| Common Name: | ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT, A-A-2787 TYPE 1 SILVER 17178 |
| Manufacturer: | LHB INDUSTRIES |
| SDS Revision Date: | 8/23/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2RRD5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LIGHTHOUSE FOR THE BLIND ST. LOUIS, MO.
SAFETY DATA SHEET
ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
SDS REVISION DATE: 08/23/2018
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
ALTERNATE NAMES:
SPECIFICATION: A-A-2787 TYPE 1 SILVER 17178
LHB PART NUMBER: 01D4---160
NATIONAL STOCK NUMBER: 8010-01-481-1135
CAGE CODE: 0FTT5
CONTRACT NUMBER: SPE8EG-16-D-0015
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE PRODUCT LABEL.
APPLICATION METHOD: SEE PRODUCT LABEL.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
LHB INDUSTRIES
8833 FLEISCHER PLACE
BERKELEY, MO 63134
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.: (800) 633-8253 (PERS)
CUSTOMER SERVICE:
LHB INDUSTRIES: (314) 423-4333
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1;H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS;H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SKIN IRRIT. 3;H316: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
EYE IRRIT. 2;H319: CAUSES SERIOUS EYE IRRITATION.
REPR. 2;H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
STOT SE 3;H336:
MAY CAUSE DROWSINESS OR DIZZINESS.
STOT RE 1;H372:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
SPECIFIC TARGET ORGANS: (CENTRAL NERVOUS SYSTEM)
AQUATIC CHRONIC 3;H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
SIMPLE ASPHYXIANT: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
2.2. LABEL ELEMENTS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
DANGER
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H316: CAUSES MILD SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRESSURIZED CONTAINER: MAY BURST IF HEATED.
[PREVENTION]:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P261: AVOID BREATHING DUST / FUME / GAS / MIST / VAPORS / SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P301+310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR / PHYSICIAN.
P304+312:
IF INHALED: CALL A POISON CENTER OR DOCTOR / PHYSICIAN IF YOU FEEL UNWELL.
P305+351+338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES
IF PRESENT AND EASY TO DO - CONTINUE RINSING.
P308+313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE / ATTENTION.
P314: GET MEDICAL ADVICE / ATTENTION IF YOU FEEL UNWELL.
P331: DO NOT INDUCE VOMITING.
P332+313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE / ATTENTION.
P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
[STORAGE]:
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P410+412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C /
122 DEG. F.
[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD
WITHIN THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
ACETONE 25 - 50 FLAM. LIQ. 2;H225 [1][2]
CAS NUMBER: 0000067-64-1 EYE IRRIT. 2;H319
STOT SE 3;H336
PROPANE 10 - 25 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000074-98-6 PRESS. GAS;H280
SOLVENT NAPHTHA (PETROLEUM), 10 - 25 ASP. TOX. 1;H304 [1]
LIGHT ALIPHATIC
CAS NUMBER: 0064742-89-8
BUTANE 5 - 10 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000106-97-8 PRESS. GAS;H280
SIMPLE ASPHYXIANT
TOLUENE 5 - 10 FLAM. LIQ. 2;H225 [1][2]
CAS NUMBER: 0000108-88-3 REPR. 2;H361D
ASP. TOX. 1; H304
STOT RE 2;H373
SKIN IRRIT. 2;H315
STOT SE 3;H336
ISOBUTANE 5 - 10 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000075-28-5 PRESS. GAS;H280
STODDARD SOLVENT 1 - 5 STOT RE 1;H372 [1][2]
CAS NUMBER: 0008052-41-3 ASP. TOX. 1;H304
IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200, THE SPECIFIC
CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION
HAS BEEN WITHHELD AS A TRADE SECRET.
[1] SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2] SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3] PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
MOVE VICTIM TO FRESH AIR.
CALL 911 OR EMERGENCY MEDICAL SERVICE IF DEEMED NECESSARY.
GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.
ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES.
IN CASE OF CONTACT WITH LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM
WATER.
KEEP VICTIM WARM AND QUIET.
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
INHALATION:
REMOVE TO FRESH AIR, KEEP PATIENT WARM AND AT REST. IF BREATHING IS
IRREGULAR OR STOPPED, GIVE ARTIFICIAL RESPIRATION. IF UNCONSCIOUS PLACE
IN THE RECOVERY POSITION AND OBTAIN IMMEDIATE MEDICAL ATTENTION. GIVE
NOTHING BY MOUTH.
