| Common Name: | LOCTITE AA 330 A KNOWN AS LOCTITE 330 DEPEND 3ML KT PT A, 1691394_1664682, LOCTI |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/4/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2LTE1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.0
ISSUE DATE: 04/04/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE AA 330 A KNOWN AS LOCTITE 330 DEPEND 3ML KT PT A
PRODUCT TYPE: ACRYLIC ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1691309
ITEM NUMBER: 1691394_1664682
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
COMBUSTIBLE LIQUID.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
CARCINOGENICITY 2
REPRODUCTIVE TOXICITY 1B
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES, HOT SURFACES - NO SMOKING. AVOID BREATHING VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TETRAHYDROFURFURYL METHACRYLATE 2455-24-5 40 - 50
METHACRYLIC ACID 79-41-4 5 - 10
ALKYL METHACRYLATE PROPRIETARY 5 - 10
METHACRYLATE MONOMER PROPRIETARY 1 - 5
EPOXY RESIN PROPRIETARY 0.1 - 1
TALC 14807-96-6 0.1 - 1
CUMENE HYDROPEROXIDE 80-15-9 0.1 - 1
1,1,2-TRICHLOROETHANE 79-00-5 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS. IN CASE OF FIRE, KEEP
CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
DO NOT TASTE OR SWALLOW. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100.4 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
TETRAHYDROFURFURYL METHACRYLATE NONE NONE
METHACRYLIC ACID 20 PPM TWA NONE
ALKYL METHACRYLATE NONE NONE
METHACRYLATE MONOMER NONE NONE
EPOXY RESIN NONE NONE
TALC 2 MG/M3 TWA 0.1 MG/M3 TWA
RESPIRABLE FRACTION. RESPIRABLE.
2.4 MPPCF TWA
RESPIRABLE.
20 MPPCF TWA
CUMENE HYDROPEROXIDE NONE NONE
1,1,2-TRICHLOROETHANE 10 PPM TWA 10 PPM
(SKIN) (45 MG/M3) PEL
(SKIN)
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
TETRAHYDROFURFURYL METHACRYLATE NONE NONE
METHACRYLIC ACID NONE NONE
ALKYL METHACRYLATE NONE NONE
METHACRYLATE MONOMER NONE NONE
EPOXY RESIN NONE NONE
TALC NONE 50 PPM
CUMENE HYDROPEROXIDE 1 PPM NONE
(6 MG/M3) TWA
(SKIN)
1,1,2-TRICHLOROETHANE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE, BUTYL-RUBBER, OR
NITRILE-RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: AMBER
ODOR: SHARP, IRRITATING
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: <10 MMHg (26.7 DEG. C (80.1 DEG. F))
BOILING POINT/RANGE: >148.9 DEG. C (>300 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.16
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 83 DEG. C (181.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 1.59%; 18.4 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. TOXIC CHLORIDES. IRRITATING ORGANIC
VAPOURS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. STRONG ACIDS. ALKALIS.
FREE RADICAL INITIATORS. OXYGEN SCAVENGERS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. EXTREMES
OF TEMPERATURE AND DIRECT SUNLIGHT. UV LIGHT. FREEZING CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM. MAY CAUSE IRRITATION TO NOSE AND THROAT.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
TETRAHYDROFURFURYL NONE IRRITANT, ALLERGEN
METHACRYLATE
METHACRYLIC ACID ORAL LD50 (MOUSE): CORROSIVE, IRRITANT,
1,332 MG/KG ALLERGEN
ORAL LD50 (MOUSE):
1,600 MG/KG
ORAL LD50 (MOUSE):
1,250 MG/KG
ORAL LD50 (RABBIT):
1,200 MG/KG
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
ALKYL METHACRYLATE ORAL LD50 (RAT): IRRITANT, ALLERGEN
>2,000 MG/KG
METHACRYLATE MONOMER NONE IRRITANT, ALLERGEN
EPOXY RESIN NONE ALLERGEN, IRRITANT
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
CUMENE HYDROPEROXIDE INHALATION LC50 ALLERGEN, CENTRAL
(MOUSE, 4 H): 200 MG/L NERVOUS SYSTEM,
CORROSIVE, IRRITANT,
MUTAGEN
1,1,2-TRICHLOROETHANE ORAL LD50 (RAT): IRRITANT, CENTRAL
835 MG/KG NERVOUS SYSTEM, LUNG,
LIVER, KIDNEY, IMMUNE
ORAL LD50 (RAT): SYSTEM, SOME EVIDENCE OF
100 - 200 MG/KG CARCINOGENICITY, MUTAGEN
DERMAL LD50 (RABBIT):
5,377 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TETRAHYDROFURFURYL NO NO NO
METHACRYLATE
METHACRYLIC ACID NO NO NO
ALKYL METHACRYLATE NO NO NO
METHACRYLATE MONOMER NO NO NO
EPOXY RESIN NO NO NO
TALC NO GROUP 2B NO
CUMENE HYDROPEROXIDE NO NO NO
1,1,2-TRICHLOROETHANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: FIRE, IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
CUMENE HYDROPEROXIDE (CAS# 80-15-9) 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/04/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 007.1
ISSUE DATE: 08/07/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME:
LOCTITE AA 330 B / SF 7387 KNOWN AS LOCTITE 330 DEPEND 3ML KT PT B
PRODUCT TYPE: ACTIVATOR
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1691310
ITEM NUMBER: 1691394_313947
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
HARMFUL IF SWALLOWED.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
ACUTE TOXICITY ORAL 4
SKIN IRRITATION 2
EYE IRRITATION 2A
REPRODUCTIVE TOXICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
ASPIRATION HAZARD 1
PICTOGRAM(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. NO
RELEASE INTO WATER. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING TOOLS.
