERMAL LD50
(RABBIT):
9,530 MG/KG
CUMENE ORAL LD50 (RAT): CENTRAL NERVOUS SYSTEM,
2.91 G/KG IRRITANT, LUNG
ORAL LD50 (RAT):
1,400 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TOLUENE DIISOCYANATE, NO NO NO
POLY(ALKYL ETHER
DERIVATIVE),
HYDROXYPROPYL
METHACRYLATE,
PROPANE DERIVATIVE
RESIN
2-HYDROXYETHYL NO NO NO
METHACRYLATE
HIGH BOILING NO NO NO
METHACRYLATE
HYDROXYALKYL NO NO NO
METHACRYLATE
ACRYLIC ACID NO NO NO
CUMENE HYDROPEROXIDE NO NO NO
1-ACETYL-2- NO NO NO
PHENYLHYDRAZINE
METHACRYLIC ACID NO NO NO
ETHYLENE GLYCOL NO NO NO
CUMENE REASONABLY GROUP 2B NO
ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE(S): ALPHA,ALPHA-DIMETHYLBENZYLHYDROPEROXIDE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS:
NONE ABOVE REPORTING DE MINIMIS.
PROPYLENE OXIDE (CAS# 75-56-9). ETHYLENE DIAMINE (CAS# 107-15-3).
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). ACRYLIC ACID (CAS#
79-10-7).
CERCLA REPORTABLE QUANTITY:
CUMENE HYDROPEROXIDE (CAS# 80-15-9) 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 08/06/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.