EYES:
IRRIGATE COPIOUSLY WITH CLEAN WATER FOR AT LEAST 15 MINUTES, HOLDING THE
EYELIDS APART AND SEEK MEDICAL ATTENTION.
SKIN:
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES. CLOTHING FROZEN TO THE
SKIN SHOULD BE THAWED BEFORE BEING REMOVED. IN CASE OF CONTACT WITH
LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM WATER.
INGESTION:
IF SWALLOWED OBTAIN IMMEDIATE MEDICAL ATTENTION. KEEP AT REST. DO NOT
INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
EYES: CAUSES SERIOUS EYE IRRITATION.
SKIN: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
INGESTION: MAY BE HARMFUL IF SWALLOWED. (NOT ADOPTED BY US OSHA)
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
FIRE INVOLVING TANKS:
SOME OF THESE MATERIALS, IF SPILLED, MAY EVAPORATE LEAVING A FLAMMABLE
RESIDUE.
SOME OF THESE MATERIALS, IF SPILLED, MAY EVAPORATE LEAVING A FLAMMABLE
RESIDUE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION: HIGH TEMPERATURES AND FIRES MAY PRODUCE SUCH
TOXIC SUBSTANCES AS CARBON MONOXIDE AND CARBON DIOXIDE.
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
DO NOT BREATHE MIST / VAPORS / SPRAY.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
5.3. ADVICE FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
WEAR CHEMICAL PROTECTIVE CLOTHING THAT IS SPECIFICALLY RECOMMENDED BY THE
MANUFACTURER. IT MAY PROVIDE LITTLE OR NO THERMAL PROTECTION.
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
SOME MAY BURN BUT NONE IGNITE READILY.
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
VAPORS MAY CAUSE DIZZINESS OR ASPHYXIATION WITHOUT WARNING.
VAPORS FROM LIQUEFIED GAS ARE INITIALLY HEAVIER THAN AIR AND SPREAD ALONG
GROUND.
CONTACT WITH GAS OR LIQUEFIED GAS MAY CAUSE BURNS, SEVERE INJURY AND/OR
FROSTBITE.
FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC GASES.
ERG GUIDE NO.: 126
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. AVOID
ALLOWING WATER RUNOFF TO CONTACT SPILLED MATERIAL.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
ALLOW SUBSTANCE TO EVAPORATE.
VENTILATE THE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
STAY UPWIND.
MANY GASES ARE HEAVIER THAN AIR AND WILL SPREAD ALONG GROUND AND COLLECT
IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
KEEP OUT OF LOW AREAS.
VENTILATE CLOSED SPACES BEFORE ENTERING.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS
CODE. 29 CFR 1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF
FLAMMABLE AND COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE THIS PRODUCT BELOW 120 DEG. F, IN A COOL, DRY, WELL VENTILATED AREA
AWAY FROM HEAT, SPARKS, FLAME, OXIDIZERS AND OUT OF DIRECT SUNLIGHT.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS AND ACIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 ACETONE OSHA TWA: 1000 PPM (2400 MG/M3)
STEL: 2400 MG/M3
ACGIH TWA: 250 PPM
STEL: 500 PPM SKIN
NIOSH 250 PPM (590 MG/M3) TWA
SUPPLIER NO ESTABLISHED LIMIT
0000074-98-6 PROPANE OSHA TWA: 1000 PPM (1800 MG/M3)
ACGIH ENSURE MINIMAL OXYGEN CONTENT
(ACGIH APPENDIX F)
NIOSH TWA: 1000 PPM (1800 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000075-28-5 PROPANE, OSHA NO ESTABLISHED LIMIT
2-METHYL-
ACGIH STEL: 1000PPM
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000106-97-8 BUTANE OSHA NO ESTABLISHED LIMIT
ACGIH TWA: 600 PPM
STEL: 750 PPM
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000108-88-3 TOLUENE OSHA TWA: 200 PPM C 300 PPM 500 PPM
(10-MINUTE MAXIMUM PEAK)
STEL: 150 PPM
ACGIH TWA: 20 PPMR
NIOSH TWA: 100 PPM (375 MG/M3)
ST: 150 PPM (560 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0008052-41-3 STODDARD OSHA TWA: 500 PPM (2900 MG/M3)