TAKE ACTION TO PREVENT STATIC DISCHARGES. AVOID BREATHING VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
HYDROCARBONS, C7, N-ALKANES, ISOALKANES, 64742-49-0 30 - 60
CYCLICS
ALDEHYDE-AMINE CONDENSATE PROPRIETARY 10 - 30
2-PROPANOL 67-63-0 10 - 30
CYCLOHEXANE 110-82-7 1 - 5
N-HEXANE 110-54-3 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR.
WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. KEEP
INDIVIDUAL CALM. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROCARBONS. CYANIDES. TOXIC AND
IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. REMOVE ALL SOURCES OF
IGNITION.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. SOAK UP WITH INERT ABSORBENT MATERIAL
(E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). STORE IN
A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT TASTE OR SWALLOW.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE; EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS AND APPLIANCES, AND ANY
OTHER SOURCES OF IGNITION.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN -20 DEG. C (-4 DEG. F) AND 50 DEG. C
(122 DEG. F)
STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF IGNITION.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
HYDROCARBONS, C7, N-ALKANES, NONE 100 PPM
ISOALKANES, CYCLICS (400 MG/M3) PEL
ALDEHYDE-AMINE CONDENSATE NONE NONE
2-PROPANOL 200 PPM TWA 400 PPM
400 PPM STEL (980 MG/M3) PEL
CYCLOHEXANE 100 PPM TWA 300 PPM
(1,050 MG/M3) PEL
N-HEXANE 50 PPM TWA 500 PPM
(SKIN) (1,800 MG/M3) PEL
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
HYDROCARBONS, C7, N-ALKANES, NONE NONE
ISOALKANES, CYCLICS
ALDEHYDE-AMINE CONDENSATE NONE NONE
2-PROPANOL NONE NONE
CYCLOHEXANE NONE NONE
N-HEXANE NONE NONE
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
CHEMICAL RESISTANT, IMPERMEABLE GLOVES. USE IMPERMEABLE GLOVES AND
PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: AMBER
ODOR: ALIPHATIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: 35 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: 176 DEG. F (80 DEG. C) APPROXIMATELY
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.78
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: -4 DEG. C (24.8 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT MISCIBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 83.84%; 645.1 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. TOXIC FUMES.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. ACIDS. BASES. ALDEHYDES. ALKALIS. AMINES. CHLORINE.
HALOGENS. ISOCYANATES. ETHYLENE OXIDE.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, SPARK AND FLAME. STORE AWAY FROM INCOMPATIBLE
MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: HARMFUL IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND
DELAYED HEALTH
EFFECTS
HYDROCARBONS, C7, N-ALKANES, NONE NO DATA
ISOALKANES, CYCLICS
ALDEHYDE-AMINE CONDENSATE NONE NO RECORDS
2-PROPANOL ORAL LD50 (RAT): ALLERGEN, CENTRAL
5,045 MG/KG NERVOUS SYSTEM,
IRRITANT
ORAL LD50 (MOUSE):
3,600 MG/KG
ORAL LD50 (RABBIT):
6,410 MG/KG
ORAL LD50 (RAT):
4.7 G/KG
ORAL LD50 (MOUSE):
4.5 G/KG
ORAL LD50 (RABBIT):
8.0 G/KG
ORAL LD50 (RABBIT):
5.03 G/KG
DERMAL LD50 (RABBIT):
12,800 MG/KG
CYCLOHEXANE ORAL LD50 (RAT): IRRITANT, CENTRAL
29,820 MG/KG NERVOUS SYSTEM
ORAL LD50 (MOUSE):
1,300 MG/KG
N-HEXANE ORAL LD50 (RAT): DEVELOPMENTAL,
28,710 MG/KG IRRITANT, LUNG,
NERVOUS SYSTEM,
DERMAL LD50 (RABBIT): REPRODUCTIVE
>2,000 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
HYDROCARBONS, C7, NO NO NO
N-ALKANES, ISOALKANES,
CYCLICS
ALDEHYDE-AMINE NO NO NO
CONDENSATE
2-PROPANOL NO NO NO
CYCLOHEXANE NO NO NO
N-HEXANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
FLAMMABLE LIQUIDS, N.O.S. (HYDROCARBONS, C7, N-ALKANES, ISOALKANES,
CYCLICS, ISOPROPANOL)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
FLAMMABLE LIQUID, N.O.S. (HYDROCARBONS, C7, N-ALKANES, ISOALKANES, CYCLICS,
ISOPROPANOL)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
EXCEPTIONS:
ID8000, (NOT MORE THAN 500 ML), MAY QUALIFY AS CONSUMER COMMODITY
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
FLAMMABLE LIQUID, N.O.S. (HYDROCARBONS, C7, N-ALKANES, ISOALKANES, CYCLICS,
ISOPROPANOL, CYCLOHEXANE)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
MARINE POLLUTANT: CYCLOHEXANE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, FIRE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
CYCLOHEXANE (CAS# 110-82-7).
CERCLA REPORTABLE QUANTITY:
2-PROPANOL (CAS# 67-63-0)
CYCLOHEXANE (CAS# 110-82-7) 1,000 LBS. (454 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 08/07/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.