SOLVENT
ACGIH TWA: 290 MG/M3
STEL: 580 MG/M3
NIOSH TWA: 350 MG/M3 C
1800 MG/M3 [15-MINUTE]
SUPPLIER NO ESTABLISHED LIMIT
0064742-89-8 SOLVENT OSHA NO ESTABLISHED LIMIT
NAPHTHA ACGIH NO ESTABLISHED LIMIT
(PETROLEUM), NIOSH NO ESTABLISHED LIMIT
LIGHT SUPPLIER NO ESTABLISHED LIMIT
ALIPHATIC
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST
USE THE APPROPRIATE, CERTIFIED RESPIRATORS.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD BE
ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: SILVER LIQUID/GAS
ODOR: SOLVENT
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE: NOT MEASURED
FLASH POINT: PROPELLANT <0 F
EVAPORATION RATE (ETHER = 1): SLOWER THAN ETHER
FLAMMABILITY (SOLID, GAS):
FLAM. AEROSOL 1;H222 EXTREMELY FLAMMABLE AEROSOL.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 0.9
UPPER EXPLOSIVE LIMIT: 9.5
VAPOR PRESSURE (PA): NOT MEASURED
VAPOR DENSITY: HEAVIER THAN AIR
SPECIFIC GRAVITY: 0.727 (6.06 LB/GAL)
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %: 53.5% BY WT., 4.67 LB/GAL (LESS WATER AND EXEMPT SOLVENTS)
MAXIMUM INCREMENTAL REACTIVITY: .083
HAPS (LBS/GAL): NOT DETERMINED
HAPS (LBS/GAL OF SOLIDS): NOT DETERMINED
HAPS (LBS/LB OF SOLIDS): NOT DETERMINED
% VOLATILE (BY VOLUME): 86.5% (BY VOLUME)
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID:
AVOID CONTACT WITH OPEN FLAME, SPARKS OR HOT SURFACES.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS AND ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HIGH TEMPERATURES AND FIRES MAY PRODUCE SUCH TOXIC SUBSTANCES AS CARBON
MONOXIDE AND CARBON DIOXIDE.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE.
2-BUTOXYETHANOL AND ITS ACETATE ARE READILY ABSORBED THROUGH THE SKIN AND
WILL CAUSE HARMFUL EFFECTS ON THE BLOOD.
INGREDIENT ORAL LD50, SKIN LD50,
MG/KG MG/KG
ACETONE - (67-64-1) 2,000.00, 2,000.00,
RAT - CATEGORY: 4 RABBIT - CATEGORY: 4
PROPANE - (74-98-6) NO DATA AVAILABLE NO DATA AVAILABLE
SOLVENT NAPHTHA (PETROLEUM), 5,000.00, 3,000.00,
LIGHT ALIPHATIC - (64742-89-8) MOUSE - CATEGORY: 5 RABBIT - CATEGORY: 5
BUTANE - (106-97-8) NO DATA AVAILABLE NO DATA AVAILABLE
TOLUENE - (108-88-3) 636.00, 8,400.00,
RAT - CATEGORY: 4 RABBIT - CATEGORY: NA
PROPANE, 2-METHYL- - (75-28-5) NO DATA AVAILABLE NO DATA AVAILABLE
STODDARD SOLVENT - (8052-41 -3) NO DATA AVAILABLE NO DATA AVAILABLE
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
ACETONE 76.00, NO DATA AVAILABLE NO DATA AVAILABLE
RAT - CATEGORY: NA
PROPANE 658.00, NO DATA AVAILABLE NO DATA AVAILABLE
RAT - CATEGORY: NA
SOLVENT NAPHTHA NO DATA AVAILABLE NO DATA AVAILABLE NO DATA AVAILABLE
(PETROLEUM),
LIGHT ALIPHATIC
BUTANE 658.00, NO DATA AVAILABLE NO DATA AVAILABLE
RAT - CATEGORY: NA
TOLUENE NO DATA AVAILABLE NO DATA AVAILABLE NO DATA AVAILABLE
PROPANE, 658.00, NO DATA AVAILABLE NO DATA AVAILABLE
2-METHYL- RAT - CATEGORY: NA
STODDARD SOLVENT NO DATA AVAILABLE NO DATA AVAILABLE NO DATA AVAILABLE
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 ACETONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000074-98-6 PROPANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO;
0000075- 28-5 PROPANE, 2-METHYL- OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000106-97-8 BUTANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000108-88-3 TOLUENE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: YES
GROUP 4: NO
0008052-41-3 STODDARD SOLVENT OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0064742-89-8 SOLVENT NAPHTHA OSHA SELECT CARCINOGEN: NO
(PETROLEUM),
LIGHT ALIPHATIC NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) 5 MAY BE HARMFUL IF SWALLOWED.
(NOT ADOPTED BY US OSHA)
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION 3 CAUSES MILD SKIN IRRITATION.
(NOT ADOPTED BY US OSHA)
SERIOUS EYE DAMAGE/ 2 CAUSES SERIOUS EYE
IRRITATION IRRITATION.
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY 2 SUSPECTED OF DAMAGING THE
UNBORN CHILD.
STOT-SINGLE EXPOSURE 3 MAY CAUSE DROWSINESS OR
DIZZINESS.
STOT-REPEATED EXPOSURE 2 MAY CAUSE DAMAGE TO ORGANS
THROUGH PROLONGED OR REPEATED
EXPOSURE.
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 FISH, 48 HR EC50 CRUSTACEA, ERC50 ALGAE,
MG/L MG/L MG/L
ACETONE - (67-64-1) 100.00, 10.00, 20.565
PIMEPHALES DAPHNIA MAGNA (72 HR),
PROMELAS ULVA PERTUSA
PROPANE - (74-98-6) NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
SOLVENT NAPHTHA NOT AVAILABLE NOT AVAILABLE 4,700.00
(PETROLEUM), (72 HR),
LIGHT ALIPHATIC - SELENASTRUM
(64742-89-8) CAPRICORNUTUM
BUTANE - (106-97-8) 6.00, FISH NOT AVAILABLE NOT AVAILABLE
(PISCIS)
TOLUENE - 5.80, 19.60, NOT AVAILABLE
(108-88-3) ONCORHYNCHUS DAPHNIA MAGNA
MYKISS
PROPANE, 2-METHYL- NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
- (75-28-5)
STODDARD SOLVENT - NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
(8052-41 -3)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.
USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.
| 14. TRANSPORT INFORMATION | |
DOT IMO / IMDG ICAO/IATA
(DOMESTIC SURFACE (OCEAN
TRANSPORTATION) TRANSPORTATION)
14.1.UN NUMBER UN1950 UN1950 UN1950
14.2. UN PROPER AEROSOLS, AEROSOLS, AEROSOLS,
SHIPPING NAME FLAMMABLE FLAMMABLE FLAMMABLE
LIMITED LIMITED LIMITED
QUANTITY QUANTITY QUANTITY
14.3. TRANSPORT 2.1 2.1 2.1
HAZARD CLASS(ES)
14.4. PACKING GROUP NOT NOT NOT
APPLICABLE APPLICABLE APPLICABLE
14.5. ENVIRONMENTAL
HAZARDS
IMDG:
MARINE POLLUTANT: NO
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE, ONLY
SELECTED REGULATIONS ARE REPRESENTED.
TOXIC SUBSTANCE CONTROL ACT (TSCA):
ALL COMPONENTS OF THIS MATERIAL ARE EITHER LISTED OR EXEMPT FROM LISTING ON
THE TSCA INVENTORY.
WHMIS CLASSIFICATION: A B1 D2A
US EPA TIER II HAZARDS:
FIRE: YES
SUDDEN RELEASE OF PRESSURE: YES
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): YES
EPCRA 311/312 CHEMICALS AND RQS (LBS):
ACETONE: (5,000.00)
TOLUENE: (1,000.00)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS: TOLUENE
PROPOSITION 65 - CARCINOGENS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%): TOLUENE
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
ACETONE
BUTANE
PROPANE
PROPANE, 2-METHYL-
STODDARD SOLVENT
TOLUENE
PENN RTK SUBSTANCES (>1%):
ACETONE
BUTANE
PROPANE
PROPANE, 2-METHYL-
STODDARD SOLVENT
TOLUENE
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH AND
SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H220: EXTREMELY FLAMMABLE GAS.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
IMPORTANT NOTE:
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED,
AS TO ACCURACY OR COMPLETENESS. THE INFORMATION IS OBTAINED FROM VARIOUS
SOURCES INCLUDING THE MANUFACTURER AND OTHER THIRD PARTY SOURCES.
THE INFORMATION MAY NOT BE VALID UNDER ALL CONDITIONS NOR IF THIS MATERIAL
IS USED IN COMBINATION WITH OTHER MATERIALS OR ANY PROCESS. FINAL
DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF
THE USER.